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Hastings Plastics
Material Safety Data Sheets for Epoxy Resins
ALL-PURPOSE HARDENER HAPEX 1227
FLOKOTE DECOUPAGE RESIN (FAST) HAPEX 1230-5-1 "COMP A"
FLOKOTE DECOUPAGE RESIN (FAST) HAPEX 1230-5-1 "COMP B"
FLOKOTE DECOUPAGE RESIN (SLOW) HAPEX 1230-5-2 "COMP A"
FLOKOTE DECOUPAGE RESIN (SLOW) HAPEX 1230-5-2 "COMP B"
LOW DENSITY RESIN HAPEX 1231
TOOLING RESIN HAPEX 1240-1
TOOLING RESIN HAPEX 1240-51
GENERAL PURPOSE RESINS HAPEX 1290
*Click on underlined link to go to MSDS*
You can print the data by selecting the sheets you want and printing that selection.
PRODUCT DATA
HASTINGS MSDS 1227
PLASTICS *Revised 10/15/98
Replaced 05/02/94
COMPANY
1704 Colorado Ave. Santa Monica, CA 90404 310-829-3449 FAX 310-828-6820
BACK TO INDEX
HAPEX 1227
SECTION I - PRODUCT IDENTIFICATION
MANUFACTURER'S NAME - HASTINGS PLASTICS COMPANY
PRODUCT SALES/INFO - (310) 829-3449
EMERGENCY PHONE NUMBER - (800) 424-9300
PRODUCT NAME - Hapex 1227
PRODUCT TYPE - Epoxy Hardener
CHEMICAL FAMILY AND
SYNONYMS - Aliphatic Polyaminoamide
HMIS RATING - Health - 2 Flammability - 1 Reactivity - 0 Protective equipment -
X
SECTION II - COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENTS EXPOSURE LIMITS
ACGIH OSHA
TWA STEL PEL STEL MFR.
1,2-Ethandediamine, N,N'=Bis(2-Aminoethyl)- NE NE NE NE NE
CAS# 112-24-3
Fatty acids, C18-unsatd Dimers, Polymers with tall NE NE NE NE NE
oil fatty acids and triethylenete-tramine.
Cas# 68082-29-1
NE = Not Established
SECTION III - PHYSICAL AND CHEMICAL PROPERTIES
COLOR: -Yellow
ODOR: - Amine
PHYSICAL STATE: - Liquid
SOLUBILITY IN WATER: - 0.5% Very Slight
VAPOR PRESSURE: - <0.001 mm Hg at 20/C (68/F)
SPECIFIED GRAVITY: - 0.96 at 25/C (77/F)
BOILING POINT: - >200/C (>392/F)
DECOMPOSITION TEMPERATURE: - >200/C (>392/F)
pH: - Not Applicable
PERCENT VOLATILE: - Nil
HAPEX 1227 MATERIAL SAFETY DATA SHEET PAGE 3 OF 32
SECTION IV - FIRST AID MEASURES
INGESTION: If swallowed, give at least 3-4 glasses of water but do not induce vomiting. Do not give anything
by mouth to an unconscious or convulsing person.
SKIN: For skin contact, immediately wipe off affected area with dry towel. Then wash with large amounts of
running water, and soap if available, for 15 minutes. Remove contaminated clothing and shoes. Get immediate
medical attention. Discard or decontaminate clothing before re-use and destroy contaminated shoes.
INHALATION: If inhaled, remove from area to fresh air. If not breathing, give artificial respiration. Get
immediate medical attention. If breathing is difficult, transport to medical care and if available, give
supplemental oxygen.
EYES: For eye contact , immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart
to ensure rinsing of the entire eye surface and lids with water. If physician is not available, flush for an
additional 15 minutes. Get immediate medical attention.
OVEREXPOSURE EFFECTS: Overexposure to this material can result in chemical burns to the skin and eyes.
Can cause irritant and allergic reactions to both skin and respiratory with symptoms such as rashes, wheezing ,
coughing and difficulty in breathing. Based on animals studies, a component in this product may have effects
on the liver, kidney, brain and developing fetus.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Asthma, chronic respiratory disease, skin and
eye conditions.
ADDITIONAL INFORMATION: Promptly remove wet contaminated non-impervious clothing. Wash before
reuse.
SECTION V - FIRE FIGHTING MEASURES
FLASH POINT: >200/F(93/C)
FLASH POINT METHOD USED: Closed Cup
FIRE FIGHTING EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical, and water spray.
FIRE FIGHTING EQUIPMENT: Use self-contained breathing apparatus.
FIRE AND EXPLOSION HAZARDS: Decomposition and combustion products may be toxic.
SECTION VI - ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES: Avoid all personal contact. Take up with absorbent material. Shovel
into sealable containers. Flush contaminated area with water.
SECTION VII - HANDLING AND STORAGE
HAPEX 1227 MATERIAL SAFETY DATA SHEET PAGE 4 OF 32
PRECAUTIONS: Avoid contact with eyes, skin and clothing. Avoid breathing mist or vapor. Do not take
internally. Use with adequate ventilation. Wear chemical splash goggles, impervious gloves and protective
clothing when handling. Individuals should wash thoroughly after handling. Keep container closed when not in
use. For manufacturing use only. (next page)
SECTION VIII - PERSONAL PROTECTION EQUIPMENT
SKIN: Wear impervious gloves.
RESPIRATORY PROTECTION: Organic chemical cartridge respirator.
EYE PROTECTION: Wear splash-proof chemical goggles or complete face shield.
VENTILATION: Good general mechanical ventilation recommended.
SECTION X - STABILITY AND REACTIVITY
STABILITY - Stable
INCOMPATIBILITY - Strong oxidizing agents, acids, and natural rubber.
HAZARDOUS DECOMPOSITION PRODUCTS - Carbon monoxide, carbon dioxide, aldchydes, nitrogen
oxides and compounds.
HAZARDOUS POLYMERIZATION - Will not occur.
SECTION XI - TOXICOLOGICAL INFORMATION
ACUTE ORAL EFFECTS (LD50): (Rat) Greater than 5.0g/kg (polyamide resin)
ACUTE DERMAL TOXICITY (LD50): (Rabbit) 0.8g/kg (component)
SENSITIZATION: May cause skin and respiratory sensitization.
SKIN IRRITATION: (Rabbit) irritant.
EYE IRRITATION: (Rabbit) Severe irritant.
SECTION XII - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD - Dispose in accordance with federal, state, and local regulations.
SECTION XIII - TRANSPORTATION INFORMATION
DEPARTMENT OF TRANSPORTATION - Not regulated.
SECTION XIV - REGULATORY INFORMATION
OSHA STATUS - This Material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal
OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to
be a hazardous chemical under that standard.
TSCA INVETORY STATUS - Chemical components listed on TSCA inventory.
SARA TITLE III: SECTION 313 TOXIC CHEMICAL(S) - This product does not contain a toxic chemical for
Routine annual Toxic Chemical Release
Reporting
under Sec# 313 (40 CFR 372).
HAPEX 1227 MATERIAL SAFETY DATA SHEET PAGE 5 OF 32
RCRA - Not a hazardous waste under RCRA (40 CFR 261).
CERCLA - Not listed.
CANADIAN INVENTORY STATUS (CEPA) - All components included on the Domestic Substance List
(DSL).
(over)
NEW JERSEY RIGHT TO KNOW: The following is required composition information:
CAS NUMBER: 68082-29-1
CHEMICAL NAME: Fatty acids, C18-unsatd., dimers, polymers with tall oil fatty acids and
triethylenetetramine.
CAS NUMBER: 112-24-3
CHEMICAL NAME: 1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-
COMMON NAME: Triethylenetetramine
PENNSYLVANIA RIGHT TO KNOW: The following is required composition information:
CAS NUMBER: 68082-29-1
CHEMICAL NAME: Fatty acids, C18-unsatd., dimers, polymers with tall oil fatty acids and triethylenetramine
COMMENT: Not on Pennsylvania Hazardous Substance list.
CAS NUMBER: 112-24-3
CHEMICAL NAME: 1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-
COMMON NAME: Triethylenetetramine
COMMENT: Hazardous Substance
DISCLAIMER OF LIABILITY
As the conditions or methods of use are beyond our control, we do not assume any
responsibility and expressly disclaim liability for any use of this material. Information
contained herein is believed to be true and accurate but all statements are made without
warranty, express or implied, regarding the accuracy of the information, the hazards
connected with the use of the material or the results to be obtained from the use thereof.
It is the user's obligation to determine the conditions of safe use and the suitability of the
material for the user's purpose.
Prepared By: Joe Morales
F#170-21A
PRODUCT DATA
HASTINGS MSDS 1230-5-1
PLASTICS COMP "A"
* REVISED 6/1/99
COMPANY REPLACES 12/11/98
1704 Colorado Ave. Santa Monica, CA 90404 310-829-3449 FAX 310-828-6820
BACK TO INDEX
HAPEX 1230-5-1 COMP "A"
SECTION I - PRODUCT IDENTIFICATION
MANUFACTURER'S NAME - HASTINGS PLASTICS COMPANY
PRODUCT INFORMATION AND SALE - (310) 829-3449
EMERGENCY PHONE NUMBER - (800) 424-9300
PRODUCT NAME - Hapex 1230-5-1 Component "A"
PRODUCT CODE NUMBER - 1230-5-1
CHEMICAL FAMILY - Epoxy Resin
CHEMICAL NAME - Modified Bispnenol A diglycdyl ether
FORMULA - Proprietary
D.O.T. CLASSIFICATION - Not regulated
HMIS: HEALTH - 2 FLAMMABILITY - 1 REACTIVITY - 1
SECTION II - HAZARDOUS INGREDIENTS ACGIH OSHA
COMPONENTS % CAS # TLV PEL
BISPHENOL A DIGLYCIDYL ETHER 90 - 98 25085-99-8 NE NE
AROMATIC HYDROCARBON (TOLUENE) 2 - 5 108-88-33 100 ppm 100 ppm
NE = NOT ESTABLISHED
SECTION III - PHYSICAL DATA
APPEARANCE AND COLOR - Straw colored liquid.
ODOR - Aromatic odor.
BOILING POINT - N/A
VAPOR PRESSURE - N/A
VAPOR DENSITY - Nonvolatile
SOLUBILITY IN WATER - Nil
PERCENT VOLATILE
(By Weight) - .5% (54 grams per liter)
EVAPORATION RATE - Nonvolatile
SPECIFIC GRAVITY - 1.145
SECTION IV - FIRE AND HAZARD EXPLOSION DATA
- >200 /F
FLASH POINT
FLAMMABLE LIMITS
(In Air % LEL) - Not Applicable
FLAMMABILITY CLASS - 3B
EXTINGUISHING MEDIA - Foam, Carbon dioxide, dry chemical or fog.
SPECIAL FIRE
FIGHTING PROCEDURES - Firefighter should wear goggles and self- contained breathing apparatus to avoid
inhalation of smoke or vapors.
UNUSUAL FIRE AND EXPLOSION HAZARDS - None Known
HAPEX 1230-5-1 "COMP A" MATERIAL SAFETY DATA SHEET PAGE 51 OF 32
SECTION V - HEALTH EFFECTS DATA
PERMISSIBLE EXPOSURE LEVEL - None Assigned
EFFECTS OF OVEREXPOSURE:
INHALATION - May cause nasal irritation, central nervous system depression or lung injury.
EYES - Mild to moderate irritation, possible minor temporary corneal injury.
SKIN - Mild irritation. May be a skin sensitizer.
EMERGENCY & FIRST AID PROCEDURES:
EYE CONTACT - Flush with water. Get medical attention if necessary.
SKIN CONTACT - Wash with soap and water. Remove and wash contaminated clothing before reuse.
INHALATION - If ill effects occur remove person to fresh air, keep that person warm and quiet and get
medical attention if necessary.
INGESTION - Not likely a problem. If large amounts are swallowed, promptly induce vomiting and get
medical attention.
PRIMARY ROUTE(S) OF
ENTRY - Inhalation, ingestion, skin and eye contact.
CARCINOGENICITY - This product does not contain 0.1% or more of any substance which is listed as
carcinogen by NTP, IARC, or OSHA.
SECTION VI - REACTIVITY DATA
STABILITY - Stable
HAZARDOUS POLYMERIZATION - Will not occur
INCOMPATIBILITY - Strong oxidizers, acids, bases and epoxy hardeners under
uncontrolled conditions.
HAZARDOUS DECOMPOSITION
PRODUCTS - Carbon monoxide, carbon dioxide, smoke. Other possible
products unknown.
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Ventilate area. Absorb spill with suitable absorbent materials and place into a closed container. For large spills,
dike area and pump into closed containers. Prevent this material from entering waterways. Wear protective
equipment during cleanup.
WASTE DISPOSAL METHOD:
At this time, this material or its containers would not be considered hazardous wastes as defined under the
federal RCRA regulations ( 40 CFR 261) if discarded.
Care should be taken to ensure that the material or its containers are disposed of in an approved facility in
accordance with current federal, state, and local regulations.
For further information, contact your state or local waste agency or the United States Environmental Protection
Agency's RCRA hotline (1-800-424-9346 or 202-382-3000).
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION - Should be worn to avoid breathing spray mist, heated vapors or if TLV is
exceeded.
PROTECTIVE GLOVES - Chemical-resistant plastic or rubber.
EYE PROTECTION - Chemical goggles.
OTHER PROTECTIVE EQUIPMENT - As Required to prevent wetting skin or clothing.
(next page)
HAPEX 1230-5-1 "COMP A" MATERIAL SAFETY DATA SHEET PAGE 8 OF 32
SECTION IX - SPECIAL PRECAUTIONS & STORAGE DATA
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: This material may cause sensitization.
Do not get in eyes, on skin or clothing. Do not allow contaminated clothing to contact skin. Avoid contact with
vapors or fumes.
OTHER PRECAUTIONS: Wear protective equipment.
SECTION X - REGULATORY INFORMATION
SARA HAZARD CLASSIFICATION: This material has been categorized as having the following hazard(s) as
defined by SARA Title III Regulations (40 CFR 370): acute.
SARA SECTION 313 LISTED INGREDIENTS: This material does not contain any substance which is subject
to the reporting requirements of 40 CFR 372.
DOT PROPER SHIPPING NONE: Not regulated by DOT.
UN NUMBER: None
DISCLAIMER OF LIABILITY
As the conditions or methods of use are beyond our control, we do not assume any
responsibility and expressly disclaim liability for any use of this material. Information
contained herein is believed to be true and accurate but all statements are made without
warranty, express or implied, regarding the accuracy of the information, the hazards
connected with the use of the material or the results to be obtained from the use thereof.
It is the user's obligation to determine the conditions of safe use and the suitability of the
material for the user's purpose.
Prepared By: Joe Morales
PRODUCT DATA
HASTINGS MSDS 1230-5-1 COMP"B"
PLASTICS *REVISED 6/1/99
REPLACES 12/21/98
COMPANY
1704 Colorado Ave. Santa Monica, CA 90404 310-829-3449 FAX 310-828-6820
BACK TO INDEX
HAPEX 1230-5-1 COMP "B"
SECTION I - PRODUCT IDENTIFICATION
MANUFACTURER'S NAME - HASTINGS PLASTICS COMPANY
PRODUCT INFORMATION AND SALE - (310) 829-3449
EMERGENCY PHONE NUMBER - (800) 424-9300
PRODUCT NAME - Hapex 1230-5-1 Comp "B"
CHEMICAL FAMILY - Epoxy Resin Hardener
FORMULA - Proprietary
HMIS Rating: - Health = 2 Fire = 1 Reactivity = 1
SECTION II - HAZARDOUS INGREDIENTS
COMPONENTS % CAS # EXPOSURE LIMITS
MODIFIED POLYAMINES 100.0 PROPRIETARY NONE ASSIGNED
PHENOL 2,4,6- Tris[(dimethylamino)methyl]- 3-5 90-72-2 NONE ASSIGNED
AROMATIC HYDRO CARBON (TOULENE) 3-5 108-88-33 100 ppm
SECTION III - PHYSICAL DATA
APPEARANCE AND ODOR - Straw colored liquid, amine odor.
BOILING POINT (/F) - N/A.
VAPOR PRESSURE (mm HG) - N/A
VAPOR DENSITY - Nonvolatile
SPECIFIC GRAVITY
(H20=1) - .960
PERCENT VOLATILE
(By Volume (%)) - 4.75%(18 grams per liter)
EVAPORATION RATE - Nonvolatile
SECTION IV - FIRE AND HAZARD EXPLOSION DATA
FLASH POINT /F
- >200 /F (SFCC)
(Method Used)
FLAMMABILITY CLASS. - Class 3B.
LEL - N/A
EXTINGUISHING MEDIA - Carbon dioxide, dry chemical, foam.
SPECIAL FIRE FIGHTING PROCEDURES - Firefighters should wear self contained breathing
apparatus to avoid inhalation of smoke or vapors.
UNUSUAL FIRE AND EXPLOSION HAZARDS - None known. Closed containers may rupture when
exposed to extreme heat.
SECTION V - HEALTH EFFECTS DATA
PERMISSIBLE EXPOSURE LEVEL:
Not established.
(over)
HAPEX 1230-5-1 "COMP B" MATERIAL SAFETY DATA SHEET PAGE 10 OF 32
EFFECTS OF OVEREXPOSURE:
INHALATION - May cause nasal irritation, central nervous system depression or lung injury.
EYE CONTACT - This product may contain alkaline materials that can cause chemical burns to the eyes. Eye
damage may be irreversible.
SKIN CONTACT - May be corrosive or highly irritation to skin. Repeated contact may cause sensitization
and/or dermatitis.
SKIN ABSORPTION - No specific information is available; however, this material may contain aliphatic
amines which may be absorbed through the skin.
EMERGENCY & FIRST AID PROCEDURES:
INHALATION - If ill effects occur remove person to fresh air, keep that person warm and quiet and get
medical attention promptly.
SKIN - Promptly wipe clean with paper or cloths and wash with soap and water. Remove and wash any
contaminated clothing before reuse.
INGESTION - Not likely a problem. If large amounts are swallowed get medical attention immediately.
EYES - Flush with plenty of water and get medical attention.
PRIMARY ROUTE(S) OF ENTRY - Inhalation, ingestion, skin and eye contact.
CARCINOGENICITY - This material does not contain 0.1% or more of any substance which is listed as a
carcinogen by NTP, IARC, or OSHA.
SECTION VI - REACTIVITY DATA
STABILITY - Stable.
CONDITIONS TO AVOID - Warm storage, ignition sources.
HAZARDOUS POLYMERIZATION - Will not occur.
INCOMPATIBILITY
(Material To Avoid) - Strong oxidizers, acids, bases and epoxy resins under
uncontrolled conditions.
HAZARDOUS DECOMPOSITION
PRODUCTS - Carbon monoxide, carbon dioxide, smoke. Other possible
products unknown
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Ventilate area. Absorb spill with suitable absorbent material and place into a closed container. For large spills,
dike area and pump into closed containers. Prevent this material from entering waterways. Wear protective
equipment during cleanup.
WASTE DISPOSAL METHOD:
At this time, this material or its containers would not be considered hazardous wastes as defined under the
federal RCRA regulations (49CFR 261) if discarded.
Care should be taken to ensure that the material or its containers are disposed of in a approved facility in
accordance with current federal, state, and local regulations.
For further information, contact your state or local waste agency or the United States Environmental Protection
Agency's RCRA hotline (1-800-424-9346 or 202-382-3000).
(next page)
HAPEX 1230-5-1 "COMP B" MATERIAL SAFETY DATA SHEET PAGE 11 OF 32
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION - Should be worn to avoid breathing spray mist, heated vapors or
if TLV is exceeded.
VENTILATION - Local exhaust and general ventilation recommended.
PROTECTIVE GLOVES - Chemical resistant plastic or rubber.
EYE PROTECTION - Chemical goggles.
OTHER PROTECTIVE
EQUIPMENT - As required to prevent wetting skin or clothing.
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING & STORING: This material may cause sensitization. Do
not get in eyes, on skin or clothing. Do not allow contaminated clothing to contact skin. Avoid contact with
vapors or fumes.
OTHER PRECAUTIONS: Wear protective equipment.
SECTION X - SHIPPING INFORMATION
D.O.T. SHIPPING NAME - Polyamines, liquid, N.O.S. (Nonylphenol Aminoethylpiperazine)
D.O.T. HAZARD CLASS - Corrosive material.
D.O.T. I.D. NUMBER - 8, UN2735, III
REGULATORY INFORMATION:
None
SARA HAZARD CLASSIFICATION:
This material has been categorized as having the following hazard(s) as defined by SARA Title III Regulations
(40 CFR 370): Acute.
SARA SECTION 313 LISTED INGREDIENTS:
This material does not contain any substance which is subject to the reporting requirements of 40 CFR 372.
DISCLAIMER OF LIABILITY
As the conditions or methods of use are beyond our control, we do not assume any
responsibility and expressly disclaim liability for any use of this material. Information
contained herein is believed to be true and accurate but all statements are made without
warranty, express or implied, regarding the accuracy of the information, the hazards
connected with the use of the material or the results to be obtained from the use thereof.
It is the user's obligation to determine the conditions of safe use and the suitability of the
material for the user's purpose.
Prepared By: Joe Morales
F#170-21A
PRODUCT DATA
HASTINGS MSDS 1230-5-2 COMP
PLASTICS "A"
ISSUED 08/14/03
COMPANY
1704 Colorado Ave. Santa Monica, CA 90404 310-829-3449 FAX 310-828-6820
BACK TO INDEX
HAPEX 1230-5-2 COMP A
SECTION I - PRODUCT IDENTIFICATION
MANUFACTURER'S NAME - HASTINGS PLASTICS COMPANY
PRODUCT SALES - (310) 829-3449
EMERGENCY PHONE NUMBER - (800) 424-9300
PRODUCT NAME - Hapex 1200A
PRODUCT CODE NUMBER - 1230-5-2 COMP A
CHEMICAL FAMILY - Epoxy Resin
CHEMICAL NAME - Modified Diethyl Ether of Bisphanol A
FORMULA - Proprietary
D.O.T. CLASSIFICATION - Not regulated
HMIS Rating: Health - 2 Fire - 1 Reactivity - 0
SECTION II - HAZARDOUS INGREDIENTS
COMPONENTS CAS # % TLV (units)
BISPHENOL A DIGLYCIDYL ETHER 25085-99-8 70-78 Not Established
O - CRESYL GLYCIDYL ETHER 26447-14-3 20-25 Not Established
CARCINOGENICITY: This chemical is not considered to be carcinogenic.
HAZARD STATEMENT: This material safety data sheet has been prepared in compliance with Federal
OSHA Hazard Communication Standard 29 CFR 1910.1200.This product is considered to be a hazardous
chemical under that standard.
SECTION III - PHYSICAL DATA
APPEARANCE AND COLOR - Straw colored liquid.
ODOR - Mild aromatic odor.
BOILING POINT - N/A
VAPOR PRESSURE - N/A.
VAPOR DENSITY - Nonvolatile
SOLUBILITY IN WATER - Nil.
PERCENT VOLATILE
(By Volume) - 0
EVAPORATION RATE - N/A.
SPECIFIC GRAVITY - 1.14 - 1.19
SECTION IV - FIRE AND HAZARD EXPLOSION DATA
FLASH POINT 0F
(Method Used) - >200 closed cup
HAPEX 1230-5-2 "COMP A" MATERIAL SAFETY DATA SHEET PAGE 13 OF 32
FLAMMABLE LIMITS
(In Air % LEL) - N/A.
EXTINGUISHING MEDIA - Foam, carbon dioxide, dry chemical, water spray. (Over)
SPECIAL FIRE
FIGHTING PROCEDURES - Firefighters should wear goggles and self-contained breathing apparatus to
avoid inhalation of smoke vapors
UNUSUAL FIRE AND
EXPLOSION HAZARDS - Decomposition and combustion products may be toxic.
SECTION V - HEALTH EFFECTS DATA
THRESHOLD LIMIT VALUE - None assigned
OVEREXPOSURE-CHRONIC: Mice receiving skin applications of the Diglycidyl Ether of Bisphenol A or essentially identical resins
for two years have yielded very limited evidence of weak carcinogenicity. The published report on this study concludes that the resin
product "is not a systemic carcinogen when applied to the skin of CF 1 mice" and the tumor data "was of no biological importance".
Based on all available data, IRAC (International Agency For Research On Cancer) has concluded in 1988 that DGEBPA is not
classified as a carcinogen.
EFFECTS OF OVEREXPOSURE:
EYES - Mild to moderate irritation, possible minor temporary corneal injury.
SKIN - Not likely to be absorbed in toxic amounts.
INHALATION - May cause nasal irritation, central nervous system depression or lung injury.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Allergy, Eczema, Dermatitis
EM ERGENCY & FIRST AID PROCEDURES:
EYE CONTACT - Flush with water. Get medical
attention if necessary.
SKIN CONTACT - W ash with soap and water. Remove and
wash contaminated clothing.
INHALATION - If ill effects occur remove person to fresh air, keep that person warm and quiet and get medical attention
promptly.
INGESTION - If conscious, give large quantities of water. get immediate medical attention.
OTHER Promptly remove wet contaminated clothing.
W ash before reuse.
PRIMARY ROUTE(S) OF EXPOSURE
ORAL LD50 - (RAT) >5,000 mg/kg
DERMAL LD50 - (RAT) >2100 mg/kg
SKIN IRRITATION - (RABBIT) Mild Irritation
EYE IRRITATION - (RABBIT) None
SENSITIZATION - (GUINEA PIG) Sensitizer
INHALATION LC50 - (RAT) 6.1 mg/L for a 4 hour exposure; toxic by inhalation (minor ingredient)
CARCINOGENICITY:
This product does not contain 0.1% or more of any substance which is listed as carcinogen by NTP, IARC or OSHA.
SECTION VI - REACTIVITY DATA
STABILITY - Stable.
HAZARDOUS POLYMERIZATION - W ill not occur.
INCOMPATIBILITY - Strong oxidizing agents.
HAZARDOUS DECOMPOSITION
PRODUCTS - Carbon monoxide, carbon dioxide, aldehydes.
CONDITIONS TO AVOID - Elevated temperatures, strong acids & bases in bulk.
SECTION VII - SPILL OR LEAK PROCEDURES
HAPEX 1230-5-2 "COMP A" MATERIAL SAFETY DATA SHEET PAGE 58 OF 32
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Ventilated area. Absorb spill with suitable absorbent material and place into a closed container. For large spills, dike area and pump
into closed containers. Prevent this material from entering waterways. W ear protective equipment during cleanup.
W ASTE DISPOSAL METHOD:
At this time, this material or its containers would not be considered hazardous wastes as defined under the federal RCRA regulations
(40 CFR 261) if discarded. Care should be taken to ensure that the material or its containers are disposed of in an approved facility in
accordance with current Federal, State, and Local regulations.
SECTION VIII - SPECIAL PROTECTION INFORM ATION
RESPIRATORY PROTECTION - Use NIOSH approved respirator suitable for organic vapors, if required.
VENTILATION - Local exhaust and general ventilation recommended
PROTECTIVE GLOVES - Rubber or polyethylene.
EYE PROTECTION - Safety glasses with side shields.
OTHER PROTECTIVE
EQUIPMENT - Protective equipment to avoid personal contact.
SECTION IX - SPECIAL PRECAUTIONS & STORAGE DATA
HMIS CODE - HEALTH: 2 FIRE: 1 REACTIVITY: 0
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING :
This material may cause sensitization. Do not get in eyes, on skin or clothing. Do not allow contaminated clothing to contact skin.
Avoid contact with vapors or fumes. Store in tightly closed containers in cool, dry area. W ash thoroughly after handling.
SECTION X - SUPPLEM ENTAL INFORM ATION
REGULATORY INFORMATION: None
SARA HAZARD CLASSIFICATION: This material has been categorized as having the following hazard(s) as defined by SARA
Title III regulations (40 CFR 370): acute
SARA SECTION 313 LISTED INGREDIENTS: This material does not contain any substance which is subject to the reporting
requirements of 40 CFR 372.
DOT PROPER SHIPPING NAME: Not regulated by DOT
UN NUMBER: None
RCRA STATUS: Not a hazardous waste under RCRA (40 CFR 261)
CERCLA STATUS: Not listed
TSCA INVENTORY STATUS: Chemical components listed on TSCA inventory.
NEW JERSEY RIGHT TO KNOW LABELING INFORMATION - This product contains the following :
CHEMICAL NAME CAS NUM BER
Phenol, 4-4'-(1-Methylethylidene) 25068-38-6
Bis-, Polymer with (Chloromethyl)Oxirane
Oxirane, {(M ethylphenoxy)M ethyl} 26447-14-3
PENNSYLVANIA RIGHT TO KNOW ACT - The following is required composition information:
I. CHEMICAL NAME CAS NUM BER
Phenol, 4-4'-(1-Methylethylidene) 25068-38-6
Polymer with (Chloromethyl)oxirane
COMM ON NAME COMM ENTS
Bisphenol A Epoxy Resin Not on Pennsylvania Hazardous Substance List
HAPEX 1230-5-2 "COMP A" MATERIAL SAFETY DATA SHEET PAGE 58 OF 32
II. CHEMICAL NAME CAS NUM BER
Oxirane, {(M ethylphenoxy)M ethyl} 26447-14-3
COMMON NAM E COMMENTS
Cresyl Glycidyl Ether Not on Pennsylvania Hazardous Substance List
( OVER )
HAZARDOUS PRODUCTS INFORMATION ACT - This product contains the following ingredients which are Controlled Products
and/or on the Ingredient Disclosure List (Canadian HPA section 13 and 14):
COMPONENTS CAS NUMBER AMOUNT %w/w
Reaction product of 25085-99-8 70 - 78%
epichloroh
DISCLAIM ER OF LIABILITY ydrin &
As the conditions or methods of use are beyond our control, we do not assume any responsibility and
expressly disclaim liability for any use of this material. Information contained herein is believed to be true
and accurate but all statements are made without warranty, express or implied, regarding the accuracy of
the information, the hazards connected with the use of the material or the results to be obtained from the use
thereof. It is the user's obligation to determine the conditions of safe use and the suitability of the material
for the user's purpose.
bisphenol
A
Prepared By: Joe Morales
F#170-21A
PRODUCT DATA
HASTINGS MSDS 1230-5-2 COMP"B"
PLASTICS *Revised 05/01/09
Replaced 08/14/03
COMPANY
1704 Colorado Ave. Santa Monica, CA 90404 310-829-3449 FAX 310-828-6820
BACK TO INDEX
HAPEX 1230-5-2 COMP "B"
SECTION I - PRODUCT IDENTIFICATION
MANUFACTURER'S NAME - HASTINGS PLASTICS COMPANY
PRODUCT INFORMATION AND SALE - (310) 829-3449
EMERGENCY PHONE NUMBER - (800) 424-9300
PRODUCT NAME - Hapex 1230-5-2 Comp "B"
CHEMICAL FAMILY - Epoxy Resin Hardener
FORMULA - Proprietary
HMIS Rating: - Health = 2 Fire = 1 Reactivity = 1
SECTION II - HAZARDOUS INGREDIENTS
COMPONENTS % CAS # EXPOSURE LIMITS
Phenol, nonyl 62-65 84852-15-3 NONE ASSIGNED
Poly(oxy(methyl-1-2-ethanedyl),alpha-(2-
aminomethylethyl)omega-(2-aminomethyethoxyl)- 30-32 9046-10-0 NONE ASSIGNED
N-eminoethylpiperazine 3-5 140-31-8
SECTION III - PHYSICAL DATA
APPEARANCE AND ODOR - Straw colored liquid, amine odor.
BOILING POINT (/F) - 432?br>
.1 mmhg at 20 c (68 F )
VAPOR PRESSURE (mm HG) -
1
VAPOR DENSITY ( Air = 1 ) -
SPECIFIC GRAVITY
(H20=1) - .960
V.O.C Content - 7 % by ASTM D 2369
(By Volume (%)) - 4.75%(18 grams per liter)
Solubilty in water( % ) - 3-4
SECTION IV - FIRE AND HAZARD EXPLOSION DATA
FLASH POINT /F
- >200 /F (SFCC)
(Method Used)
FLAMMABLE LIMITS % (lower & upper) - not determined
LEL - N/A
EXTINGUISHING MEDIA - Carbon dioxide, dry chemical, foam.
SPECIAL FIRE FIGHTING PROCEDURES - Firefighters should wear special protective clothing &
positive pressure self contained breathing apparatus to avoid inhalation of smoke or vapors.
UNUSUAL FIRE AND EXPLOSION HAZARDS - None known. .
SECTION V - HEALTH EFFECTS DATA
PERMISSIBLE EXPOSURE LEVEL:
Not established.
(over)
EFFECTS OF OVEREXPOSURE:
HAPEX 1230-5-2 "COMP B" MATERIAL SAFETY DATA SHEET PAGE 17 OF 32
INHALATION - May cause nasal irritation, central nervous system depression or lung injury.
EYE CONTACT - Causes irrition,experienced as pain,with excess blinking and tear production,and seen as
extreme redness and swelling of the eye and chemical burns of the eye. Severe eye damage may cause blinness.
SKIN CONTACT - May be corrosive or highly irritation to skin. Repeated contact may cause sensitization
and/or dermatitis.
INGESTION - Causes burning of mouth,throat,and stomach with abdominal and chest
pain,nausea,vomiting,diarrea,thrist,weakness,and collapse. Aspiration may occur during swallowing or vomting,
resulting in lung damage.
EMERGENCY & FIRST AID PROCEDURES:
INHALATION - If ill effects occur remove person to fresh air, keep that person warm and quiet and get
medical attention promptly.
SKIN - Promptly wipe clean with paper or cloths and wash with soap and water. Remove and wash any
contaminated clothing before reuse.
INGESTION - If person is conscious and can swallow, immediately give two glasses of water ( 16oz ),but do
not induce vomiting. This material is corrosive. If vomiting occurs, give fluids again. Hve a physician determine
if condition of patient will parmitinduction of vomiting or evacuation of stomach. Do not give anything by
mouth to an unconscious person
EYES - Flush with plenty of water for 15 minutes and get medical attention.
PRIMARY ROUTE(S) OF ENTRY - Inhalation, ingestion, skin and eye contact.
CARCINOGENICITY - This material does not contain 0.1% or more of any substance which is listed as a
carcinogen by NTP, IARC, or OSHA.
SECTION VI - REACTIVITY DATA
STABILITY - Stable.
CONDITIONS TO AVOID - Reacts violently with acids.
HAZARDOUS POLYMERIZATION - Will not occur.
INCOMPATIBILITY
(Material To Avoid) - Strong oxidizers, acids, bases and epoxy resins under
uncontrolled conditions.
HAZARDOUS DECOMPOSITION
PRODUCTS - Toxic levels of ammonia,comdustion products of nitrogen,carbon
mon0xide, carbon dioxide,irritating aldehydes and ketones may be formed on burning in a limited air supply.
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Ventilate area. Absorb spill with suitable absorbent material and place into a closed container. For large spills,
dike area and pump into closed containers. Prevent this material from entering waterways. Wear protective
equipment during cleanup.
WASTE DISPOSAL METHOD:
At this time, this material or its containers would not be considered hazardous wastes as defined under the
federal RCRA regulations (49CFR 261) if discarded.
Care should be taken to ensure that the material or its containers are disposed of in a approved facility in
accordance with current federal, state, and local regulations.
For further information, contact your state or local waste agency or the United States Environmental Protection
Agency's RCRA hotline (1-800-424-9346 or 202-382-3000).
(next page)
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION - Should be worn to avoid breathing spray mist, heated vapors or
HAPEX 1230-5-2 "COMP B" MATERIAL SAFETY DATA SHEET PAGE 18 OF 32
if TLV is exceeded.
VENTILATION - Local exhaust and general ventilation recommended.
PROTECTIVE GLOVES - Chemical resistant plastic or rubber.
EYE PROTECTION - Chemical goggles.
OTHER PROTECTIVE
EQUIPMENT - As required to prevent wetting skin or clothing.
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING & STORING: This material may cause sensitization. Do
not get in eyes, on skin or clothing. Do not allow contaminated clothing to contact skin. Avoid contact with
vapors or fumes.
OTHER PRECAUTIONS: Wear protective equipment.
SECTION X - SHIPPING INFORMATION
D.O.T. SHIPPING NAME - Amines, liquid, N.O.S. (Nonylphenol Aminoethylpiperazine)
D.O.T. HAZARD CLASS - Corrosive material.
D.O.T. I.D. NUMBER - 8, UN2735, III
REGULATORY INFORMATION:
None
SARA HAZARD CLASSIFICATION:
This material has been categorized as having the following hazard(s) as defined by SARA Title III Regulations
(40 CFR 370): Acute.
SARA SECTION 313 LISTED INGREDIENTS:
This material does not contain any substance which is subject to the reporting requirements of 40 CFR 372.
DISCLAIMER OF LIABILITY
As the conditions or methods of use are beyond our control, we do not assume any
responsibility and expressly disclaim liability for any use of this material. Information
contained herein is believed to be true and accurate but all statements are made without
warranty, express or implied, regarding the accuracy of the information, the hazards
connected with the use of the material or the results to be obtained from the use thereof.
It is the user's obligation to determine the conditions of safe use and the suitability of the
material for the user's purpose.
No Changes at this time
Prepared By: Joe Morales
F#170-21A
PRODUCT DATA
HASTINGS MSDS 1231
PLASTICS *Revised 04/28/09
Replaced 4/19/99
COMPANY
1704 Colorado Ave. Santa Monica, CA 90404 310-829-3449 FAX 310-828-6820
BACK TO INDEX
HAPEX 1231
SECTION I - PRODUCT IDENTIFICATION
MANUFACTURER'S NAME - HASTINGS PLASTICS COMPANY
PRODUCT INFORMATION AND SALE - (310) 829-3449
EMERGENCY PHONE NUMBER - (800) 424-9300
TRADE NAME - Hapex 1231
CHEMICAL FAMILY - Epoxy Resin
CHEMICAL NAME - Formulated Epoxy Resin containing inert additives.
D.O.T. CLASSIFICATION - Not regulated
H.M.I.S. HEALTH - 2 FIRE - 1 REACTIVITY - 1
SECTION II - HAZARDOUS INGREDIENTS
COMPONENTS CAS # % TLV (units)
O-CRESY Diglycidyl Ether 26447-14-3 N/A N/E
PHENOLIC RESIN 9003-35-4 20-26 Not established
BISPHENOL A DIGLYCIDYL 25085-99-8 50-55 Not established
ETHER
SECTION III - PHYSICAL DATA
APPEARANCE AND COLOR - Brown colored paste. Mild aromatic odor.
ODOR - Mild aromatic odor.
BOILING POINT - None.
VAPOR PRESSURE - N/A.
VAPOR DENSITY - N/A.
SPECIFIC GRAVITY (H20=1) - .45 - .50
SOLUBILITY IN WATER - Nil.
PERCENT VOLATILE (By Volume) - 0
EVAPORATION RATE - N/A.
SECTION IV - FIRE AND HAZARD EXPLOSION DATA
FLAMMABILITY CLASS - 3B
FLASH POINT - >200 Deg F
FLAMMABLE LIMITS (In Air % LEL) - N/A.
EXTINGUISHING MEDIA - Foam, Carbon dioxide, dry chemical or fog.
SPECIAL FIRE FIGHTING PROCEDURES - Firefighters should wear goggles and self-contained breathing
apparatus to avoid inhalation of smoke or vapors.
UNUSUAL FIRE AND EXPLOSION HAZARDS - None.
(Over)
HAPEX 1231 REVISED 4/19/99 PAGE 20 OF 32
SECTION V - HEALTH EFFECTS DATA
THRESHOLD LIMIT VALUE - LD50 for rats: greater than 2000 mg/kg.
EFFECTS OF OVEREXPOSURE:
EYES - Minor transient irritation. No corneal injury likely.
SKIN - Only minor irritation. May be a skin sensitizer.
INHALATION - None likely unless heated to high temperatures.
EMERGENCY & FIRST AID PROCEDURES:
EYE CONTACT - Flush with water. Get medical attention if necessary.
SKIN CONTACT - Wash with soap and water. Remove and wash contaminated clothing before reuse.
INHALATION - If ill effects occur remove person to fresh air, keep that person warm and quiet and get
medical attention necessary.
INGESTION - Not likely a problem. If large amounts are swallowed, promptly induce vomiting and get
medical attention.
SECTION VI - REACTIVITY DATA
STABILITY - Stable under normal conditions.
HAZARDOUS POLYMERIZATION - Will not occur.
INCOMPATIBILITY - Strong oxidizers, acids, bases and epoxy hardeners under uncontrolled conditions.
HAZARDOUS DECOMPOSITION
PRODUCTS - Carbon monoxide, carbon dioxide, smoke. Other possible products unknown.
CONDITIONS TO AVOID - Heat and warm storage.
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Ventilate area. Absorb spill
with suitable absorbent material and place into a closed container. For large spills. dike area and pump into
closed containers. Prevent this material from entering waterways. Wear protective equipment during cleanup.
WASTE DISPOSAL METHOD: At this time, this material or its containers would bot be
consideredhazaradous wastes as defined under the federal RCRA regulations (40 CFR 261) if discarded. Care
should be taken to ensure that the material or its containers are disposed of in an approved facility in accordance
with durrent federal, state, and local regulations.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION - None usually necessary under most industrial operating conditions.
MECHANICAL - Good general ventilation usually adequate.
PROTECTIVE GLOVES - Rubber or polyethylene.
EYE PROTECTION - Safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT - Clean long leg and long sleeve clothing.
SECTION IX - REGULATORY INFORMATION
STATUS ON SUBSTANCE LISTS: The concentrations shown are maximum or ceiling levels (weight %) to
be used for calculations for regulations. Trade Secrets are indicated by "TS".
(next page)
HAPEX 1231 REVISED 4/19/99 PAGE 21 OF 32
FEDERAL EPA
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) requires
notification of the National Response of release of quantities of Hazardous Substances Equal to or greater than
the reportable quantities (RQs) in 40 CFR 302.4.
Components present in this product at a level which could require reporting under the statute are:
*** None ***
Superfund Amendments and Reauthorization
Act of 1986 (SARA) Title III
requires emergency planning based on Threshold Planning Quantities (TPQs) and release reporting based on
Reportable Quantities (RQs) in 40 CFR 355 (used for SARA 302, 304, 311 and 312).
Components present in this product at a level which could require reporting under the statute are:
*** None ***
Superfund Amendments and Reauthorization
Act of 1986 (SARA) Title III
requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313).
This information must be included in all MSDs that are copied and distributed for this material.
Components present in this product at a level which could require reporting under the statute are:
*** None ***
STATE RIGHT-TO-KNOW
CALIFORNIA Proposition 65
This product contains trace quantities of formaldehyde, which the State of California has found to cause cancer.
MASSACHUSETTS Right-to-Know, Substance List (MSL) Hazardous Substances and Extraordinarily
Hazardous Substances on the MSL must be identified when present in products.
Components present in this product at a level which could require reporting under the statute are:
HAZARDOUS SUBSTANCES (=>1%)
UPPER BOUND
CHEMICAL CAS NUMBER CONCENTRATION %
Phenol 108-95-2 0.01
Formaldehyde 50-00-0 0.001
PENNSYLVANIA Right-to-Know, Substance List (MSL) Hazardous Substances and Extraordinarily
Hazardous Substances on the MSL must be identified when present in products.
Components present in this product at a level which could require reporting under the statute are:
***None***
Toxic Substances Control Act(TSCA) STATUS:
The ingredients of this product are on the TSCA inventory.
CALIFORNIA SCAQMD RULE 443.1 VOC'S:
None (over)
HAPEX 1231 REVISED 4/19/99 PAGE 22 OF 32
SECTION X - SPECIAL PRECAUTIONS & STORAGE DATA
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Practice good housekeeping to avoid all
skin contact and to avoid breathing vapors, especially those generated when material is heated.
DISCLAIMER OF LIABILITY
As the conditions or methods of use are beyond our control, we do not assume any
responsibility and expressly disclaim liability for any use of this material. Information
contained herein is believed to be true and accurate but all statements are made without
warranty, express or implied, regarding the accuracy of the information, the hazards
connected with the use of the material or the results to be obtained from the use thereof.
It is the user's obligation to determine the conditions of safe use and the suitability of the
material for the user's purpose.
No Changes at this time
Prepared By: Joe Morales
F#170-21A
PRODUCT DATA
HASTINGS MSDS 1240-1
PLASTICS *Revised 4/19/99
Replaces 6/24/91
COMPANY
1704 Colorado Ave. Santa Monica, CA 90404 310-829-3449 FAX 310-828-6820
BACK TO INDEX
HAPEX 1240-1
SECTION I - PRODUCT IDENTIFICATION
MANUFACTURER'S NAME - HASTINGS PLASTICS COMPANY
PRODUCT SALES AND INFORMATION - (310) 829-3449
EMERGENCY PHONE NUMBER - (800) 424-9300
PRODUCT NAME - Hapex 1240-1
PRODUCT CODE NUMBER - 1240-1
CHEMICAL FAMILY - Epoxy Resin
CHEMICAL NAME - Modified Bispnenol A diglycidyl ether
FORMULA - Proprietary
D.O.T. CLASSIFICATION - Not regulated
HMIS: HEALTH - 2 FLAMMABLITY - 1 REACTIVITY - 2
SECTION II - HAZARDOUS INGREDIENTS ACGIH OSHE
COMPONENTS % CAS # TLV PEL
FURFURAL: 2 FURFLDEHYDE 2-3 98-01-1 2 PPM (SKIN) 5 PPM(SKIN)
ETHYLENE GLYCOL MONO ETHYL ETHER 4 - 6 110-80-5 5 PPM (SKIN) 200 PPM(SKIN)
LIMESTONE 10 - 12 1317-65-3 10MG/MF 5MG/MF
BISPHENOL A DIGLYCIDYL ETHER 7 0 - 80 25085-99-8 N/E N/E
SECTION III - PHYSICAL DATA
APPEARANCE AND COLOR - Blue-colored liquid.
ODOR - Mild aromatic odor.
BOILING POINT - None.
VAPOR PRESSURE - N/A.
VAPOR DENSITY - N/A.
SOLUBILITY IN WATER - Nil.
PERCENT VOLATILE (By Volume) - 2
EVAPORATION RATE - N/A.
SPECIFIC GRAVITY - 1.23 - 1.35
SECTION IV - FIRE AND HAZARD EXPLOSION DATA
FLASH POINT - >200 /F
FLAMMABLE LIMITS (In Air % LEL) - Not Applicable
EXTINGUISHING MEDIA - Foam, Carbon dioxide, dry chemical or fog.
SPECIAL FIRE FIGHTING PROCEDURES - Firefighter should wear goggles and self-contained breathing
apparatus to avoid inhalation of smoke or vapors.
UNUSUAL FIRE AND EXPLOSION HAZARDS - None Known
(over)
HAPEX 1240-1 MATERIAL SAFETY DATA SHEET PAGE 24 OF 32
SECTION V - HEALTH EFFECTS DATA
PERMISSIBLE EXPOSURE LEVEL - None Assigned
EFFECTS OF OVEREXPOSURE:
EYES - Mild to moderate irritation, possible minor temporary corneal injury.
SKIN - Mild irritation. May be a skin sensitizer.
INHALATION - May cause nasal irritation, central nervous system depression or lung injury.
EMERGENCY & FIRST AID PROCEDURES:
EYE CONTACT - Flush with water. Get medical attention if necessary.
SKIN CONTACT - Wash with soap and water. Remove and wash contaminated clothing before reuse.
INHALATION - If ill effects occur remove person to fresh air, keep that person warm and quiet and get
medical attention if necessary.
INGESTION - Induce vomiting and consult a physician.
PRIMARY ROUTE(S) OF ENTRY - Inhalation, ingestion, skin and eye contact.
CARCINOGENICITY - This product does not contain 0.1% or more of any substance which is listed as
carcinogen by NTP, IARC, or OSHA.
SECTION VI - REACTIVITY DATA
STABILITY - Stable
HAZARDOUS POLYMERIZATION - Will not occur
INCOMPATIBILITY - Strong owidizers, acids, bases and epoxy hardeners under uncontrolled conditions.
HAZARDOUS DECOMPOSTION PRODUCTS - Carbon monowide, carbon dioxide, smoke. Other possible
products unknown.
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Ventilate area. Absorb spill
with suitable Broadcast absorbent materials, soak up resin and discard.
WASTE DISPOSAL METHOD: Burn in adequate incinerator or bury in approved landfill.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION - None usually necessary under most industrial operating conditions.
MECHANICAL - Good general ventilation usually adequate.
PROTECTIVE GLOVES - Rubber or polyethylene.
EYE PROTECTION - Safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT - Clean long leg and long sleeve clothing.
SECTION IX - SPECIAL PRECAUTIONS & STORAGE DATA
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: This material may cause sensitization. Co
not get in eyes, on skin or clothing. Do not allow contaminated clothing to contact skin. Avoid contact with
vapors or fumes.
OTHER PRECAUTIONS: Wear protective equipment.
SECTION X - REGULATORY INFORMATION
SARA HAZARD CLASSIFICATION:
This material has been categorized as having the following hazard(s) as defined by SARA Title III Regulations
(40 CFR 370): acute.
(next page)
HAPEX 1240-1 MATERIAL SAFETY DATA SHEET PAGE 25 OF 32
SARA SECTION 313 LISTED INGREDIENTS:
This material does not contain any substance which is subject to the reporing requirements of 40 CFR 372.
DOT PROPER SHIPPING NOME: Not regulated by DOT.
UN NUMBER: None
DISCLAIMER OF LIABILITY
As the conditions or methods of use are beyond our control, we do not assume any
responsibility and expressly disclaim liability for any use of this material. Information
contained herein is believed to be true and accurate but all statements are made without
warranty, express or implied, regarding the accuracy of the information, the hazards
connected with the use of the material or the results to be obtained from the use thereof.
It is the user's obligation to determine the conditions of safe use and the suitability of the
material for the user's purpose.
.
Prepared By: Joe Morales
PRODUCT DATA
HASTINGS MSDS 1240-51
PLASTICS *Revised 4/22/99
Replaces 8/28/97
COMPANY
1704 Colorado Ave. Santa Monica, CA 90404 310-829-3449 FAX 310-828-6820
BACK TO INDEX
HAPEX 1240-51
SECTION I - PRODUCT IDENTIFICATION
MANUFACTURER'S NAME - HASTINGS PLASTICS COMPANY
PRODUCT INFORMATION\SALES - (310) 829-3449
EMERGENCY PHONE NUMBER - (800) 424-9300
PRODUCT NAME - Hapex 1240-51
PRODUCT CODE NUMBER - Hapex 1240-51
CHEMICAL FAMILY - Epoxy Resin
CHEMICAL NAME - Modified Bisphanol A Diglycidyl Ether
FORMULA - Proprietary
D.O.T. CLASSIFICATION - Not regulated
HMIS Rating: Health - 2 Fire - 1 Reactivity - 0
SECTION II - HAZARDOUS INGREDIENTS
COMPONENTS CAS # % TLV PEL
BISPHENOL A DIGLYCIDYL ETHER 25085-99-8 36-38 N/E N/E
SILICA 112945-52-5 5-6 N/E N/E
O-CRESYL GLYCIDYL ETHER 26447-14-3 12-14 N/E N/E
AMORPHOUS, FUMED, CRYST.-FREE FELDSPAR 14808-60-7 32-38 0.1mg/m?0.1mg/m?br>
Feldspar, as reported on this Company's MSDS is an anhydrous, inorganic, naturally occurring igneous mineral
rock (sodium, potassium calciium, aluminum silicate) devoid of any asbestos minerals or acicular particles.
These products contain crystalline silica, as quartz up to 13% dry weight. It is non-flammable and non-toxic
and does not begin to fuse until 1950癋 (1065癈).
CARCINOGENICITY: IARC Monograph Vollume 42, 1987 concludes that "there is limited evidence for the
carcinogenicity of crystalline silica to humans." IARC classification 2A. The NTP, in the Sixth Annual Report
on Carcinogens, 1991, has added crystalline silica to its list of substances that are "reasonably anticipated to be
carcinogens".
HAZARD STATEMENT: This material safety data sheet has been prepared in compliance with Federal OSHA
Hazard Communication Standard 29 CFR 1910.1200.This product is considered to be a hazardous chemical
under that standard.
SECTION III - PHYSICAL DATA
APPEARANCE AND COLOR - Translucent Cloudy Paste
ODOR - Mild aromatic odor.
BOILING POINT - N/A
VAPOR PRESSURE - N/A.
VAPOR DENSITY - Nonvolatile
SOLUBILITY IN WATER - Nil.
PERCENT VOLATILE (By Volume) - 0
EVAPORATION RATE - N/A.
SPECIFIC GRAVITY - 1.14 - 1.19
(over)
HAPEX 1240-51 REVISED 4/21/99 PAGE 27 OF 32
SECTION IV - FIRE AND HAZARD EXPLOSION DATA
FLASH POINT /F (Method Used) - >200 closed cup
FLAMMABLE LIMITS (In Air % LEL) - N/A.
EXTINGUISHING MEDIA - Foam, carbon dioxide, dry chemical, water spray.
SPECIAL FIRE FIGHTING PROCEDURES - Firefighters should wear goggles and self-contained breathing
apparatus to avoid inhalation of smoke vapors.
UNUSUAL FIRE AND EXPLOSION HAZARDS - Decomposition and combustion products may be toxic.
SECTION V - HEALTH EFFECTS DATA
THRESHOLD LIMIT VALUE: This product contains crystalline silica which may cause delayed respiratory
disease (silicosis) if inhaled over a prolonged period of time.
OVEREXPOSURE-CHRONIC: Mice receiving skin applications of the Diglycidyl Ether of Bisphenol A or
essentially identical resins for two years have yielded very limited evidence of weak carcinogenicity. The
published report on this study concludes that the resin product "is not a systemic carcinogen when applied to the
skin of CF 1 mice" and the tumor data "was of no biological importance". Based on all available data, IRAC
(International Agency For Research On Cancer) has concluded in 1988 that DGEBPA is not classified as a
carcinogen.
EFFECTS OF OVEREXPOSURE:
EYES - Mild to moderate irritation, possible minor temporary corneal injury.
SKIN - Not likely to be absorbed in toxic amounts.
INHALATION - May cause nasal irritation, central nervous system depression or lung injury.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Allergy, Eczema, Dermatitis
EMERGENCY & FIRST AID PROCEDURES:
EYE CONTACT - Flush with water. Get medical attention if necessary.
SKIN CONTACT - Wash with soap and water. Remove and wash contaminated clothing.
INHALATION - If ill effects occur remove person to fresh air, keep that person warm and quiet and get
medical attention promptly.
INGESTION - If conscious, give large quantities of water. Get immediate medical attention.
OTHER - Promptly remove wet contaminated clothing. Wash before reuse.
PRIMARY ROUTE(S) OF EXPOSURE:
ORAL LD50 - (RAT) >5,000 mg/kg
DERMAL LD50 - (RAT) >2100 mg/kg
SKIN IRRITATION - (RABBIT) Mild Irritation
EYE IRRITATION - (RABBIT) None
SENSITIZATION - (GUINEA PIG) Sensitizer
INHALATION LC50 - (RAT) 6.1 mg/L for a 4 hour exposure; toxic by inhalation (minor ingredient)
CARCINOGENICITY: This product does not contain 0.1% or more of any substance which is listed as
carcinogen by NTP, IARC or OSHA.
SECTION VI - REACTIVITY DATA
STABILITY - Stable.
HAZARDOUS - Will not occur.
POLYMERIZATION INCOMPATIBILITY - Strong oxidizing agents.
HAZARDOUS DECOMPOSITION
PRODUCTS - Carbon monoxide, carbon dioxide, aldehydes.
CONDITIONS TO AVOID - Elevated temperatures, strong acids & bases in bulk.
(next page)
SECTION VII - SPILL OR LEAK PROCEDURES
HAPEX 1240-51 REVISED 4/21/99 PAGE 28 OF 32
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Ventilated area. Absorb spill
with suitable absorbent material and place into a closed container. For large spills, dike area and pump into
closed containers. Prevent this material from entering waterways. Wear protective equipment during cleanup.
WASTE DISPOSAL METHOD: At this time, this material or its containers would not be considered hazardous
wastes as defined under the federal RCRA regulations (40 CFR 261) if discarded. Care should be taken to
ensure that the material or its containers are disposed of in an approved facility in accordance with current
Federal, State, and Local regulations.
COMMUNITY RIGHT TO KNOW: Feldspar is regulated under EPCRA (SARA Title III). Reports should be
made as required by this Act. Calfornia's Proposition 65 lists crystalline silica as a carcinogen.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION - Use NIOSH approved respirator suitable for organic vapors, if required.
VENTILATION - Local exhaust and general ventilation recommended
PROTECTIVE GLOVES - Rubber or polyethylene.
EYE PROTECTION - Safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT - Prot ective equiptment to avoid personal contact.
SECTION IX - SPECIAL PRECAUTIONS & STORAGE DATA
HMIS CODE - HEALTH: 2 FIRE: 1 REACTIVITY: 0
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: This material may cause sensitization.
Do not get in eyes, on skin or clothing. Do not allow contaminated clothing to contact skin. Avoid contact with
vapors or fumes. Store in tightly closed containers in cool, dry area. Wash thoroughly after handling.
SECTION X - SUPPLEMENTAL INFORMATION
REGULATORY INFORMATION: None
SARA HAZARD CLASSIFICATION: This material has been categorized as having the following hazard(s) as
defined by SARA Title III regulations (40 CFR 370): acute
SARA SECTION 313 LISTED INGREDIENTS: This material does not contain any substance which is subject
to the reporting requirements of 40 CFR 372.
DOT PROPER SHIPPING NAME: Not regulated by DOT
UN NUMBER: None
RCRA STATUS: Not a hazardous waste under RCRA (40 CFR 261)
CERCLA STATUS: Not listed
TSCA INVENTORY STATUS: Chemical components listed on TSCA inventory.
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JERSEY RIGHT TO KNOW LABELING INFORMATION - This product contains the following :
HAPEX 1240-51 REVISED 4/21/99 PAGE 29 OF 32
I. CHEMICAL NAME CAS NUMBER
Phenol, 4-4'-(1-Methylethylidene) 25068-38-6
Bis-, Polymer with (Chloromethyl)Oxirane
Oxirane, {(Methylphenoxy)Methyl} 26447-14-3
PENNSYLVANIA RIGHT TO KNOW ACT - The following is required composition information:
I. CHEMICAL NAME CAS NUMBER
Phenol, 4-4'-(1-Methylethylidene) 25068-38-6
Polymer with (Chloromethyl)oxirane
COMMMON NAME COMMENTS
Bisphenol A Epoxy Resin Not on Pennsylvania Hazardous Substance List
II. CHEMICAL NAME CAS NUMBER
Oxirane, {(Methylphenoxy)Methyl} 26447-14-3
COMMON NAME COMMENTS
Cresyl Glycidyl Ether Not on Pennsylvania Hazardous Substance List
HAZARDOUS PRODUCTS INFORMATION ACT - This product contains the following ingredients which are
Controlled Products and/or on the Ingredient Disclosure List (Canadian HPA section 13 and 14):
COMPONENTS CAS NUMBER AMOUNT %w/w
Reaction product of 25085-99-8 70 - 78%
epichlorohydrin &
bisphenol A
DISCLAIMER OF LIABILITY
As the conditions or methods of use are beyond our control, we do not assume any
responsibility and expressly disclaim liability for any use of this material. Information
contained herein is believed to be true and accurate but all statements are made without
warranty, express or implied, regarding the accuracy of the information, the hazards
connected with the use of the material or the results to be obtained from the use thereof.
It is the user's obligation to determine the conditions of safe use and the suitability of the
material for the user's purpose.
Prepared By: Joe Morales
F#170-21A
PRODUCT DATA
HASTINGS MSDS 1290
PLASTICS *REVISED 4/22/99
REPLACES 3/20/92
COMPANY
1704 Colorado Ave. Santa Monica, CA 90404 310-829-3449 FAX 310-828-6820
BACK TO INDEX
HAPEX 1290
SECTION I - PRODUCT IDENTIFICATION
MANUFACTURER'S NAME - HASTINGS PLASTICS COMPANY
PRODUCT INFORMATION AND SALES - (310) 829-3449
EMERGENCY PHONE NUMBER - (800) 424-9300
PRODUCT NAME - Hapex 1290
PRODUCT CODE NUMBER - 1290
CHEMICAL FAMILY - Epoxy Resin
CHEMICAL NAME - Modified Bisphanol A Diglycidyl Ether
FORMULA - Proprietary
D.O.T. CLASSIFICATION - Not regulated
HMIS Rating: Health - 2 Fire - 1 Reactivity - 1
SECTION II - HAZARDOUS INGREDIENTS
COMPONENTS CAS # % TLV (units)
BISPHENOL A DIGLYCIDYL ETHER 25085-99-8 100 N/A
SECTION III - PHYSICAL DATA
APPEARANCE AND COLOR - Straw colored liquid.
ODOR - Mild aromatic odor.
BOILING POINT - None.
VAPOR PRESSURE - N/A.
VAPOR DENSITY - Nonvolatile
SOLUBILITY IN WATER - Nil.
PERCENT VOLATILE (By Volume) - 0
EVAPORATION RATE - N/A.
SECTION IV - FIRE AND HAZARD EXPLOSION DATA
FLASH POINT /F (Method Used) - >200
FLAMMABLE LIMITS (In Air % LEL) - N/A.
EXTINGUISHING MEDIA - Foam, carbon dioxide, dry chemical or fog.
SPECIAL FIRE FIGHTING PROCEDURES - Firefighters should wear goggles and self-contained breathing
apparatus to avoid inhalation of smoke vapors
UNUSUAL FIRE AND EXPLOSION HAZARDS - None.
SECTION V - HEALTH EFFECTS DATA
THRESHOLD LIMIT VALUE - None assigned
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HAPEX 1290 REVISED 4/22/99 PAGE 31 OF 32
EFFECTS OF OVEREXPOSURE:
EYES - Mild to moderate irritation, possible minor temporary corneal injury.
SKIN - Not likely to be absorbed in toxic amounts.
INHALATION - May cause nasal irritation, central nervous system depression or lung injury.
EMERGENCY & FIRST AID PROCEDURES:
EYE CONTACT - Flush with water. Get medical attention if necessary.
SKIN CONTACT - Wash with soap and water. Remove and wash contaminated clothing.
INHALATION - If ill effects occur remove person to fresh air, keep that person warm and quiet and get
medical attention promptly.
INGESTION - Not likely a problem. If large amounts are swallowed, promptly induce vomiting and get
medical attention.
PRIMARY ROUTE(S) OF ENTRY: Inhalation, ingestion, skin and eye contact.
CARCINOGENICITY: This product does not contain 0.1% or more of any substance which is listed as
carcinogen by NTP, IARC or OSHA.
SECTION VI - REACTIVITY DATA
STABILIT - Stable under normal conditions.
HAZARDOUS POLYMERIZATION - Will not occur.
INCOMPATIBILITY - Strong oxidizers, acids, bases and epoxy hardeners under uncontrolled conditions.
HAZARDOUS DECOMPOSITION PRODUCTS - Carbon monoxide, carbon dioxide, smoke. Other possible
products unknown.
CONDITIONS TO AVOID - Heat and warm storage.
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Ventilated area. Absorb spill
with suitable absorbent material and place into a closed container. For large spills, dike area and pump into
closed containers. Prevent this material from entering waterways. Wear protective equipment during cleanup.
WASTE DISPOSAL METHOD: At this time, this material or its containers would not be considered hazardous
wastes as defined under the federal RCRA regulations (40 CFR 261) if discarded. Care should be taken to
ensure that the material or its containers are disposed of in an approved facility in accordance with current
Federal, State, and Local regulations.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION - Should be warn to avoid breathing spray mist, heated vapors or if TLV is
exceeded.
VENTILATION - Local exhaust and general ventilation recommended
PROTECTIVE GLOVES - Rubber or polyethylene.
EYE PROTECTION - Safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT - As required to prevent wetting skin or clothing.
SECTION IX - SPECIAL PRECAUTIONS & STORAGE DATA
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: This material may cause sensitization.
Do not get in eyes, on skin or clothing. Do not allow contaminated clothing to contact skin. Avoid contact with
vapors or fumes.
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HAPEX 1290 REVISED 4/22/99 PAGE 32 OF 32
OTHER PRECAUTIONS: Wear protective equipment.
SECTION X - SUPPLEMENTAL INFORMATION
REGULATORY INFORMATION: None
SARA HAZARD CLASSIFICATION: This material has been categorized as having the following hazard(s) as
defined by SARA Title III regulations (40 CFR 370): acute
SARA SECTION 313 LISTED INGREDIENTS: This material does not contain any substance which is subject
to the reporting requirements of 40 CFR 372.
DOT PROPER SHIPPING NAME: Not regulated by DOT
UN NUMBER: None
DISCLAIMER OF LIABILITY
As the conditions or methods of use are beyond our control, we do not assume any responsibility
and expressly disclaim liability for any use of this material. Information contained herein is
believed to be true and accurate but all statements are made without warranty, express or implied,
regarding the accuracy of the information, the hazards connected with the use of the material or
the results to be obtained from the use thereof. It is the user's obligation to determine the
conditions of safe use and the suitability of the material for the user's purpose.
Prepared By: Joe Morales
F#170-21A
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