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MSDS Material Safety Data Sheet
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112-24-3

File Name: 112-24.asp

SAFETY DATA SHEET
Ident-No: REN HY 956
Hazardous according to the criteria of NOHSC.
Version 1 Print Date 05.08.2003
Revision Date 04.07.2003

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
Product information
Trade name : REN HY 956
Use : Curing agent for epoxy resins

Company : Vantico Pty Ltd
235 Settlement Road
Thomastown 3074
Telephone : +61392802300
Telefax : +61392802329
Emergency telephone : Australia: 1800 033 111 New Zealand: 0800 734 607 Asia-
number Pacific: +61 3 9663 2130

2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Modified aliphatic polyamine
preparation

Hazardous components
Chemical Name CAS-No. Symbol(s): R-phrase(s) Concentration [%]
triethylenetetramine 112-24-3 C R21 R34 R43 R52/53 >= 22.00 - < 30.00

3. HAZARDS IDENTIFICATION

Poison schedule: 5

Irritating to skin.
Risk of serious damage to eyes.
May cause sensitization by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.


4. FIRST AID MEASURES

Inhalation : Move to fresh air.
If symptoms persist, call a physician.

Eye contact : Rinse immediately with plenty of water for at least 15 minutes.
Call a physician immediately.

Skin contact : If skin irritation persists, call a physician.
Wash off immediately with soap and plenty of water.

Ingestion : Immediately give plenty of water (if possible charcoal slurry).
Obtain medical attention.
Do not induce vomiting.


Notes to physician
Treatment : No specific antidote. Treat symptomatically.


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SAFETY DATA SHEET
Ident-No: REN HY 956
Hazardous according to the criteria of NOHSC.
Version 1 Print Date 05.08.2003
Revision Date 04.07.2003

First aid facility: Eye wash station . Showering facility.
Poisons Information Centres in each State capital city can
provide advice for scheduled poisons.


5. FIRE-FIGHTING MEASURES

Suitable extinguishing : Water spray.
media Carbon dioxide (CO2).
Foam.
Dry powder.

Extinguishing media which : High volume water jet.
must not be used for safety
reasons
Special protective : Wear self-contained breathing apparatus and protective suit.
equipment for fire-fighters
Further information : Burning produces obnoxious and toxic fumes.
Carbon oxides.



6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Keep away from sources of ignition - No smoking.
Avoid contact with skin, eyes and clothing.
Do not breathe vapours/dust.

Environmental precautions : If in doubt contact Vantico Pty. Limited using contact details
provided on this SDS.

Prevent product from entering drains.
Do not contaminate surface water.
Avoid subsoil penetration.

Methods for cleaning up : Soak up with inert absorbent material and dispose of as
hazardous waste.


7. HANDLING AND STORAGE
Handling
Advice on safe handling : Irritant
sensitizing
Keep away from sources of ignition - No smoking.
Avoid formation of aerosol.
Provide sufficient air exchange and/or exhaust in work rooms.
Handle and open container with care.


Storage
Further information on : Keep away from food, drink and animal feeding stuffs.
storage conditions Keep container tightly closed.
Keep at temperatures between 2 and 40癈.



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SAFETY DATA SHEET
Ident-No: REN HY 956
Hazardous according to the criteria of NOHSC.
Version 1 Print Date 05.08.2003
Revision Date 04.07.2003




8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Control Update Basis
parameters

Engineering measures
Engineering measures
Wherever possible, the workplace must be ventilated sufficiently to ensure that exposure standards
are met. Ensure airflow, where this product is being used, is directed away from the operators.
If cured material made from this product is to be cut or sanded, ensure that dust is kept below the
Worksafe Exposure Standard for inspirable dusts (10mg/m3) or the ACGIH Exposure Standard for
respirable dusts (3mg/m3).
No special precautions required.

Personal protective equipment
Respiratory protection : In case of insufficient ventilation wear suitable respiratory
equipment.

Eye protection : Tightly fitting safety goggles.
Face-shield.

Hand protection : rubber or plastic gloves

Skin and body protection : Protective suit.
Safety shoes.

Protective measures : Avoid contact with skin and eyes by wearing long impervious
gloves, (Rubber,Neoprene, PVC complying to AS 2161) and
industrial safety glasses. Respiratory protection complying with
AS 1715, 1716 should be worn if ventilation at the workplace is
inadequate. Apply barrier creams to exposed skin areas.
Use with adequate ventilation. If risk of inhalations exists, wear
an organic vapour respirator meeting the requirements of
AS/NZS 1715 and AS/NZS 1716.

Do not breathe vapours/dust.
Keep away from sources of ignition - No smoking.
Avoid contact with skin, eyes and clothing.


9. PHYSICAL AND CHEMICAL PROPERTIES

Form : liquid

Colour : clear

Odour : amine-like

pH : approx.12
at (20 癈)
1:1 in water


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SAFETY DATA SHEET
Ident-No: REN HY 956
Hazardous according to the criteria of NOHSC.
Version 1 Print Date 05.08.2003
Revision Date 04.07.2003


Boiling point : > 200 癈

Thermal decomposition : > 200 癈

Flash point : 152 癈
Method: DIN 51758 (Pensky-Martens Closed Cup)

Vapour pressure : 0.1 Pa
at 20 癈

Density : 1 - 1.05 g/cm3
at 25 癈

Water solubility : at 20 癈
Note: miscible

Miscibility with water : miscible

Viscosity, dynamic : 370 - 470 mPa.s
at 25 癈


10. STABILITY AND REACTIVITY

Conditions to avoid : Note: Take necessary action to avoid static electricity
discharge.

Materials to avoid : Strong acids and strong bases.
Strong oxidizing agents.

Hazardous decomposition : Product will not decompose explosively.
products
Carbon oxides.

Nitrogen oxides. Burning produces obnoxious and toxic
fumes.

Hazardous reactions : Product as received will not present a dust explosion hazard.
If cured material made using this product is to be machined, or
sanded, a dust explosion hazard may be created.
All dust generated should be removed as quickly as possible,
preferably by the use of a vacuum cleaner.


11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50 rat
Dose: 4,500 mg/kg

Remarks: No adverse health effects expected, however large
amounts may cause nausea and vomiting.

Acute inhalation toxicity : Remarks: Where product is used in poorly ventilated areas,
and/or in confined spaces and/or at elevated temperatures,
vapours may be irritating to the respiratory system.


4/7
SAFETY DATA SHEET
Ident-No: REN HY 956
Hazardous according to the criteria of NOHSC.
Version 1 Print Date 05.08.2003
Revision Date 04.07.2003


Acute dermal toxicity : LD50 rat
Dose: > 2,150 mg/kg

Eye irritation : Risk of serious damage to eyes.
rabbit
Method: OECD 405

Skin irritation : irritating
rabbit
Method: OECD 404
dermal

Sensitization : Causes sensitization.
guinea pig
dermal

Further information : Chronic exposure: Product is a skin sensitiser. Repeated or
prolonged skin contact may result in allergic contact dermatitis.


12. ECOLOGICAL INFORMATION

Ecotoxicity effects

Further information on ecology
Additional ecological : Avoid subsoil penetration.
information Prevent product from entering drains.
Do not contaminate surface water.


13. DISPOSAL CONSIDERATIONS

Product : Spilt / waste material should be disposed of by incineration by
an approved agent according to local regulations.

Container : Empty containers should either be sent to an approved agent
for cleaning and recycling or incineration according to local
regulations.


14. TRANSPORT INFORMATION
Land transport

Road/ADR:
Regulation: Not dangerous goods


Rail/RID:
Regulation: Not dangerous goods



5/7
SAFETY DATA SHEET
Ident-No: REN HY 956
Hazardous according to the criteria of NOHSC.
Version 1 Print Date 05.08.2003
Revision Date 04.07.2003

Sea transport

IMDG:
Regulation: Not dangerous goods


Air transport

IATA-DGR:
Regulation: Not dangerous goods

15. REGULATORY INFORMATION
Labelling according to EEC Directive
Labelling required

Symbol(s): : Xi Irritant


R-phrase(s) : R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.


S-phrase(s) : S26 In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
S36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S61 Avoid release to the environment. Refer to
special instructions/Safety data sheets.
S61 Avoid release to the environment. Refer to
special instructions/Safety data sheets.


Exceptional labelling of : According to Directive 88/379/EEC, Article 3, Paragraph 3b,
special preparations classification derived from direct toxicological testing of the
preparation take precedence over classification derived from
using the conventional (calculation) method.

Hazardous components : triethylenetetramine
which must be listed on the
label


National legislation



Notification status



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SAFETY DATA SHEET
Ident-No: REN HY 956
Hazardous according to the criteria of NOHSC.
Version 1 Print Date 05.08.2003
Revision Date 04.07.2003


: EINECS not required
Polymer


: TSCA yes


: DSL yes


: AICS yes



16. OTHER INFORMATION

All information is based on results gained from experience and tests and is believed to be accurate
but is given without acceptance of liability for loss or damage attributable to reliance thereon as
conditions of use lie outside our control. Users should always carry out sufficient tests to establish
the suitability of any products for their intended applications. No statements shall be incorporated in
any contract unless expressly agreed in writing nor construed as recommending the use of any
product in conflict of any patent. All goods are supplied subject to Vantico's General Conditions of
Sale.

CONTACT POINT:
EH&S MANAGER
TELEPHONE: (03) 9280 2325 or (03) 9280 2300 (switch)
FACSIMILE: (03) 9280 2329




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