MATERIAL SAFETY DATA SHEET
Manufacturer: Schaeffer Mfg. Company Emergency Response Number:
Address: 102 Barton Street 314-865-4105 (24 hr Emergency Response) or
Address St. Louis, MO 63104 800-325-9962
SECTION 1 ?PRODUCT INFORMATION
Trade Name: #137ND Diesel Treat 2000 Ultra Low
Chemical Family: Petroleum Hydrocarbons
Sulfur Diesel
Formula: Proprietary Mixture
SECTION 2 ?HAZARDOUS INGREDIENTS
COMPONENTS-CHEMICAL NAMES AND COMMON CAS Exposure Limits
NAMES Number % TVL PEL
3 3
ppm mg/m ppm mg/m
Amines, polyethylene poly-reaction products with succinic 84605-20-9 20-30 NE NE
anhydride isobutylene derivatives
Xylene 1330-20-7 0.85-1.44 434 100 435
Light Aromatic Solvent Naphtha 64742-95-6 0.8-2 100 NE
2-Ethyl Hexyl Nitrate 27247-96-7 30-40 8
Petroleum Distillates 64742-47-8 15-20 200
Proprietary polymers Mixture 2-5 NE NE
Cumene 98-82-8 0.4-0.581 50 246 50 245
1,2,4 Trimethylbenzene 95-82-6 .0.55-6.57 25 25
Heavy Aromatic Solvent Naphtha 64742-94-5 7-21 NE NE
Ethylbenzene 100-41-4 <1.7 100 434 100 435
Naphthalene 91-20-3 0.17 ?2.2 25 25
Benzene 71-43-2 0.00021 10 32 10
1,3,5 Trimethylbenzene 108-67-8 0.02-0.098 25 NE
2-Butoxyethanol 111-76-2 5-10 NE NE
Trimethylbenzene 25551-13-7 0.235-1.15 25 NE 25 NE
Section 3 ?PHYSICAL DATA
Boiling Point: 300癋/148.8癈 Specific Gravity: 0.9234 - 0.9254
Vapor Pressure (mm, Hg): <.1 % Volatile: <15
Vapor Density (Air = 1): Not Determined Evaporation Rate: (=1) Not Determined
Solubility in Water: Disperses pH: Not Applicable
Appearance and Odor: Dark color, slight aromatic odor.
SECTION 4 ?FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method) 癋/癈: 135?144癋/57?62篊 PMCC Flammability Limits UEL & LEL ----Not Determined
Extinguishing Media: Carbon dioxide foam, dry chemical foam, sand, earth, waterfog.
Special Fire Fighting Procedures: For fires involving this material, do not enter any enclosed or confined space without protective
equipment including self-contained breathing apparatus. Cool exposed containers with waterspray. Avoid breathing fumes.
Unusual Fire & Explosion Hazards: Vapors may be heavier than air and travel along the ground to a distant ignition source and flash
back. Containers may rupture upon heating. The 2-Ethyl Hexyl Nitrate contained in this product may undergo a self-accelerating
exothermic reaction if the product is heated above 212癋/100癈.
SECTION 5 - REACTIVITY HAZARD DATA
STABILITY [X] STABLE [ ]UNSTABLE Hazardous Decomposition [ ] WILL [X] WILL NOT OCCUR
Conditions to Avoid: High heat, high energy ignition sources
Incompatibility (Mat. to avoid): Strong oxidizing agents, amines, phenols, halogen compounds.
Hazardous Decomposition Products: Oxides of carbon and nitrogen and by-products of incomplete combustion.
Conditions to Avoid: None.
SECTION 6 - HEALTH HAZARD DATA
Threshold Limit Value and Sources: None Established.
Acute Effects of Overexposure:
Ingestion: Nausea, abdominal discomfort, diarrhea.
Eye Contact: Liquid contact produces severe irritation to the eyes.
Skin Contact: Prolonged and repeated skin contact may cause redness, severe irritation and defatting of skin. Product may be
absorbed though skin.
Inhalation: Inhalation of vapors can cause headache, dizziness, nausea, or decreased blood pressure..
CHRONIC EFFECTS OF OVEREXPOSURE: Repeated overexposure can cause liver and kidney damage.
Emergency and First Aid Procedures:
Swallowing: If a large amount of this material is swallowed give a large amount of water to drink. Do not induce vomiting. Seek
medical attention immediately.
Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water.
Inhalation: Remove victim to fresh air. If breathing has stopped start artificial respiration immediately.
Eyes: Flush eyes with clear, cool, clean water for 15 minutes. Seek medical attention immediately.
SECTION 7 ?SPILL OR LEAK PROCEDURES
Environmental Impact: This material is not expected to present any environmental problems other than those associated with oil spills.
If spilled into a watercourse, call the Coast Guard Toll Free No. 800-424-8802.
Procedures To Be Taken If Material Is Released or Spilled: Eliminate all sources of ignition. Absorb spills with absorbent clay
Ventilate confined spaces. Keep out of sewers and watercourses.
Waste Disposal Method: Dispose of at an approved waste or disposal site facility in accordance with all applicable federal, state and
local laws and regulations. This product is expected to be an RCRA hazardous waste due to its reactivity and presence of Benzene D018
Date Prepared: Rev. 08/27/2008 OF-1049 Rev. (1999)
#137ND
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SECTION 8 ?SPECIAL PROTECTION INFORMATION
Respiratory Protection: None required under ordinary conditions of use. Use NIOSH/MSHA approved full face respirator with an
organic cartridge if the recommended exposure limit is exceeded or when working with this material in a
confined space.
Ventilation: Use explosion proof ventilation to control vapor concentration.
Eye Protection: Chemical resistant goggles or full face shield.
Protective Clothing: Viton or Nitrile gloves. Wear long sleeve shirt or chemical protective suit and neoprene boots.
SECTION 9 ?SPECIAL PRECAUTIONS
Precautions To Be Taken In Handling and Storage: Do not store near heat, spark, flame or strong oxidizers. Keep containers closed
when not in use. Properly bond and ground containers and transferring equipment when transferring this product to different containers.
Special Comments: This product is a combustible liquid. Avoid breathing vapors. Avoid prolonged or repeated skin contact. Remove
contaminated shoes and clothing, launder before reuse. Throw away shoes. Wash skin thoroughly with soap and water after handling.
Keep away from food and feed products
SECTION 10 ?ADDITIONAL HEALTH AND TOXICOLOGICAL DATA
HMIS & NFPA Ratings: Health = 2 Fire = 2 Reactivity = 1
Contaminated clothing should be disposed of properly and/or decontaminated before reuse. Under no circumstance should vomiting be
induced. Vomiting can cause aspiration of the product into the lungs. If aspirated into the lungs, chemical pneumonia, which may cause
death in spite of treatment with oxygen and antibiotics, may occur.
This product contains 0.17-2.2% of Naphthalene CAS #91-20-3, 0.0021% of Benzene CAS # 71-43-2 , and <1.7% of Ethylbenzene
CAS# 100-41-4 which are chemicals found on the National Toxicology Programs Annual Reports, International Agency for Cancer
Research's Monographs or OSHA's Subpart Z list as suspected human cancer causing agents.
This product contains 0.17-2.2% of Naphthalene CAS #91-20-3, 0.00021% of Benzene CAS # 71-43-2 , and <7.1% of Ethylbenzene
CAS# 100-41-4 and 0.029-0.29% which are chemicals know to the State of California to cause cancer and/or birth defects.
For SARA Title III Information, see next page.
This product is an IRC (ignitable, corrosive, reactive) substance under CERCLA. If 36 gallons of the material is spilled
which will release 100lbs. of 2-Ethyl Hexyl Nitrate into the environment and unless the material is cleaned up immediately
for reprocessing, recycling or reuse this may trigger the reporting requirements of CERCLA Section 103.
All of the ingredients of this product are on the US TSCA Inventory list and are in compliance with the Canadian
Environmental Protection Act and are present on the Domestic Substance List.
DOT Shipping Name 5 gallon pails, 30 gallon drums and 55gallon drums: UN1993, Flammable Liquids, N.O.S.,
(Petroleum Distillates, Heavy Aromatic Naphtha, 2-Ethylhexyl Nitrate, 2-Butoxyethanol),3,PG III
DOT Shipping Name 4x1 gallon cases: UN1993, Flammable Liquids, N.O.S., (Petroleum Distillates, Heavy Aromatic
Naphtha, 2-Ethylhexyl Nitrate, 2-Butoxyethanol),3,PG III, Limited Quantity
DOT Shipping Name: Bulk: 275 and 330 gallon IBC: DOT Shipping Name 5 gallon pails, 30 gallon drums and 55gallon
drums: UN1993, Flammable Liquids, N.O.S., (Petroleum Distillates, Heavy Aromatic Naphtha, 2-Ethylhexyl Nitrate, 2-
Butoxyethanol),3,PG III, Marine Pollutant, (2-Ethylhexyl Nitrate, Naphthalene, 1,2,4 Trimethylbenzene)
DOT Shipping Name: Bulk: >500 gallons: DOT Shipping Name 5 gallon pails, 30 gallon drums and 55gallon drums:
UN1993, Flammable Liquids, N.O.S., (Petroleum Distillates, Heavy Aromatic Naphtha, 2-Ethylhexyl Nitrate, 2-
Butoxyethanol),3,PG III,RQ,(Naphthalene, Xylene), Marine Pollutant, (2-Ethylhexyl Nitrate, Naphthalene, 1,2,4
Trimethylbenzene)
IMDG Shipping Name: 5 gallon pails, 30 gallon drums and 55gallon drums: UN1993, Flammable Liquids, N.O.S.,
(Petroleum Distillates, Heavy Aromatic Naphtha, 2-Ethylhexyl Nitrate, 2-Butoxyethanol),3,PG III, Marine Pollutant, (2-
Ethylhexyl Nitrate, Naphthalene, 1,2,4 Trimethylbenzene)
IMDG Shipping Name: 4X1 gallon cases: UN1993, Flammable Liquids, N.O.S., (Petroleum Distillates, Heavy Aromatic
Naphtha, 2-Ethylhexyl Nitrate, 2-Butoxyethanol),3,PG III, Marine Pollutant, (2-Ethylhexyl Nitrate, Naphthalene, 1,2,4
Trimethylbenzene)
#137ND
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SARA Title III Information
I. Section 302/304 Extremely Hazardous
Component CAS# % TPQ RQ (lbs.) TPQ (gal*) RQ (gal*)
Benzene 71-43-2 0.00021 10 613,497
II. CERCLA Section 102(a) & 302.4 Hazardous Substance & Section 313 Toxic Chemical
Component CAS# % RQ (lbs.) RQ (gals.)
Benzene 71-43-2 0.00021 10 613,497
Xylene 1330-20-7 0.85-1.44 100 898
Cumene 98-82-6 0.4-0.581 5000 111,677
Ethylbenzene 100-41-4 1.7 1000 7,575
Naphthalene 91-20-3 0.17-2.2 100 585
Section 313 Chemicals
Component CAS# %
2-Butoxyethanol 111-76-2 5-10
Benzene 71-43-2 0.00021
Xylene 1330-20-7 00.85-1.44
Cumene 98-82-6 0.4-0.581
Ethylbenzene 100-41-4 1.7
Naphthalene 91-20-3 0.17-2.2
*Product RQ for Stationary Source to release Regulatory Requirement RQ as specified by CERCLA.
III. Title III Section 311 Hazard Categorization
Acute Chronic Fire Pressure Reactivity
X X X X
Although the information and recommendations set forth herein (hereafter referred to as information) are presented in
good faith and believed to be accurate and factual as of the date hereof, Schaeffer Mfg. Company makes no
representation as to the completeness or accuracy thereof. Information is supplied upon the condition that the person
receiving the same will make their own determination as to its safety and suitability for their purposes prior to use. In
no event will Schaeffer Mfg. Company be responsible for damages of any natures whatsoever resulting from the use
or reliance upon information. No representation or warranty, either expressed or implied, of merchantability or
fitness for a particular purpose is made with respect to information of the product to which the information
refers.
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