#996 TWO-PART EPOXY ADHESIVE (PART B)
M A T E R I A L S A F E T Y D A T A S H E E T
SECTION 1. PROPRIETARY PRODUCT IDENTIFICATION/MANUFACTURER
1.1 Proprietary Product Name: #996 Two-Part Epoxy Adhesive - Part B
1.2 Chemical Family: Epoxy Curative
1.3 Manufacturer:
Johnsonite
16910 Munn Road
Chagrin Falls, Ohio 44023
Phone: (800) 899-8916
(440) 543-8916
Fax: (440) 543-8920
24 hour Emergency Telephone: 864-967-7691
SECTION 2. HAZARDOUS INGREDIENTS AND EXPOSURE LIMITS
Chemical CAS % by ACGIH OSHA
Name Number Weight TLV PEL
Polyamide Resin 68410-23-1 23-33 N.A. N.A.
Polyamide Proprietary 6-12 N.A. N.A.
Phenol 108-95-2 6-9 5ppm 5ppm
Tetraethylene Pentamine 112-57-2 1-4 N.A. N.A.
5mg/M3 5mg/M3
Butyl Benzyl Phthalate 85-68-7 3-8
10mg/M3 10mg/M3
Calcium Carbonate 1317-65-3 35-50
10mg/M3 10mg/M3
Silica 67762-90-7 1-3
SECTION 3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: Causes eye burns or irritation. Can cause severe respiratory irritation. Can
cause central nervous system depression. Can cause dermatitis.
POTENTIAL HEALTH EFFECTS:
EYE: May cause severe irritation. May damage eyes.
SKIN: Prolonged exposure may cause skin irritation or burns. May cause drying or flaking of skin. Skin
absorption of material may cause systemic toxicity.
Revision 09 - Released November, 2006 #996 Part B MSDS Full Disclosure
INGESTION: May cause severe injury to intestinal tract, liver, kidneys, stomach, throat, lungs, mouth, and
mucous membranes. Harmful or fatal if swallowed. Do not ingest.
INHALATION: Overexposure may cause severe respiratory tract irritation. Prolonged overexposure may
cause central nervous system depression with narcotic effects (headaches, dizziness, unconsciousness). Keep
exposure below OSHA exposure limits.
CHRONIC EFFECTS/ CARCINOGENICITY (Cancer Causing):
IARC: Not suspected as a human carcinogen
NTP: Not suspected as a human carcinogen
OSHA: Not suspected as a human carcinogen
OTHER: None known
SECTION 4. FIRST AID MEASURES
EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
SKIN: Wash with soap and water. Get medical attention if irritation develops or persists. Immediately remove
contaminated clothing.
INGESTION: If swallowed, seek medical attention immediately.
INHALATION: Remove to fresh air. Restore breathing if necessary. Get medical attention.
This material can cause lung damage. Do not leave victim unattended.
SECTION 5. FIRE-FIGHTING MEASURES
OSHA Class: None
Class: N.A.
FLASH POINT: > 200癋 (Setaflash Method)
LOWER EXPLOSIVE LIMIT (%): N.A.
GENERAL HAZARD: May release flammable mixtures when temperatures are at or above the flash point.
Toxic gases will form upon combustion. Closed containers may explode when exposed to extreme heat.
Vapors are heavier than air and may travel a considerable distance.
FIRE-FIGHTING EQUIPMENT: Respiratory and eye protection required for fire fighting personnel. Full
protective equipment and a self-contained breathing apparatus (SCBA) should be used in all indoor fires and
any large outdoor fires.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, smoke and fumes,
hydrocarbon fragments, nitrogen oxides, amino compounds.
SECTION 6. ACCIDENTAL RELEASE MEASURES (Spills or leaks)
Keep all sources of ignition and hot metal away from spill. Isolate the danger area and keep unauthorized
personnel out. Stop spill if it can be done with minimal risk. Wear appropriate protective equipment including
respirator protection as conditions warrant (See Section 8). Prevent additional discharge of material. Notify the
appropriate authorities immediately. Contain spilled liquid with sand, earth, or other noncombustible, inert,
absorbent material. Prevent run-off from entering storm sewers, ditches, or waterways. Use non sparking tools
to transfer absorbed waste material into properly identified drums. Treat waste material with same precautions
as the adhesive. Do not use solvent or flammable liquid to help clean-up and accidental releases. Release to
the environment may be reportable under environmental regulations.
SECTION 7. HANDLING AND STORAGE
Revision 09 - Released November, 2006 #996 Part B MSDS Full Disclosure
HANDLING: Open container slowly to relieve any pressure. Bond and ground all equipment
when transferring from one vessel to another. This material can accumulate static charge by
flow and agitation. Use spark proof tools and explosion proof equipment as directed by local
fire codes. Do not enter confined spaces such as tanks without following proper entry
procedures as described in OSHA regulations 29 CFR 1910.146. Do not breathe vapors. The
use of respiratory protection is recommended when airborne concentrations of vapor exceed
exposure guidelines. Wash thoroughly after handling. Do not wear contaminated clothing or
shoes. Wear appropriate protective gloves and clothing to prevent prolonged or repeated skin
contact. Avoid contact with eyes. Use good hygienic practices. Keep out of reach of children.
Wash with soap and water before eating, drinking, smoking, or using toilet facilities.
EMPTY CONTAINERS MAY CONTAIN LIQUID AND VAPOR RESIDUE AND MAY BE
DANGEROUS: Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, or other sources of ignition. They may explode and
cause injury or death. "Empty" drums should be completely drained, properly bunged, and
promptly shipped to the supplier or drum reconditioner. All containers should be disposed of
in accordance with governmental regulations.
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, smoke and fumes,
hydrocarbon fragments, nitrogen oxides, amino compounds.
STORAGE: Keep containers tightly closed. Use and store this material in a cool, dry, well-
ventilated area away from heat, direct sunlight, hot metal surfaces, and all sources of
ignition. Post area "No smoking or open flames". Store only in approved containers. Protect
containers against physical damage. Indoor storage should meet OSHA standards and
appropriate fire codes. Wash with soap and water before eating, drinking, smoking or using toilet facilities.
Consult NFPA and OSHA codes.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an organic vapor
cartridge may be used under conditions where airborne concentrations are expected to exceed exposure
guidelines. Protection provided by air purifying respirators is limited. Refer to respirator manufacturer's
selection guide for appropriate respirator for conditions encountered. If in doubt, seek the advice of an
industrial hygienist or safety professional for appropriate air purifying respiratory equipment. Use a positive
pressure air supplied respirator if there is a potential for an uncontrolled release, exposure levels are not
known, or in any other circumstances where air purifying respirators may not provide adequate protection.
Respiratory protection does not provide safety from flammable atmospheres. Do not enter concentrations of
vapors at, near, or above the lower flammable limit. When respiratory protection is used, a respiratory
protection program meeting OSHA regulations at 29 CFR 1910.134 must be followed.
SKIN PROTECTION: The use of gloves impermeable to the specific material handled is advised to prevent
prolonged or repeated skin contact. Where splashing is likely to occur, aprons impermeable to the specific
material may be worn. Refer to glove and protective clothing manufacturer's selection guide for appropriate
material.
EYE/FACE PROTECTION: Approved chemical splash goggles should be worn to safeguard against
potential eye contact, irritation, or injury. Where splashing is likely to occur, hard hats and face shields may be
used to provide additional protection. Eye wash facilities should be available in the work area.
ENGINEERING CONTROLS: Provide sufficient mechanical ventilation to maintain exposure below OSHA
limits. The use of local exhaust ventilation is recommended. Provide mechanical ventilation of confined
spaces. If current ventilation practices are not adequate to maintain airborne concentrations below the
established exposure guidelines, additional ventilation or exhaust systems may be required. Use explosion
proof ventilation equipment.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Revision 09 - Released November, 2006 #996 Part B MSDS Full Disclosure
SPECIFIC GRAVITY: 1.3 (68癋)
BOILING POINT: > 350癋
FREEZE POINT: < 32癋
APPROXIMATE VISCOSITY: ~ 30,000 CPS (75癋)
SOLUBILITY IN WATER: Slightly soluble.
% SOLIDS BY WEIGHT: > 99
APPEARANCE AND ODOR: Beige paste with an amine or ammonia odor.
SECTION 10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Keep away from flames and spark producing equipment. Not dangerously
unstable. Avoid build-up of static electricity.
HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBLE MATERIALS: Strong oxidizing agents, strong reducing agents, acids, bases, or unstable
chemicals, chloroform, peroxides, sulfur dichloride, strong alkalis, anhydrides, mercaptans, materials that react
with amines.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, smoke and fumes,
hydrocarbon fragments, nitrogen oxides, amino compounds.
SECTION 11. TOXICOLOGICAL INFORMATION
SKIN: DERMAL LD50 = N.A. mg/kg
INGESTION: ORAL LD50 = N.A. mg/kg
CHRONIC: Liver and kidney damage. May cause corneal opacity. May cause central nervous system
depression causing headaches, nausea, and dizziness.
CHRONIC/CARCINOGENICITY (CANCER CAUSING): This product does not contain
any chemicals known to the State of California (Proposition 65) to cause cancer or
reproductive toxicity.
OTHER: None known.
SECTION 12. ECOLOGICAL INFORMATION
No information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Incinerate at an EPA approved facility or dispose of in accordance with federal, state, and local regulations.
Johnsonite #996 Part B is a hazardous waste if discarded. (CFR, Vol. 40, Part 261, Pgs. 51-114).
See Section 2, Page 1 of this MSDS for hazardous ingredients.
Proper waste disposal is the responsibility of the owner of the waste.
SECTION 14. TRANSPORT INFORMATION
DOT:
PROPER SHIPPING NAME: Not regulated
HAZARD CLASSIFICATION:
UN#:
PACKING GROUP:
ALL PACKAGED MATERIAL MUST BE LABELED IN ACCORDANCE WITH DOT
AND OSHA STANDARDS
Revision 09 - Released November, 2006 #996 Part B MSDS Full Disclosure
SECTION 15. REGULATORY INFORMATION
OSHA: Hazardous material by definition of Hazard Communication Standard
(29CFR 1910.1200).
SECTION 313: This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of Superfund Amendments and Reauthorization Act of 1986 and
CFR Part 372: Butyl Benzyl Phthalate.
V.O.C.: < 0.1 lbs/gallon (SCAQMD Rule 1168)
< 12 grams/liter
HMIS RATINGS: Health = 2 Flammability = 1 Reactivity = 0
Personal Protective Equipment = See Section 8.
(Hazard Ratings Scale: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe)
TSCA: Components of this product are listed on the TSCA inventory.
WHMIS: This product is a "controlled product" under Canadian Workplace Hazardous Materials Information
System.
SECTION 16. OTHER INFORMATION
Johnsonite believes the statements, technical information, and recommendations contained herein
are reliable. They are given without any warranty or guarantee of any kind, expressed or implied.
Revision 09 - Released November, 2006 #996 Part B MSDS Full Disclosure
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