The Full Text for all R-Phrases are Displayed in Section 16
3 HAZARDS IDENTIFICATION
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful in contact with skin and if
swallowed. Causes burns. May cause sensitisation by skin contact.
CLASSIFICATION Xn;R21/22. C;R34. R43. N;R51/53.
HUMAN HEALTH
Corrosive. Prolonged contact causes serious eye and tissue damage.
4 FIRST-AID MEASURES
GENERAL INFORMATION
In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Do not breathe vapour/spray. Avoid
contact with eyes.
INHALATION
Move the exposed person to fresh air at once. Contact physician if discomfort continues.
INGESTION
Do not induce vomiting. Drink plenty of water. Get medical attention.
SKIN CONTACT
Remove affected person from source of contamination. Wash skin thoroughly with soap and water for several minutes. Contact physician if
irritation persists.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
Contact physician if irritation persists.
5 FIRE-FIGHTING MEASURES
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PUTTY HARDENER
EXTINGUISHING MEDIA
Fire can be extinguished using: Water. Foam. Dry chemicals. Carbon dioxide (CO2).
SPECIAL FIRE FIGHTING PROCEDURES
Keep up-wind to avoid fumes. Avoid water in straight hose stream; will scatter and spread fire. Keep run-off water out of sewers and water
sources. Dike for water control.
SPECIFIC HAZARDS
Avoid breathing fire vapours.
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Avoid contact with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Provide adequate ventilation.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY
alerted to the Environmental Agency or other appropriate regulatory body.
SPILL CLEAN UP METHODS
Absorb spillage with non-combustible, absorbent material. Transfer to a container for disposal. Containers with collected spillage must be
properly labelled with correct contents and hazard symbol.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Use only in well-ventilated areas. Provide good ventilation. Avoid inhalation of vapours. Avoid contact with skin and eyes. Do not eat,
drink or smoke when using the product. Do not use in confined spaces without adequate ventilation and/or respirator. Observe good
industrial hygiene practices.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry and cool place.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
PROTECTIVE EQUIPMENT
PROCESS CONDITIONS
Provide eyewash, quick drench.
ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
If ventilation is insufficient, suitable respiratory protection must be provided.
HAND PROTECTION
Use protective gloves made of: Rubber or plastic.
EYE PROTECTION
Wear approved chemical safety goggles where eye exposure is reasonably probable.
HYGIENE MEASURES
Keep away from food, drink and animal feeding stuffs. Good personal hygiene is necessary. Wash hands and contaminated areas with
water and soap before leaving the work site. Do not eat, drink or smoke when using the product. Change work clothing daily before leaving
work place.
SKIN PROTECTION
Avoid contact with skin. Wear apron or protective clothing in case of contact.
PUTTY HARDENER
ODOUR Amine.
SOLUBILITY Soluble in water
BOILING POINT (癈) RELATIVE DENSITY
>232 0.98 20 篊
VAPOUR PRESSURE pH-VALUE, CONC. SOLUTION
<0.01 mmHg 10.5 @ 20 篊
FLASH POINT (癈) >93
10 STABILITY AND REACTIVITY
STABILITY
Stable under normal temperature conditions and recommended use.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition. Avoid excessive heat for prolonged periods of time. Avoid exposure to high
temperatures or direct sunlight.
MATERIALS TO AVOID
Avoid contact with acids and oxidising substances.
HAZARDOUS DECOMPOSITION PRODUCTS
Fire or high temperatures create: Nitrous gases (NOx). Oxides of: Carbon monoxide (CO). Carbon dioxide (CO2). Vapours/gases/fumes
of: Ammonia or amines.
11 TOXICOLOGICAL INFORMATION
TOXIC DOSE 1 - LD 50 2000 mg/kg (oral rat)
INHALATION
Vapour from this chemical can be hazardous when inhaled.
INGESTION
Harmful if swallowed.
SKIN CONTACT
May be absorbed through the skin. Prolonged or repeated exposure may cause severe irritation. May cause sensitisation by skin contact.
Risk of sensitisation or allergic reactions among sensitive individuals.
EYE CONTACT
Risk of serious damage to eyes.
HEALTH WARNINGS
Causes burns.
ROUTE OF ENTRY
Inhalation. Skin absorption. Ingestion. Skin and/or eye contact.
TARGET ORGANS
Prolonged or repeated exposure may cause: Risk of serious damage to eyes. May cause damage to the liver. May cause damage to the
kidneys. Central and/or peripheral nervous system damage.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Avoid release to the environment. The product contains substances which are toxic to aquatic organisms and which may cause long term
adverse effects in the aquatic environment.
MOBILITY
The product is soluble in water. Do not discharge into drains, water courses or onto the ground.
WATER HAZARD CLASSIFICATION
WGK 2
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.
WASTE CLASS
08 04 99
14 TRANSPORT INFORMATION
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PUTTY HARDENER
GENERAL The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
15 REGULATORY INFORMATION
LABELLING
Dangerous for the
Corrosive
environment
CONTAINS
2-PIPERAZIN-1-YLETHYLAMINE
TRIETHYLENETETRAMINE
RISK PHRASES
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
SAFETY PHRASES
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label
where possible).
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
16 OTHER INFORMATION
REVISION DATE 10/08/2005
REV. NO./REPL. SDS GENERATED 8
DATE 06.01.05
RISK PHRASES IN FULL
R21 Harmful in contact with skin.
R21/22 Harmful in contact with skin and if swallowed.
R22 Harmful if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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