10988 - THERMAL BONDING SYSTEM REVISION DATE:NOVEMBER 2003
SAFETY DATA SHEET
THERMAL BONDING SYSTEM
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY:
PRODUCT NAME: THERMAL BONDING SYSTEM
PART No.: ETBS-B
SUPPLIER: H K WENTWORTH PTY LIMITED
P.O. BOX 339
BROOKVALE, NSW 2100
AUSTRALIA
Tel: 02 9938 1566
Fax: 02 9938 1566
2. COMPOSITION/INFORMATION ON INGREDIENTS:
NAME CONTENT
CAS No.: EINECS Nr.: CLASSIFICATION
TRIETHYLENETETRAMINE 5-10 %
112-24-3 203-950-6 C R-21, 34, 43, 52/53
4,4'-METHYLENEDIANILINE 1-5 %
T ,N R-45, 39/23/24/25, 43, 48/20/21/22, 51/53 Carc2
101-77-9 202-974-4
Mut3
ZINC OXIDE 30-60 %
1314-13-2 N R-50/53
The Full Text for all R-Phrases are Displayed in Section 16
3. HAZARDS IDENTIFICATION:
Irritating to eyes and skin. May cause sensitisation by skin contact. May cause cancer.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment. Harmful: possible risk of irreversible effects through inhalation, in contact
with skin and if swallowed. Carcinogen Category 2. Mutagen Category 3.
HAZARDOUS SUBSTANCE: DANGEROUS GOODS
4. FIRST AID MEASURES:
GENERAL: Move the exposed person to fresh air at once. Get medical attention if any discomfort
continues.
INHALATION: Move the exposed person to fresh air at once. Provide rest, warmth and fresh air. Get
medical attention if any discomfort continues. Perform artificial respiration if breathing
has stopped. When breathing is difficult, properly trained personnel may assist affected
person by administering 100% oxygen. Get medical attention.
INGESTION: DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT
OR DRINK FLUIDS! Rinse mouth thoroughly. Provide rest, warmth and fresh air. Get
medical attention immediately!
SKIN: Remove affected person from source of contamination. Wash the skin immediately with
soap and water. Get medical attention promptly if symptoms occur after washing.
EYES: Remove victim immediately from source of exposure. Make sure to remove any contact
lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while
lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
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10988 - THERMAL BONDING SYSTEM REVISION DATE:NOVEMBER 2003
5. FIRE FIGHTING MEASURES:
EXTINGUISHING MEDIA: Fire can be extinguished using: Foam. Dry chemicals, sand, dolomite etc.
DO NOT use water if avoidable.
6. ACCIDENTAL RELEASE MEASURES:
SPILL CLEANUP METHODS: Wear necessary protective equipment. Stop leak if possible without risk. DO NOT touch
spilled material. Absorb in vermiculite, dry sand or earth and place into containers.
7. HANDLING AND STORAGE:
USAGE PRECAUTIONS: Avoid spilling, skin and eye contact. Keep away from heat, sparks and open flame.
Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is
above accepted level.
STORAGE PRECAUTIONS: Keep in cool, dry, ventilated storage and closed containers. Keep in original container.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION:
INGREDIENT NAME: CAS No.: STD LT EXP 8 Hrs ST EXP 15 Min
4,4'-METHYLENEDIANILINE 101-77-9 MEL 0.08 mg/m3
INGREDIENT COMMENTS: MEL = Maximum Exposure Limit.
PROTECTIVE EQUIPMENT:
VENTILATION: Provide adequate general and local exhaust ventilation.
RESPIRATORS: No specific recommendation made, but respiratory protection must be used if the
general level exceeds the Occupational Exposure Level (OEL).
PROTECTIVE GLOVES: Use protective gloves.
EYE PROTECTION: Wear approved safety goggles.
OTHER PROTECTION: Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
prolonged vapour contact.
HYGIENIC WORK PRACTICES: DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before
eating, smoking and using the toilet. Wash promptly with soap & water if skin becomes
contaminated. Promptly remove any clothing that becomes contaminated. No eating or
drinking while working with this material.
9. PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: Paste or slurry.
COLOUR: Cream.
SOLUBILITY DESCRIPTION: Immiscible with water.
>100
FLASH POINT (癈): Method:
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10988 - THERMAL BONDING SYSTEM REVISION DATE:NOVEMBER 2003
10. STABILITY AND REACTIVITY:
STABILITY: Normally stable.
CONDITIONS TO AVOID: Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidisers.
HAZARDOUS DECOMP. Fire creates: Acrid smoke/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
PRODUCTS:
11. TOXICOLOGICAL INFORMATION:
INHALATION: Harmful: possible risk of irreversible effects through inhalation.
INGESTION: Harmful: possible risk of irreversible effects if swallowed. May cause stomach pain or
vomiting.
SKIN: Harmful: possible risk of irreversible effects in contact with skin. May cause
sensitisation by skin contact.
EYES: Irritating to eyes.
HEALTH WARNINGS: Known or suspected carcinogen for humans. Known or suspected mutagen.
OTHER HEALTH EFFECTS: Carcinogen Category 2. Mutagen Category 3.
12. ECOLOGICAL INFORMATION:
ECOLOGICAL INFORMATION: Dangerous for the environment if discharged into watercourses.
13. DISPOSAL CONSIDERATIONS:
DISPOSAL METHODS: Dispose of in accordance with Local Authority requirements.
14. TRANSPORT INFORMATION:
LABEL FOR CONVEYANCE:
UN No. ROAD: 2735
UK ROAD TRANSPORT CLASS: 8
UK ROAD PACK GR.: III
ADR CLASS No.: 8
ADR CLASS: Class 8: Corrosive substances.
ADR ITEM No.: III
ADR LABEL No.: 8
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10988 - THERMAL BONDING SYSTEM REVISION DATE:NOVEMBER 2003
HAZCHEM CODE: 3X
CEFIC TEC(R) No.: 80GC7-II+III
PROPER SHIPPING NAME I: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE,
N.O.S (TRIETHYLENETETRAMINE)
RID CLASS No.: 8
RID ITEM No.: III
UN No. SEA: 2735
IMDG CLASS: 8
IMDG PACK GR.: III
EmS No.: F-A; S-B
MFAG TABLE No.: See Guide
MARINE POLLUTANT: No.
UN No., AIR: 2735
ICAO CLASS: 8
AIR PACK GR.: III
15. REGULATORY INFORMATION:
LABEL FOR SUPPLY:
RISK PHRASES: R-36/38 Irritating to eyes and skin.
R-43 May cause sensitisation by skin contact.
R-45 May cause cancer.
R-50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R-68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in
contact with skin and if swallowed.
SAFETY PHRASES: P-11 Restricted to professional users.
S-24/25 Avoid contact with skin and eyes.
S-36/37 Wear suitable protective clothing and gloves.
S-38 In case of insufficient ventilation, wear suitable respiratory equipment.
S-45 In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
S-53 Avoid exposure - obtain special instructions before use.
ENVIRONMENTAL LISTING: Rivers (Prevention of Pollution) Act 1961. Control of Pollution (Special Waste
Regulations) Act 1980.
EU DIRECTIVES: System of specific information relating to Dangerous Preparations. 91\155. Dangerous
Substance Directive 67\548. Dangerous Preparations Directive 88\379.
STATUTORY INSTRUMENTS: Chemicals (Hazard Information and Packaging) Regulations. Control of Substances
Hazardous to Health.
APPROVED CODE OF PRACTICE: Classification and Labelling of Substances and Preparations Dangerous for Supply.
Safety Data Sheets for Substances and Preparations L62.
GUIDANCE NOTES: Occupational Exposure Limits EH40. Introduction to Local Exhaust Ventilation
HS(G)37. CHIP for everyone HSG(108).
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10988 - THERMAL BONDING SYSTEM REVISION DATE:NOVEMBER 2003
16. OTHER INFORMATION:
USER NOTES: CN No 39073000
REVISION COMMENTS: Revised in accordance with CHIP3 and EU Directive 1999/45/EC
ISSUED BY: Helen O'Reilly
REVISION DATE: NOVEMBER 2003
REV. No./REPL. SDS GENERATED: 1
SDS No.: 10988
DISCLAIMER: This information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process unless
specified in the text. The information contained in this safety data sheet is correct to the
best of our knowledge, information and belief at the date of its publication. The
information given is designed only as guidance for the safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or
quality specification
R-PHRASES (Full Text): R-45 May cause cancer. R-39/23/24/25 Toxic: danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed. R-43 May cause
sensitisation by skin contact. R-48/20/21/22 Harmful: danger of serious damage to
health by prolonged exposure through inhalation, in contact with skin and if swallowed.
R-51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment. R-21 Harmful in contact with skin. R-34 Causes burns. R-52/53
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment. R-50/53 Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
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