Material Safety Data Sheet
Preparation Date: 04-Jan-2010 Revision Date: 29-Dec-2009 Revision Number: 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code F436-5021A
Trade Name PERMA-SHIELD FR GRAY
Contact Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Emergency Telephone Number 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
DANGER!
COMBUSTIBLE LIQUID AND VAPOR.
HARMFUL IF INHALED.
CAUSES SKIN AND EYE BURNS.
HARMFUL OR FATAL IF SWALLOWED.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT.
Potential Health Effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute Effects
Eyes Causes burns.
Skin Causes burns. May cause sensitization by skin contact.
Inhalation Irritating to respiratory system. Respirable crystalline silica (quartz) can cause silicosis, a
fibrosis (scarring) of the lungs.
Ingestion May be harmful if swallowed.
Chronic Effects
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Cancer hazard.
Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure.)
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Kidney disorders. Liver disorders. Skin disorders.
Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.
Potential Environmental Effects See Section 12 for additional Ecological information
Target Organ Effects Blood, Central nervous system, Central Vascular System, Eyes, Kidney, Liver, Lungs, Nasal
Cavities, Prostate, Respiratory system, Skin
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
CAS-No Weight %
Component
13463-67-7 10 - 30
TITANIUM DIOXIDE (TOTAL DUST)
10 - 30
MODIFIED POLYAMINE
98-00-0 15.7659
FURFURYL ALCOHOL
14808-60-7 11.5755
CRYSTALLINE SILICA (QUARTZ)
100-51-6 10.1831
BENZYL ALCOHOL
1477-55-0 5 - 10
M-XYLENEDIAMINE
66402-68-4 1-5
SILICON DIOXIDE/ALUMINUM OXIDE
65997-17-3 1-5
FIBROUS GLASS
7631-86-9 1-5
AMORPHOUS SILICA
7631-86-9 1-5
AMORPHOUS SILICA
1344-28-1 1-5
ALUMINUM OXIDES
108-95-2 1.491
PHENOL (SKIN)
25036-25-3 1-5
BISPHENOL A TYPE EPOXY RESIN
14808-60-7 0.2411
CRYSTALLINE SILICA (QUARTZ)
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable Properties Combustible material.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -
Foam - Dry chemical
Hazardous Decomposition Products Oxides of carbon, hydrocarbons. Ammonia.
Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective Equipment and Precautions for Firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier than
air and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system.
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Methods for Cleaning Up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
Other Information Not applicable
7. HANDLING AND STORAGE
Handling
Close container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. If
splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.
When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Storage
Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)
TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3 STEL:
TITANIUM DIOXIDE (TOTAL
15 mg/m3 20 mg/m3
DUST)
TWA: 40 mg/m3 TWA: TWA: 40 mg/m3 TWA: TWA: 10 ppm TWA: 40 TWA: 10 ppm TWA: 40
FURFURYL ALCOHOL TWA: 10 ppm Skin
10 ppm STEL: 15 ppm 10 ppm STEL: 15 ppm mg/m3 STEL: 60 mg/m3 mg/m3 STEL: 15 ppm
STEL: 15 ppm
STEL: 60 mg/m3 Skin STEL: 60 mg/m3 Skin STEL: 60 mg/m3
STEL: 15 ppm Skin
TWA: 200 mg/m3 TWA:
50 ppm
TWA: 0.025 mg/m3 TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 TWA: 0.10 mg/m3 TWA: 0.1 mg/m3
CRYSTALLINE SILICA
(QUARTZ)
Skin Ceiling: 0.1 mg/m3 Skin Ceiling: 0.1 mg/m3 Ceiling: 0.1 mg/m3 Skin CEV: 0.1 mg/m3 Skin Peak: 0.1 mg/m3
M-XYLENEDIAMINE
TWA: 5 mg/m3 TWA: TWA: 5 mg/m3 STEL: TWA: 5 mg/m3 TWA:
SILICON TWA: 0.5 fibres/cm3
TWA: 5 mg/m3 TWA:
3
10 mg/m3 0.2 mg/m3 STEL: 10
DIOXIDE/ALUMINUM OXIDE 0.2 mg/m
0.2 mg/m3 STEL: 10 mg/m3
mg/m3
Ceiling: 5 mg/m3 TWA: 10 mg/m3 TWA: 1 TWA: 1 fibres/cm3 TWA: 0.15 mg/m3 TWA:
FIBROUS GLASS TWA: 1 fiber/cm3 TWA:
5 mg/m3 TWA: 0.5 TWA: 0.2 mg/m3 TWA: 0.5 mg/m3 TWA: 0.1
fibre/cm3 TWA: 5
mg/m3 TWA: 0.05 mg/m3 TWA: 0.2 mg/m3 5 mg/m3 TWA: 0.1 mg/m3 TWA: 0.2 mg/m3
3 3 3 3
TWA: 5 mg/m3 TWA:
mg/m TWA: 0.2 mg/m TWA: 0.05 mg/m TWA: mg/m TWA: 0.01
TWA: 0.1 mg/m3 TWA: 0.5 mg/m3 TWA: 0.02 mg/m3 TWA: 0.002 0.01 mg/m3 TWA: 0.002
0.02 mg/m3 TWA: 0.01 mg/m3 TWA: 0.025 mg/m3 TWA: 0.05 mg/m3 STEL: 10 mg/m3
3
mg/m TWA: 0.1 mg/m mg/m3 TWA: 0.5 mg/m3
3 3
mg/m TWA: 0.002
mg/m3 STEL: 10 mg/m3 STEL: 0.6 mg/m3 STEL:
10 mg/m3
3 3 3
TWA: 10 mg/m3 TWA: 10 mg/m3
ALUMINUM OXIDES TWA: 1 mg/m TWA: 10 mg/m TWA: 5 TWA: 10 mg/m
mg/m3 TWA: 15 mg/m3
TWA: 19 mg/m3 TWA: 5 TWA: 19 mg/m3 TWA: 5 TWA: 5 ppm TWA: 19 TWA: 19 mg/m3 TWA: 5
PHENOL (SKIN) TWA: 5 ppm Skin
mg/m3 Skin
ppm Skin ppm Skin ppm STEL: 10 ppm
STEL: 38 mg/m3
3 3 3 3
TWA: 0.1 mg/m3
CRYSTALLINE SILICA TWA: 0.025 mg/m TWA: 0.1 mg/m TWA: 0.1 mg/m TWA: 0.10 mg/m
(QUARTZ)
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Engineering Measures Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Skin Protection Lightweight protective clothing, Apron, Impervious gloves
Eye/face Protection Goggles. If splashes are likely to occur, wear face-shield.
Respiratory Protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,
wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.
Follow respirator manufacturer's directions for respirator use.
General Hygiene Handle in accordance with good industrial hygiene and safety practice.
Considerations Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point 77癈 / 170.0癋
Boiling Point/Range No information available.0.0
Upper Exposure Limits No information available
Lower Exposure Limits No information available
Evaporation Rate No information available
Vapour Pressure No information available
Vapour Density No information available
Specific Gravity 1.46958
Density 12.22911
VOC Content (lbs/gal) 2.100
% Volatile by Weight 17.1730
% Volatile by Volume 22.5535
10. STABILITY AND REACTIVITY
Chemical stability Stable. Conditions to Avoid Heat, flames and sparks. Epoxy
constituents.
Incompatible Products Strong oxidizing agents. Bases. Possibility of Hazardous None under normal processing
Acids. Reducing agents. Reactions
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
TITANIUM DIOXIDE (TOTAL DUST) 10000 mg/kg ( Rat )
FURFURYL ALCOHOL 177 mg/kg ( Rat ) 3825 mg/kg ( Rat ) 400 mg/kg ( 233 ppm ( Rat ) 4 h
Rabbit )
CRYSTALLINE SILICA (QUARTZ) 500 mg/kg ( Rat )
BENZYL ALCOHOL 1230 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 8.8 mg/L ( Rat ) 4 h
M-XYLENEDIAMINE 930 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 700 ppm ( Rat ) 1 h
AMORPHOUS SILICA 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.2 mg/L ( Rat ) 1 h
AMORPHOUS SILICA 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.2 mg/L ( Rat ) 1 h
ALUMINUM OXIDES 5000 mg/kg ( Rat )
316 mg/m3 ( Rat ) 4 h
PHENOL (SKIN) 317 mg/kg ( Rat ) 525 mg/kg ( Rat ) 630 mg/kg ( Rabbit
)
CRYSTALLINE SILICA (QUARTZ) 500 mg/kg ( Rat )
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Irritation No information available
Corrosivity No information available
Sensitization No information available
Chronic Toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component ACGIH IARC NTP OSHA Mexico
TITANIUM DIOXIDE (TOTAL Group 2B X
DUST)
CRYSTALLINE SILICA A2 Group 1 Known X
(QUARTZ)
FIBROUS GLASS Group 1 Group 2A
CRYSTALLINE SILICA A2 Group 1 Known X
(QUARTZ)
Mutagenic Effects No information available
Reproductive Effects No information available
Developmental Effects No information available
Teratogenicity No information available
Target Organ Effects Blood, Central nervous system, Central Vascular System, Eyes, Kidney, Liver, Lungs, Nasal
Cavities, Prostate, Respiratory system, Skin.
Endocrine Disruptor Information No information available
Component EU - Endocrine Disrupters EU - Endocrine Disruptors - Japan - Endocrine Disruptor
Candidate List Evaluated Substances Information
FURFURYL ALCOHOL Group III Chemical
BISPHENOL A TYPE EPOXY RESIN Group III Chemical
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
FURFURYL ALCOHOL LC50= 32 mg/L Pimephales EC50 = 328 mg/L 24 h
promelas 96 h
BENZYL ALCOHOL EC50 = 35 mg/L 3 h LC50= 460 mg/L Pimephales EC50 = 63.7 mg/L 5 min EC50 EC50 = 23 mg/L 48 h
promelas 96 h LC50= 10 mg/L = 63.7 mg/L 15 min EC50 =
Lepomis macrochirus 96 h 71.4 mg/L 30 min EC50 = 50
mg/L 5 min
FIBROUS GLASS LC50 5.6 - 7.4 礸/L EC50 = 0.9 礸/L 48 h LC50 =
Pimephales promelas 96 h 5 礸/L 96 h LC50 1.4 - 2.3
LC50 9.4 - 9.7 礸/L 礸/L 96 h
Pimephales promelas 96 h
LC50 24.2 - 48.4 礸/L Lepomis
macrochirus 96 h
AMORPHOUS SILICA EC50 = 440 mg/L 72 h LC50= 5000 mg/L Brachydanio EC50 = 7600 mg/L 48 h
rerio 96 h
AMORPHOUS SILICA EC50 = 440 mg/L 72 h LC50= 5000 mg/L Brachydanio EC50 = 7600 mg/L 48 h
rerio 96 h
PHENOL (SKIN) EC50 = 150 mg/L 96 h LC50= 24 mg/L Pimephales EC50 = 28.8 mg/L 5 min EC50 EC50 = 23.0 mg/L 48 h LC50
promelas 96 h LC50= 8.9 mg/L = 31.6 mg/L 15 min EC50 = = 13 mg/L 48 h
Oncorhynchus mykiss 96 h 23.28 mg/L 5 min EC50 =
LC50= 23.88 mg/L Lepomis 25.61 mg/L 15 min EC50 21 -
macrochirus 96 h LC50 5 - 12 36 mg/L 30 min
mg/L Oncorhynchus mykiss 96
h LC50= 40 mg/L Poecilia
reticulata 96 h LC50= 27.8
mg/L Brachydanio rerio 96 h
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13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in accordance
with local, state and federal regulations.
Contaminated Packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other modes of Transportation.
Proper Shipping Name PAINT IN OIL
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Does not Comply
CHINA Does not Comply
ENCS Does not Comply
KECL Does not Comply
PICCS Does not Comply
AICS Does not Comply
U.S. Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - Threshold
Values
PHENOL (SKIN) 108-95-2 1.491 1.0
SARA 311/312 Hazardous Categorization
Chronic Health Hazard No
Acute Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
Quantities
SILICON DIOXIDE/ALUMINUM X
OXIDE
FIBROUS GLASS X
PHENOL (SKIN) 1000 lb X X X
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs
PHENOL (SKIN) 1000 lb 1000 lb
U.S. State Regulations
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California Proposition 65
This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65
CRYSTALLINE SILICA (QUARTZ) 14808-60-7 Carcinogen
FIBROUS GLASS 65997-17-3 Carcinogen
CRYSTALLINE SILICA (QUARTZ) 14808-60-7 Carcinogen
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
TITANIUM DIOXIDE (TOTAL X X X X
DUST)
FURFURYL ALCOHOL X X X X
CRYSTALLINE SILICA X X X X
(QUARTZ)
BENZYL ALCOHOL X X
M-XYLENEDIAMINE X X X X
SILICON X X X
DIOXIDE/ALUMINUM OXIDE
FIBROUS GLASS X X X X X
AMORPHOUS SILICA X X
AMORPHOUS SILICA X X
ALUMINUM OXIDES X X X X
PHENOL (SKIN) X X X X X
CRYSTALLINE SILICA X X X X
(QUARTZ)
Other International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
D2B Toxic materials
E Corrosive material
Component NPRI
FURFURYL ALCOHOL Part 5 Substance
ALUMINUM OXIDES Part 1, Group 1 Substance (fibrous form)
PHENOL (SKIN) Part 1, Group 1 Substance
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date: 29-Dec-2009
Revision Summary No information available
HMIS Health 0 Flammability 0 Reactivity 1
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Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any
of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards which exist.
End of MSDS
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Material Safety Data Sheet
Preparation Date: 30-Dec-2009 Revision Date: 29-Dec-2009 Revision Number: 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code F436-0436B
Trade Name PERMA-SHIELD FR EPOXY
Contact Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Emergency Telephone Number 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
WARNING!
COMBUSTIBLE LIQUID AND VAPOR.
HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT.
Potential Health Effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute Effects
Eyes Irritating to eyes.
Skin Irritating to skin. May cause sensitization by skin contact.
Inhalation Irritating to respiratory system.
Ingestion May be harmful if swallowed.
Chronic Effects
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Kidney disorders. Liver disorders. Skin disorders.
Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.
Potential Environmental Effects See Section 12 for additional Ecological information
Target Organ Effects Blood, Central nervous system, Central Vascular System, Eyes, Kidney, Liver, Lungs, Nasal
Cavities, Prostate, Respiratory system, Skin
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
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3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS-No Weight %
Component
25085-99-8 60 - 100
BISPHENOL A TYPE EPOXY RESIN
98-00-0 5.8905
FURFURYL ALCOHOL
7631-86-9 1-5
AMORPHOUS SILICA
65997-17-3 1-5
MINERAL FIBER
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable Properties Combustible material.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -
Foam - Dry chemical
Hazardous Decomposition Products Oxides of carbon, hydrocarbons. Aldehydes.
Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective Equipment and Precautions for Firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier than
air and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system.
Methods for Cleaning Up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
Other Information Not applicable
7. HANDLING AND STORAGE
Handling
Close container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. If
splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.
When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
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Storage
Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)
TWA: 40 mg/m3 TWA: TWA: 40 mg/m3 TWA: TWA: 10 ppm TWA: 40 TWA: 10 ppm TWA: 40
FURFURYL ALCOHOL TWA: 10 ppm Skin
10 ppm STEL: 15 ppm 10 ppm STEL: 15 ppm mg/m3 STEL: 60 mg/m3 mg/m3 STEL: 15 ppm
STEL: 15 ppm
STEL: 60 mg/m3 Skin STEL: 60 mg/m3 Skin STEL: 60 mg/m3
STEL: 15 ppm Skin
TWA: 200 mg/m3 TWA:
50 ppm
Ceiling: 5 mg/m3 TWA: 10 mg/m3 TWA: 1 TWA: 1 fibres/cm3 TWA: 0.15 mg/m3 TWA:
MINERAL FIBER TWA: 1 fiber/cm3 TWA:
5 mg/m3 TWA: 0.5 TWA: 0.2 mg/m3 TWA: 0.5 mg/m3 TWA: 0.1
fibre/cm3 TWA: 5
mg/m3 TWA: 0.05 mg/m3 TWA: 0.2 mg/m3 5 mg/m3 TWA: 0.1 mg/m3 TWA: 0.2 mg/m3
mg/m3 TWA: 0.2 mg/m3 TWA: 0.05 mg/m3 TWA: mg/m3 TWA: 0.01 TWA: 5 mg/m3 TWA:
TWA: 0.1 mg/m3 TWA: 0.5 mg/m3 TWA: 0.02 mg/m3 TWA: 0.002 0.01 mg/m3 TWA: 0.002
0.02 mg/m3 TWA: 0.01 mg/m3 TWA: 0.025 mg/m3 TWA: 0.05 mg/m3 STEL: 10 mg/m3
mg/m3 TWA: 0.002 mg/m3 TWA: 0.1 mg/m3 mg/m3 TWA: 0.5 mg/m3
mg/m3 STEL: 10 mg/m3 STEL: 0.6 mg/m3 STEL:
10 mg/m3
Engineering Measures Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Skin Protection Lightweight protective clothing, Apron, Impervious gloves
Eye/face Protection If splashes are likely to occur, wear Goggles.
Respiratory Protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,
wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.
Follow respirator manufacturer's directions for respirator use.
General Hygiene Handle in accordance with good industrial hygiene and safety practice.
Considerations Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point 77癈 / 170.0癋
Method Pensky Martens - Closed Cup
Boiling Point/Range No information available
Upper Exposure Limits No information available
Lower Exposure Limits No information available
Evaporation Rate No information available
Vapour Pressure No information available
Vapour Density No information available
Specific Gravity 1.18513
Density 9.86206
VOC Content (lbs/gal) .581
% Volatile by Weight 5.8910
% Volatile by Volume 6.1735
10. STABILITY AND REACTIVITY
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10. STABILITY AND REACTIVITY
Chemical stability Stable. Conditions to Avoid Heat, flames and sparks.
Amines.
Incompatible Products Strong oxidizing agents. Bases. Possibility of Hazardous None under normal processing
Acids. Amines. Reducing agents. Reactions
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
FURFURYL ALCOHOL 177 mg/kg ( Rat ) 3825 mg/kg ( Rat ) 400 mg/kg ( 233 ppm ( Rat ) 4 h
Rabbit )
AMORPHOUS SILICA 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.2 mg/L ( Rat ) 1 h
Irritation No information available
Corrosivity No information available
Sensitization No information available
Chronic Toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component ACGIH IARC NTP OSHA Mexico
MINERAL FIBER Group 1 Group 2A
Mutagenic Effects No information available
Reproductive Effects No information available
Developmental Effects No information available
Teratogenicity No information available
Target Organ Effects Blood, Central nervous system, Central Vascular System, Eyes, Kidney, Liver, Lungs, Nasal
Cavities, Prostate, Respiratory system, Skin.
Endocrine Disruptor Information No information available
Component EU - Endocrine Disrupters EU - Endocrine Disruptors - Japan - Endocrine Disruptor
Candidate List Evaluated Substances Information
BISPHENOL A TYPE EPOXY RESIN Group III Chemical
FURFURYL ALCOHOL Group III Chemical
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
FURFURYL ALCOHOL LC50= 32 mg/L Pimephales EC50 = 328 mg/L 24 h
promelas 96 h
AMORPHOUS SILICA EC50 = 440 mg/L 72 h LC50= 5000 mg/L Brachydanio EC50 = 7600 mg/L 48 h
rerio 96 h
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Component Freshwater Algae Freshwater Fish Microtox Water Flea
MINERAL FIBER LC50 5.6 - 7.4 礸/L EC50 = 0.9 礸/L 48 h LC50 =
Pimephales promelas 96 h 5 礸/L 96 h LC50 1.4 - 2.3
LC50 9.4 - 9.7 礸/L 礸/L 96 h
Pimephales promelas 96 h
LC50 24.2 - 48.4 礸/L Lepomis
macrochirus 96 h
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in accordance
with local, state and federal regulations.
Contaminated Packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other modes of Transportation.
Proper Shipping Name PAINT IN OIL
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Does not Comply
CHINA Complies
ENCS Does not Comply
KECL Complies
PICCS Complies
AICS Complies
U.S. Federal Regulations
SARA 313
SARA 311/312 Hazardous Categorization
Chronic Health Hazard No
Acute Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
Quantities
MINERAL FIBER X
CERCLA
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
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Component CAS-No California Prop. 65
MINERAL FIBER 65997-17-3 Carcinogen
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
FURFURYL ALCOHOL X X X X
AMORPHOUS SILICA X X
MINERAL FIBER X X X X X
Other International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
B3 Combustible liquid
D2B Toxic materials
Component NPRI
FURFURYL ALCOHOL Part 5 Substance
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date: 29-Dec-2009
Revision Summary No information available
HMIS Health 2 Flammability 2 Reactivity 1
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any
of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards which exist.
End of MSDS
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