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MSDS Material Safety Data Sheet
CAS

32610-77-8 112-24-3 108-95-2

File Name: 32610-77-8_112-24-3_108-95.asp

Page 1                                                                                                 4/22/05
MATERIAL SAFETY DATA SHEET

SECTION 1 - MATERIAL IDENTIFICATION

Neptune Research, Inc.
1683 Latham Road
West Palm Beach, Florida 33409

Emergency Telephone 800-255-3924

PRODUCT TRADE NAME: Quick Setting Epoxy-Catalyst
CHEMICAL FAMILY: ALIPHATIC AMINES
FORMULA: PROPRIETARY MIXTURE / TRADE SECRET

EMERGENCY OVERVIEW:

HMIS HEALTH 2 FLAMMABILITY 1 REACTIVITY 0

PHYSICAL FORM: Viscous liquid COLOR: Amber ODOR: Phenolic

HAZARDS: Severe eye irritant. Moderate skin irritant. May cause skin sensitization.

EXTINGUISHING MEDIA : Ignition will give rise to a Class B fire. In case of large fire use: alcohol foam,
water spray. In case of small fire use: carbon dioxide (CO2), dry chemical, dry sand or limestone.

C.A.S. CHEMICAL NAME: Mixture SYNONYMS: None EMPIRICAL FORMULA: Mixture

INTENDED USE: Epoxy Curing Agent

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS

Num % CAS Number Chemical Name
1. =50.00 32610-77-8 REACTION PRODUCTS MIXTURE
2. =20.00 112-24-3 TRIETHYLENETETRAMINE
3. =30.00 108-95-2 PHENOL

This product is a proprietary mixture of different ingredients. All ingredients are on the TSCA inventory or
are not required to be listed on the TSCA inventory. This is not intended to be complete compositional
disclosure.

OSHA (ACGIH) EXPOSURE LIMITS

TWA STEL CEILING
ppm mg/m3 ppm mg/m 3 ppm mg/m3

1. OSHA N/E N/E N/E N/E N/E N/E
ACGIH N/E N/E N/E N/E N/E N/E

2. OSHA N/E N/E N/E N/E N/E N/E
ACGIH N/E N/E N/E N/E N/E N/E

3. OSHA 5.0 19(Skin) N/E N/E N/E N/E
ACGIH 5.0 19(Skin) N/E N/E N/E N/E
N/E = Not Established.
Page 2
SECTION 3 - HEALTH HAZARDS

ROUTES OF EXPOSURE: Eye Contact, Skin Contact, Ingestion, and Skin Absorption.

EXPOSURE STANDARDS: See Section 2 for exposure standards on ingredients. Maintain air contaminant
concentrations in the workplace at the lowest feasible levels.

HEALTH HAZARDS: Severe eye irritant. Moderate skin irritant. May cause skin sensitization.

TARGET ORGANS: Eye, Skin, Liver or the hepatic system, Kidney, Spleen, Pancreas

SIGNS AND SYMPTOMS OF EXPOSURE (Acute effects): Contact with eyes causes severe irritation and
pain. Contact with skin causes irritation, redness and discomfort which is transient. Inhalation of mists may
cause irritation in the respiratory tract. Coughing and chest pain may result. Risk of exposure to hazardous
concentrations of vapor under normal working conditions in a well ventilated space is minimal. However,
conditions such as spraying, or sudden release of hot liquid, which generate an aerosol, mists or fog should
be avoided. Product is readily absorbed through the skin and may cause nausea, headache and general
discomfort.

SIGNS AND SYMPTOMS OF EXPOSURE (Possible Longer Term Effects): Repeated and/or prolonged
exposure may cause allergic reaction/sensitization. Repeated and/or prolonged exposures may result in:
liver disorders (such as jaundice or liver enlargement), kidney disorders (such as edema, or proteinuria),
adverse eye effects (such as conjunctivitis or corneal damage), adverse skin effects (such as rash, irritation
or corrosion).

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Eye disease, Kidney disorders,
Liver disorders, Skin disorders and Allergies

CARCINOGENS UNDER OSHA, ACGIH, NTP, IARC: This product contains no listed carcinogens in
concentrations of 0.1 percent or greater.

SECTION 4 - FIRST AID

EYE CONTACT: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Seek medical advice.

SKIN CONTACT: Remove contaminated clothing and shoes. Remove product and immediately flush
affected area with water for at least 15 minutes. Destroy contaminated leather apparel. Seek medical advice.
Launder contaminated clothing prior to reuse.

INHALATION: Move patient to fresh air. If breathing has stopped or is labored give assisted respiration (e.g.
mouth-to-mouth). Supplemental oxygen may be indicated. Seek medical advice. Prevent aspiration of
vomit. Turn victim's head to the side.

INGESTION: If swallowed, call a physician immediately. Remove stomach contents by gastric suction or
induce vomiting only as directed by medical personnel. Never give anything by mouth to an unconscious
person.
SECTION 5 - FIRE AND EXPLOSION DATA

FLASH POINT (closed cup): 135.56 C (276.01 F) AUTOIGNITION TEMPERATURE: No Data

UPPER EXPLOSION LIMIT (UEL): No Data LOWER EXPLOSION LIMIT (LEL): No Data
Page 3
SECTION 5 - FIRE AND EXPLOSION DATA CONTINUED

FIRE HAZARD CLASSIFICATION (OSHA/NFPA): Class IIIB

EXTINGUISHING MEDIA: Ignition will give rise to a Class B fire. In case of large fire use: water spray,
alcohol foam. In case of small fire use: carbon dioxide (CO2), dry chemical, dry sand or limestone.

SPECIAL FIRE FIGHTING PROCEDURES: Firefighters sho uld wear butyl rubber boots, gloves, and body
suit and a self-contained breathing apparatus.

UNUSUAL FIRE AND EXPLOSION HAZARDS: May generate toxic or irritating combustion products.
Sudden reaction and fire may result if product is mixed with an oxidizing agent. May generate carbon
monoxide gas. May generate toxic nitrogen oxide gases. May generate ammonia gas. Personnel in vicinity
and downwind should be evacuated.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

CONTAINMENT TECHNIQUES (Removal of ignition sources, diking etc): Stop the leak, if possible. Reduce
vapor spreading with a water spray. Shut off or remove all ignition sources. Construct a dike to prevent
spreading (includes molten liquids until they freeze).

CLEAN-UP PROCEDURES: If recovery is not feasible, admix with dry soil, sand or non-reactive absorbent
and place in an appropriate chemical waste container. Transfer to containers by suction, preparatory for
later disposal. Flush area with water spray. Clean-up personnel must be equipped with self contained
breathing apparatus and butyl rubber protective clothing. For large spills, recover spilled material with a
vacuum truck.

OTHER EMERGENCY ADVICE: Wear protective clothing, boots, gloves, and eye protection.

SECTION 7 - HANDLING AND STORAGE

STORAGE: Keep away from: acids, oxidizers. Keep in cool, dry, ventilated storage and in closed containers.
Do not store in reactive metal containers.

HANDLING: Avoid contact with skin or eyes. When handling, do not eat, drink, or smoke. Avoid using in any
spray application without strict conformance to all applicable electrical codes and the OSHA limit for
maximum allowable airborne concentrations.

OTHER PRECAUTIONS: Emergency showers and eye wash stations should be readily accessible. Adhere
to work practice rules established by government regulations (e.g. OSHA). Do not use sodium nitrite or other
nitrosating agents in formulations containing this product. Cancer-causing nitrosamines could be formed.

SECTION 8 - PERSONAL PROTECTION / EXPOSURE CONTROLS

EYE PROTECTION: Splash-proof eye goggles. In emergency situations, use eye goggles with a full face
shield.

HAND PROTECTION: Neoprene rubber gloves. Impermeable gloves. Cuffed butyl rubber gloves. Nitrile
rubber gloves. Polyvinyl chloride gloves. Rubber Gloves. The breakthrough time of the selected glove(s)
must be greater than the intended use period.

RESPIRATORY PROTECTION: Not required under normal conditions in a well-ventilated workplace. Under
the following conditions a respirator may be required: when product vapor concentration exceeds the limits
listed in section 2, during repair and cleaning of equipment, during transfer or discharge of the product,
Page 4
SECTION 8 - PERSONAL PROTECTION / EXPOSURE CONTROLS CONTINUED

sampling, spray applications. Types of respirators that may be used include the following: Chemical
Cartridge Respirator with face piece to protect against the organic vapor, Supplied air respirator with full
face piece (NIOSH Approved), Self-contained breathing apparatus in pressure demand mode. In emergency
conditions use a self-contained breathing apparatus in pressure demand mode.

PROTECTIVE CLOTHING: Long sleeved clothing.

ENGINEERING CONTROLS: Maintain air concentrations in work spaces in accord with standards outlined
in Sections 2 and 3.

WORK AND HYGIENIC PRACTICES: Provide readily accessible eye wash stations and safety showers.
Wash at the end of each workshift and before eating, smoking or using the toilet. Discard contaminated
leather articles.

SECTION 9 - TYPICAL PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: Viscous liquid COLOR: Yellowish to Amber ODOR: Phenolic

PH: Alkaline VAPOR PRESSURE (mm Hg at 21C (70F)): <1.00 BOILING POINT: >230.00 C (>446.00 F)

SOLUBILITY IN WATER (%): = 5.0 SPECIFIC GRAVITY: (Water = 1): 1.0

SECTION 10 - STABILITY AND REACTIVITY

CHEMICAL STABILITY: Stable

CONDITIONS TO AVOID (if unstable): Not applicable

INCOMPATIBILITY (Materials to A void): Mineral acids (i.e. sulfuric, phosphoric, etc.). Organic acids (i.e.
acetic acid, citric acid etc.). Oxidizing Agents (i.e. perchlorates, nitrates etc.). Reactive metals (i.e. sodium,
calcium, zinc etc.). Sodium or Calcium Hypochlorite. CAUTION! N-Nitrosamines, many of which are known
to be potent carcinogens, may be formed when the product comes in contact with nitrous acid, nitrites or
atmospheres with high nitrous oxide concentrations. Product slowly corrodes copper, aluminum, zinc and
galvanized surfaces. Reaction with peroxides may result in violent decomposition of peroxide possibly
creating an explosion. Materials reactive with hydroxyl compounds. Nitrites, nitrosating agents. A reaction
accompanied by large heat release occurs when the product is mixed with acids. Heat generated may be
sufficient to cause vigorous boiling creating a hazard due to splashing or splattering of hot material.

HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxide can react with water vapors to form
corrosive nitric acid (TLV=2 ppm). Carbon Monoxide in a fire. Carbon Dioxide in a fire. Ammonia when
heated. Nitrogen Oxides in a fire. Irritating and toxic fumes at elevated temperatures. Nitric acid in a fire.
nitrosamines. Aldehydes. The oxides of nitrogen gases (except nitrous oxide) emitted on decomposition are
highly toxic.

HAZARDOUS POLYMERIZATION: Will not occur
Page 5
SECTION 11 - TOXICOLOGICAL PROPERTIES

ACUTE ORAL TOXICITY (LD50, RAT): 2200.00 mg/kg

ACUTE INHALATION TOXICITY (LC50, RAT): >10.00 mg/L / 1 hr (No deaths) (Estimate)

IRRITATION EFFECTS DATA: Severe irritant to the eyes of a rabbit. Moderate irritant to the skin of a rabbit.

CHRONIC/SUBCHRONIC DATA: Results from a battery of short term genotoxicity tests on this material or
its components indicate mutagenic activity. Adsorption of phenolic solutions through the skin may be very
rapid and can cause death. Lesser exposures can cause damage to the kidneys, liver, pancreas, and
spleen, and edema of the lungs. Chronic exposures can cause death from liver and kidney damage.

SECTION 12 - ECOLOGICAL INFORMATION

ENVIRONMENTAL FATE: 108-95-2 PHENOL; Biodegradability = 99.5% at 7 days

SECTION 13 - DISPOSAL CONSIDERATIONS

WASTE DISPOSAL: Comply with all Federal, State and Local Regulations.

SECTION 14 - TRANSPORT INFORMATION

D.O.T. SHIPPING NAME: NOT A REGULATED MATERIAL
TECHNICAL SHIPPING NAME: NONE ESTABLISHED
D.O.T. HAZARD CLASS: NONE ESTABLISHED
UN/NA NUMBER: NONE ESTABLISHED

SECTION 15 - REGULATORY INFORMATION

US FEDERAL REGULATIONS:

TOXIC SUBSTANCES CONTROL ACT (TSCA): All components are included in the EPA Toxic Substances
Control Act (TSCA) Chemical Substance Inventory.

OSHA Hazard Communication Standard (29CFR1910.1200) hazard class(es): Irritant. kidney toxin.
Sensitizer.

EPA SARA Title III Section 312 (40CFR370) hazard class: Immediate Health Hazard. Delayed Health
Hazard.

EPA SARA Title III Section 313 (40CFR372) toxic chemicals above "de minimis" level are: PHENOL

STATE REGULATIONS:

PROPOSITION 65 SUBSTANCES (component(s) known to the State of California to cause
cancer and/or reproductive toxicity and subject to warning and discharge requirements
under the "Safe Drinking Water and Toxic Enforcement Act of 1986"): None
Page 6
SECTION 16 - INTERNATIONAL REGULATIONS

CANADA DSL: Included on Inventory.

WHMIS HAZARD CLASSIFICATION: Class D Division 2A, Class D Division 2B,

WHMIS INGREDIENT DISCLOSURE LIST: PHENOL, TRIETHYLENETETRAMINE (TETA)

This product has been classified in accordance with the hazard criteria of the
CPR and the MSDS contains all the information required by the CPR.

WHMIS SYMBOLS: Stylized T,

EUROPEAN ECONOMIC COMMUNITY (EEC) EINECS/ELINCS MASTER INVENTORY: Included on
EINECS inventory or polymer substance, monomers included on EINECS inventory or no longer polymer.

EEC SYMBOL: TOXIC (T)

EEC RISK (R) PHRASES: May cause sensitization by skin contact (R43). Irritating to skin (R38). Risk of
serious damage to eyes (R41). Toxic in contact with skin (R24).

EEC SAFETY PHRASES: In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice (S26). Wear suitable protective clothing, gloves and eye/face protection (S36/37/39). In case
of accident or if you feel unwell, seek medical advice immediately (show the label where possible) (S45).

AUSTRALIA AICS: Included on Inventory.

JAPAN MITI: Not on Inventory.

PHILIPPINES PICCS: Included on Inventory.

KOREA ECL: Included on Inventory.

CHINA SEPA: Included on Inventory.

SECTION 17 OTHER INFORMATION

MSDS REVISION STATUS: None

FOR INDUSTRY USE ONLY!!!

The information contained herein is based on the data available to us and is believed to be accurate. The data is offered
in good faith as typical values and not as product specification. The information in this data sheet was compiled from
information supplied by the vendors of the components of this compound. Neptune Research Inc. makes no warranty
either expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. The
recommended industrial hygiene and safe handling procedures are believed to be genuinely applicable. However, each
user should review these recommendations in the specific context of the intended use and determine whether they are
appropriate. Neptune Research Inc. assumes no responsibility for injury from the use of the product described herein.
The information is intended only to assist in the safe handling of this material.

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