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25068-38-6 471-34-1 7727-43-7 1317-61-9 28906-96-9 1332-58-7 14808-60-7 1675-54-3

File Name: 25068-38-6_471-34-1_7727-43-7_1317-61-9_28906-96-9_1332-58.asp

                                                                                               Material Safety Data Sheet




Revision Date: 06/12/2006 Issue date: 06/12/2006

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product name: Cold Weld Bonding Compound Item No. : 14600_RESIN
Product type: Epoxy Resin Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com


2. COMPOSITION/INFORMATION ON INGREDIENTS


Hazardous components % ACGIH TLV OSHA PEL OTHER
Epichlorohydrin-4,4'-isopropylidene 30-60 None None None
diphenol resin
25068-38-6

Calcium carbonate 10-30 10 mg/m?TWA 15 mg/m?TWA (total dust) None
471-34-1 (particulate matter 5 mg/m?TWA (respirable
containing no asbestos fraction)
and <1% crystalline silica)
Barium sulfate 10-30 0.5 mg/m?TWA as Ba 0.5 mg/m?TWA None
7727-43-7 0.5 mg/m?TWA 0.5 mg/m?TWA as Ba
10 mg/m?TWA 15 mg/m?TWA total dust
5 mg/m?TWA respirable
fraction
Iron oxide 10-30 1 mg/m?TWA as Fe None None
1317-61-9

Bisphenol A, formaldehyde, 1-5 None None None
epichlorohydrin polymer
28906-96-9

Clay 1-5 2 mg/m?TWA respirable 15 mg/m?TWA total dust None
1332-58-7 fraction, particulate matter 5 mg/m?TWA respirable
containing no asbestos fraction
and < 1% crystalline silica
Silica, quartz 0.1-1 0.05 mg/m?TWA 0.1mg/m?TWA None
14808-60-7 respirable fraction (respirable)



3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
HMIS:
Physical state: Paste HEALTH: 2*
Color: Black FLAMMABILITY: 1
Odor: Mild PHYSICAL HAZARD: 0
Personal Protection: See Section 8

WARNING: MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE EYE AND SKIN IRRITATION.
MAY BE HARMFUL IF SWALLOWED.

Relevant routes of exposure: Eye contact, Ingestion, Inhalation, Skin contact

Potential Health Effects
Item No. : 14600_RESIN Product name: Cold Weld Bonding Compound
1 of 5
Inhalation: Mild respiratory tract irritation.
Skin contact: Allergic skin reaction. Moderate skin irritation. Itching. Redness.
Eye contact: Moderate eye irritation. Redness.
Ingestion: May be harmful if swallowed.

Existing conditions aggravated by Skin disorders. Skin allergies. Eye disorders.
exposure:

See Section 11 for additional toxicological information.

4. FIRST AID MEASURES


Inhalation: Remove to fresh air. If symptoms develop and persist, get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Get medical attention if symptoms occur.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Get
medical attention if symptoms develop and persist.

Notes to physician: None.

5. FIRE-FIGHTING MEASURES

Flash point: Greater than 204篊 (400篎) Open cup

Autoignition temperature: Not available

Flammable/Explosive limits-lower %: Not available

Flammable/Explosive limits-upper %: Not available

Extinguishing media: Foam, dry chemical or carbon dioxide.

Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Unusual fire or explosion hazards: In the event of fire, cool tanks with water spray. Closed containers may rupture (due to build up of
pressure) when exposed to extreme heat.

Hazardous combustion products: Oxides of carbon. Irritating organic fragments.

6. ACCIDENTAL RELEASE MEASURES

Environmental precautions: Prevent product from entering drains or open waters.

Clean-up methods: Remove all ignition sources. Immediately contact emergency personnel. Scrape up as much material
as possible. Clean residue with soap and water. Store in a closed container until ready for disposal.




Item No. : 14600_RESIN Product name: Cold Weld Bonding Compound
2 of 5
7. HANDLING AND STORAGE

Handling: Keep away from heat, spark and flame. Do not breathe mist or vapors. Keep container closed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.

Storage: Store in original container until ready to use. Keep in a cool, well ventilated area away from heat,
sparks and open flame. Keep container tightly closed until ready for use.

Incompatible products: Refer to Section 10.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits.

Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits
exists.

Skin protection: Chemical resistant, impermeable gloves.

Eye/face protection: Chemical splash goggles or safety glasses with side shields.

See Section 2 for exposure limits.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Paste
Color: Black
Odor: Mild
Vapor pressure: Not available
pH: Not applicable
Boiling point/range: Greater than 149癈 (300癋)
Melting point/range: Not available
Specific gravity: 1.82
Vapor density: Not available
Evaporation rate: Not available
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not available
VOC content: 0% (value for resin and hardener together)

10. STABILITY AND REACTIVITY

Stability: Stable

Hazardous polymerization: Will not occur.

Hazardous decomposition products: None

Incompatability: Strong acids. Strong bases. Strong oxidizers.

Conditions to avoid: Excessive heat. Storage with incompatible materials.

11. TOXICOLOGICAL INFORMATION


Carcinogen Status




Item No. : 14600_RESIN Product name: Cold Weld Bonding Compound
3 of 5
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Epichlorohydrin-4,4'-isopropylidene No No No
diphenol resin
25068-38-6
Calcium carbonate No No No
471-34-1
Barium sulfate No No No
7727-43-7
Iron oxide No No No
1317-61-9
Bisphenol A, formaldehyde, No No No
epichlorohydrin polymer
28906-96-9
Clay No No No
1332-58-7
Silica, quartz Known Carcinogen Group 1 Yes
14808-60-7



Literature Referenced Target Organ & Other Health Effects

Hazardous components Health Effects/Target Organs
Epichlorohydrin-4,4'-isopropylidene Allergen, Irritant
diphenol resin
25068-38-6
Calcium carbonate Nuisance dust
471-34-1
Barium sulfate Lung
7727-43-7
Iron oxide Cardiac, Central nervous system, Irritant, Kidney, Liver, Lung
1317-61-9
Bisphenol A, formaldehyde, Allergen, Irritant
epichlorohydrin polymer
28906-96-9
Clay Nuisance dust
1332-58-7
Silica, quartz Some evidence of carcinogenicity, Lung, Immune system
14808-60-7

12. ECOLOGICAL INFORMATION

Ecological information: Not available

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Dispose according to EPA and local governmental regulations.

EPA hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be
different for bulk packaging.

U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

WaterTransportation (IMO/IMDG):
Item No. : 14600_RESIN Product name: Cold Weld Bonding Compound
4 of 5
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
Marine pollutant: None known

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: Bisphenol A diglycidyl ether (CAS# 1675-54-3).

CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 311/312: Immediate Health Hazard
CERCLA/SARA 313: None above reporting de minimus.

California Proposition 65: This product contains a chemical known to the State of California to cause cancer.



Canada Regulatory Information


CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: D.2.B

16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: Corrected information in Section(s) 2.

Prepared by: Gary Pierson, Sr. Product Safety and Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.




Item No. : 14600_RESIN Product name: Cold Weld Bonding Compound
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