sarBrrDlra ssrnr 02760
ilonrnnur-,
@ Pg.
Rcviseal 4116198
Contact Information
ChBnical Product
1.
Part Numbers:
Bakelite Preforms/
ProductName:
SeeSection16
PowderelPellets
LEqO Corporation
3000rlakeview
St. J{seph, 1\lll' 49085
616-983-5531
Inforjmation:
800-424-9300
Che$tres
202483-7616')
(Chehtrec Int'[
mposifion/Information on Ingredients
2.
Typialo/o
ACGIH
OSHA
bv V/eight
TLV
PEL ,,
No.
9AS
<3
5 ppm skin
108-95-2 5 ppn skin
Phcnol
Carbong$ct 3.5mg/nE
1333-864 3.5mg/mH
<18
2mg/mE
2.4mg/mE
None
Coal Dust
<40
2 mg/mB
7782-42-s 15mppof
Oraphite
<60
t200ra6-2 20 mppcf 3 nc/mE
Mica
<20
2rrglmB
14307-96-6 20 mppcf
Talc I
<70
l0 mg/mHInhale
15mg/mETotal
Particles otherwise
nbt
3 mg/mERespir
5 mg/mERespir
(PNOC)
classified
Iljrzard Identification
3.
EnmncrncvOrrenrmw
I
No ungsufi spill bazard,moderatefirc hazar{ moderatehealthrisk by ingestion/inhalatioL Gmnular,
nodular,pellet orbriquette fomr with a slightphenol odor. Phenolic molding conpoundwithtwo stage
rcsin. i
HealthI Iazard Data
applies tbccompound theform
in
infurmstion
othenrise, following to
the
:cificallyindicated
Unlessspr
sol4 nott o articles,parts, eto. molded of the oompound. norns,l moldiag, tbe rneterial substantially
In
completesits progressionto a cross-linkedinsoluble,infusiblc solid.
polf.mer)
As sold l te product is aplastie moldirg compound:A plastic resin (Phenol-formaldabyde
ildr"trrj mixed andrpactedwith one or urors of a variety of orgmic and /inorganic filhng materials.
PA[: E11-110
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I
r!
i
Pe.2
I
Sngnr 02760
M.rrnni^lr, SaFnrYD.lr^1,
fully *crued"orleasted,ft" pl-d" . .- |
Howtcr, *assold" I
filling matcrials.
embedded
infirsibleandbindsthewell-disperse4
t"rio i" ins{iluble,
ingredicnrs
some unreacted
"curcd' or reaoted contains
and
thc plcsticiesin is not oompletcly I
unlikelyto poseahazudibut because I
churicals areexuernely
these
thtl io it Sodissolved,
dissolved
Es
theyaretuf-Oo* in thcir purcforms,OSIIA requires tloey rcported describe haandoB I
and
be
that
of hazandous
urount
.efrOrrtl. Undernormalconditions storage handling, significant
no
and
of
I
vapory I
phonol is more solubleh tbe resin than in umter,
should evoive from the "as sold" product. Because I
thcncis noltit"ty significanthealth hszad tbrcWh skin absorption.The greatmajority of filling I
I
materials
within cornpoundgrauulestbat are large enougbnot to corrstiartean inhalation
are embed&ed
someparticlesof plastic resin and/m filling matsrialsmay be Presntin a size that
Nelvertheless,
bazaral. ]
inorganicE[ing matsrial mixcd in
con*ituteq a respirabledust (including in someproductsup to 19/o
afrr i
compounding).This respirabledust noaycontain one ot more of the following matsials: carbonblaslq
coal dust, FUrousglass,graphirc,mica, mineral wool fiber, talc, and/orwood florr (soft). Chronic
inhalation bf eachofthe abovehrs bnassociatedwith fibrotic hng diseasc. most or all' it has
For
bccn i
especiallyamongsurokers.Inhalationof dust should be
tirloftrrng carrcer,
associaediwith increased
and good-ventilation,but if not , respiratorsshould
iavoidableivith propa matErialhandtingprocedures
wom. [he primary asutehealth risk ftom oiposlrrc to ihe product "as sold" is initation, especially
lbe
Oe dirst. Ingestion,intralationof dust, and contactwith skin and eyesshouldbe avoided.
Itom
ti
curingoftbe productdrring normalproccssing) deoomposition
lAg used puring polymerization (e-g., or
gaseous phenoland
l(c.g.,ovcr,hcating bumingof theproduct) smallanouutsof ammonia,
or
of
dioxidcale cvolvcd.Breathing
(aswell aswaftr vapor,catrbon mouoxide, carbon
and
lformataeryrde
firmes ib" htrmftl. [f theodorof ammonia formaldehyde noticeable, tbeairborne
is then
or
cE
l
improrcments
should carefullymonitorcd andventilation
lconcentrat{on those
of chemicals be
consiilered.
I
approaching orceeding PELs.
the
beginto bedctectable odorat consentrstions, or
by
lThosechdmicals
abo$ one-fifft.thePEL.In any case,
lTheodor{lf 6enol begins benoticeable a concentration
to at
pf ventilation bestbedetermined useof instrmentsto monitorairborreconceatratims
by
can
ladequary
a
lof a'nmo{ia"phenol, formaldehyde. matcrialmaycre,ate
Crindingor machining cured
and of molded
smallamormts gaseous ammonia
hazard inhaled mayrelease
and of
IdustthatBi,oses a respiratory if
or Ehronic fledth llaznrd Inforqation Ordinry uscof thisproductis unlikely to produce
lAcute
phenricals. to
cherricals setat levelsdesigned avoid
PELgfor these
lsignifica4 er|posure hazardous
to are
with propcrmaterial procedures, veirtilationand
lanysigru$cant health andareachiwable
risk handling
Nevertheless, OSHArequirements, foflowiqgis a list of possible if
per healthttazard
the
lhousekeefing.
lonewerebxposed thefotlowingchcmicals lwcls muchhigber,or in a ditrerent form, thm expected
at
to
fron ordiirary of thisproduct:
use
: Higbty toxic. Poisoningmay ocour via skin absorption,vapor inhalation, or ingcstion.
of the vaporsmay caussevene initation to the nose,thmat and respiratorytract lvlay cause
liver, , andhcart.lantagc.
- Irritantto eyes,
lungs,andskin.Hasbeenshown carsecanccr
inlaboratory
to
PAII 811-110
v uv6/v6 Io: zd t a-tr oLo vvz 6v t I
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Serntv Dlre SnPnr 02760
thefollowingstatement included:
be
animals.
Nationaloanoer
canccr.
rioal(formaldehydefknounr theState Califomiato caus
of
to
containsa
exposure cancer humans'
in
to
fomraldohyde
finds littte cvidencc connect
to
institute
tract'
respiratory
and
Aubioda - Irritantto eyes, membranes
mucous
- with
tracb.Exposure high levelsis associaed
sf
utu"f - toituotto eyesandreryiratory
ffi"
deolinesin inulmonaryfirnstion and cardiovascularshcss.
- Initant to eyes,nose,and throal Can causerespiratoryCfrectssgch as
bronchitig emphysemaand progrcssivemassivcfib,rosis,with long et(Po$ur.
init*ion andinflamation
- Mechanical noseanilskin Cancause
initat to eyes,
tact'
regionandupperrespiratory
ngeal
ofthe
studies
pneumoconiosiq although
- lrit oito oyes respGtorytrasts. cause
Can
md
pneumocnniosis a mixcd dtst reaetioa
is
suggest
t- loit*t to eyes.OSTIAbeliwes tbat t?teevidencestongly sugges$thst it is a
agF t.
- Initantto eyesand skin. Severalsnrdicshave shoun cxoossrisk of non
nalignant IrcspiratorYdissase.
is
Mcdicalevidcnce
hacts.
membranes respiratory
and
mucous
, lnitant to eyes,
talcs containamphibolesand othe,r minc'rals.
by the
(poft) - lnitant to eyes,muoousmembranes rryperrespiratorytrasB. Vrious
and
lorn
speciesof lrvooddust can Elicit allcrgic conhct dernratitisin snsitizedindividuals. May cause
respiritory
scnsitizatidn.
Aid Measures
medical
amouots watsrfor at least15minutes.Cret
of
wi& copious
@rsh
an$mion.
SKIN:i Washtborougbly with soapand water.
vcntilation. Ifbreathing is affcst4 removeto fresh air. tf
,ATION: Use with adequate
rthing stops,apply mouth to mouth resusciadon. Get medical atteffion.
TION: If consciotu, give water im:ncdiately ond inducevomiting by placing finger down
Never give anythingby mouthto an unconsciols person- Cretnedical atffition.
Fighting Measures
Method Used: Not applicable'
No flashpoint.
Point:
Limits (% W Volumein Air):
[mmable
Upper: No data
Lower: Dut 0,030ozlfti
I
TEMPERATURE: applicable.
Not
AUIO-IGNITION
COMBUSTION PRODUCTS: Not available.
MEDIA: Water,foam,dry ohe,mical,
cubondioride.
hathingapparatus
approvedself-containcd
MSHAA.IIOSH
GHTINGINSTRUCTIONS:
when fighting fircs in an enclosedareaare recommended.Avoid inhqlation of gases. Orgaaic dust/air
PAt: 811-1r0
o
Pg-4
SrrnrvData SrmnrA2764
ard
a&osphrrs
or dust-ladcn
mixtures @ @
a
of
sources ryrition.
Measures
Ac idental Release
6.
sawdut'or sand'Avoid
comPound"
SI{AL
merecommended. produot contains
This
motors
witb explosion-proof
ger b*i* dust. Vacrnrm
e
whichis subjectto
frerIpnenot
Ht ndling and Storage
7.
practices. Preveotarqrmulations of dust raisddrrring
TIAND
pra )essrng.Use adequateventilation.
rGE: Kccp containerclosedto avoid contamination. Store io .ool' dty plt"t.
STOR"
ControlslPersonalProtection
Er Dosure
E.
dtring usc.
ENGNigER$IC CONTROLS:Uselocalexhaust removsdusts[d vspolsevolved
to
Us ,explosion-proof
motors.
ifTLVs arc
rccommctrded
MOSH approved respirarors
IATORY PROTECTION:
RESP]
CXI ceded.
recommendcd-
SKIN \IID HAND PROTBCTION:Gloves
glasses sideshields.
with
Safety
PROTECTION:
EYEI ND FACE
good
EQUIPMENT:Eyewashfaoilig shouldbeavailable.Practice
OTI{E t PROTECTrVE
andmaintain cleanworkenvironnent.
a
hy ;iene
Pl ysical and Chemical Properties
9.
APPE\RANCE: Granular,nodular,pellct or briqucttc.
BOIL]NG POINT: Not available.
FREEZE-MELT POINT: Not availablc.
VAPC PRESSURE(mm): Not available.
R
VAPCRDENSITY (air: 1): Notavaiiable.
SOLU BILITY IN S/ATEk Negligible.
-2.20
SPEC. GRAWIYz1.32
FIC
pH: It ot available.
odor.
ODOI.: Slightphenol
VOI-A.TILES:Not available.
PERC UNT
=
EVAI ORATIONRATE (Butyl AcEtat l): Not available.
10. silability and Reactivity
at
Avoid coffanination,elposurcto flameor hcat,or storagc
CIIEI IICAL STABILITY: Stable.
te lperanres excess l00iF.
in of
maffiials,this producr sensitive ssng sxidi"ing
is
INCC \TIPATIBILITY:Like mostorganic to
a$;ntsandmayeithcrdecompose ienrite whenmixedwith same.
or
PAI: E11-110
O 7 / O 8 / g g W E D1 6 : 3 1 F A X 6 1 6 9 8 2 8 9 7 7 LECO TARTETING
Pg.5
Snrnrv Dlr^L Srupr 02760
MA
wolved duftS polynecization
may
Vepors
DECOIvpOStnONPRODUCTS:
TIAZA TDOUS
eoxain phenol,
formaldehyde ammonia
and
(DOUSPOLYa,IERIZATION: Should occur-
not
I{AZA
To ricologicalInformation
11.
Noaer ported.
12. Ec llogical Information
Not av ilable.
13. Di posal Consideration
Bury c incinerste accondanoc local,state ftderalrogulotions'
and
with
in
TI rnsportatio n Informadon
I4,
U.S"4,DOT: Not regulsted.
15. Rt gulatory Information
'IJKAL I(ts('ULATTUNS:
Controllweotory.
OnToxic Substance
STATUS:
None.
.A REPORTABLE QUAIITITY:
TITLE Itr:
None'
;tion302Erctemely}lazardous
Substanses:
Fire.
Chronic,
tion 311/312HazardousCotegorics:
Phenol
rtion313Toxic Chemicals:
Notrcgulated
STATUS:
[S: D1B
16. o her Information
P Numbers:
".tl
Brdck:
sll-110 811-111 811-111-250 811-113 8'rA2l 8L'A23
s1 8LlA29
8lr-X27-100
t-22s 8Lr-226 8rl-227
811-290 811-301 811-304
8l 1-230 811-288 811-289
8i 811-312 811-316
1-305 811-308811A09
Grl)en:
8ll-L22 811-123 811-rs+110 811-294 811-29s 8nA96
8lt-325 811-329 811-333
M4ttled (Brown/Green):
PA[: Ell-110
ut / u6/c6
Smp"rvData SmPr 02764
-127 811-128
(0-44=Extreme)
fndex:
qrcssd
arrdwn$ howetw, ,u rluflttlt
In goodlifrh as snthoritolfve
nenifunm
PAt: 811-110
|