Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoxiCure Hardener
Article number: 20-8132-xxx
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 1 / 5
1 Identification of the substance / preparation and of the company
Product: Buehler EpoxiCure Hardener
Article number: 20-8132-xxx
Registration number: not applicable
Use: Epoxy activator
Identified use: none
Method of operation: See product information.
Company: Buehler GmbH
In der Steele 2
D-40599 D黶seldorf (Germany/Allemagne)
Phone: 0800 707 6273
Fax: 0800 707 6274
Homepage: www.buehler-met.de/en/
E-mail: sales@buehler.co.uk
Emergency phone: 0800 707 6273 (Only valid if dialled within the UK)
Responsible: Simonavicius@chemiebuero.de
2 Hazards identification
Physico-chemical hazards: See chapter 10.
Human health dangers: See R-phrases.
Environmental hazards: See R-phrases.
Other hazards: none
Hazard symbols:
Corrosive Dangerous for the
environment
R-phrases: R 40: Limited evidence of a carcinogenic effect.
R 68: Possible risk of irreversible effects.
R 34: Causes burns.
R 43: May cause sensitisation by skin contact.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
3 Composition / Information on ingredients
2,2?Iminodiethylamine 10 - < 25%
C, R21/22-34-43 CAS: 111-40-0, EINECS/ELINCS: 203-865-4, EU-INDEX: 612-058-00-x, ECBnr:
Triethylenetetramine 20 - 40%
C, R21-34-43-52/53 CAS: 112-24-3, EINECS/ELINCS: 203-950-6, EU-INDEX: 612-059-00-5, ECBnr:
Reaction product: bisphenol-A-(epichlorhydrin) Epoxy resin (number average molecular weight 80 - < 100%
Xi-N, R36/38-43-51/53 CAS: 25068-38-6, EINECS/ELINCS: 500-033-5, EU-INDEX: 603-074-00-8, ECBnr:
Propylidynetrimethanol, propoxylated, reaction products with ammonia 25 - < 50%
C, R21/22-34 CAS: 39423-51-3, EINECS/ELINCS: 500-105-6, EU-INDEX: , ECBnr:
Butyl 2,3-epoxypropyl ether 10 - < 20%
Xn, R10-20/22-37-40-43-52/53-68 CAS: 2426-08-6, EINECS/ELINCS: 219-376-4, EU-INDEX: 603-039-00-7, ECBnr:
For the wording of the listed risk phrases refer to section 16.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00010 GB
Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoxiCure Hardener
Article number: 20-8132-xxx
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 2 / 5
4 First aid measures
General information: Remove contaminated soaked clothing immediately and dispose of safely.
Inhalation: Ensure supply of fresh air.
In the event of symptoms seek for medical treatment.
Skin contact: In case of contact with skin wash off immediately with soap and water.
Consult a doctor if skin irritation persists.
Eye contact: In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
Ingestion: Consult a doctor immediately.
Do not induce vomiting.
Rinse out mouth and give plenty of water to drink.
Advice to doctor: Treat symptomatically.
5 Fire-fighting measures
Suitable extinguishing media: Carbon dioxide.
Foam.
Water spray jet.
Dry powder.
Extinguishing media that must not Full water jet.
be used:
Special exposure hazards arising Unknown risk of formation of toxic pyrolysis products.
from the substance or preparation
itself or combustion products:
Special protective equipment for Use self-contained breathing apparatus.
firefighters:
Wear full protective suit.
Additional information: Fire residues and contaminated firefighting water must be disposed of in accordance within the local
regulations.
6 Accidental release measures
Personal precautions: Ensure adequate ventillation.
High risk of slipping due to leakage/spillage of product.
Environmental precautions: Prevent spread over a wide area (e.g. by containment or oil barriers).
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up: Pick up with absorbent material (e.g. sand, sawdust, universal absorbent, diatomaceous earth).
Dispose of absorbed material in accordance within the regulations.
7 Handling and storage
Advice on safe handling: Use only in well-ventilated areas.
No special measures necessary if used correctly.
Advice on protection against fire No special measures necessary.
and explosion:
Requirements for storage rooms Keep only in original container.
and vessels:
Advice on storage compatibility: Do not store together with oxidizing agents.
Further information on storage Keep container tightly closed.
conditions:
Keep container in a well-ventilated place.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00010 GB
Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoxiCure Hardener
Article number: 20-8132-xxx
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 3 / 5
8 Exposure controls / personal protection
Additional advice on system Ensure adequate ventilation on workstation.
design:
Ingredients with occupational exposure limits to be monitored: (GB)
2,2?Iminodiethylamine 10 - < 25%
1ppm*, 4,3mg/m?, General remarks: Sk
* LTEL: Long-term exposure limit
Respiratory protection: not applicable
Hand protection: Nitrile, >480 min (EN 374).
Eye protection: Safety glasses.
Skin protection: Light protective clothing of plastic material.
General protective measures: It is essential for pregnant women to avoid inhaling the product and not to let it come in contact with
the skin.
Avoid contact with eyes and skin.
Do not inhale vapours.
Hygiene measures: Do not eat, drink, smoke or take drugs at work.
Remove soiled or soaked clothing immediately.
Use barrier skin cream.
After worktime and before work breaks the affected skin areas must be thoroughly cleaned.
Delimitation and monitoring of the not determinated
environmental exposition:
9 Physical and chemical properties
Form: liquid
Color: yellow
Odor: ammoniac-like
pH-value: alkaline
pH-value [1%]: not determinated
Boiling point [癈]: 83-207
Flash point [癈]: 118
Flammability [癈]: not determinated
Lower explosion limit: not applicable
Upper explosion limit: not applicable
Oxidizing properties: no
Vapour pressure [kPa]: not determinated
Density [g/ml]: 1,0363
Density at [癈]: 20癈
Bulk density [kg/m砞: not applicable
Solubility in water: partially miscible
Partition coefficient [n- not determinated
octanol/water]:
Viscosity: not applicable
Relative vapour density not determinated
determined in air:
Evaporation speed: not determinated
Melting point [癈]: not determinated
Autoignition temperature [癈]: not applicable
Decomposition temperature [癈]: not determinated
10 Stability and reactivity
Hazardous reactions: Reactions with acids and strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products known.
products:
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00010 GB
Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoxiCure Hardener
Article number: 20-8132-xxx
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 4 / 5
11 Toxicological information
Acute oral toxicity: not determinated
Acute dermal toxicity: not determinated
Acute inhalational toxicity: not determinated
Irritant effect on eye: not determinated
Irritant effect on skin: not determinated
Sensitization: not determinated
Subacute toxicity: not determinated
Chronic toxicity: not determinated
Mutagenicity: not determinated
Reproduction toxicity: not determinated
Carcinogenicity: not determinated
Experiences made in practice: none
General remarks: Toxicological data are not available.
The product was classified on the basis of the calculation procedure of the preparation directive.
12 Ecological information
Fish toxicity: not determinated
Daphnia toxicity: not determinated
Behaviour in environment not determinated
compartments:
Behaviour in sewage plant: not determinated
Bacteria toxicity: not determinated
Biological degradability: not determinated
COD: not determinated
BOD 5: not determinated
AOX-advice: The product contains organically bound halogen in accordance with the formulation.
2006/11/EC: yes
General information: The product was classified on the basis of the calculation procedure of the preparation directive.
13 Disposal considerations
Disposal / Product: Disposal in an incineration plant in accordance with the regulations of the local authorities.
Dispose of as hazardous waste.
Disposal / Contaminated Packaging that cannot be cleaned should be disposed of as for product.
packaging:
Uncontaminated packaging may be taken for recycling.
Waste no. (recommended): 080409*
14 Transport information
Classification according to ADR: UN 2735 Amines, liquid, corrosive, n.o.s. (Triethylenetetramine, 3-Azapentan-1,5-diamine) 8, III
- Classification Code: C7
- ADR Limited Quantities: LQ7: 5l
- Label:
Classification according to IMDG: UN 2735 Amines, liquid, corrosive, n.o.s. (Triethylenetetramine, 3-Azapentan-1,5-diamine- mixture)
8 III
- IMDG Limited Quantities: LQ: 5 l
- EMS: F-A, S-B
- Label:
Classification according to IATA: UN 2735 Amines, liquid, corrosive, n.o.s. (Triethylenetetramine, 3-Azapentan-1,5-diamine- mixture)
8 III
- Label:
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00010 GB
Safety Data Sheet 1907/2006/EC (GB)
Buehler EpoxiCure Hardener
Article number: 20-8132-xxx
Buehler GmbH
Date printed: 22.04.2008, Revision: 22.04.2008 Page 5 / 5
15 Regulatory information
Exposure scenario: not applicable
Chemical safety report: not applicable
Labelling: The product is classified and labelled in accordance within EC-directives.
Hazard symbols:
Corrosive Dangerous for the
environment
Contains: - Propylidynetrimethanol, propoxylated, reaction products with ammonia
- Triethylenetetramine
- Butyl 2,3-epoxypropyl ether
- 2,2?Iminodiethylamine
- Reaction product: bisphenol-A-(epichlorhydrin) Epoxy resin (number average molecular weight
700
R-phrases: R 40: Limited evidence of a carcinogenic effect.
R 68: Possible risk of irreversible effects.
R 34: Causes burns.
R 43: May cause sensitisation by skin contact.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S-phrases: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
S 61: Avoid release to the environment. Refer to special instructions, safety data sheets.
Special labelling: Contains epoxy-containing compounds. Observe manufacturer's instructions.
Authorisation, TITEL VII: not applicable
Restrictions, TITEL VIII: not applicable
EEC-REGULATIONS: 1967/548 (2004/73, 29. ATP); 1991/689 (2001/118); 1999/13; 2004/42; 648/2004; 1907/2006.
TRANSPORT-REGULATIONS: ADR (2007); IMDG-Code (33. Amdt.); IATA-DGR (2008).
NATIONAL REGULATIONS (GB) EH40/2005 Workplace exposure limits with amendments October 2007.
16 Other informations
R-phrases (Chapter 03): R 40: Limited evidence of a carcinogenic effect.
R 68: Possible risk of irreversible effects.
R 52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R 10: Flammable.
R 43: May cause sensitisation by skin contact.
R 36/38: Irritating to eyes and skin.
R 20/22: Harmful by inhalation and if swallowed.
R 21/22: Harmful in contact with skin and if swallowed.
R 21: Harmful in contact with skin.
R 34: Causes burns.
R 37: Irritating to respiratory system.
Modified position: Minus: Chapter: 15 R-phrases:
Observe employment restrictions yes
for people:
VOC (1999/13/CE): not determinated
Customs Tariff: not determinated
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall
not establish a legally valid contractual relationship.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00010 GB
|