Material Safety Data Sheet
Date of printing : 2/7/2007. : 2/7/2007.
Date of issue
Section 1. Chemical product and company identification
Prepared For Prepared by
Akzo Nobel Coatings Inc.
25 Brush Street
Pontiac, MI 48341
1-866-SIKKENS
IN CASE OF EMERGENCY (HEALTH OR SPILLS):
CHEMTREC (US and Canada) (800) 424-9300
Product no. : 21000
Product - Class : Cetol 1
Customer Part Numbe :
Customer ShipTo ID :
Section 2. Hazards identification
Emergency overview : Warning!
Effects of Overexposure : HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED.
CAUSES SEVERE SKIN IRRITATION.
CAUSES RESPIRATORY TRACT AND EYE IRRITATION.
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: EYE, LENS OR
CORNEA.
SUSPECT CANCER HAZARD
CONTAINS MATERIAL WHICH MAY CAUSE CANCER
FLAMMABLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: KIDNEYS,
LUNGS, LIVER, HEART, CENTRAL NERVOUS SYSTEM.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep away
from heat, sparks and flame. Keep container closed. Use only with adequate ventilation. Wash
thoroughly after handling. Risk of cancer depends on duration and level of exposure.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eyes : Irritating to eyes.
Other effects of eye contact may include : burning, eye damage, redness, swelling, tearing,
Skin : Toxic in contact with skin. Severely irritating to the skin.
Other effects of skin contact may include: dehydration, dermatitis, discoloration,
Effects due to absorption through skin may include: CNS effects, dizziness, drowsiness, fatigue,
headache, nausea, weakness,
Inhalation : Irritating to respiratory system.
Other effects of inhalation may include: anesthesia, asthma, blood effects, CNS effects, confusion,
depression, dizziness, drowsiness, fatigue, headache, incoordination, nausea, pulmonary edema,
weakness,
Ingestion : Toxic if swallowed.
Other effects of ingestion may include : CNS effects, diarrhea, dizziness, drowsiness, fatigue, headache,
incoordination, irritation, nausea, vomiting, weakness,
Material Safety Data Sheet Continued on next page
21000 2/7/2007. Page: 2/7
Potential chronic health : CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC [ethyl benzene]. Classified
SUSPECTED by Raw Material Supplier [methyl ethyl ketoxime]. Classified 2B (Possible for human.) by
effects
IARC [carbon black]. Classified 2B (Possible for human.) by IARC [cobalt bis (2-ethylhexanoate)].
MUTAGENIC EFFECTS: None by OSHA standard.
TERATOGENIC EFFECTS: Classified POSSIBLE for human [ethyl benzene]. Classified POSSIBLE for
human [cumene].
Contains material which causes damage to the following organs: eye, lens or cornea.
Contains material which may cause damage to the following organs: kidneys, lungs, liver, heart, central
nervous system (CNS).
Medical conditions : skin disorders, respiratory conditions,
aggravated by over-
exposure
NOTICE: Reports have associated repeated and prolonged OVEREXPOSURE to solvents with permanent brain and nervous system
damage. Intentional misuse by deliberately concentrating and inhaling the contents of this package may be harmful or fatal.
See toxicological information (section 11)
Section 3. Composition, information on ingredients
CAS # % by Vapor Exposure Limits (ACGIH-TLV/OSHA-PEL)
Name
weight pressure
aliphatic solvent ......... 10 - 25 Not available. Not available.
soya alkyd ......... 10 - 25 Not available. Not available.
aliphatic hydrocarbon 64742-47-8 10 - 25 0.02 kPa (0.2 Not available.
mm Hg) (at
20癈)
heat bodied linseed oil 67746-08-1 10 - 25 Not available. Not available.
ACGIH TLV (United States).
petroleum hydrocarbon 8052-41-3 5 - 10 0.07 kPa (0.5
mm Hg) (at TWA: 100 ppm 8 hour(s).
OSHA PEL (United States).
20癈)
TWA: 500 ppm 8 hour(s).
ACGIH TLV (United States).
aromatic solvent ......... 1-5 Not available.
TWA: 100 ppm 8 hour(s).
ACGIH TLV (United States).
xylene, mixed isomers 1330-20-7 1-5 0.7 kPa (5.1
mm Hg) (at TWA: 100 ppm 8 hour(s).
20癈) STEL: 150 ppm 15 minute(s).
OSHA PEL (United States).
TWA: 100 ppm 8 hour(s).
ACGIH TLV (United States).
1,2,4-trimethylbenzene 95-63-6 1-5 Not available.
TWA: 25 ppm 8 hour(s).
linseed alkyd ......... 1-5 Not available. Not available.
tall oil fa alkyd ......... 1-5 Not available. Not available.
1,3,5-trimethylbenzene 108-67-8 1-5 Not available. Not available.
ACGIH TLV (United States).
ethyl benzene 100-41-4 0.1 - 1 0.9 kPa (7.1
mm Hg) (at TWA: 100 ppm 8 hour(s).
20癈) STEL: 125 ppm 15 minute(s).
OSHA PEL (United States).
TWA: 100 ppm 8 hour(s).
ACGIH TLV (United States).
carbon black 1333-86-4 0.1 - 1 Not available.
TWA: 3.5 mg/m3 8 hour(s).
OSHA PEL (United States).
TWA: 3.5 mg/m3 8 hour(s).
cobalt bis (2-ethylhexanoate) 136-52-7 0.1 - 1 Not available. Not available.
Material Safety Data Sheet Continued on next page
21000 2/7/2007. Page: 3/7
Section 4. First aid measures
Eye contact : Get medical attention immediately if symptoms occur. Immediately flush eyes with plenty of water for at
least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact
lenses.
Skin contact : Get medical attention immediately if symptoms occur. Flush contaminated skin with plenty of water.
Continue to rinse for at least 10 minutes. Remove contaminated clothing and shoes. W ash
contaminated clothing thoroughly with water before removing, or wear gloves. Wash clothing before
reuse. Thoroughly clean shoes before reuse.
Inhalation : Get medical attention immediately if symptoms occur. Move exposed person to fresh air. If fumes are
still suspected to be present, the rescuer should wear an appropriate mask or a self-contained breathing
apparatus. Keep person warm and at rest. If not breathing, if irregular breathing, or respiratory arrest
occurs provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth
to an unconscious person. Get medical attention immediately.
Section 5. Fire fighting measures
Flammability of the Flammable.
:
product
Auto-ignition temperature : The lowest known value is 232.22癈 (450癋) (petroleum hydrocarbon).
Flash points Closed cup: 45 to 46癈 (113 to 115癋). (Setaflash.)
:
Flammable limits The greatest known range is Lower: 1% Upper: 7.5% (xylene, mixed isomers)
:
Products of combustion : These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Fire Hazards in Presence : Flammable in presence of open flames, sparks and static discharge, of oxidizing materials.
of Various
DANGER - Rags, steel wool or waste soaked with this product may spontaneously catch fire if
Substances/Conditions
improperly discarded. Immediately after use, place rags, steel wool or waste in a sealed water-filled
metal container. Waste should be understood to include contaminated articles, including spray booth
filters and strippings.
Explosion Hazards in : Not available.
Presence of Various
Substances/Conditions
Fire-fighting media and : SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use alcohol foam, water spray or fog. Cool containing vessels with water jet in order to
instructions
prevent pressure build-up, autoignition or explosion.
Protective clothing (fire) : Be sure to use an approved/certified respirator or equivalent.
Section 6. Accidental release measures
Spill and Leak : Immediately contact emergency personnel. Eliminate all ignition sources. Keep unnecessary personnel
away. Use suitable protective equipment (Section 8). Do not touch or walk through spilled material.
If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil
may be used in the absence of other suitable materials) and use a non-sparking or explosion proof
means to transfer material to a sealed, appropriate container for disposal. For large spills dike spilled
material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled
material in an appropriate container for disposal.
Dispose of as in Section 13.
Material Safety Data Sheet Continued on next page
21000 2/7/2007. Page: 4/7
Section 7. Handling and storage
Handling : Do not ingest. Avoid contact with eyes, skin and clothing. Keep container closed. Use only with
adequate ventilation. Avoid breathing vapor or mist. Keep away from heat, sparks and flame. To avoid
fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Wash thoroughly after handling.
Storage : Store in an approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed
and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
OTHER PRECAUTIONS: All precautions must be observed. Empty container may retain product residues.
Section 8. Exposure controls, personal protection
Selection of personal protective equipment (PPE) is to be established by the employer performing a PPE hazard assessment. In the
U.S.A, OSHA requires completion of a documented PPE hazard assessment as described in 29 CFR 1910.132.
Engineering controls : Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors
below their respective occupational exposure limits. Ensure that eyewash stations and safety showers
are close to the work-station location.
Personal protection
Eyes : Safety glasses.
Body : Synthetic apron.
Respiratory : Wear appropriate respirator when ventilation is inadequate.
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous
fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the
provision of local exhaust ventilation, suitable respiratory protective equipment should be used.
Hands : Impervious gloves.
Protective clothing :
(pictograms)
HYGIENIC PRACTICES: Good personal hygiene practices are required at all times when handling chemicals. These practices include,
but are not limited to, washing when safety equipment is removed, at the end of each shift or when going on breaks and especially if
contamination occurs.
Section 9. Physical and chemical properties
Physical state and : Liquid.
Appearance
Color Not available.
:
Odor Characteristic.
:
pH Not available.
:
Boiling/condensation The lowest known value is 137.222 to 142.778癈 (279 to 289癋) (xylene, mixed isomers).
:
point
Melting/freezing point Not available.
:
Specific gravity Weighted average: 0.81 (Water = 1)
:
Vapor pressure The highest known value is 0.7 kPa (5.1 mm Hg) (at 20癈) (xylene, mixed isomers).
:
Vapor density Heavier than air
:
Volatility Not available.
:
Odor threshold Not available.
:
Evaporation rate The highest known value is Lower than 1. (aliphatic hydrocarbon) compared to butyl acetate
:
VOC 530 (g/l).
:
Solubility Not available.
:
Material Safety Data Sheet Continued on next page
21000 2/7/2007. Page: 5/7
Section 10. Stability and reactivity
Stability and reactivity : Stable.
Conditions of instability : heat, open flame, sparks, freezing, light, dusty conditions,
Incompatibility with various : Reactive with oxidizing agents.
Slightly reactive to reactive with acids.
substances
Hazardous Reaction Products : Possibly hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Hazardous polymerization : Will not undergo hazardous polymerization.
Section 11. Toxicological information
Toxicity data
Ingredient name Test Result Route Species
aromatic solvent LD50 >2000 mg/kg Dermal Rat
>590 mg/m3 (4 hour(s))
LC50 Inhalation Rat
xylene, mixed isomers LD50 4300 mg/kg Oral Rat
LD50 >1700 mg/kg Dermal Rabbit
LC50 5000 ppm (4 hour(s)) Inhalation Rat
1,2,4-trimethylbenzene LD50 3400 mg/kg Oral Rat
LD50 >3160 mg/kg Dermal Rabbit
18000 mg/m3 (4 hour(s))
LC50 Inhalation Rat
1,3,5-trimethylbenzene LD50 5000 mg/kg Oral Rat
24000 mg/m3 (4 hour(s))
LC50 Inhalation Rat
ethyl benzene LD50 3500 mg/kg Oral Rat
LD50 15486 mg/kg Dermal Rabbit
55000 mg/m3 (2 hour(s))
LC50 Inhalation Rat
carbon black LD50 >8000 mg/kg Oral Rat
Section 12. Ecological information
Ecotoxicity data
Ingredient name Species Period Result
aliphatic hydrocarbon Oncorhynchus mykiss (LC50) 96 hour(s) 2.9 mg/l
xylene, mixed isomers Oncorhynchus mykiss (LC50) 96 hour(s) 3.3 mg/l
Oncorhynchus mykiss (LC50) 96 hour(s) 8.2 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 8.6 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 12 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 13.3 mg/l
Pimephales promelas (LC50) 96 hour(s) 13.4 mg/l
1,2,4-trimethylbenzene Pimephales promelas (LC50) 96 hour(s) 7.72 mg/l
1,3,5-trimethylbenzene Scenedesmus subspicatus 48 hour(s) 25 mg/l
(EC50)
Scenedesmus subspicatus 48 hour(s) 53 mg/l
(EC50)
ethyl benzene Daphnia magna (EC50) 48 hour(s) 2.93 mg/l
Daphnia magna (EC50) 48 hour(s) 2.97 mg/l
Selenastrum capricornutum 48 hour(s) 7.2 mg/l
(EC50)
Oncorhynchus mykiss (LC50) 96 hour(s) 4.2 mg/l
Pimephales promelas (LC50) 96 hour(s) 9.09 mg/l
Poecilia reticulata (LC50) 96 hour(s) 9.6 mg/l
Products of degradation : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2...).
Toxicity of the products : The products of degradation are as toxic as the product itself.
of biodegradation
Material Safety Data Sheet Continued on next page
21000 2/7/2007. Page: 6/7
Section 13. Disposal considerations
Waste information : The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product,
solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements.
Consult your local or regional authorities.
Section 14. Transport information
Note: Information contained in this section may vary from the actual shipping description depending on quantity in containers, mode of
shipment and use of exemptions.
Regulatory UN Proper shipping name Class Packing group Label Additional information
information number
DOT Packaging instruction
UN1263 PAINT (including paint, 3 III
Passenger Aircraft
lacquer, enamel, stain,
Classification FLAMMABLE LIQUID
shellac, varnish, polish, Quantity limitation: 60 L
3
liquid filler and liquid
Cargo Aircraft
lacquer base)
Quantity limitation: 220 L
RQ: 2149.91lbs
(975.017kgs) [xylene,
mixed isomers]
TDG UN1263 PAINT (including paint, 3 III -
lacquer, enamel, stain,
Classification
shellac, varnish, polish, 3
liquid filler and liquid
lacquer base)
IMDG Class PAINT (including paint, 3 III
1263 -
lacquer, enamel, stain,
shellac, varnish, polish, 3
liquid filler and liquid
lacquer base)
IATA-DGR 1263 PAINT (including paint, 3 Quantity limitation -
III
lacquer, enamel, stain,
Class Passenger Aircraft -
shellac, varnish, polish, Limited quantity
3
liquid filler and liquid 10 L
lacquer base)
Quantity limitation -
Passenger Aircraft
220 L
Quantity limitation -
Cargo Aircraft
60 L
Section 15. Regulatory information
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains
all the information required by the Controlled Products Regulations.
U.S. Federal regulations : All components in this product have been verified as being on the TSCA Inventory.
(HAPS) Clean air act (CAA) 112 regulated toxic substances: toluene; ethyl benzene; xylene, mixed isomers;
cumene; butoxyethoxyethanol; cobalt bis (2-ethylhexanoate)
SARA 313
Material Safety Data Sheet Continued on next page
21000 2/7/2007. Page: 7/7
: xylene, mixed isomers 3.00 - 7.00
Form R - Reporting
1,2,4-trimethylbenzene 3.00 - 7.00
requirements
ethyl benzene 0.10 - 1.00
cobalt bis (2-ethylhexanoate) 0.10 - 1.00
: WARNING: This product contains a chemical known to the State of California to cause cancer, birth
State regulations
defects or other reproductive harm.: ethyl benzene, carbon black, cobalt bis (2-ethylhexanoate), toluene,
quartz
International regulations
International lists : All components of this product are on the CEPA DSL inventory.
** All values in this section reported as percentage by weight, unless otherwise specified.
Section 16. Other information
HMIS III ? *2 WHMIS (Canada)
Health
Hazardous Material 2
Flammability
Information System Class B-3: Combustible liquid with a flash point between 37.8癈
0
Physical Hazard (100癋) and 93.3癈 (200癋).
(U.S.A.) Class D-1B: Material causing immediate and serious toxic effects
Personal protection
(TOXIC).
Class D-2A: Material causing other toxic effects (VERY TOXIC).
Class D-2B: Material causing other toxic effects (TOXIC).
Notice to reader
The absence of a positive finding indicates that we believe, to the best of our knowledge, that the
negative is true.
Disclaimer: While Akzo Nobel Coatings believes that the data contained herein are accurate and derived
from qualified sources, the data are not to be taken as a warranty or representation for which Akzo
Nobel Coatings assumes legal responsibility. They are offered solely for your consideration,
investigation and verification. Any use of these data and information must be determined by the user to
be in accordance with applicable Federal, State, Provincial and local laws and regulations.
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