3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 10/19/2006
Material Saf Data Sheet
ety
Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1:PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M F Barrier W ater Tight S
ire ealant 1000 NSand 1003 SL
MANUFACTURER: 3M
DIVISION: Building Safety Solutions Dept
ADDRESS: 3M Center
S P MN 5 14 -
t. aul, 5 4 1000
EMERGENCY PHONE: 1- 00- - 7 or (65 7 - 01 (24hours)
8 364 35 7 1) 37 65
Isu Date: 10/19/2006
se
p edesDate: 08 /11/2006
Su erc
c ment Gro p 08 8 10-
-5 3
Do u u:
Pro c Us
du t e:
Specific Use: Sealant Used F F P
or ire rotection
SECTION 2:INGREDIENTS
Ingredient C. S. .
A. No % b Wt
y
Calcium Carbonate 1317 65 3
-- 15- 4 0
S anes and S
ilox ilcones, Di- Hydrox Terminated
Me, y- 70131- -
67 8 25- 35
Poly(Dimethylsilox ane) 6314 - 9
8 62- 20 - 25
Ketox S
ime ilane 229 4 5 -
8 -49 3 -7
Amorphous S ilica 7631- 6-
89 0.5- 4.5
(Trimethoxysilylpropyl)Ethylenediamine 17 24 3
60- - 0.5- 1.0
SECTION 3:HAZARDS IDENTIFICATION
3. EMERGENCY OVERVIEW
1
s al rm: P aste
Sp if Phy ic Fo
ec ic
r, lo Grade: Low odor, thix otropic caulk
Odo Co r,
s al rm: S olid
General Phy ic Fo
ards May cause allergic sk reaction.
in
Immediate health, hy ic and env nmental haz
p s al, iro :
3. POTENTIAL HEALTH EFFECTS
2
Ey Co
e ntac t:
Mild Eye I
rritation: Signs/symptoms may include redness, pain, and tearing.
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 10/19/2006
Sk Co
in ntac t:
Mild S in I
k rritation: S igns/symptoms may include localized redness, swelling, and itching.
Allergic S in Reaction (non-
k photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalatio n:
Respiratory Tract I
rritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Inges n:
tio
Gastrointestinal I
rritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Target Organ Efec :
f ts
Persons previously sensitized to amines may develop a cross-
sensitization reaction to certain other amines.
SECTION 4: FIRST AID MEASURES
4. FIRST AID PROCEDURES
1
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
e ntac F
t: lush eyes with large amounts of water. I signs/symptoms persist, get medical attention.
f
Ey Co
in ntac Remove contaminated clothing and shoes. I mmediately flush sk with large amounts of water. Get medical
in
Sk Co t:
attention. W ash contaminated clothing and clean shoes before reuse.
Inhalatio Remove person to fresh air. I signs/symptoms develop, get medical attention.
f
n:
wed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
IfSwallo
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5:FIRE FIGHTING MEASURES
5. FLAMMABLE PROPERTIES
1
No Data Available
Au ignitio temp
to n erature
Not Applicable
Flas Po
h int
Not Applicable
Flammab Limits-LEL
le
Not Applicable
Flammab Limits-UEL
le
Not Applicable
OSHA Flammab ilityClasif atio
s ic n:
5. EXTINGUISHING MEDIA
2
Non-
combustible. Choose material suitable for surrounding fire.
5. PROTECTION OF FIRE FIGHTERS
3
Sp ial Fire Fighting Pro edu : W ear full protective equipment (Bunk Gear) and a self-
er contained breathing apparatus
ec c res
(SCBA).
ards Not applicable.
Unu u Fire and Ex lo io Haz
s al p sn :
No See STABILITY AND REACTIVITY (
te: SECTION 10)f r haz
o ardo sc mb s n and thermal dec mp s n
u o u tio o o itio
inf rmatio
o n.
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 10/19/2006
SECTION 6:ACCIDENTAL RELEASE MEASURES
Ac idental Releas Meas res Observe precautions from other sections. Call 3M-HELP line (1- 00- - 7 ) for more
S 8 364 35 7
c e u:
information on handling and managing the spill. Ventilate the area with fresh air. Collect as much of the spilled material as possible.
Clean up residue with detergent and water. Place in a closed container approved for transportation by appropriate authorities. Dispose
of collected material as soon as possible.
In the ev o a releas o thismaterial, u er s u determine ifthe releas q alif asrep rtab ac o
ent f ef the s ho ld e u ies o le c rding to
lo al, tate,
cs and f
ederal regulatio .
ns
SECTION 7 HANDLING AND STORAGE
:
71 HANDLING
.
Do not eat, drinkor smok when using this product. W ash ex
e posed areas thoroughly with soap and water. Avoid contact with
oxidizing agents. F industrial or professional use only.
or
72 STORAGE
.
Store away from acids. Store away from oxidizing agents.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
:
81 ENGINEERING CONTROLS
.
Use with appropriate local exhaust ventilation.
82 PERSONAL PROTECTIVE EQUIPMENT (
. PPE)
82. Ey
.1 e/Fac Pro tio
e tec n
Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields.
82. Sk Pro tio
.2 in tec n
Avoid prolonged or repeated sk contact. S
in elect and use gloves and/or protective clothing to prevent sk contact based on the
in
results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate
compatible materials. Gloves made from the following material(s) are recommended: P olyvinyl Chloride.
82. Res irato Pro tio
.3 p ry tec n
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
82. Prev
.4 entio o Swallo
nf wing
Do not eat, drinkor smok when using this product. W ash ex
e posed areas thoroughly with soap and water.
83 EXPOSURE GUIDELINES
.
Ingredient Au rity
tho Ty e
p Limit Additio Inf rmatio
nal o n
Calcium Carbonate ACGIH TW A 10 mg/m3
Calcium Carbonate OSHA TW A, respirable 5 mg/m3 Table Z-
1
Calcium Carbonate OSHA TW A, as total dust 15 mg/m3 Table Z-
1
Amorphous S ilica CMRG TW A, as respirable 3 mg/m3
dust
SOURCE OF EXP URE LI T DATA:
OS MI
ACGI American Conference of Governmental I
H: ndustrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 10/19/2006
OSHA: Occupational Safety and Health Administration
AI
HA: American Industrial Hygiene Association W ork place Environmental Exposure Level (W EEL)
SECTION 9:PHYSICAL AND CHEMICAL PROPERTIES
Paste
Sp if Phy ic Fo
ec ic s al rm:
Low odor, thix otropic caulk
Odo Co r,
r, lo Grade:
Solid
General Phy ic Fo
s al rm:
No Data Available
Au ignitio temp
to n erature
Not Applicable
Flas Po
h int
Not Applicable
Flammab Limits-LEL
le
Not Applicable
Flammab Limits-UEL
le
1.32 [ S :W ATER=
Ref td 1]
Sp if Grav
ec ic ity
No Data Available
Melting p int
o
Nil
So b
lu ilityin Water
16 g/l
Vo latile OrganicCo o nds
mp u
1.2 %
Perc v latile
ent o
SECTION 10:STABILITY AND REACTIVITY
Stab : table.
ility S
nditio toAv id: Strong acids; trong bases; trong ox
S S idizing agents
Materialsand Co ns o
ardo sPo meriz n: Hazardous polymerization will not occur.
Haz u ly atio
Hazardo sDec mp s n o By Pro c
u o o itio r - du ts
Su s e
b tanc Condition
Carbon dioxide During Combustion
Oxides of Nitrogen During Combustion
ardo sDec mp s n: silicon diox calcium ox and possible traces of incompletely burned carbon products.
ide, ide
Haz u o o itio
SECTION 11:TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MS for Tox
DS icological I
nformation on this material and/or its
components.
SECTION 12:ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13:DISPOSAL CONSIDERATIONS
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 10/19/2006
Was Dis o al Metho Dispose of waste product in a sanitary landfill. As a disposal alternative, dispose of waste product in a
te ps d:
facility permitted to accept chemical waste.
mb RCRA) Not regulated
EPA Hazardo sWas Nu er (
u te :
Sinc regu
e latio v , o u ap lic le regu
ns ary c ns lt p ab latio o au ritiesb o dis o al.
ns r tho ef re p s
SECTION 14:
TRANSPORT INFORMATION
ID Nu er()
mb s:
9 - 00- 27 7 9 - 00- 27 - 9 - 00- 27 - 9 - 00- 28 7
8 04 5 6- , 8 04 5 8 3, 8 04 5 9 1, 8 04 5 1-
Pleas c ntac the emergenc nu erslis o the f t p o the MSDS f r Trans o
eo t y mb ted n irs age f o p rtatio Inf rmatio f r this
n o no
material.
SECTION 15:REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Haz Catego :
ard ries
F Hazard -No P
ire ressure Hazard -No Reactivity Hazard -No I
mmediate Hazard -Yes Delayed Hazard -No
FIFRA
Status Regis
tratio Nu er
n mb
Registered 5 3- 0
38 5
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European I
nventory of Existing Chemical Substances (EI
NECS),
or are exempt polymers whose monomers are listed on EI NECS .
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
ThisMSDS hasb p ared tomeet the U. OSHA Haz Co
een rep S. ard mmu atio Standard, CFR 1910.
nic n 29 1200.
SECTION 16:OTHER INFORMATION
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3M MATERIAL SAFETY DATA SHEET 3M Fire Barrier Water Tight Sealant 1000 NS and 1003 SL 10/19/2006
NFPA Haz Clasif atio
ard s ic n
Health:2 Flammab :1
ility Reac ity
tiv :0 Sp ial Haz
ec ards
:None
National F P
ire rotection Association (NF A) hazard ratings are designed for use by emergency response personnel to address the hazards that are
P
presented by short-term, acute ex posure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and tox properties of the material but also include the tox properties of combustion or decomposition products that are k
ic ic nown to
be generated in significant quantities.
HMIS Haz Clasif atio
ard s ic n
2 Reac ity 0
Health: Flammab :1
ility tiv : Pro tio
tec n:B
Hazardous Material I dentification System (HMI 庐) hazard ratings are designed to inform employees of chemical hazards in the work
S place. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMI 庐 ratings are to be used with a fully implemented HMI 庐 program. HMI 庐 is a registered markof the National P and Coatings
S S S aint
Association (NP CA).
Revision Changes:
Section 2: I
ngredient table was modified.
Section 8 Ex
: posure guidelines ingredient information was modified.
Section 8 Ex
: posure guideline note was deleted.
DI CLAI
S MER: The information in this Material S afety Data S heet (MS ) is believed to be correct as of the date issued. 3M
DS
MAKESNO W ARRANTI , EXP ES RES ED OR I LI I
S MP ED, NCLUDI BUT NOT LI TED TO, ANY I LI W ARRANTY
NG, MI MP ED
OF MERCHANTABI TY OR F TNES F A P
LI I S OR ARTI CULAR P URP E OR COURS OF P
OS E ERF ORMANCE OR US AGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user' method of
s
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniq uely
within the user' k
s nowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user' method of use or application.
s
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M mak no representations as to its completeness or accuracy.
es
I addition, information obtained from a database may not be as current as the information in the MS available directly from 3M.
n DS
3M MSDSsare availab at www. c m
le 3M.o
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