PLASTIC STEEL PUTTY (A) HARDENER MSDS
ISSUE DATE: 20 September, 2007
MATERIAL SAFETY DATA SHEET
PLASTIC STEEL PUTTY (A) HARDENER
1 IDENTIFICATION OF MATERIAL AND SUPPLIER
PRODUCT NAME: DEVCON PLASTIC STEEL PUTTY (A) HARDENER
PRODUCT NO. D10110, D10120 (Hardener component of a two part epoxy system)
SUPPLIER ITW POLYMERS & FLUIDS ITW POLYMERS & FLUIDS (NZ)
100 HASSALL ST UNIT 2 / 38 TRUEGOOD DRIVE
WETHERILL PARK EAST TAMAKI, 2013
NEW SOUTH WALES AUCKLAND
AUSTRALIA NEW ZELAND
T: 02 9757 8800 T: 09 272 1945
F: 02 9757 3855 F: 09 273 6489
EMERGENCY PHONE: T: 02 9757 8800 T: 09 272 1945
2 HAZARDS IDENTIFICATION
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS
(According to the criteria of the NOHSC and the ADG-6 code)
SIGNAL WORD(S)
Xn; Harmful. C; Corrosive.
RISK PHRASES
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitization by skin contact.
SAFETY PHRASES
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label
where possible)
3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS-No. Content Classification
2-PIPERAZIN-1-YLETHYLAMINE 140-31-8 0 - < 10 % C; R34. Xn; R21/22 R43
NONYL PHENOL 25154-52-3 0 - < 10 % Xn; R20/22. C; R34. R43
TRIETHYLENETETRAMINE 112-24-3 30 - < 60 % C; R34. Xn R21 R43
4 FIRST AID MEASURES
GENERAL INFORMATION
Avoid contact with skin and eyes. Do not breathe vapour. In case of accident or if you feel unwell, seek medical advice immediately
Show label or this safety data sheet to doctor in attendance if possible.
INHALATION
Move the exposed person to fresh air at once. Contact physician if discomfort continues.
INGESTION
Do not induce vomiting. Rinse mouth with water. Drink plenty of water. Get medical attention immediately!
SKIN CONTACT
Remove affected person from source of contamination. Wash skin thoroughly with soap and warm water for several minutes. Contact
physician if irritation persists.
DEVCON PLASTIC STEEL PUTTY (A) HARDENER MSDS Page 1 of 4
PLASTIC STEEL PUTTY (A) HARDENER MSDS
EYE CONTACT
Promptly wash eyes with plenty of clean water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical
attention. Contact physician if irritation persists.
5 FIRE FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
Fire can be extinguished using: Water, Foam. Carbon Dioxide (CO2). Dry Chemicals.
SPECIFIC HAZARDS
Avoid breathing fire vapours.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SPECIAL FIRE FIGHTING PROCEDURES
Keep upwind to avoid fumes. Keep run-off water out of sewers and watercourses. Dike for water control.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY
alerted to the Environmental Agency or other appropriate regulatory body.
SPILL CLEAN UP METHODS
Absorb with sand or other inert absorbent. Transfer to a container for disposal. Containers with collected spillage must be properly
labeled with correct contents and hazard symbol.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded. Do not eat, drink or smoke when using the product. Observe good industrial hygiene practices.
STORAGE PRECAUTIONS
Store in tightly closed original container in a cool, dry well-ventilated place. Keep away from heat, sparks and open flame.
8 EXPOSURE CONTROL / PERSONAL PROTECTION
No exposure data available for product or ingredients.
PROTECTIVE EQUIPMENT
PROCESS CONDITIONS
Provide eyewash, quick drench.
ENGINEERING MEASURES
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded.
RESPIRATORY EQUIPMENT
Not usually required in well ventilated areas.
Select and use respirators in accordance with AS/NZS 1715/1716.
In poorly ventilated areas use Type A organic vapour/gas filter with half face piece.
When sanding/grinding cured product the use of a P1 dust mask (disposable) or with replaceable filters is recommended.
Filter capacity and respirator type depends on exposure levels and type of contaminant. If entering spaces where the airborne
concentration of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive pressure air
supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is recommended.
DEVCON PLASTIC STEEL PUTTY (A) HARDENER MSDS Page 2 of 4
PLASTIC STEEL PUTTY (A) HARDENER MSDS
HAND PROTECTION
Use protective gloves made of: Rubber or plastic.
EYE PROTECTION
Wear approved chemical safety goggles where eye exposure is reasonably probable.
HYGIENE MEASURES
Keep away from food, drink and animal feeding stuffs. Good personal hygiene is necessary. Wash hands and contaminated areas with
water and soap before leaving the work site. Do not eat, drink or smoke when using the product. Change work clothing daily before
leaving work place.
SKIN PROTECTION
Apron or protection suit should be worn.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Paste
COLOUR White ?Cream
ODOUR Amine odour.
SOLUBILITY Slightly soluble in water
BOILING POINT (癈) > 232 RELATIVE DENSITY 0.98 @ 20 篊
pH-VALUE, CONC. SOLUTION 10.5 @ 20 篊 FLASH POINT (癈) > 93
AUTO IGNITION TEMPERATURE (篊) Not Determined
10 STABILITY & REACTIVITY
STABILITY
Stable under normal temperature conditions and recommended use.
Reaction with resin component will generate heat, mixing large volumes should be avoided.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition.
MATERIALS TO AVOID
Avoid contact with: Strong acids. Strong oxidising agents. Amines.
HAZARDOUS DECOMPOSITION PRODUCTS
Fire or high temperatures create: Nitrous gases (NOx). Oxides of: Carbon monoxide (CO). Carbon dioxide (CO2). Vapours/gases/fumes
of: Acids ?Organic, Aldehydes.
11 TOXICOLOGICAL INFORMATION
INHALATION
Vapour from this material can be hazardous if inhaled.
INGESTION
Harmful if swallowed.
SKIN CONTACT
Causes burns. May be absorbed through the skin. Prolonged or repeated exposure may cause severe irritation. May cause sensitisation
by skin contact. Risk of sensitisation or allergic reactions among sensitive individuals.
EYE CONTACT
Risk of serious damage to the eyes.
HEALTH WARNINGS
Causes burns.
ROUTE OF ENTRY
Inhalation, Skin Absorption, Ingestion, Skin and/or eye contact.
TARGET ORGANS
Prolonged or repeated exposure may cause: Risk of serious damage to eyes, May cause damage to the liver, May cause damage to the
kidneys, Central and/or peripheral nervous system damage.
DEVCON PLASTIC STEEL PUTTY (A) HARDENER MSDS Page 3 of 4
PLASTIC STEEL PUTTY (A) HARDENER MSDS
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Avoid release to the environment. The product contains a substance which is toxic to aquatic organisms. And which may cause long
term adverse effects in the aquatic environment.
MOBILITY
Do not discharge into drains, water courses or onto the ground.
DEGRADABILITY
No available information
13 DISPOSAL INFORMATION
DISPOSAL METHODS
Mix resin and hardener components completely to create a solid that can be disposed as general waste.
Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
Not classified as Dangerous Goods in accordance with ADG-6.
This product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).
15 REGULATORY INFORMATION
POISONS SCHEDULE: S5 (SUSDP)
6 OTHER INFORMATION
ISSUE DATE: 20 September, 2007
CONTACT POINT: Technical Manager Phone: (02) 9757 8800 (Australia)
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
DEVCON PLASTIC STEEL PUTTY (A) HARDENER MSDS Page 4 of 4
PLASTIC STEEL PUTTY (A) RESIN MSDS
ISSUE DATE 20 September, 2007
MATERIAL SAFETY DATA SHEET
PLASTIC STEEL PUTTY (A) RESIN
1 IDENTIFICATION OF MATERIAL AND SUPPLIER
PRODUCT NAME: DEVCON PLASTIC STEEL PUTTY (A) RESIN
PRODUCT NO. D10110, D10120 (Resin component of a two part epoxy system)
SUPPLIER ITW POLYMERS & FLUIDS ITW POLYMERS & FLUIDS (NZ)
100 HASSALL ST UNIT 2 / 38 TRUEGOOD DRIVE
WETHERILL PARK EAST TAMAKI, 2013
NEW SOUTH WALES AUCKLAND
AUSTRALIA NEW ZELAND
T: 02 9757 8800 T: 09 272 1945
F: 02 9757 3855 F: 09 273 6489
EMERGENCY PHONE: T: 02 9757 8800 T: 09 272 1945
2 HAZARDS IDENTIFICATION
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS
(According to the criteria of the NOHSC and the ADG-6 code)
SIGNAL WORD(S)
Xi; Irritant;
RISK PHRASES
R36/38 Irritating to respiratory system and skin.
R43 May cause sensitization by skin contact.
SAFETY PHRASES
S24/25 Avoid contact with skin & eyes.
S28 After contact with skin, wash immediately with plenty of water.
S37/39 Wear suitable gloves and eye/face protection.
S61 Avoid release into the environment. Refer to special instructions / safety data sheets.
3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS-No. Content Classification
EPOXY RESIN (Number Average MW=700) 25068-38-6 30 - < 60 % Xi; R36/38,R43.
4 FIRST AID MEASURES
GENERAL INFORMATION
Avoid contact with skin and eyes. In case of accident or if you feel unwell, seek medical advice immediately. Show label or this safety
data sheet to doctor in attendance.
INHALATION
Move the exposed person to fresh air at once. Contact physician if discomfort continues.
INGESTION
Rinse mouth thoroughly, Do not induce vomiting. Rinse mouth with water. If vomiting occurs, the head should be kept low so that
stomach vomit does not enter the lungs. Never make an unconscious person vomit or drink fluids. Get medical attention immediately!
SKIN CONTACT
Remove affected person from source of contamination. Wash skin thoroughly with soap and warm water for several minutes. Contact
physician if irritation persists.
EYE CONTACT
Promptly wash eyes with plenty of clean water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical
attention. Contact physician if irritation persists.
PLASTIC STEEL PUTTY (A) RESIN MSDS Page 1 of 4
PLASTIC STEEL PUTTY (A) RESIN MSDS
5 FIRE FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
Fire can be extinguished using: Alcohol resistant foam. Carbon Dioxide (CO2). Dry Chemicals.
SPECIFIC HAZARDS
Avoid breathing fire vapours.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SPECIAL FIRE FIGHTING PROCEDURES
Keep upwind to avoid fumes. Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with
water until fire is out. Keep run-off water out of sewers and watercourses. Dike for water control.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY
alerted to the Environmental Agency or other appropriate regulatory body.
SPILL CLEAN UP METHODS
Absorb with sand or other inert absorbent. Transfer to a container for disposal. Containers with collected spillage must be properly
labeled with correct contents and hazard symbol.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded. Do not eat, drink or smoke when using the product. Observe good industrial hygiene practices.
STORAGE PRECAUTIONS
Store in tightly closed original container in a cool, dry well-ventilated place. Keep away from heat, sparks and open flame.
8 EXPOSURE CONTROL / PERSONAL PROTECTION
No exposure data available for product or ingredients.
PROTECTIVE EQUIPMENT
PROCESS CONDITIONS
Provide eyewash, quick drench.
ENGINEERING MEASURES
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded.
RESPIRATORY EQUIPMENT
Not usually required in well ventilated areas.
Select and use respirators in accordance with AS/NZS 1715/1716.
In poorly ventilated areas use Type A organic vapour/gas filter with half face piece.
When sanding/grinding cured product the use of a P1 dust mask (disposable) or with replaceable filters is recommended.
Filter capacity and respirator type depends on exposure levels and type of contaminant. If entering spaces where the airborne
concentration of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive pressure air
supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is recommended.
HAND PROTECTION
Use protective gloves made of: Rubber or plastic.
PLASTIC STEEL PUTTY (A) RESIN MSDS Page 2 of 4
PLASTIC STEEL PUTTY (A) RESIN MSDS
EYE PROTECTION
Wear approved chemical safety goggles where eye exposure is reasonably probable.
HYGIENE MEASURES
Keep away from food, drink and animal feeding stuffs. Good personal hygiene is necessary. Wash hands and contaminated areas with
water and soap before leaving the work site. Do not eat, drink or smoke when using the product. Change work clothing daily before
leaving work place.
SKIN PROTECTION
Protection suit should be worn.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Liquid
COLOUR Grey
ODOUR Slight Odour.
SOLUBILITY Insoluble in water
BOILING POINT (癈) > 260 RELATIVE DENSITY 2.8 @ 20 篊
VAPOUR PRESSURE Not known EVAPORATION RATE Not known
pH-VALUE, CONC. SOLUTION 7.0 @ 20?C FLASH POINT (癈) > 204
AUTO IGNITION TEMPERATURE (篊) > 300?C
10 STABILITY & REACTIVITY
STABILITY
Stable under normal temperature conditions and recommended use.
Reaction with hardener component will generate heat, mixing large volumes should be avoided.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition.
MATERIALS TO AVOID
Avoid contact with: Strong acids. Strong oxidising agents. Amines.
HAZARDOUS DECOMPOSITION PRODUCTS
Fire or high temperatures create: Nitrous gases (NOx). Oxides of: Carbon monoxide (CO). Carbon dioxide (CO2). Vapours/gases/fumes
of: Acids ?Organic, Aldehydes.
11 TOXICOLOGICAL INFORMATION
Name EPOXY RESIN (Number Average MW <=700)
Toxic Dose 1 - LD 50 >2000 mg/kg (oral rat)
Toxic Dose 2 - LD 50 >2000 mg/kg (oral rat)
INGESTION
May cause discomfort.
SKIN CONTACT
Irritating to skin. This product contains a small amount of sensitizing substance which may provoke an allergic reaction among sensitive
individuals after repeated contact.
EYE CONTACT
May cause irritation to eyes.
HEALTH WARNINGS
This material contains epoxy resin, which may cause sensitisation and development of allergy.
ROUTE OF ENTRY:
Inhalation, Ingestion, Skin and/or eye contact.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Avoid release to the environment. The product contains a substance which is toxic to aquatic organisms. And which may cause long
term adverse effects in the aquatic environment.
MOBILITY
Do not discharge into drains, water courses or onto the ground.
PLASTIC STEEL PUTTY (A) RESIN MSDS Page 3 of 4
PLASTIC STEEL PUTTY (A) RESIN MSDS
DEGRADABILITY
No available information
13 DISPOSAL INFORMATION
DISPOSAL METHODS
Mix resin and hardener components completely to create a nonhazardous solid that can be disposed as general waste.
Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
Not classified as Dangerous Goods by (ADG-6) (Australia).
International regulations (IMDG, IATA, ADR/RID):
DG CLASS: 9: Miscellaneous dangerous substances and articles,
SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID , N.O.S. (EPOXY RESIN (Number
average MW <= 700))
UN NUMBER: 3082
PACK GROUP: III
IMDG Page Number: 9
IMDG EMS: F-A, S-F.
Marine Pollutant: No.
15 REGULATORY INFORMATION
POISONS SCHEDULE: S5 (SUSDP)
6 OTHER INFORMATION
ISSUE DATE: 20 September, 2007
CONTACT POINT: Technical Manager Phone: (02) 9757 8800 (Australia)
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the
date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's
responsibility to satisfy himself as to the suitability of such information for his own particular use.
PLASTIC STEEL PUTTY (A) RESIN MSDS Page 4 of 4
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