MATERIAL
SPRAY-CURE SAFETY
DATA SHEET
Date Prepared: 6/1/98
Supersedes: All Previous
Product Name: Duraflow 250 (Part B-Hardener)
1. Chemical Product and Company Information
Product Name: Duraflow 250 (Part B-Hardener)
ChemMasters In Case of Emergency Contact:
300 Edwards Street CHEMTREC 800/424-9300
Madison, Ohio 44057
440-428-2105
2. Composition / Information on Ingredients
Hazardous Components CAS # Exposure Limits % by Wt
OSHA (PEL/TWA) ACGIH (TLV/TWA) OTHER
0.1 mg/m3 (ceiling)* 0.1 mg/m3 (ceiling)*
m-xylene diamine 84852-15-3 -- --
Triethylenepentamine* 112-57-2 -- 1.0 ppm -- <5%
* Tetraethylenepentamine (TEPA) as reported here is a complex mixture of TEPA and other ethyleneamines.
Some of these amines include Triethylenetetramine (112-24-3) and Diethylenetriamine (111-40-0). The ACGIH
has established a TLV of 1 ppm for airborne concentrations of Diethylenetriamine with a skin hazard notation.
3. Hazards Identification
WARNING
CORROSIVE LIQUID
Causes eye burns
Causes skin burns and/or allergic skin reaction
May cause allergic respiratory reaction
Potential Health Hazards - Acute
Eye: May cause chemical burn -- damage irreversible.
Skin: Sensitizer -- may cause allergic reaction which can be severe in certain individuals. Moderately toxic, may
cause chemical burns.
Inhalation: May cause headaches, nausea, dizziness and respiratory irritation. Sensitizer -- may cause allergic
respiratory reaction.
Ingestion: No specific information available. Moderately toxic. May cause gastrointestinal irritation, ulceration and/
or burns of mouth and throat.
Potential Health Effects - Chronic
Overexposure may cause CNS depression and/or lung damage.
Carcinogenicity: NTP IARC Monographs OSHA Regulated
NO NO NO
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Date Prepared: 6/1/98
Supersedes: All Previous
Product Name: Duraflow 250 (Part B-Hardener)
4.First Aid Measures
Eye: Immediately flush with plenty of water for at least 15 minutes. Get medical attention.
Skin: Flush immediately with plenty of water for at least 15 minutes while removing contaminated clothing.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
Ingestion: Do NOT induce vomiting. Give victim a glass of water. Call a physician immediately. Never give anything
by mouth to an unconscious person.
SEEK MEDICAL ATTENTION IF SYMPTOMS PERSIST
5. Fire Fighting Measures
Flash Point (method used): >200oF (TCC)
Flammable Limits (% volume in air): Lower = Not applicable Upper = Not applicable
Auto Ignition Temperature: Not applicable
Extinguishing Media: Dry chemicals, CO2, Halon, water spray or foam.
Hazard Combustion Products: Carbon dioxide, carbon monoxide and/or oxides of nitrogen.
Fire Fighting Instructions: Remove all ignition sources. Wear self contained breathing apparatus and complete
personal protective equipment when entering confined areas where potential exposure to vapors or products of
combustion exists.
6. Accidental Release Measures
Spill: Absorb with inert material, then place in chemical waste container for later disposal.
7. Handling and Storage
Handling: Use with adequate ventilation. Avoid contact with skin and eyes. Always use good industrial hygiene
practices and safety guidelines when dealing with this potentially hazardous product.
Storage: Keep containers closed and store in a dry, well ventilated area.
8. Exposure Controls / Personal Protection
Exposure Controls: Mechanical exhaust should be used. A source of clean water should be available for flushing
eyes and skin.
Personal Protection: Protective clothing, chemical splash goggles, rubber gloves and a vapor respirator.
9. Physical and Chemical Properties
Appearance: Amber gel or liquid
Odor: Ammoniacal odor
Boiling Point: >477oF
Melting Point: Not applicable
Vapor Pressure (mm/Hg): No data available
Vapor Density (Air = 1): >1
Solubility in Water: Partially
Specific Gravity (H2O = 1): 0.99
Evaporation Rate (n-Butyl Acetate = 1): Not applicable
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Date Prepared: 6/1/98
Supersedes: All Previous
Product Name: Duraflow 250 (Part B-Hardener)
10. Stability and Reactivity
Chemical Stability: Stable
Conditions to Avoid: Excessive heat
Incompatibility (materials to avoid): Contamination with strong acids, bases, epoxy resins or isocyanates can cause
polymerization.
Hazardous Decomposition or By-products: Thermal decomposition may include carbon monoxide, carbon
dioxide and/or oxides of nitrogen.
Hazardous Polymerization: Will not occur
11. Toxicological Information
Components Oral LD50 Dermal LD50 Inhalation LC50
(rat) (rabbit) (rat)
Triethylenepentamine >500 mg/kg >2000 mg/kg --
12. Ecological Information
No data available
13. Disposal Considerations
Dispose of in accordance with all federal, state and local regulations. If uncertain of local regulations in your
area, contact the proper environmental authorities for disposal.
Under RCRA 40 CFR 261 this material is hazardous waste number D002.
14. Transportation Information
For U S National Shipments
Shipping Description: Corrosive Liquid N.O.S. (Modified Polyamidoamine), 8, UN1760, III
Emergency Response Guide Number: 60
Hazard Class: Corrosive
15. Regulatory Information
OSHA: This material is hazardous by definition of Hazardous Communications Standard (29 CFR 1910.1200)
CERCLA Reportable Quantity: Not applicable
SARA Title III:
Section 311/312 hazard categories: acute health, delayed health
Section 313 reportable ingredients:
Components CAS # Maximum %
Not applicable -- --
16. Other Information
MSDS Status: New
Industrial Abbreviation Legend on page 4 of this MSDS.
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Date Prepared: 6/1/98
Supersedes: All Previous
Product Name: Duraflow 250 (Part B-Hardener)
Industrial Abbreviation Legend
mg/m 3
ACGIH American Conference of Governmental Industrial milligrams per cubic meter
NIOSH National Institute for Occupational Safety and Health
Hygienists
NTP National Toxicology Program
CAA Clean Air Act (EPA)
CERCLA Comprehensive Environmental Response, OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
Compensation & Liability Act of 1980 (Superfund) (EPA)
ppm parts per million
CNS Central Nervous System
CWA Clean Water Act (EPA) RCRA Resource Conservation and Recovery Act (EPA)
SARA EPA's Superfund Amendment and Reauthorization
DOT Department of Transportation
Act (EPA)
EPA Environmental Protection Agency
g/kg grams per kilogram STEL Short-Term Exposure Limit, ACGIH terminology
TLV Threshold Limit Value
IARC Internal Agency for Research on Cancer
TWA Time-Weighted Average
LC50 Lethal Concentration in which 50% of the test animals are
expected to die
LD50 Lethal Dose in which 50% of the test animals are
expected to die
THIS PRODUCT IS FORMULATED AND LABELED FOR
INDUSTRIAL AND COMMERCIAL APPLICATION ONLY
The information contained herein is given in good faith and based on data considered accurate. However, no warranty is
expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. ChemMasters
assumes no responsibility for personal injury or property damage to vendees, users or third parties caused by the material.
Such vendees or users assume all risks associated with the use of the material.
This is the last page of this MSDS.
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