MATERIAL SAFETY DATA SHEET
FOR COATINGS, RESINS & RELATED MATERIALS
SECTION I
PRODUCT IDENTIFICATION
Manufacturer Ennis Paint, Inc. Information Ph: 800-331-8118
P.O. Box 404 Emergency Ph: 800-424-9300
Ennis, Texas 75120 Revised: 11/30/05
Product Class: Thermoplastic Roadmarking Compound
Hydrocarbon Type
HAZARD RATINGS: HTH 1
Trade Name: Ennis Paint Thermoplastic
CAS. Number: NONE-EXTREME FIRE 1
N/A 鈥? Formula Mixture
0- 4 REACTIVITY 1
SECTION II
HAZARDOUS INGREDIENTS
Applies to Leaded Yellow Only
Exposure Limits
INGREDIENTS CAS # wt % ACGIH/TLV
OSHA/PEL
Silica Encapsulated
Pigment Yellow 34 * 116565-74-3 10.0 MAX Not Established Not Established
*Contains 2-10% chrome yellow pigment (encapsulated lead chromate and other lead
compounds). As noted in OSHA lead standard, repeated prolonged exposure to lead chromate
may cause delayed effects involving the blood, gastrointestinal, nervous and reproductive
systems. However, this product contains encapsulated lead chromate, a much safer form.
White and lead free yellow products do not contain any hazardous ingredients.
SECTION III
PHYSICAL DATA
BOILING POINT: Not Applicable VAPOR DENSITY: Not Applicable
EVAPORATION RATE: Not Applicable VAPOR PRESSURE: Not Applicable
APPEARANCE: Solid Powder or Block SOLUBILITY IN WATER: Not Applicable
SPECIFIC GRAVITY: 1.70 - 2.20 MELTING POINT: R&B 95-120掳C
Odor: Odorless
SECTION IV
FIRE AND EXPLOSION HAZARD DATA
FLASHPOINT-COC >500掳F LEL: N/A UEL: N/A
EXTINQUISHING MEDIA:
Water, Dry Chemical, CO2, Foam
SPECIAL FIREFIGHTING PROCEDURES:
DURING EMERGENCY CONDITIONS, OVEREXPOSURE TO THERMAL DECOMPOSITION
PRODUCTS MAY CAUSE A HEALTH HAZZARD. AN APPROVED SELF-CONTAINED
BREATHING APPARATUS SHOULD BE WORN.
UNUSUAL FIRE & EXPLOSION HAZARDS:
WHEN EXPOSEED TO FLAME, EMITS ACRID FUMES.
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DUST MAY FORM EXPLOSIVE MIXTURE WITH AIR.
SECTION V
REACTIVITY DATA
STABLE
STABILITY: UNSTABLE
WILL NOT OCCUR
HAZARDOUS POLYMERIZATION: MAY OCCUR
INCOMPATIBILITY: Strong Oxidation Agents
CONDITIONS TO AVOID: Temperatures Above 500掳F, Open Flame.
HAZARDOUS DECOMPOSITION PRODUCTS: May include CO, Co2, and Aliphatic
Aldehydes.
SECTION VI
HEALTH HAZARD DATA
PERMISSABLE EXPOSURE LEVEL:
鈥? SEE SECTION II FOR INFORMATION ABOUT INDIVIDUAL INGREDIENTS.
ACUTE EXPOSURE:
鈥? INHALATION: OVEREXPOSURE TO NUISANCE DUST CAN LEAD TO DIFFICULITY IN
BREATHING AND MAY IRRITATE SKIN, EYES, AND RESPIRATORY SYSTEM.
鈥? EYES: POWDER OR DUST MAY CAUSE IRRITATION.
鈥? SKIN: MOLTEN MATERIAL CAN CAUSE SERIOUS BODILY BURNS.
鈥? INGESTION: NONE KNOWN
CHRONIC EXPOSURE:
鈥? Inhalation: NO CHRONIC EXPOSURE EFFECTS ARE KNOWN.
EMERGENCY AND FIRST AID PROCEDURES:
鈥? EYES: FLUSH THOROUGHLY WITH WATER, GET IMMEDIATE MEDICAL ATTENTION
IF CONTACT OCCURRED WITH MOLTEN MATERIAL OR IF IRRATION PERSISTS.
鈥? SKIN: WASH EXPOSED AREAS WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
IF CONTACT OCCURRED WITH MOLTEN THERMOPLASTIC APPLY WATER OR ICE
PACK IMMEDIATELY. DO NOT ATTEMPT TO REMOVE LARGE PATCHES OF AFFIXED
THERMOPLASTIC FROM SKIN, SEEK PROMT MEDICAL ATTENTION
鈥? INHALATION: MOVE VICTIM AWAY FROM SOURCE OF EXPOSURE AND INTO
FRESH AIR IF SYMPTOMS OF OVEREXPOSURE DEVELOP, GET MEDICAL ATTENTION.
GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED.
鈥? INGESTION: IF LARGE AMOUNTS ARE INGESTED, INDUCE VOMITING. SEEK
APPROPRIATE MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON
SECTION VII
SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
鈥? Sweep, Shovel, or Vacuum into container for disposal or reuse.
WASTE DISPOSAL METHOD:
鈥? Dispose of in accordance with local, state and federal regulations.
鈥? Avoid discharge to natural waters.
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SECTION VIII
SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION:
鈥? WEAR APPROPRIATE, PROPERLY FITTED RESPIRATOR (NIOSH/OSHA APPROVED)
DURING APPLICATION. IF APPLICATION IS LIKELY TO EXCEED ACCEPTABLE
CRITERIA. SPECIFICALLY A NIOSH APPROVED ORGANIXC VAPOR/DUST FILTRATION
TYPE IS RECCOMENDED
VENTILATION:
鈥? ADEQUATE VENTILATION IS NECESSARY WHEN APPLYING OR MIXING AND
EXHAUST WITH PROPER AIRFLOW IS ALWAYS RECOMMENDED.
鈥? AVOID ANY DIRECT INHALATION OF HEATED MATERIAL.
EYE PROTECTION:
鈥? WEAR APPROVE SAFETY FACE SHIELD, THIS WILL HELP PREVENT EYE INJURY.
OTHER PROTECTIVE EQUIPMENT:
鈥? GLOVES, LONG SLEEVES, HATS AND FACE SHIELDS ARE RECOMMENDED TO
PREVENT THE POSSIBILITY OF BURNS.
鈥? TRAIN AND EDUCATE EMPLOYEES IN THE SAFE USE OF THE PRODUCT.
SECTION IX
SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
鈥? PROTECT FROM MOISTURE DAMAGE WITH APPROPIATE COVERINGS
鈥? REMOVE ALL INGNITION SOURCES FROM MATERIAL HANDLING, TRANSFER, AND
PROCESSSING AREAS. MECHANICAL AND LOCAL EXHAUST SHOULD BE PROVIDED
IN UNVENTILATED WORK AREAS.
SECTION X
ADDITIONAL REGULATORY INFORMATION
DOT CLASSIFICATION SOLID STATE, GRANULAR OR BLOCK FORM: NOT DOT REGULATED.
DOT PROPER SHIPPING NAME: COMPOUND PAVEMENT MARKING
DOT CLASSIFICATION MOLTEN LIQUID STATE, TEMPERATURES ABOVE 100掳C , IS DOT
REGULATED.
DOT PROPER SHIPPING NAME: ELEVATED TEMPERATURE MATERIAL, LIQUID, N.O.S.
9, UN 3257, III.
TSCA-U.S. TOXIC SUBSTANCES CONTROL ACT:
ALL COMPONENTS OF THIS MIXTURE ARE IN COMPLIANCE WITH THE INVENTORY
LISTING REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL
SUBSTANCES INVENTORY.
The following applies to Leaded Yellow Only; White and Lead Free Yellow
products do not contain lead or chromium
SARA TITLE III SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT TO KNOW ACT OF 1986 AND OF 40 CFR 372:
CAS# CHEMICAL NAME PERCENT BY WEIGHT
7440-47-3 Elemental Chromium 1.2 Maximum
7440-92-1 Elemental Lead 5.3 Maximum
PROP 65 (CARCINOGEN):
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER.
CAS# CHEMICAL NAME PERCENT BY WEIGHT
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7440-47-3 Elemental Chromium 1.2 Maximum
7440-92-1 Elemental Lead 5.3 Maximum
PROP 65 (TERATOGEN):
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CAS# CHEMICAL NAME PERCENT BY WEIGHT
7440-47-3 Elemental Chromium 1.2 Maximum
7440-92-1 Elemental Lead 5.3 Maximum
PROP 65 (BOTH CARCINOGEN AND TERATOGEN):
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER OR BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CAS# CHEMICAL NAME PERCENT BY WEIGHT
7440-47-3 Elemental Chromium 1.2 Maximum
7440-92-1 Elemental Lead 5.3 Maximum
This statement and exact wording is included as required by the State of California. The conclusion
that all chromium (IV) and lead compounds have the same toxicological properties is not
supported by current toxicological data for lead chromate pigments.
SECTION XI
MISCELLANEOUS INFORMATION
THE INFORMATION OFFERED HEREIN IS, TO THE BEST OF OUR KNOWLEDGE, TRUE
AND ACCURATE, BUT ALL RECOMMENDATIONS ARE MADE WITHOUT WARRANTY,
EXPRESS OR IMPLIED, SINCE THE CONDITIONS OF USE ARE BEYOND OUR CONTROL,
NEITHER ENNIS PAINT, INC., NOR ITS AGENTS SHALL BE LIABLE FOR ANY INJURY, LOSS OR
DAMAGE, DIRECT OR CONSEQUENTIAL, ARISING FROM THE USE OR THE INABILITY TO USE
THE PRODUCT DESCRIBED HEREIN. NO PERSON IS AUTHORIZED TO MAKE ANY
STATEMENT OR RECOMMENDATION NOT CONTAINED IN THE MATERIAL DATA SHEET,
AND ANY SUCH STATEMENT OR RECOMMENDATION, IF MADE SHALL NOT BIND THE
CORPORATION.
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