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MSDS Material Safety Data Sheet
CAS

25068-38-6 7727-43-7 471-34-1 1309-38-2 112945-52-5 101359-87-9 1327-36-2 111-40-0 13474-96-9 13463-67-7

File Name: 25068-38-6_7727-43-7_471-34-1_1309-38-2_112945-52-5_101359-87-9.asp

LOCTITE CORPORATION                                                            09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 01 of 05

Loctite(R) Cold Weld Bonding Compound
14600

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Loctite(R) Cold Weld Bonding Compound
Item No.: 14600
Part No.: 14600
Product Type: Epoxy adhesive/sealant

2. COMPOSITION, INFORMATION ON INGREDIENTS


Ingredients CAS No. %

RESIN
Epoxy resin 25068-38-6 40-45
Barium sulfate 7727-43-7 20-25
Calcium carbonate 471-34-1 20-25
Iron oxide 1309-38-2 15-20
SILICA, AMORPHOUS TREATED 112945-52-5 1-3

HARDENER
Calcium carbonate 471-34-1 35-40
Polymercaptan 101359-87-9 25-30
Barium sulfate 7727-43-7 10-15
Aluminum silicate 1327-36-2 5-10
DIETHYLENETRIAMINE 111-40-0 5-10
Heptakis(dipropyleneglycol)-
triphosphate 13474-96-9 1-3
TITANIUM DIOXIDE 13463-67-7 1-3
SILICA, AMORPHOUS TREATED 112945-52-5 0.1-1


Ingredients which have exposure limits

Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)

RESIN
Barium sulfate 10 mg/m3 dust 10 mg/m3 dust None
5 mg/m3 respir.
Calcium carbonate 10 mg/m3 dust 15 mg/m3 dust None
5 mg/m3 respir.
Iron oxide 5 mg/M3 (Fe) 10 mg/M3 (Fe) None
particulate
SILICA, AMORPHOUS TREATED 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust

HARDENER
Calcium carbonate 10 mg/m3 dust 15 mg/m3 dust None
5 mg/m3 respir.
Barium sulfate 10 mg/m3 dust 10 mg/m3 dust None
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 02 of 05

Product Name: Loctite(R) Cold Weld Bonding Compound
Item No.: 14600

2. COMPOSITION, INFORMATION ON INGREDIENTS (continued)

5 mg/m3 respir.
DIETHYLENETRIAMINE 1 ppm skin 1 ppm TWA None
4.2mg/m3 skin 4mg/m3
TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None
5 mg/m3 resp
SILICA, AMORPHOUS TREATED 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust

Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)

RESIN

HARDENER

3. HAZARDS IDENTIFICATION

Toxicity: Skin and eye irritant. Skin sensitizer.
Moderately toxic by ingestion.
Primary Routes of Entry: Skin, ingestion, inhalation.
Signs and symptoms
of Exposure: May cause eye irritation and other allergic
responses such as skin sensitization or dermatitis
Existing Conditions
Aggravated by Exposure: None known

Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA

RESIN
Epoxy resin ALG IRR NO NO NO
Barium sulfate LUN NO NO NO
Calcium carbonate NUI NO NO NO
Iron oxide No Data NO NO NO
SILICA, AMORPHOUS TREATED NUI NO N/A NO

HARDENER
Calcium carbonate NUI NO NO NO
Polymercaptan No Data NO NO NO
Barium sulfate LUN NO NO NO
Aluminum silicate No Data NO NO NO
DIETHYLENETRIAMINE ALG IRR NO NO NO
Heptakis(dipropyleneglycol)-
triphosphate No Data NO NO NO
TITANIUM DIOXIDE IRR NUI NO NO NO
SILICA, AMORPHOUS TREATED NUI NO N/A NO
-------------------------------------------------------------------------------
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 03 of 05

Product Name: Loctite(R) Cold Weld Bonding Compound
Item No.: 14600

3. HAZARDS IDENTIFICATION (continued)

Abbreviations

N/A Not Applicable ALG Allergen
IRR Irritant LUN Lung
NUI Nuisance dust


4. FIRST AID MEASURES

Ingestion: Do not inuce vomiting. Keep individual
calm. Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist,
obtain medical attention.
Skin Contact: Wash thoroughly with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.

5. FIRE FIGHTING MEASURES

Flash Point: More than 400癋 Method: Open cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None

Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken in case
of spill or leak: Scrape up as much as possible. Store in closed
containers until disposal. Do not store scrap
resin with scrap hardener.

7. HANDLING AND STORAGE

Safe Storage: Store in a cool, dry area.
DO NOT STORE SCRAP RESIN WITH SCRAP HARDENER
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid skin contact. Keep away from eyes.
Avoid prolonged breathing of vapors.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 04 of 05

Product Name: Loctite(R) Cold Weld Bonding Compound
Item No.: 14600

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration
below TLV.

See Section 2 for Exposure Limits.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Resin: Black paste
Hardener: Beige paste
Odor: Resin: Mild
Hardener: Sulfur
Boiling Point: More than 300癋
pH: Does not apply
Solubility in Water: Insoluble
Specific Gravity Resin: 1.82
Hardener: 1.75
Volatile Organic Compound
(EPA Method 24) Not available
Vapor Pressure: Not available
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available

10. STABILITY AND REACTIVITY

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Oxidizing agents.
Hazardous Decomposition
Products (non-thermal): None

11. TOXICOLOGICAL INFORMATION

See Section 3.

12. ECOLOGICAL INFORMATION

No data available

13. DISPOSAL CONSIDERATIONS

Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number D005 - May be a TCLP waste per 40CFR 261.24/Barium
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 05 of 05

Product Name: Loctite(R) Cold Weld Bonding Compound
Item No.: 14600

14. TRANSPORT INFORMATION

DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None

15. REGULATORY INFORMATION

CA Proposition 65: No Prop65 chemicals are known to be present.

16. OTHER INFORMATION

Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 1
Reactivity Hazard: 0
Specific Hazard: Does not apply

Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 1
Reactivity Hazards: 0
Personal Protection: See Section 8.

NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.

Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0015

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