M102-0491 HEAVY BODIED SANDING SEALER
MATERIAL SAFETY DATA SHEET
RPM Wood Finishes Group
3194 Hickory Boulevard
Hudson, North Carolina 28638
828-728-8266
EMERGENCY PHONE (CHEM TREC): . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-800-424-9300
FOR ALL INTERNATIONAL TRANSPORTATION ACCIDENTS. . . . . . . . . . . . . . . . .1-703-527-3887 (collect)
Health: 2 Flammability: 4 Reactivity 0
PRODUCT NAME: M102-0491 HEAVY BODIED SANDING SEALER
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
REVISION DATE: 09/06/04
SUPERCEDES: 05/05/04
MSDS NO. M102-0491
OSHA HAZ. CLASS: Mucous membrane (respiratory tract) irritant. Neurotoxin - may
cause nervous system damage. Eye irritant. Hepatotoxin - may
cause liver damage.
II. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME % CAS # PEL
isobutyl acetate 11-20 110-19-0 150 ppm TWA; 700 mg/m3 TWA
propane 11-20 74-98-6 1000 ppm TWA; 1800 mg/m3 TWA
acetone 11-20 67-64-1 1000 ppm TWA; 2400 mg/m3 TWA
isopropyl acetate 1-10 108-21-4 250 ppm TWA; 950 mg/m3 TWA
isobutane 1-10 75-28-5 No PEL established
Cellulose Nitrate, Cellulose Ester 1-10 9004-70-0 No PEL established
toluene 1-10 108-88-3 200 ppm TWA; C 300 ppm
diisononyl phthalate 1-10 68515-48-0 No PEL established
isopropanol 1-10 67-63-0 400 ppm TWA; 980 mg/m3 TWA
isobutyl isobutyrate 1-10 97-85-8 No PEL established
amorphous silica 1-10 112926-00-8 see Table Z-3
n-butyl acetate 1-10 123-86-4 150 ppm TWA; 710 mg/m3 TWA
MAK 1-10 110-43-0 100 ppm TWA; 465 mg/m3 TWA
butanol <1 78-92-2 150 ppm TWA; 450 mg/m3 TWA
m-xylene <1 108-38-3 No PEL established
ethylbenzene <1 100-41-4 100 ppm TWA; 435 mg/m3 TWA
o-xylene <1 95-47-6 No PEL established
p-xylene <1 106-42-3 No PEL established
III. HAZARDS IDENTIFICATION
Absorption., Inhalation, ingestion, skin, eyes.
Routes of Entry:
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Skin disease including eczema and sensitization. Eye disease. Kidney disease. Liver
Medical Conditions Aggravated:
disease. Pre-existing skin or respiratory conditions. Digestive tract disease.
Immediate (Acute) Health Effects
Irritation may be delayed for several hours. Can cause severe respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
Substance causes moderate skin irritation. Continued or prolonged contact may
Skin Contact:
irritate the skin and cause a skin rash (dermatitis). Moderately irritating to the skin.
Can cause minor skin irritation, defatting, and dermatitis.
Can cause irritation. Can cause moderate irritation, tearing and reddening, but not
Eye Contact:
likely to permanently injure eye tissue. Contact with the eyes may cause moderate to
severe eye injury. Eye contact may result in tearing and reddening, but not likely to
permanently injure eye tissue. Temporary vision impairment (cloudy or blurred
vision) is possible.
A single exposure is not likely to result in the product being absorbed through the
Skin Absorption:
skin in harmful amounts. Can be absorbed through the skin but exposure must be
extensive before adverse health effects occur. Toxic and may be harmful if absorbed
through the skin; may produce target organ damage. Minimal hazard in normal
industrial use. May cause gastrointestinal discomfort.
Harmful if swallowed. Aspiration of material into the lungs can cause chemical
Ingestion:
pneumonitis which can be fatal. Minimal toxicity May cause nausea. Irritating to
mouth, throat, and stomach. Can cause abdominal discomfort, nausea, vomiting and
diarrhea.
Target Organ Acute Toxicity:
Isobutyl acetate eyes, skin, respiratory system, CNS
Propane CNS
Acetone respiratory system, skin, eyes, CNS
Isopropyl acetate eyes, skin, respiratory system, CNS
Isobutane CNS
Toluene CNS, liver, kidneys, skin, eyes, respiratory system
Isopropyl alcohol eyes, skin, respiratory system
n-Butyl acetate eyes, skin, respiratory system, CNS
Methyl n-amyl ketone skin, eyes, CNS, PNS, respiratory system
n-Butyl alcohol eyes, CNS, skin, respiratory system
m-Xylene CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
Ethyl benzene eyes, respiratory system, skin, CNS
o-Xylene CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
p-Xylene CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
Long-Term (Chronic) Health Effects:
ACGIH. IARC. NIOSH. NTP. OSHA. Contains a substance that is a probable cancer
Carcinogenicity:
hazard based on human studies.
Possible reproductive hazard. A component in this product has been shown to cause
Reproductive and Developmental
Toxicity: birth defects and reproductive disorders in laboratory animals at doses that could be
encountered in the workplace.
No data available to indicate product or any components present at greater than 0.1%
Mutagenicity:
is mutagenic or genotoxic.
M102-0491 HEAVY BODIED SANDING SEALER Page 2 of 7
Upon prolonged and/or repeated exposure, can cause severe respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
Prolonged or repeated contact may produce defatting of the skin leading to irritation
Skin Contact:
and dermatitis. Prolonged or repeated contact may cause irritation. Continued or
prolonged contact may irritate the skin and cause a skin rash (dermatitis). May cause
lingering affects but not likely to result in permanent damage if the exposure is
eliminated. Upon prolonged or repeated contact, can cause moderate skin irritation,
defatting, and dermatitis. Not likely to cause permanent damage.
Upon prolonged or repeated contact, can cause severe irritation. Eye contact may
Eye Contact:
result in corneal injury. Symptoms may include discomfort or pain, excess blinking
and tear production, with marked redness and swelling of the conjunctiva. Temporary
vision impairment (cloudy or blurred vision) is possible.
Contains methanol. Upon prolonged or repeated exposure, may cause deterioration of
Skin Absorption:
the optic nerve if large quantities are absorbed through the skin. Repeated absorption
of large quantities may lead to blindness. Upon prolonged or repeated exposure,
harmful if absorbed through the skin. May cause severe irritation and systemic
damage.
Respiratory Tract. Skin. Respiratory Tract. Nervous System. Eyes. Liver. Eyes.
Target Organ Chronic Toxicity:
Nervous System. Skin. Kidneys. Liver. Digestive Tract. Blood.
No additional health information available.
Supplemental Health Hazard
Information:
IV. FIRST AID
Remove to fresh air. If breathing is difficult, have a trained individual administer
Inhalation:
oxygen. If not breathing, give artificial respiration and have a trained individual
administer oxygen. Get medical attention immediately.
Immediately flush eyes with plenty of water. Get medical attention, if irritation
Eyes:
persists. Flush immediately under running water for 15 minutes. If redness or
irritation occurs, seek medical attention. Immediately flush eyes with plenty of water
for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from
transferring to the uncontaminated eye. Get immediate medical attention and monitor
the eye daily as advised by your physician.
Immediately flush with water for 15 minutes. Wash the contaminated skin with soap
Skin Contact:
and water. If irritation develops, call a physician. Wash with soap and water. Remove
contaminated clothing and launder. Get medical attention if irritation develops or
persists.
Induce vomiting as a last measure. Induced vomiting may lead to aspiration of the
Ingestion:
material into the lungs potentially causing chemical pneumonitis that may be fatal.
First aid is normally not required. If conscious, give plenty of water to drink. Get
medical attention. If unconscious, do not give anything to drink. Get medical
attention. Minimal risk of harm if swallowed. Do not induce vomiting. Seek medical
attention immediately. Provide medical care provider with this MSDS.
No additional first aid information available.
Notes to MD:
M102-0491 HEAVY BODIED SANDING SEALER Page 3 of 7
V. FIRE FIGHTING MEASURES
Flammability Summary:
o
-144 (CALC.) F
Flash Point:
36.0 @ 77?F
Upper Flammable/Explosive
Limit, % in air:
1.27 @ 77?F
Lower Flammable/Explosive
Limit, % in air:
Flammable Liquid. Can release vapors that form explosive mixtures at temperatures
Fire Hazards:
at or above the flash point. Empty containers that retain product residue (liquid,
solid/sludge, or vapor) can be dangerous. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose container to heat, flame, sparks, static electricity, or other
sources of ignition. Any of these actions can potentially cause an explosion that may
lead to injury or death. Container may explode in heat of fire. Vapors may be ignited
by heat, sparks, flames or other sources of ignition at or above the low flash point
giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of
ignition and flash back.
Water spray Carbon dioxide Foam Flammable component(s) of this material may be
Extinguishing Media:
lighter than water and burn while floating on the surface. Use alcohol resistant spray,
Carbon Dioxide, water spray or dry chemical to extinguish a fire involving this
chemical. H2O, CO2, dry chemical, foam. Alcohol foam Water spray, foam, dry
chemical Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing
agents. Water spray or fog may also be effective for extinguishing if swept across the
base of the fire. Water can also be used to absorb heat and keep exposed material
from being damaged by fire.
Flammable component(s) of this material may be lighter than water and burn while
Fire Fighting Instructions:
floating on the surface. Use methods for the surrounding fire.Do not enter fire area
without proper protection including self-contained toxic breathing apparatus and full
protective equipment. Fight fire from a safe distance and a protected location due to
the potential of hazardous vapors and decomposition products. Flammable
component(s) of this material may be lighter than water and burn while floating on
the surface. Use water spray/fog for cooling.
Hazardous Combustion Products: Carbon dioxide, Carbon monoxide Hydrogen cyanide Nitrogen containing gases
Toxic gases
VI. ACCIDENTAL RELEASE MEASURES
Exposure to the spilled material may be irritating or harmful. Follow personal
Health Consideration for Spill
Response: protective equipment recommendations found in Section VIII of this MSDS.
Additional precautions may be necessary based on special circumstances created by
the spill including; the material spilled, the quantity of the spill, the area in which the
spill occurred. Also consider the expertise of employees in the area responding to the
spill.
Prevent the spread of any spill to minimize harm to human health and the
Spill Mitigation Procedures
General Methods: environment if safe to do so. Wear complete and proper personal protective
equipment following the recommendation of Section VIII at a minimum. Dike with
suitable absorbent material like granulated clay. Gather and store in a sealed container
pending a waste disposal evaluation.
VII. HANDLING AND STORAGE
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Use spark-proof tools and explosion-proof equipment. Wash thoroughly after
Handling:
handling. Avoid contact with material. "Empty" containers retain product residue
(liquid and/or vapor) and can be dangerous. Remove contaminated clothing and wash
before reuse. Ground and bond containers when transferring material. Use bonding
and grounding when transferring quantities of material. Harmful or irritating material.
Avoid contact and avoid breathing the material. Use only in a well ventilated area.
Keep away from sources of ignition. Keep away from heat, sparks, and flame. Store in
Storage:
a cool place in original container and protect from sunlight. Do not store in direct
sunlight. Keep container closed when not in use. Store in a cool dry ventilated
location. Isolate from incompatible materials and conditions. Keep container(s)
closed.
VIII. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
Ventilation should effectively remove and prevent buildup of any vapor/mist/fume
Engineering Controls:
generated from the handling of this product. Explosion proof exhaust ventilation
should be used. Local exhaust ventilation or other engineering controls are normally
required when handling or using this product to avoid overexposure.
Protective Equipment
Respirators should be selected by and used under the direction of a trained health and
Respiratory Tract:
safety professional following requirements found in OSHA's respirator standard (29
CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). A
written respiratory protection program, including provisions for medical certification,
training, fit testing, exposure assessments, maintenance, inspection, cleaning, and
convenient, sanitary storage should be implemented.
Wear chemically resistant safety glasses with side shields when handling this product.
Eyes:
Wear additional eye protection such as chemical splash goggles and/or face shield
when the possibility exists for eye contact with splashing or spraying liquid, or
airborne material. Do not wear contact lenses. Have an eye wash station available.
Avoid skin contact by wearing chemically resistant gloves, an apron and other
Skin:
protective equipment depending upon conditions of use. Inspect gloves for chemical
break-through and replace at regular intervals. Clean protective equipment regularly.
Wash hands and other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
IX. PHYSICAL DATA
CLOUDY LIQUID
Physical State:
STRONG SOLVENT
Odor:
11.461
Solids Vol %:
18.4621
Solids Wt %:
4.4381
Material VOC lbs/gal:
532.9744
Material VOC gms/l:
5.1592
Coatings VOC lbs/gal:
619.5769
Coatings VOC gms/l:
6.5886
Weight per gallon:
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X. STABILITY AND REACTIVITY
Stable. Normally stable. Keep away from heat, sparks and flame. Stable under
Stability Information:
normal conditions.
Avoid: heat, sparks, flame and oxidizing agents. Contact with oxidizing materials.
Conditions to Avoid:
None known.
Strong oxidizing agents. Strong acids. Strong alkalies. Amines. Oxidizing materials.
Chemical Incompatibility:
Acids. Acetic anhydride. Peroxides.
Hazardous Polymerization will not occur.
Hazardous Polymerization:
XI. TOXICOLOGICAL INFORMATION
Chemical Name CAS Number LD50/LC50
Acetic acid, isobutyl ester 110-19-0 Oral LD50 Rat : 13400 mg/kg; Dermal LD50 Rabbit : >17400 mg/kg
Acetone 67-64-1 Inhalation LC50 Rat : 50100 mg/m3/8H; Inhalation LC50 Mouse : 44
gm/m3/4H; Oral LD50 Rat : 5800 mg/kg; Oral LD50 Mouse : 3 gm/kg
Acetic acid, isopropyl ester 108-21-4 Inhalation LC50 Rat : 50600 mg/m3/8H; Oral LD50 Rat : 6750 mg/kg;
Dermal LD50 Rabbit : >20 mL/kg
Propane, 2-methyl- 75-28-5 Inhalation LC50 Rat : 57 pph/15M
Nitrocellulose 9004-70-0 Oral LD50 Rat : >5 gm/kg; Oral LD50 Mouse : >5 gm/kg
Toluene 108-88-3 Inhalation LC50 Rat : 49 gm/m3/4H; Inhalation LC50 Mouse : 400 ppm/24H;
Oral LD50 Rat : 636 mg/kg; Dermal LD50 Rabbit : 14100 uL/kg
Isopropyl alcohol 67-63-0 Inhalation LC50 Rat : 16000 ppm/8H; Oral LD50 Rat : 5045 mg/kg; Oral
LD50 Mouse : 3600 mg/kg; Dermal LD50 Rabbit : 12800 mg/kg
Isobutyric acid, isobutyl ester 97-85-8 Inhalation LC50 Rat : 5000 ppm/6H; Oral LD50 Rat : 12800 mg/kg; Dermal
LD50 Rabbit : >8600 mg/kg
Acetic acid, butyl ester 123-86-4 Inhalation LC50 Rat : 2000 ppm/4H; Inhalation LC50 Mouse : 6 gm/m3/2H;
Oral LD50 Rat : 10768 mg/kg; Oral LD50 Mouse : 6 gm/kg; Dermal LD50
Rabbit : >17600 mg/kg
2-Heptanone 110-43-0 Oral LD50 Rat : 1670 mg/kg; Oral LD50 Mouse : 730 mg/kg; Dermal LD50
Rabbit : 12600 uL/kg
sec-Butyl alcohol 78-92-2 Inhalation LC50 Rat : 8000 ppm/4H; Oral LD50 Rat : 790 mg/kg; Oral LD50
Mouse : 2680 mg/kg; Dermal LD50 Rabbit : 3400 mg/kg
m-Xylene 108-38-3 Oral LD50 Rat : 5 gm/kg; Dermal LD50 Rabbit : 14100 uL/kg
Benzene, ethyl- 100-41-4 Oral LD50 Rat : 3500 mg/kg; Dermal LD50 Rabbit : 17800 uL/kg
p-Xylene 106-42-3 Inhalation LC50 Rat : 4550 ppm/4H; Oral LD50 Rat : 5 gm/kg
XII. ECOLOGICAL INFORMATION
Keep out of waterways. No ecological information available.
Overview (for ingredients):
XIII. DISPOSAL CONSIDERATIONS
The waste may be a listed and/or characteristic hazardous waste. The waste may be a
Waste Description for Spent
Product: characteristic hazardous waste. The waste may be a "special" waste. Spent or
discarded material is a hazardous waste.
Comply with all Local, State, Federal, and Provincial Environmental Regulations.
Disposal Methods:
Clean up and dispose of waste in accordance with all federal, state, and local
environmental regulations. Dispose of by incineration following Federal, State, Local,
or Provincial regulations.
If discarded, this product is considered a RCRA ignitable waste, D001.
Potential EPA Waste Codes:
Components Subject to USEPA Land Disposal Restrictions:
Acetone 67-64-1 14.02 %
Toluene 108-88-3 5.1 %
n-Butyl alcohol 78-92-2 0.74 %
Ethyl benzene 100-41-4 0.09 %
M102-0491 HEAVY BODIED SANDING SEALER Page 6 of 7
XIV. TRANSPORTATION INFORMATION
AEROSOLS, FLAMMABLE, 2.1, UN 1950
DOT
See 49CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations.
XV. REGULATORY INFORMATION
Chemical Name Regulation CASRN %
Toluene SARA 313 Reportable: 108-88-3 5.1
Isopropyl alcohol SARA 313 Reportable: 67-63-0 4.42
sec-Butyl alcohol SARA 313 Reportable: 78-92-2 0.74
2-Butoxyethanol SARA 313 Reportable: 111-76-2 0.42
m-Xylene SARA 313 Reportable: 108-38-3 0.15
Ethyl benzene SARA 313 Reportable: 100-41-4 0.09
o-Xylene SARA 313 Reportable: 95-47-6 0.06
p-Xylene SARA 313 Reportable: 106-42-3 0.04
108-88-3 5.1
Toluene California Proposition 65
Developmental Toxicity:
110-19-0 19.9
isobutyl acetate New Jersey Right To Know:
74-98-6 14.74
propane New Jersey Right To Know:
67-64-1 14.02
acetone New Jersey Right To Know:
108-21-4 9.91
isopropyl acetate New Jersey Right To Know:
75-28-5 6.68
Isobutane New Jersey Right To Know:
XVI. ADDITIONAL INFORMATION
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION
Other Information:
CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY
FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A
PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES
OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA
OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS
AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND
INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION
OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE
ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
MSDS glossary.
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