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Revised 4/18/07
Replaces 12/14/05
Printed 10/31/07
MSDS ID: 8060022
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT PART NUMBER: 8060022
DESCRIPTION: 7261 BLACK
COMPANY: EMERGENCY RESPONSE NUMBERS:
Markem Corporation Transportation:
150 Congress Street United States: (800) 424-9300
Keene, NH 03431 International: (703) 527-3887(collect)
Product Safety and Environmental:
(603) 352-1130
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2. HAZARDOUS INGREDIENTS
COMPONENT CAS # PCT(WT)
Carbon black 1333-86-4 7-13
Formaldehyde 50-00-0 0.1-1
Phenol 108-95-2 1-5
Tributyl phosphate 126-73-8 40-60
Exposure and physical property information is presented in Section 9.
If the total percentage is less than 100, the balance of this product is not
considered to be hazardous as defined in the OSHA Hazard Communication
Standard (29 CFR 1910.1200).
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3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS RATING SYSTEM NFPA RATING SYSTEM
Health: 2 Health: 2
Flammability: 1 Flammability: 1
Reactivity: 0 Reactivity: 0
Protection: B
POTENTIAL HEALTH CONSIDERATIONS
LIKELY ROUTES OF ENTRY:
Contact; Inhalation; Absorption; Ingestion
TARGET ORGANS:
Respiratory Tract;
POTENTIAL IMMEDIATE EFFECTS FROM OVEREXPOSURE
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3. HAZARDS IDENTIFICATION (Cont.)
EYE CONTACT
Can cause minor eye irritation, tearing or reddening.
SKIN CONTACT
Can cause severe skin irritation, defatting, and dermatitis. Not likely to
cause permanent skin damage.
Skin Sensitizer! Avoid exposure. If sensitized, repeated exposures will result
in skin irritation, even at very low concentrations.
SKIN ABSORBTION
Toxic if absorbed through the skin causing systemic damage.
INHALATION
Can cause respiratory irritation, dizziness, weakness, fatigue, nausea,
headache and possible unconsciousness.
Respiratory Sensitizer! Avoid exposure. If sensitized, repeated exposures
will result in respiratory irritation and shortness of breath, even at very
low concentrations. These asthma-type symptoms may develop immediately or be
delayed up to several hours.
INGESTION
Irritating to mouth, throat, and stomach. Can cause abdominal discomfort,
nausea, vomiting and diarrhea.
POTENTIAL LONG-TERM EFFECTS FROM OVEREXPOSURE:
CANCER INFORMATION
Contains a substance that is a possible cancer hazard based on human studies.
No IARC cancer hazard information available.
Contains a substance which is cassified by ACGIH as A4: Not classifiable as a
human carcinogen.
No NTP cancer hazard information available.
Classified by IARC as Group 2B: The agent (mixture) is possibly carcinogenic
to humans.
REPRODUCTIVE SYSTEM INFORMATION
Contains a substance that is a possible reproductive hazard based on tests
with laboratory animals.
ADDITIONAL HEALTH HAZARD INFORMATION
Formaldehyde: Exposure to formaldehyde vapor at concentrations >1 ppm may
cause significant irritation of the eyes and respiratory tract. Irritation
threshold is about 0.3 ppm. Formaldehyde was found to be weakly active in
in vitro genotoxicity tests, but inactive in vivo. Lifetime inhalation of
formaldehyde vapor at concentrations above 5 ppm for 6 hours/day caused nasal
tumors in laboratory animals.
Tributyl phosphate: TBP was found not to be neurotoxic either acutely at 1000
mg/kg or after three months of exposure at up to 325 mg/kg/day. Assuming
similar absorption of TBP by oral and inhalation routes of exposure and a
breathing rate of approximately 170 mL/min, these values are approximately
equivalent to inhalation exposures of 4900 mg/cu m acutely and 1590 mg/cu m
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3. HAZARDS IDENTIFICATION (Cont.)
per day subchronically. The ACGIH TLV (TWA) for TBP is 2.2 mg/cu m. This
indicates that a minimum of a 700-fold safety factor exists for TBP as a
potential neurotoxin(1). Large doses have been reported to cause dyspnea,
weakness, pulmonary edema, and twitching in rats. Chronic inhalation of
large doses can lead to general poisoning with paralysis, urinary bladder
hyperplasia, and increased liver weight.(1) Healy, C.E.; Beyrouty, P.C.;
and Broxup, B.R., Am. Ind. Hyg. Assoc J. 56:349-355 (1995).
MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY OVEREXPOSURE
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4. FIRST AID MEASURES
EYE CONTACT
Immediately flush eyes with plenty of water for at least 20 minutes retracting
eyelids often. Get immediate medical attention.
SKIN CONTACT
Wash with soap and water. Remove contaminated clothing and launder. Get
medical attention if irritation develops or persists.
INHALATION
Remove to fresh air. If not breathing, perform rescue breathing and, if
available, have a trained person administer oxygen.
Get medical attention immediately.
INGESTION
Emergency personnel should be contacted immediately and be provided with
this MSDS. For ingestion of small quantities of chemicals, the risk
associated with inducing vomiting usually exceeds the poisoning risk.
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5. FIRE FIGHTING MEASURES
FLAMMABILITY DATA
FLASH POINT: >200 F, >93 C
EXPLOSIVE/FLAMMABILITY LIMITS ESTIMATED FROM INGREDIENTS:
LOWER LIMIT: ND %
UPPER LIMIT: ND %
AUTOIGNITION TEMPERATURE ESTIMATED FROM INGREDIENTS:
500 F, 260 C
GENERAL HAZARDS
Material may ignite if heated to temperatures above the flash point
in the presence of a source of ignition.
EXTINGUISHING MEDIA
Use alcohol foam, carbon dioxide (CO2) or dry chemical. Water may not be
effective to extinguish fire. Use water spray to cool fire-exposed containers
and to protect personnel.
FIRE FIGHTING INSTRUCTIONS
Do not enter fire area without proper protection including self-contained
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5. FIRE FIGHTING MEASURES (Cont.)
breathing apparatus and full protective equipment. Fight fire from a
safe distance and a protected location. Heat may build pressure and rupture
closed containers, spreading fire and increasing risk of burns or injuries.
Use water spray/fog for cooling. Even if material is water soluble, it may
not be practical to extinguish fire by water dilution. Notify authorities if
liquid enters sewers or other public waters.
HAZARDOUS COMBUSTION PRODUCTS
carbon dioxide; carbon monoxide; phosphorus compounds
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6. ACCIDENTAL RELEASE MEASURES
SPILL CLEAN-UP PROCEDURES
Prevent the spread of any spill to minimize harm to human health and the
environment. Dike with suitable absorbent material. Wear complete and
proper personal protective equipment and ventilate the area.
HEALTH CONSIDERATIONS AND PROTECTIVE EQUIPMENT
Information on the selection and use of personal protective equipment is found
in Section 8 of this MSDS. Personal protective equipment needs must be
evaluated based on information provided on this sheet and the special
circumstances created by the spill including; material spilled, quantity, the
area in which it occurred and the expertise of employees in the area
responding to the spill. Never exceed any occupational exposure limits and
consider that the evaporation of volatile solvents can lead to the
displacement of air creating an environment that can cause asphxyiation.
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7. HANDLING AND STORAGE
HANDLING
Avoid contact with material, avoid breathing vapors, use only in a well
ventilated area.
STORAGE
Store in a cool, dry place. Isolate from incompatible materials.
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8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
ENGINEERING CONTROLS
Local exhaust ventilation or other engineering controls may be needed when
handling or using this product to keep exposure to airborne contaminants below
the exposure limit. These controls should be explosion-proof when exhausting
flammable vapors.
RESPIRATORY PROTECTION
A component of this material has an extremely low established exposure limit.
If air monitoring indicates airborne concentrations at or above the exposure
limit a respiratory protection program is required. Engineering controls
are usually preferable to a respirator program.
Use engineering or administrative controls to minimize exposure in preference
to using respirators. Protection provided by air purifying respirators is
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8. EXPOSURE CONTROLS AND PERSONAL PROTECTION (Cont.)
limited. Use a positive pressure air supplied respiratory if there is any
potential for an uncontrolled release, exposure levels are not known, the work
atmosphere may be deficient of oxygen, or any other circumstances where air
purifying respirators may not provide adequate protection.
EYE PROTECTION
Chemically resistant safety glasses with side shields must be worn when
handling this product. Further eye protection such as chemical splash goggles
and/or face shield must be worn when the possibility exists for eye contact
due to splashing or spraying liquid or airborne particles. Contact lenses
should not be worn. An eye wash station should be available.
SKIN PROTECTION
Prevent skin contact by wearing gloves and other protective equipment.
Inspect gloves for chemical break-through and replace if detected. Clean
protective equipment thoroughly after each use. Do not remove from workplace.
An emergency shower in the area is recommended.
Appropriate gloves to be used for MARKEM products that are mixtures have not
been determined. Glove type(s) for ingredients present at 10% or more
(if known) are:
Neoprene; Butyl rubber, Polyethylene,
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9. PHYSICAL AND CHEMICAL PROPERTIES - PRODUCT
APPEARANCE: Liquid
COLOR: Black
ODOR: Characteristic
SPECIFIC GRAVITY(g/ml): 1.17
PERCENT VOLATILE: 44
VOC CONTENT(lb/gl): 2.49 lb/gal
VAPOR PRESSURE (Pa): Not determined
BOILING PT OR RANGE(F): ND
pH: NA
VISCOSITY: ND
VAPOR DENSITY: Heavier than air
FREEZING POINT(F): ND
EVAPORATION RATE: <0.01 (n-Butyl acetate = 1)
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9.1 EXPOSURE, PHYSICAL AND CHEMICAL PROPERTIES FOR COMPONENTS
COMPONENT ACGIH OSHA
TWA\CEIL STEL TWA CEIL
1333-86-4 3.5 mg/m3 NE 3.5 mg/m3 NE
50-00-0 0.3 ppm C 2 ppm 0.75 ppm NE
108-95-2 5 ppm NE 5 ppm NE
126-73-8 0.2 ppm NE 0.2 ppm NE
SPECIFIC EVAP RATE WATER VAPOR
GRAVITY N-BUTYL SOLUBILITY PRESSURE
COMPONENT CAS NUMBER ACETATE=1 Weight % mmHg at F
1333-86-4 1.800 ND Negligible;ND
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9.1 EXPOSURE, PHYSICAL AND CHEMICAL PROPERTIES FOR COMPONENTS (Cont.)
50-00-0 1.000 ND ND ND
108-95-2 1.070 ND ND ND
126-73-8 0.980 <0.01 Negligible;7.3@302F
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10. STABILITY AND REACTIVITY
STABILITY
Stable under normal conditions.
CONDITIONS TO AVOID
Heat, sparks, open flame, other ignition sources, oxidizing conditions, and
elevated temperatures.
INCOMPATIBILITY
strong oxidizing agents;
HAZARDOUS DECOMPOSITION PRODUCTS
carbon dioxide; carbon monoxide; phosphorus compounds
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11. TOXICOLOGICAL INFORMATION
Carbon black:
Carcinogenicity
NTP: Not classified
OSHA: Not classified
ACGIH: Not classifiable as a human carcinogen (A4)
IARC: Carbon black is possibly carcinogenic to humans (Group 2B)
Evaluation: There is inadequate evidence in humans for the carcinogenicity
of carbon black. There is sufficient evidence in experimental animals for
the carcinogenicity of carbon black. There is sufficient evidence in
experimental animals for the carcinogenicity of carbon black extracts.
Overall evaluation: Carbon black is possibly carcinogenic to humans (Group 2B)
[IARC. Monographs on the Evaluation of the Carcinogenic Risk of
Chemicals to Man. Geneva: World Health Organization, International Agency
for Research on Cancer,1972-PRESENT. (Multivolume work).,p. 65 247 (1996)].
Summary of Data Reported and Evaluation:
Exposure data: In the late 1980s and early 1990s, more extensive studies in
western Europe and the United States have found ... even lower exposures may
occur among some workers in industries using carbon black, such as rubber,
printing ink and paint manufacture, and exposures to carbon black in the use
of rubber, printing ink or paint are negligible.
[IARC. Monographs on the Evaluation of the Carcinogenic Risk of
Chemicals to Man. Geneva: World Health Organization, International Agency
for Research on Cancer,1972-PRESENT. VOL.: 65 (1996) (p. 149)].
LD50 (oral, rat): >8000 mg/kg
LC50 (inhalation, rat): 27000 mg/m3 (27 mg/L) (1-hour exposure).
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11. TOXICOLOGICAL INFORMATION (Cont.)
CHRONIC INHALATION: Hamsters, mice, guinea pigs, rabbits and monkeys
exposed to carbon blacks (channel black or furnace black) at concentrations of
85 mg/m3 (channel black) and 56 mg/m3 (furnace black) intermittently for
periods up to 3000 hours (13,000 hours for monkeys) showed no significant
effects other than accumulation of dusts in the lungs. The channel black
contained extremely low levels of benzene-extractable material and the furnace
black contained 0.28% extractable material.
SUBCHRONIC TOXICITY:
Rat, inhalation, duration 90 days
Target organ: lungs
Effect: inflammation, hyperplasia, fibrosis
NOEL =1.1 mg/m3
Formaldehyde:
LD50 (oral, rat): 590 mg/kg
LC50 (inh, rat): 1000 mg/m3 (30-minute exposure).
LD50 (dermal, rabbit): 270 mg/kg.
CARCINOGENICITY: Rats and mice were exposed to 0, 2, 5.6 and 14.3 ppm
formaldehyde for 2 years and observed for an additional 6 months. Significant
increases in the incidence of squamous cell carcinomas in the nasal cavities
were observed in the rats exposed to 14.3 ppm. Two nasal cancers were
observed in the mice. Male monkeys, rats and hamsters were
exposed to up to 3 ppm for 22 hours per day for 26 wks. Non-cancerous growths
were observed in the noses of the monkeys and rats. No effects were
demonstrated in the hamsters.
IARC evaluation of the carcinogenicity of formaldehyde to experimental
animals: sufficient evidence.
SKIN SENSITIZATION: Formaldehyde was a potent skin sensitizer in guinea pigs.
Phenol:
Eye rabbit: 5 mg, Effect: Severe
Oral LDLo infant: 10 mg/kg Effect: Behavioral (Muscle weakness);
Lungs, Thorax or Respiration LUNGS, (Cyanosis)
Oral LDLo human: 14 gm/kg Effect: Behavioral (Muscle weakness),
Lungs, thorax or Respiration (Cyanosis)
Oral LDLo human: 140 mg/kg Effect: Behavioral (Hallucinations,
distorted perceptions), Skin and appendages (Sweating)
Oral LD50 rat::317 mg/kg
Inhalation LC50 rat: 316 mg/m3
Skin LD50 rat: 669 mg/kg Effect: Behavioral (Tremor), Kidney, Ureter, Bladder
(Hematuria);
Skin and Appendages (After topical application: Cutaneous sensitization).
Tributyl phosphate:
Acute toxicity:
Oral LD50 rat: 1390 mg/kg, Effect: kidney, ureter, bladder (changes in
(tubules)
Inhalation LC50 rat: 28 gm/m3/1H
Eye rabbit: 500 mg, Effect: Severe
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11. TOXICOLOGICAL INFORMATION (Cont.)
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12. ECOLOGICAL INFORMATION
Phenol:
TDLO Minnows 30 min 79 ug/l, LC50
Crangon crangon 5600 mg/l 3 min, 20 mg/l 1 hr, 80 mg/l 3 hr, 40 mg/l 6-24 hr,
30 mg/l 48-72 hr, 25 mg/l 96 hr,
LC50 Fathead minnow >50 mg/l/1 hr, >50 mg/l/24 hr, 33 mg/l/72 hr,
32 mg/l/96 hr.
If it is released to the environment, its primary removal mechanism is
boidegradation which is generally rapid (days). Since phenol is a benchmark
chemical for biodegradability studies, there is a large body of information on
its degradation which concludes that phenol rapidly degrades in sewage, soil,
fresh water and seawater.
If phenol is released to the atmosphere, it will exist predominantly in the
vapor phase. Phenol's estimated half-life by reaction with
hydroxyl radicals in air is 0.61 days.
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13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with all federal, state, local or provincial
regulations.
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14. TRANSPORT INFORMATION, DOT and IATA:
DOT & IATA: NOT RESTRICTED
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15. REGULATORY INFORMATION
Those ingredients appearing on the following list that do not appear
in Section 2 are present at <0.1% for carcinogens, <1% for other hazardous
substances, or are not considered hazardous in this product.
UNITED STATES OF AMERICA
FEDERAL REGULATIONS
CERCLA: The following components have CERCLA reportable quantities:
CASRN DESCRIPTION CERCLA RQ WEIGHT%
50-00-0 FORMALDEHYDE 100 lb final RQ; 0
45.4 kg final RQ
108-95-2 PHENOL 1000 lb final RQ; 4
454 kg final RQ
RCRA: The following components are subject to RCRA land disposal restrictions:
CASRN DESCRIPTION
108-95-2 PHENOL
SARA TITLE III
SECTION 302 Extremely Hazardous Substances (EHS)
CASRN DESCRIPTION
50-00-0 FORMALDEHYDE
108-95-2 PHENOL
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15. REGULATORY INFORMATION (Cont.)
SECTION 311/312 Community Right to Know
CASRN DESCRIPTION
50-00-0 FORMALDEHYDE
108-95-2 PHENOL
SARA HAZARD CATEGORY INFORMATION
FIRE: NO
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE: NO
IMMEDIATE (ACUTE) HEALTH HAZARD: YES
DELAYED (CHRONIC) HEALTH HAZARD: YES
SECTION 313 Toxic Chemical Release Inventory Reporting (TRI)
CASRN DESCRIPTION
50-00-0 FORMALDEHYDE 0
108-95-2 PHENOL 4
TSCA
SECTION 8(b) Inventory: All chemicals in this product appear in the inventory
or are exempt from the listing requirements.
SECTION 12(b) Export: The following chemicals are subject to export reporting
CASRN DESCRIPTION
126-73-8 TRIBUTYL PHOSPHATE
STATE REGULATIONS
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65)
The following chemical(s) in this product are known to the State of
California to cause cancer:
CASRN DESCRIPTION WGT%
1333-86-4 CARBON BLACK 7-13
50-00-0 FORMALDEHYDE 0.1-1
The following chemical(s) in this product are known to the State of
California to be hazards to reproductive health: WGT%
None
None
MASSACHUSETTS Right to Know Law
CASRN DESCRIPTION %
1333-86-4 CARBON BLACK 7-13
50-00-0 FORMALDEHYDE 0.1-1
108-95-2 PHENOL 1-5
126-73-8 TRIBUTYL PHOSPHATE 40-60
NEW JERSEY Right to Know Law
CASRN DESCRIPTION %
1333-86-4 CARBON BLACK 7-13
50-00-0 FORMALDEHYDE 0.1-1
108-95-2 PHENOL 1-5
126-73-8 TRIBUTYL PHOSPHATE 40-60
PENNSYLVANIA Right to Know Law
CASRN DESCRIPTION %
1333-86-4 CARBON BLACK 7-13
50-00-0 FORMALDEHYDE 0.1-1
108-95-2 PHENOL 1-5
126-73-8 TRIBUTYL PHOSPHATE 40-60
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16. OTHER INFORMATION
Note: A CAS number in the form TSXXXX-XX-X is a trade secret.
NA= Not applicable
ND= Not determined
TS= Trade secret
MSDS prepared by Richard C. Berry
This information is offered in good faith as typical values and not as product
specifications. No warranty, either expressed or implied, is made. The
recommended industrial hygiene and safe handling practices are believed to be
generally applicable, however each user must review the recommendations and
determine the suitablity for their intended use.
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