MATERIAL SAFETY DATA SHEET
Date Prepared: 12/4/01 Page: 1
Clear Scratch Patch MSDS Number: 130021
SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Material Identity
Product Name: Clear Scratch Patch
Product Numbers: 105651
Product Use: Urethane Repair Paste
Company Emergency Telephone Numbers:
Fibre Glass-Evercoat CHEMTREC: 1-800-424-9300
a Division of Illinois Tool Works Inc. CANUTEC: 1-613-996-6666
6600 Cornell Road
Cincinnati, Ohio USA
Phone: 513-489-7600 Prepared By: Safety Department
SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient(s) CAS Number EINECS Number % (by weight)
Mineral Spirits 8052-41-3 232-489-3 50 ?55
Polyurethane Resin Proprietary Proprietary 45 ?50
Amorphous Silica 112945-52-5 231-545-4 1?
Ethyl Benzene 100-41-4 202-849-4 0?
OSHA Regulatory Status: This material is classified as hazardous under OSHA
regulations.
SECTION 3. HAZARDS IDENTIFICATION
***EMERGENCY OVERVIEW***
WARNING! COMBUSTIBLE LIQUID AND VAPOR. HARMFUL IF
SWALLOWED. CAUSES EYE, SKIN, NOSE AND THROAT IRRITATION.
Potential Health Effects
Acute Effects (Short Term):
Eye: Contact with liquid or vapor may result in irritation, redness, tearing,
and blurred vision.
Skin: May cause mild skin irritation. Prolonged or repeated contact may
dry the skin. Symptoms may include redness, burning, drying and
cracking of skin, and skin burns.
Swallowing: Ingestion of this material may cause gastrointestinal irritation,
nausea, diarrhea, and vomiting. Aspiration of this material into the
lungs due to vomiting may produce chemical pneumonitis which
can be fatal.
MATERIAL SAFETY DATA SHEET
Date Prepared: 12/4/01 Page: 2
Clear Scratch Patch MSDS Number: 130021
Inhalation: Excessive inhalation of vapors may cause nasal and respiratory
irritation, acute nervous system depression, fatigue, weakness,
nausea, headache, and dizziness. Symptoms usually occur at air
concentrations higher than the recommended exposure limits (See
Section 8).
Chronic Effects of Overexposure (Long Term):
Mineral Spirits: This substance may have effects on the central nervous system.
Cancer Information: The International Agency for Research on Cancer
(IARC) has classified ethyl benzene as a group 2B carcinogen
(possibly carcinogenic to humans) based on the increase of kidney
tumors in rats and an increase in lung and liver cancer in mice.This
material may contain trace amounts of chemicals considered to be
carcinogenic by OSHA, (Benzene-IARC Group 1).
Other Health Effects: NOTICE: Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal.
Primary Route(s) of Entry: Inhalation, Skin contact, Eye contact, Ingestion,
Skin absorption.
SECTION 4. FIRST AID MEASURES
Eyes: Flush eyes gently with water for at least 15 minutes. Seek
immediate medical attention.
Skin: Remove contaminated clothing. Wash exposed area with soap and
water. If symptoms persist, seek medical attention. Launder
clothing before reuse.
Swallowing: Consult a physician or poison control center immediately. DO NOT
INDUCE VOMITING. If individual is drowsy or unconscious, do not
give anything by mouth; place individual on the left side with the
head down. If possible, do not leave individual unattended.
Inhalation: If symptoms develop, immediately move individual away from
exposure and into fresh air. Seek immediate medical attention;
keep person warm and quiet. If person is not breathing, begin
artificial respiration. If breathing is difficult, oxygen may be benificial
if administered by trained personnel.
MATERIAL SAFETY DATA SHEET
Date Prepared: 12/4/01 Page: 3
Clear Scratch Patch MSDS Number: 130021
SECTION 5. FIRE FIGHTING MEASURES
Flash Point: 104 篎 (40 篊)
Explosive Limit: Lower: 1.0% Upper: 7.0%
Autoignition Temperature: 410.0 篎 (210.0 篊)
OSHA Flammability Class: Combustible Liquid-Class II
Hazardous Products of Combustion: May form toxic and corrosive gases:
carbon dioxide, carbon monoxide, nitrogen oxide and various
hydrocarbons.
Fire and Explosion Hazards: Vapors are heavier than air and may travel along
the ground or may be moved by ventilation and ignited by pilot lights, other
flames, sparks, heaters, smoking, electric motors, static discharge, or
other ignition sources at locations distant from material handling point.
Extinguishing Media: Regular foam, carbon dioxide, dry chemical.
Fire Fighting Instructions: Water may be used to keep fire-exposed containers
cool until fire is out. Wear a self-contained breathing apparatus NIOSH
approved with a full facepiece operated in the positive pressure demand
mode with appropriate turn-out gear and chemical resistant personal
protective equipment.
NFPA Rating: Health - 2, Flammability - 1, Reactivity - 0
SECTION 6. ACCIDENTAL RELEASE MEASURES
In Case of Spill: Eliminate all sources of ignition such as flares, flames (including
pilot lights), and electrical sparks. Ventilate the area. Wear proper protective
equipment (Section 8). Avoid breathing vapors. Collect with an inert absorbant
and dispose of properly.
SECTION 7. HANDLING AND STORAGE
Handling: All hazard precautions given in the data sheet must be observed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling. Use only
with adequate ventilation. Do not take internally. Close container after each use.
Keep out of reach of children.
Storage: Store material in a cool, well-ventilated area. For maximum product
quality, avoid prolonged storage at temperatures above 75癋 (25癈). Do not use
or store near heat, sparks, or open flame. Keep container tightly closed. Avoid
contact with incompatible materials.
MATERIAL SAFETY DATA SHEET
Date Prepared: 12/4/01 Page: 4
Clear Scratch Patch MSDS Number: 130021
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection: Chemical splash goggles in compliance with OSHA regulations are
recommended.
Skin Protection: Protective gloves and proper clothing should be worn to prevent
skin contact. Gloves should be made of neoprene or natural rubber.
A barrier cream may be used for additional skin protection. To
prevent repeated or prolonged skin contact, wear impervious
clothing and boots.
Respiratory Protection: Use a NIOSH approved respirator designed to remove
particulate matter and organic solvent vapors.
Engineering Controls: Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below acceptable limits.
Explosion-proof ventilation system is acceptable.
Exposure Guidelines:
Hazardous Ingredients CAS Number OSHA PEL/TWA ACGIH TLV
Mineral Spirits 8052-41-3 500 ppm 100 ppm
Ethyl Benzene 100-41-4 100 ppm 100 ppm
15 mg/m3 10 mg/m3
Amorphous Silica 112945-52-5
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
428 ?572 癋/ 220 Heavier than air.
Boiling Point: Vapor Density:
- 300 癈
0.894 / 7.45 lbs/gal 50 - 55 %
Specific Gravity / Percent Volatiles
Density: by weight:
Slower than ethyl Paste
Evaporation Rate: Physical State:
ether.
-22 癋/ -30 癈 Neutral
Melting Point: pH:
Sharp, aromatic Insoluble in water.
Odor: Solubility:
odor.
1 mmHg @ 68 癋 / Clear Paste
Vapor Pressure: Appearance:
20 癈
Unknown lbs/gal
Octanol/Water VOC (as applied):
Partition
MATERIAL SAFETY DATA SHEET
Date Prepared: 12/4/01 Page: 5
Clear Scratch Patch MSDS Number: 130021
SECTION 10. STABILITY AND REACTIVITY
Hazardous Polymerization: Product will not undergo hazardous polymerization.
Hazardous Decomposition: May form: carbon dioxide, carbon monoxide,
nitrogen oxide and various hydrocarbons.
Chemical Stability: Stable under normal handling conditions.
Incompatibility: Avoid contact in uncontrolled conditions with: halogens and
strong oxidizing agents.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity Data:
Ingredient CAS # LD50 Oral-Rat LC50 Inhalation-Rat
Ethyl Benzene 100-41-4 3,500 mg/kg N/E
Amorphous Silica 112945-52-5 3,160 mg/kg N/E
Carcinogenicity: See Cancer Information, Section 3.
Mutagenicity: No significant evidence found.
Teratogenicity: No significant evidence found.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity: This product should not be released to sewage, draining systems or
any body of water exceeding concentrations of approved limits under
applicable regulations and permits.
SECTION 13. DISPOSAL CONSIDERATION
RCRA Hazardous Waste: This material as supplied, if discarded,
would be regulated as a hazardous waste under RCRA (40 CFR 261).
Dispose of in accordance with applicable federal, state, and local
regulations.
RCRA Hazard Class: This material would be regulated as EPA Hazardous
Waste Number D001 based on the characteristic of ignitablity.
SECTION 14. TRANSPORT INFORMATION
DOT Description: The DOT Classification for shipping is dependant on
quantity, type of packaging (a kit may include other components), or
method of shipment.
SECTION 15. REGULATORY INFORMATION
MATERIAL SAFETY DATA SHEET
Date Prepared: 12/4/01 Page: 6
Clear Scratch Patch MSDS Number: 130021
US Federal Regulations
TSCA (Toxic Substances Control Act) Status
TSCA (USA) The intentional ingredients of this product are listed.
CERCLA RQ - 40 CFR 302.4(a)
Component RQ (lbs.)
Ethyl Benzene 1000
SARA Title III: Section 302- Extremely Hazardous Substances
None
SARA Title III: Section 313- Toxic Chemical List
Component CAS Number Percentage
Ethyl Benzene 100-41-4 0-2%
International Regulations
EINECS (Europe) The intentional ingredients of this product are listed.
DSL (Canada) The intentional ingredients of this product are listed.
WHMIS Classification
Health Hazard: D2A, D2B (Other Toxic Effects)
Physical Hazard: B3 (Combustible)
State and Local Regulations
California Proposition 65:
This product contains the following chemical(s) known to the state of
California to cause cancer. BENZENE.
This product contains the following chemical(s) known to the state of
California to cause birth defects or reproductive harm. BENZENE, TOLUENE
SECTION 16. OTHER INFORMATION
HMIS Rating: Health ?2*, Flammability - 1, Reactivity - 0
Key- 0=Least, 1=Slight, 2=Moderate, 3=Serious, 4=Extreme, *=Chronic Effects
Other Precautions for Use: None known.
Additional Information may be obtained by calling the Evercoat MSDS Hotline at
1-800-729-7600.
NOTICE: The information accumulated herein is believed to be correct as of the date issued from
sources, which are believed to be accurate and reliable. Since it is not possible to anticipate all
circumstances of use, recipients are advised to confirm, in advance of need, that the information
is current, applicable and suitable to their circumstances.
|