MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Supershine?Clear Fast Drying Hoof Polish & Sealer
GENERAL USE: Hoof Polish and Sealer
PRODUCT DESCRIPTION: Clear flammable liquid, acetone odor
MANUFACTURER'S NAME DATE PREPARED: December 16, 2008
Page 1 of 4
W. F. Young, Inc. SUPERSEDES: New
ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION
302 Benton Drive (413) 526-9999
(CITY, STATE AND ZIP CODE) COUNTRY EMERGENCY TELEPHONE NUMBER
East Longmeadow, MA 01028 USA (413) 526-9999
SECTION 2 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Clear liquid, extremely flammable, potentially hazardous vapors. Contains a phenolic resin that inherently contains a small amount of phenol.
Can cause eye and skin irritation upon contact. Inhalation of vapors can cause anesthetic effect leading to death in poorly ventilated areas.
Hazard Symbols for this product - F, Xi Risk Phrases - R11,36, 66, 67.
POTENTIAL HEALTH EFFECTS
INHALATION: High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting and malaise.
SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate reddening, swelling and possible necrosis.
EYES: Contact causes severe irritation and pain associated with redness and swelling of the conjunctiva.
INGESTION: Moderately toxic; may cause headache, dizziness, diarrhea and general weakness; large doses may result in red blood cell
hemolysis.
CARCINOGENICITY No Yes No
NTP? IARC MONOGRAPHS? OSHA REGULATED?
IARC classifies Phenol as Group 3, limited or inadequate evidence of carcinogenicity.
SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS
OSHA PEL ACGIH TWA
% RQ
HAZARDOUS COMPONENTS CAS # EINECS #
PPM MG/M3 PPM MG/M3 LBS
(by weight)
Acetone (b,c) 67-64-1 200-662-2 70 - 80 750 800 500 5000
Phenol (a,b,c,d,e,f) 108-95-2 203-632-7 0.4 - 0.6 5 19 5 19 1000
The remaining components of this product are non-hazardous or are in small enough quantities as to not meet regulatory thresholds for
disclosure. These components contain no substances or impurities which would influence the classification of this product.
(a,c) See Section 15
(b) Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled
according to regulations in 40 CFR 260-281.
(d) Indicates an Extremely Hazardous Substance, if your facility has a designated amount of this substance, Threshold Planning Quantity (TPQ) in inventory, the
regulations of 40 CFR 355 and 370 apply, including submission of Tier I / Tier II forms every March 1.
(e) Indicates substance appears on National Toxicology Program (NTP) list of carcinogens, International Agency for Research on Cancer (IARC) list of
carcinogens or is regulated by the Occupational Safety and Health Administration (OSHA) as a possible carcinogen.
(f) Indicates an employee's skin exposure shall be prevented or reduced to the extent necessary in the circumstances through the use of gloves, coveralls,
goggles, or other appropriate equipment.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Supershine?Clear Fast Drying Hoof Polish & Sealer
Page 2 of 4
December 16, 2008
SECTION 4 - FIRST AID MEASURES
INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR
and seek emergency medical attention.
SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation
persists, seek medical attention.
EYES: Check for and remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation
persists, seek medical attention.
INGESTION: Give two glasses of water for dilution; Induce vomiting by sticking fingers down throat; never give anything by mouth to an
unconscious person; seek medical attention.
SECTION 5 - FIRE FIGHTING MEASURES
FLAMMABLE LIMITS LEL: 2.6% UEL: 12.8%
FLASH POINT (METHOD USED)
AUTOIGNITION TEMPERATURE: NFPA CLASS:
869?F (465?C)
20.3?F ( -6.5?C ) TCC IA
GENERAL HAZARDS: Product is flammable. Products of combustion include compounds of carbon, hydrogen and oxygen, including carbon
monoxide.
EXTINGUISHING MEDIA
Carbon dioxide, water, water fog, dry chemical, chemical foam.
FIRE FIGHTING PROCEDURES
Self - contained respiratory equipment; cool containers to prevent pressure buildup and possible explosion when exposed to extreme heat.
Caution - material is flammable!
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers can explode due to buildup of pressure when exposed to extreme heat. Vapors may cause a flash fire or ignite
explosively. Vapors may travel a considerable distance to a source of ignition and flash back.
HAZARDOUS COMBUSTION PRODUCTS
Smoke, fumes or vapors, oxides of carbon.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: COMBUSTIBLE - Evacuate and ventilate area; remove all sources
of sparks, ignition and open flames; confine and absorb into approved absorbent; place material into approved containers for disposal; do not
wash to sewer or waterway.
SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: This material is combustible. It should be stored in tightly closed containers
in a cool, well ventilated area. Vapor may form explosive mixtures in air. All sources of ignition should be controlled. This material may be
classified as Flammable liquids, n.o.s. UN 1993 if transported by vessel or aircraft. Certain exemptions may qualify for shipping as ORM-D.
Refer to 49 CFR 173.120. Keep this and other chemicals out of reach of children. Avoid inhaling concentrated fumes or vapors.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation of confined spaces.
Use explosion-proof ventilation equipment.
PERSONAL PROTECTION:
RESPIRATORY PROTECTION: None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds
limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134, ANSI Z88.2, or European Standard EN 149 for complete
regulations.
PROTECTIVE GLOVES: Neoprene, butyl or nitrile rubber gloves with cuffs.
EYE PROTECTION: Chemical splash goggles. Refer to 29 CFR 1910.133, ANSI Z87.1, or European Standard EN166.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyewash station nearby.
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Supershine?Clear Fast Drying Hoof Polish & Sealer
Page 3 of 4
December 16, 2008
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR VAPOR DENSITY (AIR = 1)
Black liquid, acetone odor >1
SPECIFIC GRAVITY (WATER = 1) EVAPORATION RATE (Water = 1)
0.865 <1
SOLUBILITY IN WATER % VOLATILE (BY WEIGHT)
Highly miscible 78%
pH VAPOR PRESSURE
Not applicable 184 mm Hg @ 20?C
BOILING POINT FREEZING POINT
133?F ( 56.1?C ) Not determined
VISCOSITY VOLATILE ORGANIC COMPOUNDS (VOC's)
Slightly viscous 5.05 pounds / gallon ( 601 grams / liter )
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Extreme temperatures, open flames.
STABILITY UNSTABLE:
STABLE: X
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of
carbon, hydrocarbons, fumes or vapors, and smoke may be produced.
CONDITIONS TO AVOID: None
HAZARDOUS POLYMERIZATION MAY OCCUR:
WILL NOT OCCUR: X
SECTION 11 - TOXICOLOGICAL INFORMATION
LD50 of Ingredient LC50 of Ingredient
Hazardous Ingredients CAS # EINECS #
Species and Route Species
5800 mg / kg 50,100 ppm / 8H
Acetone (b,c) 67-64-1 200-662-2
Oral - rat Inhalation - rat
317 mg / kg 82 ppm
Phenol (a,b,c,d,e,f) 108-95-2 203-632-7
Oral - rat Inhalation - rat
(a,c) See Section 15
SECTION 12 - ECOLOGICAL INFORMATION
No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Based on the
chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system in
limited quantities. However, such treatment should be evaluated and approved for each specific biological system. None of the ingredients in
this mixture are classified as a Marine Pollutant.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. This product may produce hazardous
vapors in a closed disposal container creating a dangerous environment. Refer to 40 CFR 260 - 299 for complete waste disposal regulations.
Consult your local, state, or federal agency before disposing of any chemicals. Do not flush to sanitary sewer or waterway. According to the
European Waste Catalogue, waste codes are application specific and should be assigned by the user based on the application for which the
product is used.
SECTION 14 - TRANSPORT INFORMATION
PROPER SHIPPING NAME: Consumer Commodity
DOT HAZARD CLASS / Pack Group: ORM - D / None IATA HAZARD CLASS / Pack Group: 3.3
REFERENCE: 49 CFR 173.144-.156 IMDG HAZARD CLASS: 3.3
UN / NA IDENTIFICATION NUMBER: None (domestic US only) RID/ADR Dangerous Goods Code: 3.3
LABEL: None Required UN TDG Class / Pack Group: 3.3
HAZARD SYMBOLS: None Hazard Identification Number (HIN): None
Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United
Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes,
packaging materials and methods of shipping.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Supershine?Clear Fast Drying Hoof Polish & Sealer
Page 4 of 4
December 16, 2008
SECTION 15 - REGULATORY INFORMATION
TSCA (Toxic Substance Control Act)
All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory) or are exempted
from listing because a Low Volume Exemption has been granted in accordance with 40 CFR 723.50.
SARA TITLE III (Superfund Amendments and Reauthorization Act)
311/312 Hazard Categories
Immediate health, fire hazard
313 Reportable Ingredients:
(a) Indicates a toxic chemical subject to annual reporting requirements of Section 313 of the Emergency Planning and Community Right-To-
Know Act of 1986 and of 40 CFR 372.
CERCLA (Comprehensive Response Compensation and Liability Act)
(c) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or
spills to the environment of the Reportable Quantity (RQ for this mixture = 7,000 lbs) or greater amounts, according to 40 CFR 302.
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986
There are no reportable chemicals present known to the state of California to cause cancer or reproductive toxicity.
CPR (Canadian Controlled Products Regulations)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the
information required by the Controlled Products Regulations. WHMIS Classification: B2, D2B
IDL (Canadian Ingredient Disclosure List)
Components of this product identified by CAS number and listed on the Canadian Ingredient Disclosure List are shown in Section 3.
DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List)
Components of this product identified by CAS number are listed on the DSL or NDSL, or are otherwise in compliance with the New
Substances Notification (NSN) regulations. Only ingredients classified as "hazardous" are listed in Section 3 unless otherwise indicated.
EINECS (European Inventory of Existing Commercial Chemical Substances)
Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances.
WGK Water Quality Index: 1 VbK Index: A I
Risk Phrases SYMBOL(S) REQUIRED Safety Phrases
FOR LABEL
R11 Highly flammable. S9 Keep container in a well-ventilated place.
R36 Irritating to eyes. S16 Keep away from sources of ignition.
R66 Repeated exposure may cause skin dryness Flammable Irritant S26 In case of contact with eyes, rinse immediately
or cracking. with plenty of water and seek medical advice.
R67 Vapours may cause drowsiness and
dizziness.
SECTION 16 - OTHER INFORMATION
Specific toxicity tests have not been conducted on this product. Our hazard evaluation is based on information from similar products, the
ingredients, technical literature, and/or professional experience.
HMIS HAZARD RATINGS HEALTH * = Chronic Health Hazard 2 = MODERATE
2*
FLAMMABILITY 0 = INSIGNIFICANT 3 = HIGH
3
PHYSICAL HAZARD 1 = SLIGHT 4 = EXTREME
0
PERSONAL PROTECTIVE EQUIPMENT Safety Glasses, Gloves
B
REVISION SUMMARY: MSDS Prepared by:
This MSDS has been revised in the following sections: Comprehensive Data Base, Inc.
No changes noted P.O. Box 686
Seffner, FL 33583 USA
(863) 644 - 3298 www.compdatabase.com or www.msds.cc
The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the
manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current,
applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use
of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as
described in Section 1.
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