HENRY 452 EpoxyPro Part B
Page 1 of 6
MSDS Preparation Date (dd/mm/yyyy): 16/10/2008
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Manufacturer's name and address: Supplier's name and address:
Refer to Manufacturer
The W.W. Henry Company
400 Ardex Park Drive
Aliquippa, PA, U.S.A.
15001
Information Telephone No. (724) 203-8499
:
Visit our Website: http://www.wwhenry.com
CHEM-TEL: 1-800-255-3924 OR 1-813-248-0585 (call collect)
24 Hr. Emergency Tel # :
Product Identifier : HENRY 452 EpoxyPro Part B
N/Ap : Mixture.
Chemical Name : Chemical Family
N/Ap Trade Name/Synonyms : Henry?452 Part B
Chemical Formula :
: General purpose,
N/Ap
Molecular Weight : Material Use
two-part epoxy flooring
adhesive.
Class D1B (Materials Causing Immediate and Serious Toxic Effects, Toxic Material);
WHMIS Classification :
Class D2B (Materials Causing Other Toxic Effects, Toxic Material);
Class E (Corrosive Material)
* - Chronic hazard 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe
HMIS Rating :
*2 1 1
Health: Flammability: Reactivity:
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
OSHA PEL
ACGIH TLV
TWA STEL PEL STEL
Ingredients % (weight)
CAS #
60.00 - 100.00 N/Av N/Av N/Av N/Av
Polyamide resin 68410-23-1
5.00 - 10.00 N/Av 20 mppcf N/Av
2 mg/m?br>
Talc 14807-96-6
(respirable)
1.00 - 5.00 N/Av N/Av
10 mg/m? 20 mppcf
Silica, amorphous fumed 112945-52-5
(inhalable); 3 (as
mg/m? Amorphous
(respirable) silica)
(as PNOS)
10.00 - 30.00 N/Av N/Av N/Av
1 ppm (skin)
Triethylenetetramine 112-24-3
(AIHA WEEL)
Note:: This product does NOT contain asbestos.
This material is classified as hazardous under OSHA regulations (29CFR 1910.1200).
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Brown paste. Ammonia odour.
Danger!
Polymerization occurs when components are mixed. Potential for exothermic hazard. Prolonged contact may cause corrosive burns and eye
damage. May cause severe irritation and corrosive damage in the mouth, throat and stomach. Harmful or fatal if absorbed through the skin.
May cause skin sensitization.
If dusts are formed, prolonged inhalation may result in chronic respiratory disease.
***POTENTIAL HEALTH EFFECTS***
Eyes, skin, respiratory system and digestive system.
Target organs :
Inhalation: YES Skin Absorption: NO YES YES
Skin & Eyes: Ingestion:
Routes of exposure :
Signs and symptoms of short-term (acute) exposure
HENRY 452 EpoxyPro Part B
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MSDS Preparation Date (dd/mm/yyyy): 16/10/2008
Inhalation : May cause irritation to the nose, throat and upper respiratory tract. Symptoms may include sore
throat, running nose and shortness of breath.
: May cause moderate to severe skin irritation. Symptoms may include redness, itching and
Skin
swelling. Prolonged contact may produce chemical burns to affected skin areas.
: Direct contact may strongly irritate or burn the eyes. Contact may cause redness, swelling and a
Eyes
painful sensation. Exposure to low vapour concentrations may cause swelling (edema) of the eyes,
resulting in blurring of vision with a bluish haze and/or appearance of halos around lights.
Ingestion : May cause severe irritation and corrosive damage in the mouth, throat and stomach. Symptoms
may include abdominal pain, nausea, vomiting, diarrhea and collapse.
Effects of long-term (chronic) exposure
: Prolonged or repeated contact may cause drying, cracking and defatting of the skin. If
dusts are formed, prolonged inhalation may result in chronic respiratory disease.
Conditions aggravated by overexposure
: Pre-existing skin, eye and respiratory disorders.
: See TOXICOLOGICAL INFORMATION, Section 11.
Carcinogenic status
: Possible sensitizer. See TOXICOLOGICAL INFORMATION, Section 11.
Additional health hazards
Potential environmental effects
See ECOLOGICAL INFORMATION (Section 12).
:
SECTION 4 - FIRST AID MEASURES
If inhaled, move to fresh air. If irritation persists, seek prompt medical attention.
Inhalation :
Remove contaminated clothing. Wash off with soap and plenty of water. Seek
Skin contact :
immediate medical attention/advice.
Immediately flush eyes with running water for at least 15 minutes. Seek immediate
Eye contact :
medical attention/advice.
Never give anything by mouth to an unconscious person. Do NOT induce vomiting.
Ingestion :
Seek immediate medical attention/advice.
Treat symptomatically. Prompt medical attention is important.
Notes For Physician :
SECTION 5 - FIRE FIGHTING MEASURES
Fire hazards/conditions of flammability
: Not flammable under normal conditions of use. Closed containers may rupture if
exposed to excess heat or flame due to a build-up of internal pressure.
Flammability classification (OSHA 29 CFR 1910.1200)
: Non-flammable.
: > 171.1癈 / 340癋
Flash point
N/Av : N/Av
Flash point Method : Auto-ignition temperature
Upper flammable limit (% by vol.)
Lower flammable limit (% by vol.)
N/Av : N/Av
:
None.
Oxidizing properties :
Not applicable. : Not applicable.
Flame Projection Length : Flashback observed
Explosion data: Sensitivity to mechanical impact / static discharge
: Not expected to be sensitive to mechanical impact or static discharge.
Dry chemical, foam, carbon dioxide and water fog. Do not use water jet, as this may
Suitable extinguishing media :
spread burning material.
Special fire-fighting procedures/equipment
: Firefighters should wear proper protective equipment and self contained breathing
apparatus with full face piece operated in positive pressure mode. Move containers
from fire area if safe to do so. Water spray may be useful in cooling equipment
exposed to heat and flame. After fires have been extinguished, carefully clean all
equipment and surfaces exposed to fumes.
Hazardous combustion products
: Carbon oxides; Ammonia; nitrogen oxides (NOx); hydrogen cyanide ; Aldehydes;
Ketones; other unidentified organic compounds.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Restrict access to area until completion of clean-up. All persons dealing with clean-up
Personal precautions :
should wear the appropriate chemically protective equipment. Refer to point 8 on this
Safety Data Sheet, EXPOSURE CONTROLS / PERSONAL PROTECTION, for
additional information on acceptable personal protective equipment.
Do not allow product to enter waterways. Do not allow material to contaminate
Environmental precautions :
ground water system.
HENRY 452 EpoxyPro Part B
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MSDS Preparation Date (dd/mm/yyyy): 16/10/2008
Ventilate area of release. Eliminate all ignition sources. Stop spill or leak at source if
Spill response/cleanup :
safely possible. Contain material, preventing it from entering sewer lines or
waterways. Use inert, non-combustible absorbents to assist the pick up of material.
Scrape up product and place it into a container for disposal. Refer to Section 13 for
disposal of contaminated material. Notify the appropriate authorities as required.
None known.
Prohibited materials :
Special spill response procedures
If a spill/release in excess of the EPA reportable quantity is made into the
:
environment, immediately notify the national response center in the United States
(phone: 1-800-424-8002).
US CERCLA Reportable quantity (RQ): None reported.
SECTION 7 - HANDLING AND STORAGE
Persons with recurrent skin eczema or sensitization problems should be excluded
Safe Handling procedures :
from working with this product. Once a person is sensitized, no further exposure to the
material that caused the sensitization should be permitted. Wear suitable protective
equipment during handling. Use with adequate ventilation. Training the workers on
the potential health hazards associated with product vapor, dust or fume is important.
Secondary inhalation exposures could occur when cleaning equipment, or when
removing or laundering the clothing. Avoid breathing vapors, fumes or dust. Avoid
contact with skin, eyes and clothing. Keep away from heat and sources of ignition.
Keep away from oxidizing materials. Keep containers tightly closed when not in use.
Wash thoroughly after handling.
Store in a cool, dry, well-ventilated area. No smoking in the area. Do not store near
Storage requirements :
any incompatible materials (see Section 10). Storage area should be clearly identified,
clear of obstruction and accessible only to trained and authorized personnel. Protect
against physical damage.
See Section 10.
Incompatible materials :
Always keep in containers made of the same materials as the supply container.
Special packaging materials :
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Ventilation and engineering measures
: Use with adequate ventilation. Provide adequate cross air circulation. Use general or
local exhaust ventilation to maintain air concentrations below recommended exposure
limits.
: In case of insufficient ventilation wear suitable respiratory equipment.
Respiratory protection
NIOSH-approved, organic vapour cartridge respirators are recommended. Advice
should be sought from respiratory protection specialists.
: Impervious gloves must be worn when using this product. Advice should be sought
Skin protection
from glove suppliers.
: Chemical splash goggles are recommended.
Eye / face protection
Wear sufficient clothing to prevent skin contact. An eyewash station and safety
Other protective equipment :
shower should be made available in the immediate working area.
General hygiene considerations
Avoid contact with eyes, skin and clothing. Avoid breathing vapors, fumes or dust.
:
Do not eat, drink or smoke when using this product. Clean all equipment and clothing
at end of each work shift. Separate contaminated work clothes from street clothes.
Contaminated work clothing should not be allowed out of the workplace.
For individual ingredient exposure levels, see Section 2.
Permissible exposure levels :
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
paste brown
Physical state : Appearance :
Ammonia N/Av
Odour : Odour threshold :
N/Av
pH :
N/Av 1.02
Boiling point : Specific gravity :
N/Av
Melting/Freezing point : Coefficient of water/oil distribution
: N/Av
insoluble
Vapour pressure (mmHg @ 20?C / 68?F) Solubility in water :
: N/Av
N/Av
Vapour density (Air = 1) : Evaporation rate (n-Butyl acetate = 1)
: N/Av
94%
Volatile organic Compounds (VOC's) Volatiles (% by weight) :
HENRY 452 EpoxyPro Part B
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MSDS Preparation Date (dd/mm/yyyy): 16/10/2008
< 10 g/L
:
Weight / Gallon: 8.07 lbs. /
N/Av
: :
General Info.
Particle size
3.66 kg (water = 8.3 lbs /
3.76 kg)
SECTION 10 - REACTIVITY AND STABILITY DATA
Stable under the recommended storage and handling conditions prescribed.
Stability and reactivity :
Excessive heating above 50癈 / 122癋 may degrade the resin component. Mixing Part
A and Part B may produce heat.
Polymerization occurs when components are mixed. Reaction is exothermic and can
Hazardous polymerization :
be hazardous depending on temperature and quantity.
Extreme heat. Avoid contact with incompatible materials.
Conditions to avoid :
Materials To Avoid And Incompatibility
: Oxidizing agents; Acids; Aldehydes; Ketones; Halogenated compounds; Nitrogen
compounds.
Hazardous decomposition products
: None known, refer to hazardous combustion products in Section 5.
SECTION 11 - TOXICOLOGICAL INFORMATION
There is no available data for the product itself, only for the ingredients. See
Toxicological data :
below for individual ingredient acute toxicity data.
LC50(4hr) LD50
Ingredients inh, rat oral dermal
N/Av N/Av
Polyamide resin N/Av
N/Av N/Av
Talc N/Av
N/Av 3160 mg/kg (rat)
Silica, amorphous fumed N/Av
N/Av 2500 mg/kg (rat);
Triethylenetetramine 805 mg/kg (rabbit)
1600 mg/kg (mouse)
No components are listed as carcinogens by ACGIH, IARC, OSHA or NTP.
Carcinogenic status :
None known.
Reproductive effects :
None known.
Teratogenicity :
None known.
Mutagenicity :
Not available.
Epidemiology :
May cause severe skin sensitization with allergic contact dermatitis symptoms such
Sensitization to material :
as swelling, rash and eczema. May can an allergic respiratory reaction (e.g. asthma)
in some hypersensitive individuals.
N/Av
Synergistic materials :
Moderate to severe irritation. Prolonged exposure: Corrosive.
Irritancy :
See Section 3 for additional information.
other important hazards :
SECTION 12 - ECOLOGICAL INFORMATION
The product should not be allowed to enter drains or water courses, or be deposited
Environmental effects :
where it can affect ground or surface waters. No data is available on the product itself.
Important environmental characteristics
: N/Av
: No data is available on the product itself.
Ecotoxicological
SECTION 13 - DISPOSAL CONSIDERATIONS
Handle waste according to recommendations in Section 7.
Handling for Disposal :
Dispose in accordance with all applicable federal, state, provincial and local
Methods of Disposal :
regulations. Contact your local, state, provincial or federal environmental agency for
specific rules.
If this product, as supplied, becomes a waste in the United States, it may meet the
RCRA :
criteria of a hazardous waste as defined under RCRA, Title 40 CFR 261. It is the
responsibility of the waste generator to determine the proper waste identification and
disposal method. For disposal of unused or waste material, check with local, state
and federal environmental agencies.
HENRY 452 EpoxyPro Part B
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MSDS Preparation Date (dd/mm/yyyy): 16/10/2008
SECTION 14 - TRANSPORTATION INFORMATION
Packing
Regulatory
Group
UN Number Shipping Name Class
Information Label
not regulated
None Not regulated.
TDG none
None.
TDG
Additional
information
not regulated
None Not regulated.
49CFR/DOT none
None.
49CFR/DOT
Additional
information
SECTION 15 - REGULATORY INFORMATION
Canadian Information:
Canadian WHMIS Classification: This product is a WHMIS Controlled Product. It meets one or more of the
criteria for a controlled product provided in Part IV of the Controlled Products Regulations (CPR). Refer to
Section 1 for a WHMIS Classification for this product.
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the
information required by the CPR.
Canadian Environmental Protection Act (CEPA): All components of this product are on the Canadian DSL list.
US Federal Information:
TSCA: All listed ingredients appear on the Toxic Substances Control Act (TSCA) inventory.
CERCLA Reportable Quantity (RQ) (40 CFR 117.302): None reported.
SARA TITLE III: Sec. 313, Toxic Chemicals Notification, 40 CFR 372: This material is not subject to SARA notification
requirements, since it does not contain any Toxic Chemical constituents above de minimus concentrations.
US State Right to Know Laws:
California Proposition 65: To the best of our knowledge, this product does not contain any chemicals known to the State
of California to cause cancer or reproductive harm.
SECTION 16 - OTHER INFORMATION
ACGIH: American Conference of Governmental Industrial Hygienists
Legend :
CAS: Chemical Abstract Services
CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act
of 1980
CFR: Code of Federal Regulations
DOT: Department of Transportation
DSL: Domestic Substances List
EPA: Environmental Protection Agency
IARC: International Agency for Research on Cancer
Inh: Inhalation
N/Av: not available
N/Ap: not applicable
NIOSH: National Institute of Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
PEL: Permissible exposure limit
RCRA: Resource Conservation and Recovery Act
SARA: Superfund Amendments & Reauthorization Act
STEL: Short Term Exposure Limit
HENRY 452 EpoxyPro Part B
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MSDS Preparation Date (dd/mm/yyyy): 16/10/2008
TLV: Threshold Limit Values
TSCA: Toxic Substance Control Act
TWA: Time Weighted Average
WHMIS: Workplace Hazardous Materials Identification System
1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 2008.
References :
2. International Agency for Research on Cancer Monographs, searched 2008.
3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2008
(Chempendium and RTECs).
4. Material Safety Data Sheet from manufacturer.
5. US EPA Title III List of Lists October 2006 version.
6. California Proposition 65 List September 12, 2008 version.
DISCLAIMER OF LIABILITY
The Information presented herin is supplied as a guide to those who handle or use this product and has been prepared
in good faith by technically knowledgeable personnel. It is not intendedd to be all-inclusive. The manner and conditions
of use and handling may involve other and additional considerations. Safe work practices must be employed when
working with any materials. It is important that the end user makes a determination regarding the adequacy of the safety
procedures employed during the use of this product.
No warranty of any kind is given or implied. The W.W. Henry Company will not be liable for any damages, losses,
injuries or consequential damages which may result from the use or reliance on any inforamtion contained herein. This
Material Safety Data Sheet is valid for three (3) years.
Prepared By:
The W.W. Henry Company
400 Ardex Park Drive
Aliquippa, PA, U.S.A.
15001
(724) 203-8499
Visit our Website: http://www.wwhenry.com
MSDS Preparation Date (dd/mm/yyyy)
16/10/2008
:
END OF DOCUMENT
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