HMIS: H=3*, F=1, R=0, PPE=J
* = Chronic health effects may occur
MATERIAL SAFETY DATA SHEET
for
COATINGS, RESINS, and RELATED MATERIALS
SECTION I - PRODUCT IDENTIFICATION
Corporate Address: Trade Name & Synonyms:
47 PARK AVENUE ALCHEMETAL
ELVERSON, PA 19520
Formula:
D5353 AQUEOUS AC-78
24-Hr Emergency Tel No: 610-286-3500
P.C. Number: D5353
Date of Preparation: 01 June 2006
FAX: 610-286-3510 Supercedes: None
IMPORTANT: BEFORE USING ALCHEMETAL D5353 AQUEOUS AC-78,
HAVE ALL PROCESSING PERSONNEL READ THIS DOCUMENT!
SECTION II - HAZARDOUS INGREDIENTS AND OCCUPATIONAL EXPOSURE LIMITS
Chemical(s) with CAS RN and Manufacturer's
vapor pressure (if applicable) OSHA PEL ACGIH TLV Recommendation
NICKEL TWA = 1 mg/m3 TWA = 1.5 mg/m3 No
7440-02-0 recommendation
NICKEL OXIDE TWA = 1 mg/m3 TWA = 0.2 mg/m3 No
1313-99-1 recommendation
N-METHYLPYRROLIDONE (NMP) Not Not No
872-50-4 established established recommendation
0.3 mm Hg at 20 C
FURFURYL ALCOHOL (skin) (skin) No
98-00-0 TWA = 10 ppm, TWA = 10 ppm recommendation
1.00 mm Hg at 31 C 40 mg/m3. STEL = 15 ppm
DIMETHYLAMINOETHANOL (DMAE) Not Not No
108-01-0 established established recommendation
4.0 mm Hg at 20 C
WHITFORD CORPORATION Page 2
MATERIAL SAFETY DATA SHEET
ALCHEMETAL D5353 AQUEOUS AC-78
23 January 2007
SECTION III - PHYSICAL DATA
Appearance . . . . . . . . Viscous, metallic-gray, liquid.
Boiling point (range) . . 100 TO 202 degrees C
Vapor density . . . . . . . Heavier than air
Evaporation rate . . . . Slower than ether
Specific gravity (H2O = 1) 2.11
Percent volatile by volume 76.3 %
Volatile organics (VOC) 2.40 Lbs VOC/Gal less water
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Lower Explosive Limit (%): 1.30
Flash point (Method Used): 94 degrees C (Setaflash)
Extinguishing Media:
Use carbon dioxide (CO2), alcohol foam, dry chemical, or water spray/water fog
extinguishing systems.
Special Fire Fighting Procedures:
Firemen and emergency responders: wear full turnout gear or Level A equipment including
positive-pressure, self-contained breathing apparatus (SCBA). If evacuation of personnel is
necessary, evacuate to an upwind area. Decontaminate personnel and equipment with a
water wash-down after fire and smoke exposure.
Unusual Fire and Explosion Hazards:
The product vapor is heavier than air and may travel a considerable distance to a source
of ignition and flashback.
SECTION V - HEALTH HAZARD DATA
Primary Route(s) of Entry and Exposure:
Inhalation: Yes Skin absorption: Yes Ingestion: Yes Skin or eye contact: Yes
Carcinogenicity: The following chemicals comprise 0.1% or more of this mixture and are listed
and/or classified as carcinogens or potential carcinogens by NTP, IARC, OSHA or ACGIH.
Chemical Reference Category
NICKEL NTP ANTICIPATED CARCINOGEN
IARC POSSIBLE HUMAN CARCINOGEN (GROUP 2B)
ACGIH CONFIRMED HUMAN CARCINOGEN
NICKEL OXIDE NTP ANTICIPATED CARCINOGEN
ACGIH CONFIRMED HUMAN CARCINOGEN
WHITFORD CORPORATION Page 3
MATERIAL SAFETY DATA SHEET
ALCHEMETAL D5353 AQUEOUS AC-78
23 January 2007
Effects of Overexposure, NICKEL:
Inhalation - Epidemiological studies of workers exposed to dust and
fumes generated in the production of stainless steel,
nickel alloys, and nickel powder have not indicated the
presence of a significant respiratory cancer hazard.
Skin contact - Repeated contact with metallic nickel may cause nickel sensi-
tivity and allergic skin rashes. Skin contact may cause an
allergic skin rash in previously sensitized individuals.
Skin absorption - No data found.
Eye contact - No data found.
Ingestion - NIOSH has concluded that nickel and its inorganic compounds
are not carcinogenic when ingested. The US FDA has affirmed
that nickel is Generally Recognized As Safe (GRAS) as a
direct human food ingredient.
Systemic &
other effects - No data found.
Supplemental The NTP has listed nickel as reasonably anticipated to be a
health carcinogen based on the production of injection-site tumors.
information - The IARC found there was inadequate evidence that metallic
nickel is carcinogenic to humans, but since there was
sufficient evidence that it is carcinogenic to animals, IARC
concluded that metallic nickel is possibly carcinogenic to
humans (Group 2B).
Repeated intratracheal instillation of nickel powder produced
an increased incidence of malignant lung tumors in rats. How-
ever, nickel powder did not produce an increased incidence of
malignant lung tumors in hamsters when administered at maximum
tolerated dose. Single intratracheal instillations of nickel
powder in hamsters at doses near LD50 produced an increased
incidence of fibrosarcomas, mesotheliomas and rhabdomosarcomas.
Nickel metal powder has caused tumors at the side of injection
in rodents; however, studies do not suggest a significant risk
risk for humans from nickel-containing prostheses.
WHITFORD CORPORATION Page 4
MATERIAL SAFETY DATA SHEET
ALCHEMETAL D5353 AQUEOUS AC-78
23 January 2007
Effects of Overexposure, NICKEL OXIDE:
Inhalation - Temporary irritation of the respiratory tract may result
from excessive overexposure.
Skin contact - No data found.
Skin absorption - No data found.
Eye contact - This material is an inert dust hazard and may cause
mechanical irritation to the eyes.
Ingestion - No data found.
Systemic &
other effects - No data found.
Supplemental Both the NTP Third Annual Report on Carcinogens and IARC
health Monographs cite limited evidence for carcinogenicity to
information - humans of certain nickel compounds and sufficient evidence
for carcinogenicity to animals. However, both state it is
not possible to identify which specific nickel compounds
might be carcinogenic to humans. Nickel, as found in this
pigment, is not listed in the groups of compounds thought
to be carcinogenic to either humans or animals.
Effects of Overexposure, N-METHYLPYRROLIDONE (NMP):
Inhalation - May cause irritation of the respiratory tract.
Skin contact - NMP is a moderate skin irritant and may cause delayed skin irri-
tation. Human experience has demonstrated redness, cracking and
blistering of skin through repeated or prolonged contact.
Skin absorption - No significant signs or symptoms indicative of any health hazard
are expected to occur as a result of skin absorption exposure.
Eye contact - Eye contact with NMP may cause moderate eye irritation
including burning sensation, tearing, redness or swelling.
May cause temporary corneal clouding.
Ingestion - NMP may be a health hazard if ingested in large quantities.
Symptoms include nausea, dizziness, and vomiting.
Systemic &
other effects - No relevant human data found.
WHITFORD CORPORATION Page 5
MATERIAL SAFETY DATA SHEET
ALCHEMETAL D5353 AQUEOUS AC-78
23 January 2007
Supplemental NMP was reported to effect pregnancy and/or fetal development
health in laboratory animals. Recently completed studies and an inde-
information - pendent, expert review of previous studies confirm that NMP is
not a mutagen, teratogen, carcinogen, or reproductive toxin.
Effects of Overexposure, FURFURYL ALCOHOL:
Inhalation - Vapors and mists of this material may cause headache, irri-
tation of the respiratory tract, and central nervous system
depression.
Skin contact - This material may cause irritation of the skin, skin rash,
and allergic reactions.
Skin absorption - Furfuryl alcohol is harmful via skin absorption.
Eye contact - Vapors and mists may cause eye irritation.
Ingestion - May cause irritation of mouth and stomach, and central
nervous system depression with weakness, headache, diarrhea,
dizziness, drowsiness, nausea, vomiting, unconsciousness
with convulsions, coma and death due to respiratory failure.
Small amounts may stimulate respiration while large amounts
may depress respiration and reduce body temperature.
Systemic &
other effects - No data found.
Supplemental
information - No data found.
Effects of Overexposure, DIMETHYLAMINOETHANOL (DMAE):
Inhalation - Vapors and aerosols will cause severe irritation of the
respiratory tract. DMAE has a strong objectionable odor that
may cause nausea, vomiting, headache or dizziness.
Skin contact - Short contact periods will severely irritate skin. Repeated or
prolonged contact will result in skin burns. Skin sensitization
may develop after repeated or prolonged contact with the skin.
Skin absorption - DMAE can be absorbed through the skin. Adverse effects similar
to inhalation may occur.
Eye contact - This material will induce chemical burns on contact with eyes.
Contact may cause blindness.
WHITFORD CORPORATION Page 6
MATERIAL SAFETY DATA SHEET
ALCHEMETAL D5353 AQUEOUS AC-78
23 January 2007
Ingestion - This material is classified as "slightly toxic" by ingestion.
Severe irritation of the mouth, esophagus, and stomach can
develop following ingestion of DMAE. Adverse effects similar
to inhalation may occur.
Supplemental One case of asthmatic sysmptoms from DMAE exposure which
health included sneezing, coughing and wheezing following inhalation
information - has been reported.
Emergency & First Aid Procedures:
Inhalation: If overcome by product vapors, mists or processing fumes, remove the
person from exposure immediately; call a physician. If breathing is irregular or
stopped, start resuscitation. Administer oxygen if a qualified person is available.
Skin contact: In case of skin contact, remove contaminated clothing. Flush the
skin with large amounts of water, then wash the skin with soap and water.
Eye contact: In case of eye contact, flush the eyes with water for 15 minutes. If
contact lenses are worn, quickly remove them, then flush the eyes with water. Have
a physician examine the eyes.
Ingestion: If material is ingested, seek immediate medical attention. If vomiting
occurs, keep the head below the hips to prevent aspiration of liquid into the lungs.
SECTION VI - REACTIVITY DATA
Stability:
- stable
Incompatability (Materials to Avoid):
- strong oxidizing agents, acids, and alkali/base/caustic solutions
- ammonium nitrate, perchlorates, phosphorous, selenium, and sulfur
Hazardous Decomposition Products:
- oxides of nickel
- oxides of carbon
- oxides of nitrogen
Hazardous Polymerization:
- will not occur
WHITFORD CORPORATION Page 7
MATERIAL SAFETY DATA SHEET
ALCHEMETAL D5353 AQUEOUS AC-78
23 January 2007
SECTION VII - SPILL OR LEAK PROCEDURES
Steps to be Taken in Case Material is Released or Spilled:
Spill Supervisor: Ensure cleanup personnel wear all appropriate Personal Protective
Equipment, including respiratory protection. If this product has a numerical flash-
point, remove all ignition sources; if the flashpoint is none, this precaution is
unnecessary. Keep nonessential personnel away from the contaminated area.
Prevent this material from entering sewers and watercourses by diking or impounding
the spilled material. Advise authorities if the product has entered or may enter,
sewers, watercourses, or extensive land areas.
Ventilate the contaminated area. If this product has a numerical flashpoint, use
nonsparking (bronze, aluminum, plastic, wood) tools to clean up the spill. If the
flashpoint is none, use conventional steel tools (or those just described) to clean
up the spill. EXCEPTIONS: If this product is Ultralon DCO Acid or a Xylar coating,
(except Xylar 500), use plastic shovels/scoops/rubber squeegees to clean up the
spill because of the products' acid content. Use the recommended tool type to mix
the appropriate sorbent into the spilled material. Use an absorbent like sawdust
for aqueous, waterborne and solvent-borne coatings. Use an absorbent like sand,
earth or clay for Ultralon DCO Acid and Xylar coatings (except Xylar 500).
Collect the saturated sorbent and transfer it into a covered container. Steel
containers are acceptable for all wastes except wastes which contain acid. Use
suitable plastic containers for acid-bearing wastes.
Label the waste container. Dispose of waste in compliance with all Federal, state,
regional, and local regulations.
Waste Disposal Method:
As the US EPA, state, regional and other regulatory agencies may have jurisdiction
over the disposal of your facility's hazardous waste, it is incumbent upon you, the
waste generator, to learn of and satisfy all the requirements which affect you.
Dispose of hazardous waste at a properly permitted disposal facility. Ensure
conformity to all applicable waste disposal regulations.
The US EPA Hazardous Waste Numbers which follow are applicable to the unadul-
terated product if it enters the "waste stream." Refer to Title 40 of the Code
of Federal Regulations, Part 261 (40 CFR 261). This part of the Code identifies
wastes which are subject to regulation under various sections of the Code and
which are subject to the notification requirements of Section 3010 of the
Resource Conservation and Recovery Act (RCRA).
- None
WHITFORD CORPORATION Page 8
MATERIAL SAFETY DATA SHEET
ALCHEMETAL D5353 AQUEOUS AC-78
23 January 2007
SECTION VIII - SAFE HANDLING & USE INFORMATION
Respiratory Protection:
Respiratory protection may not be needed if local exhaust is sufficient to main-
tain levels of hazardous ingredients below occupational exposure limits. If needed,
use a NIOSH/MSHA approved respirator equipped with organic vapor cartridges and
high-efficiency, particulate air (HEPA) filters.
Do not use respirators beyond their capabilities. For emergencies and unknown
concentrations, use supplied-air respiratory protection or a positive-pressure,
self-contained, breathing apparatus (SCBA).
Ventilation:
Use only with adequate ventilation, i.e., ventilation in compliance with
occupational exposure limits. Ensure processing (curing) ovens are properly
vented to prevent the introduction of processing fumes into the workplace.
Local Exhaust:
Local exhaust is recommended to ensure adequate ventilation.
Mechanical (General):
Use explosion-proof equipment and good manufacturing practice.
Special:
Safety showers and eyewash fountains should be readily available to personnel
who handle this material. Enforce "No Smoking" rules. If this product has a
numerical flashpoint, do not handle it in close proximity to unshielded light fixtures.
Protective Gloves:
Wear chemical-resistant gloves (butyl rubber or neoprene). Protective gloves
should be inspected frequently and discarded when they exhibit cuts, pinholes,
or signs of excessive wear.
Eye Protection:
Wear splash goggles. If extra protection is needed, wear a face shield over the
splash goggles. Face shields are effective only if worn in addition to splash goggles.
Other Protective Equipment:
Wear a chemical-resistant, butyl-rubber apron and other protective clothing, as
deemed appropriate, to avoid skin contact with material.
WHITFORD CORPORATION Page 9
MATERIAL SAFETY DATA SHEET
ALCHEMETAL D5353 AQUEOUS AC-78
23 January 2007
SECTION IX - SPECIAL PRECAUTIONS
Precautions to be Taken When Handling and Storing:
Wear all appropriate Personal Protective Equipment. Wear respiratory protection or ensure
adequate ventilation at all times. Use this product in a manner which minimizes splashes
and/or the creation of dust.
Protect from freezing. Keep containers closed when not in use. Do not handle or store
material near heat, sparks, open flames, or other sources of ignition. Store at room
temperatures, i.e., 40 to 95 F (4 to 35 C).
Other Precautions:
Good personal hygiene and good housekeeping are important. Wear fresh clothing
daily. Contaminated clothes and shoes must not be worn home. Launder contaminated
clothing before reuse. Remove contaminated shoes; clean and dry before reuse.
Do not smoke or eat in the work area. Thoroughly wash hands and face before
eating. Take every precaution to avoid inhalation and ingestion of product residue.
Do not use compressed air to clean contaminated floors or equipment. Surfaces
should be cleaned by vacuuming or wet scrubbing. Vacuum cleaners should be
suitable for use in an industrial environment (explosion proof, if necessary)
and equipped with high-efficiency, particulate air (HEPA) filters).
Avoid breathing product vapors, spray mist, and residue. Avoid breathing
processing fumes. Avoid skin contact. Avoid eye contact. Avoid ingestion.
Spilled material may cause the floor or contaminated area to become slippery.
SECTION X - REGULATORY INFORMATION
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA).
This product contains the following chemicals which are subject to the reporting requirements
of the Act and Title 40 of the Code of Federal Regulations, Part 372.
CHEMICAL CAS NUMBER PERCENTAGE
NICKEL 7440-02-0 59.820000
NICKEL COMPOUND 1313-99-1 0.180000
N-METHYL-2-PYRROLIDONE 872-50-4 1.824425
WHITFORD CORPORATION Page 10
MATERIAL SAFETY DATA SHEET
ALCHEMETAL D5353 AQUEOUS AC-78
23 January 2007
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs), under the reporting requirements
of 40 CFR 61. This product contains the following HAPs:
CHEMICAL CAS NUMBER PERCENTAGE
NICKEL 7440-02-0 59.820000
Nickel Compound 1313-99-1 0.180000
1,4-Dioxane 123-91-1 0.000003
Ethylene oxide 75-21-8 0.000000
4,4'-Methylenedianiline 101-77-9 0.007645
TOXIC SUBSTANCES CONTROL ACT (TSCA): All chemicals in this product appear in the
Toxic Substance Control Act Chemical Substance Inventory.
NON-WARRANTY. The information presented in this publication is based upon the
research and experience of Whitford. No representation or warranty is made
concerning the accuracy or completeness of the information presented in this
publication. Whitford makes no warranty or representation of any kind, expressed
or implied, including without limitation any warranty of merchantability or
fitness for any particular purpose, and no warranty or representation shall be
implied by law or otherwise. Any products sold by Whitford are not warranted as
suitable for any particular purpose to the buyer. The suitability of any product
for any purpose particular to the buyer is for the buyer to determine. Whitford
Corporation assumes no responsibility for the selection of products suitable to
the particular purposes of any particular buyer. Whitford Corporation shall in
no event be liable for any special, incidental, or consequential damages.
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