Material Safety Data Sheet
Section 1: Product & Company Identification
Product Name: Marine Fuel Stabilizer - Gasoline
Product Number (s): 06161, 06162, 06163, 06164, 76163, 76164
fuel stabilizer for gasoline
Product Use:
Manufacturer / Supplier Contact Information:
In United States: In Canada: In Mexico:
CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico
885 Louis Drive 2-1246 Lorimar Drive Av. Benito Ju醨ez 4055 G
Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orqu韉ea
www.crcindustries.com www.crc-canada.ca San Lu韘 Potos? SLP CP 78394
1-215-674-4300 (General) 1-905-670-2291 www.crc-mexico.com
(800) 521-3168 (Technical) 52-444-824-1666
(800) 272-4620 (Customer Service)
24-Hr Emergency ?CHEMTREC: (800) 424-9300 or (703) 527-3887
Section 2: Hazards Identification
Emergency Overview
As defined by OSHA's Hazard Communication Standard, this product is hazardous.
Appearance & Odor: Amber liquid, faint petroleum odor
Potential Health Effects:
ACUTE EFFECTS:
EYE: Eye contact may result in light irritation and redness.
SKIN: Short term contact with skin is unlikely to cause any problems. Excessive or prolonged and
repeated contact may result in dryness, dermatitis, erythema, oil acne, cracking and defatting of
the skin.
INHALATION: Inhalation of vapors or mist may be irritating to the respiratory passages. Prolonged exposure
may result in dizziness and nausea.
INGESTION: May result in nausea or stomach discomfort.
CHRONIC EFFECTS: None known
TARGET ORGANS: lungs (oil mist)
Medical Conditions Aggravated by Exposure: Pre-existing skin disorders
See Section 11 for toxicology and carcinogenicity information on product ingredients.
Page 1 of 7
Product Name: Marine Fuel Stabilizer ?Gasoline
Product Number (s): 06161, 06162, 06163, 06164, 76163, 76164
Section 3: Composition/Information on Ingredients
COMPONENT CAS NUMBER % by Wt.
64742-52-5 /
Hydrotreated naphthenic oil 90 ?99
64742-53-6
Hydroxyethylated aminoethylamide proprietary 2-5
Petroleum naphtha 64742-88-7 1-3
Section 4: First Aid Measures
Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists.
Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if
irritation persists. Wash contaminated clothing prior to re-use.
Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If
breathing is difficult give oxygen. Call a physician.
Ingestion: If swallowed, observe for signs of stomach discomfort or nausea. If symptoms persist, seek
medical help. Do not induce vomiting. If there is any suspicion of aspiration into lungs, obtain
immediate medical attention.
Note to Physicians: Treat symptomatically.
Section 5: Fire-Fighting Measures
As defined by OSHA, this product is a Class IIIB Combustible Liquid (not regulated).
Flammable Properties:
Flash Point: >315?/ > 157?(COC)
F C Upper Explosive Limit: ND
Autoignition Temperature: > 600?F Lower Explosive Limit: ND
Fire and Explosion Data:
Suitable Extinguishing Media: Halon, dry chemical, foam, CO2, water mist or fog, or any Class B extinguishing agent
Products of Combustion: Fumes, smoke, carbon monoxide
Explosion Hazards: Containers, when exposed to heat from fire, may build pressure and rupture.
Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for
protection against suffocation and possible toxic decomposition products. Proper eye and
skin protection should be provided. Use water spray to keep fire-exposed containers cool
and to knock down vapors which may result from product decomposition.
Section 6: Accidental Release Measures
Personal Precautions: Use personal protection recommended in Section 8.
Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into
sewers or storm drains.
Methods for Containment & Clean-up: Dike area to contain spill. Ventilate the area with fresh air. If in confined space
or limited air circulation area, clean-up workers should wear appropriate
respiratory protection. Recover or absorb spilled material using an absorbent
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Product Name: Marine Fuel Stabilizer ?Gasoline
Product Number (s): 06161, 06162, 06163, 06164, 76163, 76164
designed for chemical spills. Place used absorbents into proper waste
containers.
Section 7: Handling and Storage
Handling Procedures: Keep away from flames, sparks or hot surfaces. Wash thoroughly after using product and
before handling food. Use proper grounding and bonding techniques when transferring
material. For product use instructions, please see the product label.
Storage Procedures: Store in a cool dry area out of direct sunlight. Containers should be tightly closed while in
storage.
Aerosol Storage Level: NA
Section 8: Exposure Controls/Personal Protection
Exposure Guidelines:
OSHA ACGIH OTHER
COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT
mg/m3
Hydrotreated naphthenic oil 5* NE 5* 10* NE
Hydroxyethylated aminoethylamide NE NE NE NE NE
Petroleum naphtha NE NE NE NE NE
* oil mist
N.E. ?Not Established (c) ?ceiling (s) ?skin (v) ?vacated
Controls and Protection:
Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally
preferred because it can control the emissions of the contaminant at the source, preventing
dispersion into the general work area. Use mechanical means if necessary to maintain vapor
levels below the exposure guidelines. If working in a confined space, follow applicable OSHA
regulations.
Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls
are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved
cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual
employee exposure levels. Use a self-contained breathing apparatus in confined spaces and
for emergencies.
Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid
contact, wear splash-proof goggles.
Skin Protection: Use protective gloves such as nitrile or neoprene. Also, use full protective clothing if there is
prolonged or repeated contact of liquid with skin.
Section 9: Physical and Chemical Properties
Physical State: liquid
Color: amber
Odor: faint petroleum
Odor Threshold: ND
Specific Gravity: 0.901
Initial Boiling Point: > 465?F / > 240?C
Freezing Point: ND
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Product Name: Marine Fuel Stabilizer ?Gasoline
Product Number (s): 06161, 06162, 06163, 06164, 76163, 76164
Vapor Pressure: ND
Vapor Density: >5 (air = 1)
Evaporation Rate: slow
Solubility: negligible
Coefficient of water/oil distribution: ND
pH: NA
Volatile Organic Compounds: wt %: 2.6 g/L: 23.4 lbs./gal: 0.2
Section 10: Stability and Reactivity
Stability: Stable
Conditions to Avoid: Sources of ignition
Incompatible Materials: Strong oxidizers, halogens
Hazardous Decomposition Products: Oxides of carbon and nitrogen; aldehydes
Possibility of Hazardous Reactions: No
Section 11: Toxicological Information
Long-term toxicological studies have not been conducted for this product. The following information is available for
components of this product.
Acute Toxicity:
Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat)
Hydrotreated naphthenic oil > 5000 mg/kg > 2000 mg/kg 2.18 mg/L/4H
Hydroxyethylated aminoethylamide No data No data No data
Petroleum naphtha > 2000 mg/kg > 2000 mg/kg No data
Chronic Toxicity:
OSHA IARC NTP
Component Carcinogen Carcinogen Carcinogen Irritant Sensitizer
Hydrotreated naphthenic oil No No No E (mild) / S No
(mild)
Hydroxyethylated aminoethylamide No No No Unknown Unknown
Petroleum naphtha No No No E (mild) / Unknown
S (moderate) /
R (mild)
E ?Eye S ?Skin R - Respiratory
Reproductive Toxicity: No information available
Teratogenicity: No information available
Mutagenicity: Hydrotreated naphthenic oil: Mutagenic index of less than 1.0
Synergistic Effects: No information available
Other: IARC has determined in reviewing cancer prevalence of exposed workers that the
carcinogenic activity of refined oils is related to the severity of processing of the base
oil. The base oils contained in this product have been highly refined to remove
aromatics, thus reducing carcinogenic potential. IP346: DMSO < 3.0%
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Product Name: Marine Fuel Stabilizer ?Gasoline
Product Number (s): 06161, 06162, 06163, 06164, 76163, 76164
Section 12: Ecological Information
Ecological studies have not been conducted for this product. The following information is available for components of this
product.
Ecotoxicity: hydrotreated naphthenic oil ?96 Hr LC50, Fathead minnow: >30,000 mg/L (static)
Persistence / Degradability: This product is not readily biodegradable.
Bioaccumulation / Accumulation: No information available
Mobility in Environment: No information available
Section 13: Disposal Considerations
This product is not a RCRA hazardous waste. (See 40 CFR Part 261.20 ?261.33)
Waste Classification:
Empty containers may be recycled.
All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more
stringent than state, provincial or national requirements.
Section 14: Transport Information
Not Regulated
US DOT (ground):
Not Regulated
ICAO/IATA (air):
Not Regulated
IMO/IMDG (water):
None
Special Provisions:
Section 15: Regulatory Information
U.S. Federal Regulations:
Toxic Substances Control Act (TSCA):
All ingredients are either listed on the TSCA inventory or are exempt.
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA):
Reportable Quantities (RQ's) exist for the following ingredients: None
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to
the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Superfund Amendments Reauthorization Act (SARA) Title III:
Section 302 Extremely Hazardous Substances (EHS): None
Section 311/312 Hazard Categories: Fire Hazard No
Reactive Hazard No
Release of Pressure No
Acute Health Hazard No
Chronic Health Hazard No
Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements
of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR Part 372:
None
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Product Name: Marine Fuel Stabilizer ?Gasoline
Product Number (s): 06161, 06162, 06163, 06164, 76163, 76164
Clean Air Act:
Section 112 Hazardous Air Pollutants (HAPs): None
U.S. State Regulations:
California Safe Drinking Water and Toxic Enforcement Act (Prop 65):
This product may contain the following chemicals known to the state of
California to cause cancer, birth defects or other reproductive harm: ethylbenzene (< 0.03%)
Consumer Products VOC Regulations: This product is not regulated.
State Right to Know:
New Jersey: 800967-5341P, 800967-5548P, 95-63-6, 100-41-4
Pennsylvania: 95-63-6, 100-41-4
Massachusetts: 95-63-6, 100-41-4
Rhode Island : 95-63-6, 100-41-4
Canadian Regulations:
Controlled Products Regulations:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
WHMIS Hazard Class: Not Regulated
Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt.
European Union Regulations:
RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the
Council of 27 January 2003. This product does not contain any of the restricted substances as
listed in Article 4(1) of the RoHS Directive.
None
Additional Regulatory Information:
Section 16: Other Information
NFPA
HMIS?(II)
Health: 1
Flammability: 1
1
Reactivity: 0
1 0
PPE: B
Ratings range from 0 (no hazard) to 4 (severe hazard)
Prepared By: Michelle Rudnick
CRC #: 587C
Revision Date: 08/04/2009
Changes since last revision: MSDS reformatted to meet the requirements of the Canadian Controlled Products
Regulations.
Page 6 of 7
Product Name: Marine Fuel Stabilizer ?Gasoline
Product Number (s): 06161, 06162, 06163, 06164, 76163, 76164
The information contained in this document applies to this specific material as supplied. It may not be valid for this
material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries'
knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and
directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a
health & safety professional, or CRC Industries.
ACGIH: American Conference of Governmental Industrial Hygienists NA: Not Applicable
CAS: Chemical Abstract Service ND: Not Determined
CFR: Code of Federal Regulations NIOSH: National Institute of Occupational Safety & Health
DOT: Department of Transportation NFPA: National Fire Protection Association
DSL: Domestic Substance List NTP: National Toxicology Program
g/L: grams per Liter OSHA: Occupational Safety and Health Administration
HMIS: Hazardous Materials Identification System PMCC: Pensky-Martens Closed Cup
IARC: International Agency for Research on Cancer PPE: Personal Protection Equipment
IATA: International Air Transport Association ppm: Parts per Million
ICAO: International Civil Aviation Organization RoHS: Restriction of Hazardous Substances
IMDG: International Maritime Dangerous Goods STEL: Short Term Exposure Limit
IMO: International Maritime Organization TCC: Tag Closed Cup
lbs./gal: pounds per gallon TWA: Time Weighted Average
LC: Lethal Concentration WHMIS: Workplace Hazardous Materials Information
LD: Lethal Dose System
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