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MSDS Document
Product Calumet Mineral Spirits, Rule 66
1. Chemical Product and Company Identification
Trade Name of this Product Calumet Mineral Spirits, Rule 66
Synonyms: 0415-00
MSDS ID MSDS02008
Manufacturer Contact Name
Calumet Lubricants Co. CCV Anne Goldsmith
1756 old hwy 7 Phone Number
Cotton Valley, LA. 71018 (317) 328-5660
Emergency Phone
CHEMTREC (800) 424-9300
CHEMTREC International (703) 527-3887
Revision Date 4/9/2007
Fire
2
Health Reactivity
1 0
Specific
2. Composition and Information on Ingredients
Ingredient CAS Number Weight % ACGIH TLV PEL STEL
Medium Aliphatic 64742-88-7 70% - 80% 0
Solvent Naphtha
Hydrotreated Light 64742-47-8 20% - 30%
Distillates (petroleum)
3. Hazard Identification
*****EMERGENCY OVERVIEW*****
* Warning: Combustible Liquid and Vapor.
* This product is a clear, hydrocarbon liquid.
* It has a solvent petroleum odor. The product floats on water.
* The Flash Point is >100 degrees F.
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* Keep away from heat, sparks, and flame.
* When burned the product produces carbon monoxide and other asphyxiants during
combustion.
* Avoid breathing vapor. Harmful if inhaled and may cause delayed lung injury.
* Aspiration hazard if swallowed - can enter lungs and cause damage.
* Use ventilation adequate to keep vapor below recommended exposure limits.
* Avoid contact with eyes, skin and clothing. Material splashed into the eyes will irritate
tissues. Gently flush material from eyes with clean water.
* Unprotected exposure to this product will cause skin dryness.
* Remove product soaked clothing and wash with mild soap. Wash thoroughly after
handling.
* As with any petroleum product, avoid mixing this product with strong oxidizers.
* This product is not listed on the NTP, IARC, OSHA, or ACGIH lists of suspected or
confirmed carcinogens.
* This product may be toxic to fish but will be toxic to birds and wildlife through ingestion
during pelage cleaning.
* This product is readily biodegradable in the presence of air and sunlight.
* Spilled material is slippery and may cause falls.
*****END OF EMERGENCY OVERVIEW*****
POTENTIAL HEALTH EFFECTS
PRIMARY ROUTE(S) OF ENTRY
Skin.
EYES
Tests on similiar materials suggest acute irritation be expected.
SKIN
Tests on similiar materials indicate acute irritation is expected to occur upon short-term
exposure, chronic dermatitis on prolonged contact.
INGESTION
ACUTE ASPIRATION HAZARD. Tests on similar materials indicate possibility of the following
symptoms: headache, nausea, drowsiness, fatigue, pneumonitis, pulmonary adema, central
nervous system depression, convulsions, and loss of consciousness.
INHALATION
Tests on similiar material indicate the possibility of the following symptoms: headache,
nasal and respiratory irritation, nausea, drowsiness, breathlessness, fatigue, central nervous
system depression, convulsions, and loss of consciousness.
CHRONIC (CANCER INFORMATION)
Prolonged and/or repeated contact with this material may produce skin irritation and
inflammation.
Carcinogen listed by : National Toxicology Program (No)
CHRONIC (CANCER INFORMATION) - Continued
I. A. R. C. (NO)
OSHA (NO)
ACGIH (NO)
This product does not require a cancer hazard warning in accordance with the OSHA Hazard
Communication Standard.
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MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Personnel with pre-existing skin disorders should avoid contact with this product.
4. First Aid Information
EYES
Flush eyes immediately with water for at least 15 minutes or until irritation subsides,
occasionally lifting lower and upper lids. Get medical attention promptly.
SKIN
Wash thoroughly with soap and water. Immediately remove contaminated clothing and wash
before reuse. If irritation or rash develops, obtain medical assistance. Immediately remove
soaked clothing.
INGESTION
CALL PHYSICIAN IMMEDIATELY. Do not induce vomiting except at the instruction of a
physician. Never give anything by mouth to an unconscious person.
INHALATION
Remove patient to fresh air and consult a physician. If breathing is difficult, give oxygen. If
not breathing give artifical respiration.
5. Fire Fighting Measures
FLAMMABLE PROPERTIES
FLASH POINT: >100癋 >38癈 Tag Closed Cup
AUTOIGNITION: 473F
FLAMMABILITY CLASS: IIIA
LOWER EXPLOSIVE LIMIT (%): 0.8 vol %
UPPER EXPLOSIVE LIMIT (%): Not Available
FIRE AND EXPLOSION HAZARD
Material is combustible.
EXTINGUISHING MEDIA
Dry Chemical, carbon dioxide, and foam. CAUTION: Water stream may spread fire.
FIRE FIGHTING INSTRUCTIONS
Use water spray only to cool containers exposed to flames. Do not enter enclosed or a
confined work space without proper protective equipment. Fire fighting personnel should
wear respiratory protection (positive pressure if available). If leak or spill has not ignited,
use water spray to disperse the vapors.
Products of combustion include fumes, smoke and carbon monoxide.
6. Accidental Release Measures
NOTIFICATION PROCEDURES: Notify emergency response personnel. Evacuate area and
remove ignition sources. Build dike to contain flow. Remove free liquid. Shut off ignition
source. Report spills as required to appropriate authorities. U. S. Coast Guard regulations
require immediate reporting of spills that could reach any waterway including intermittent
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dry creeks. Report spill to Coast Guard toll free number (800) 424-8802. In case of accident
or road spill notify CHEMTREC (800) 424-9300.
PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: Absorb on inert material. Shovel
up and dispose of at an appropriate waste disposal facility in accordance with current
applicable laws and regulations, and product characteristics at time of disposal.
ENVIRONMENTAL PRECAUTIONS: Prevent spills from entering storm sewers or drains and
contact with soil.
PERSONAL PRECAUTIONS: See Section 8
7. Handling and Storage
HANDLING AND STORAGE PRECAUTIONS
Store as OSHA Class II combustible liquid. Keep away from flames, sparks or hot surfaces.
Never use a torch to cut or weld on or near container. Empty oil containers can contain
explosive vapors. Wash thoroughly after handling. Do not store with strong oxidizers.
STORAGE PRECAUTIONS
Empty containers retain product residue (liquid and vapor) and can be dangerous.
Storage Temperature: ambient
Storage Pressure: atmospheric
WORK/HYGIENIC PRACTICES
Wash hands with soap and water before eating, drinking, smoking or use of toilet facilities.
Take a shower after work if general contact occurs. Remove oil-soaked clothing and launder
before reuse. Launder or discard contaminated shoes and leather gloves.
8. Exposure Controls and Personal Protection
ENGINEERING CONTROLS
Use adequate ventilation to keep oil mists of this material below applicable standard(s). See
Section on occupational exposure limits.
EYE/FACE PROTECTION
Safety glasses, splash goggles, or face shield as appropriate. Have suitable eye water wash
available.
SKIN PROTECTION
Avoid prolonged and/or repeated skin contact. If prolonged contact cannot be avoided, wear
protective impervious gloves and clothing. Acceptable materials for gloves are neoprene;
nitrile; viton.
OTHER/GENERAL PROTECTION
If there is a likelihood of splashing, an oil resistant clothing should be worn. Never wear oil
soaked clothing. Launder or dry clean before wearing. Discard oil soaked shoes. Affix
warning labels on containers in accordance with 29 CFR 1910.1200 (Hazard Communication
Standard).
Loading, unloading, tank gauging, etc., remain upwind. Request assistance of safety and
industrial hygiene personnel to determine air concentrations.
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INGREDIENT NAME, CAS #, EXPOSURE LIMITS, PERCENT BY VOLUME
------------------------------------------------------ -----------------------------------
Medium Aliphatic Solvent Naphtha Stoddard Solvent ,CAS NUMBER: 64742-88-7, OSHA
TWA-100ppm, 70.0 to 80.0%
9. Physical and Chemical Properties
APPEARANCE
Clear liquid.
ODOR
Petroleum Naphtha
ODOR THRESHOLD
N.D.
BASIC PHYSICAL PROPERTIES
PHYSICAL STATE: Liquid
BOILING POINT: IBP >300 (D86)癋 IBP >149 (D86)癈
MELTING POINT: Not Available
VAPOR PRESSURE: 3.37 mm Hg @ 68癋(20癈)
VAPOR DENSITY (AIR=1): 5
SPECIFIC GRAVITY @ 60癋(water=1): 0.7653
MOLECULAR WEIGHT: 150.0
SOLUBILITY (H2O): negligible in water
PERCENT VOLATILES: 100
VISCOSITY: 1.2 cst @ 100癋
Physical data may vary slightly to meet specifications.
10. Stability and Reactivity
STABILITY: Stable under normal conditions
CONDITIONS TO AVOID (STABILITY)
Sources of ignition.
INCOMPATIBLE MATERIALS
Strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
Incomplete combustion may produce carbon monoxide and other asphyxiants.
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HAZARDOUS POLYMERIZATION: will not occur
11. Toxicological Information
ACUTE STUDIES
EYE EFFECTS
Slight irritation on contact.
SKIN EFFECTS
May cause irritation or dermatitis with prolonged and repeated contact.
ACUTE ORAL EFFECTS
Tests on similar materials indicate an order of acute oral toxicity.
ACUTE INHALATION EFFECTS
Acute toxicity expected on inhalation.
This product is not listed as carcinogenic or a potential carcinogen by the National
Toxicology Program, by the I.A.R.C. monographs or by OSHA. Therefore, if the precautions
outlined in this
bulletin are followed to minimize repeated or prolonged skin contact which could cause
irritation, these oils should pose no carcinogenic hazard to humans. Prolonged repeated
skin contact with low viscosity materials may defat the skin resulting in possible irritation
and dermatitis. Nevertheless, good industrial hygienic practices are recommended.
12. Ecological Information
If applied to leaves, this product may kill grasses and small plants by interfering with
transpiration and respiration. This product is not toxic to fish but may coat gill structures
resulting in suffocation if spilled in shallow, running water. Product may be moderately toxic
to amphibians by preventing dermal respiration. This product may cause gastrointestinal
distress to birds and mammals through ingestion during pelage grooming.
This product is rapidly biodegradable. Biodegradation is possible within 90 to 120 days in
aerobic environments at temperatures above 70o F (21o C).
13. Disposal Considerations
Product as supplied does not meet the characteristics of a hazardous waste as defined in 40
CFR 261.21-24. If mixed with other products, waste mixture must be characterized. DO NOT
dispose of this product in drains or storm sewers. DO NOT dispose of this product in a
landfill without prior solidification. Waste product should be recycled. Consider waste
brokering.
14. Transportation Information
PROPER SHIPPING NAME: Petroleum Distillates, nos, Class 3, UN 1268, PG III
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HAZARD CLASS: Class 3 Flammable Liquid
DOT IDENTIFICATION NUMBER: UN1268
DOT SHIPPING LABEL: DOT Hazardous Material
15. Regulatory Information
U.S. FEDERAL REGULATORY INFORMATION
SARA 302 Threshold Planning Quantity: NOT APPLICABLE
SARA 304 Reportable Quantity: NOT APPLICABLE
SARA TITLE III - Section 311/312 Hazard classes:
?Immediate/Acute Health Effects: yes
?Delayed/Chronic Health Effects: no
?Fire Hazard: yes
?Sudden Release of Pressure Hazard: no
?Reactivity Hazard: no
EPA/TSCA Inventory: The components of this product are listed on the
EPA/TSCA inventory of chemicals.
SARA TITLE III - Section 313 Supplier notification:
The following chemicals are subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendments and reauthorization Act of 1986 and 40 CFR Part 372:
Benzene: CAS # 71-43-2, <1.0 wt%
Ethylbenzene: CAS # 100-41-4, <1.0 wt%
Naphthalene: CAS # 91-20-3, <1.0 wt%
Toluene: CAS # 108-88-3, <1.0 wt%
Xylene:CAS # 1330-20-7, <1.0 wt%
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): No
chemicals in this product are subject to the reporting requirements of CERCLA Section
101(14)(F). When this product is used in a mixture, or as an ingredient in another product, or
in a manufacturing operation, the petroleum exclusion may terminate and an accidental spill
may require reporting to the National Response Center.
CANADIAN REGULATORY INFORMATION
The components of this product are listed on the Canadian (DSL) Domestic Substances List.
EUROPEAN (ECC) REGULATORY INFORMATION
The components of this product are listed on the European Inventory of Existing
Commercial Substances. EINECS# 265-191-7
16. Other Information
SUPERCEDES MSDS DATED:08/15/05
Revised: Sections; 2,5,8,9, and 15.
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
The information contained herein is based upon data available to us, and reflects our best
professional judgement. However, no warranty of merchantability, fitness for any use, or
other warranty is expressed or implied regarding the accuracy of such data, the results to be
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obtained from the use thereof, or that any such use does not infringe any patent. Since the
information contained herein may be applied under conditions of use beyond our control
and with which we may be unfamiliar, we do not assume any responsibility for the results of
such application. This information is furnished upon the condition that the person receiving
it shall make his own determination of the suitability of the material for his particular
purpose.
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