3M MATERIAL SAFETY DATA SHEET 76810/76811 3M(TM) ESPE(TM) FILTEK(TM) SUPREME/ ELIPAR FREELIGHT
PROMOTIONAL KIT 02/11/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
PRODUCT NAME: 76810/76811 3M(TM) ESPE(TM) FILTEK(TM) SUPREME/ ELIPAR FREELIGHT
PROMOTIONAL KIT
MANUFACTURER: 3M
DIVISION: 3M ESPE Dental Products
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 02/11/2004
Supercedes Date: Initial Issue
Document Group: 19-0528-0
ID Number(s):
70-2011-2027-9, 70-2011-2028-7
This product is a kit or a multipart product which consists of multiple, independently packaged components. An MSDS for
each of these components is included. Please do not separate the component MSDSs from this cover page. The document
numbers of the MSDSs for components of this product are:
18-0179-4
No revision information is available.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
Page 1 of 1
3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) FILTEK(TM) SUPREME UNIVERSAL RESTORATIVE 06/29/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) ESPE(TM) FILTEK(TM) SUPREME UNIVERSAL RESTORATIVE
MANUFACTURER: 3M
DIVISION: 3M ESPE Dental Products
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 06/29/2004
Supercedes Date: 02/17/2004
Document Group: 18-0179-4
Product Use:
Intended Use: For use by dental professionals
Specific Use: Composite restorative material
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
SILANE TREATED CERAMIC 444758-98-9 65 - 75
BISPHENOL A POLYETHYLENE GLYCOL DIETHER DIMETHACRYLATE 41637-38-1 5 - 15
DIURETHANE DIMETHACRYLATE 72869-86-4 5 - 15
SILANE TREATED SILICA 248596-91-0 5 - 10
BISPHENOL A DIGLYCIDYL ETHER METHACRYLATE 1565-94-2 1 - 10
TRIETHYLENE GLYCOL DIMETHACRYLATE 109-16-0 <5
WATER 7732-18-5 <2
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
Odor, Color, Grade: Tooth colored, slight acrylate odor
General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction.
3.2 POTENTIAL HEALTH EFFECTS
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) FILTEK(TM) SUPREME UNIVERSAL RESTORATIVE 06/29/2004
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam).
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) FILTEK(TM) SUPREME UNIVERSAL RESTORATIVE 06/29/2004
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Ventilate the area with fresh air. Collect as much of the spilled material as possible.
Clean up residue. Collect the resulting residue containing solution. Place in a closed container approved for transportation by
appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid eye contact. Avoid skin contact. A no-touch technique is recommended. If skin contact occurs, wash skin with soap and water.
Acrylates may penetrate commonly-used gloves. If product contacts glove, remove and discard glove, wash hands immediately with
soap and water and then re-glove.
7.2 STORAGE
Store out of direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Not applicable.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid skin contact. See Sect. 7.1 for more information about skin protection.
8.2.3 Respiratory Protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
8.2.4 Prevention of Swallowing
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) FILTEK(TM) SUPREME UNIVERSAL RESTORATIVE 06/29/2004
Do not ingest.
8.3 EXPOSURE GUIDELINES
None Established
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Paste
Specific Physical Form:
Tooth colored, slight acrylate odor
Odor, Color, Grade:
Solid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
Not Applicable
Boiling point
No Data Available
Density
Not Applicable
Vapor Density
Not Applicable
Vapor Pressure
1.9 [Ref Std: WATER=1]
Specific Gravity
No Data Available
pH
No Data Available
Melting point
Nil
Solubility in Water
Not Applicable
Evaporation rate
Not Applicable
Volatile Organic Compounds
Not Applicable
Percent volatile
Not Applicable
VOC Less H2O & Exempt Solvents
Not Applicable
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) FILTEK(TM) SUPREME UNIVERSAL RESTORATIVE 06/29/2004
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal
alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
LE-F100-0079-5, 70-2010-3329-0, 70-2010-3330-8, 70-2010-3331-6, 70-2010-3332-4, 70-2010-3333-2, 70-2010-3334-0, 70-
2010-3335-7, 70-2010-3337-3, 70-2010-3338-1, 70-2010-3339-9, 70-2010-3340-7, 70-2010-3341-5, 70-2010-3342-3, 70-2010-
3343-1, 70-2010-3344-9, 70-2010-3345-6, 70-2010-3346-4, 70-2010-3347-2, 70-2010-3348-0, 70-2010-3349-8, 70-2010-3350-6,
70-2010-3351-4, 70-2010-3352-2, 70-2010-3353-0, 70-2010-3354-8, 70-2010-3355-5, 70-2010-3356-3, 70-2010-3357-1, 70-
2010-3358-9, 70-2010-3359-7, 70-2010-3361-3, 70-2010-3362-1, 70-2010-3363-9, 70-2010-3364-7, 70-2010-3365-4, 70-2010-
3366-2, 70-2010-3367-0, 70-2010-3369-6, 70-2010-3370-4, 70-2010-3371-2, 70-2010-3372-0, 70-2010-3373-8, 70-2010-3374-6,
70-2010-3375-3, 70-2010-3376-1, 70-2010-3377-9, 70-2010-3378-7, 70-2010-3379-5, 70-2010-3380-3, 70-2010-3381-1, 70-
2010-3382-9, 70-2010-3383-7, 70-2010-3384-5, 70-2010-3385-2, 70-2010-3386-0, 70-2010-3387-8, 70-2010-3388-6, 70-2010-
3400-9, 70-2010-3401-7, 70-2010-3402-5, 70-2010-3403-3, 70-2010-3408-2, 70-2010-3409-0, 70-2010-3410-8, 70-2010-3411-6,
70-2010-3412-4, 70-2010-3413-2, 70-2010-3414-0, 70-2010-3415-7, 70-2010-3416-5, 70-2010-3417-3, 70-2010-3418-1, 70-
2010-3419-9, 70-2010-3420-7, 70-2010-3421-5, 70-2010-3422-3, 70-2010-3423-1, 70-2010-3424-9, 70-2010-3425-6, 70-2010-
3426-4, 70-2010-3427-2, 70-2010-3428-0, 70-2010-3429-8, 70-2010-3430-6, 70-2010-3431-4, 70-2010-3432-2, 70-2010-3433-0,
70-2010-3434-8, 70-2010-3435-5, 70-2010-3436-3, 70-2010-3437-1, 70-2010-3438-9, 70-2010-3439-7, 70-2010-3440-5, 70-
2010-3441-3, 70-2010-3442-1, 70-2010-3443-9, 70-2010-3444-7, 70-2010-3445-4, 70-2010-3446-2, 70-2010-3447-0, 70-2010-
3448-8, 70-2010-3449-6, 70-2010-3450-4, 70-2010-3451-2, 70-2010-3452-0, 70-2010-3453-8, 70-2010-3454-6, 70-2010-3455-3,
70-2010-3456-1, 70-2010-3457-9, 70-2010-3458-7, 70-2010-3459-5, 70-2010-3460-3, 70-2010-3461-1, 70-2010-3462-9, 70-
2010-3463-7, 70-2010-3464-5, 70-2010-3467-8, 70-2010-3469-4, 70-2010-3470-2, 70-2010-3472-8, 70-2010-3473-6, 70-2010-
3474-4, 70-2010-3475-1, 70-2010-3476-9, 70-2010-3477-7, 70-2010-3478-5, 70-2010-3479-3, 70-2010-3480-1, 70-2010-3481-9,
70-2010-3483-5, 70-2010-3484-3, 70-2010-3485-0, 70-2010-3486-8, 70-2010-3487-6, 70-2010-3488-4, 70-2010-3489-2, 70-
2010-3490-0, 70-2010-3491-8, 70-2010-3492-6, 70-2010-3493-4, 70-2010-3494-2, 70-2010-3606-1, 70-2010-3607-9, 70-2010-
3608-7, 70-2010-3609-5, 70-2010-3611-1, 70-2010-3614-5, 70-2010-3615-2, 70-2010-3616-0, 70-2010-3617-8, 70-2010-3618-6,
70-2010-3619-4, 70-2010-3620-2, 70-2010-3621-0, 70-2010-3622-8, 70-2010-3623-6, 70-2010-3624-4, 70-2010-3687-1, 70-
2010-3688-9, 70-2010-3689-7, 70-2010-3690-5, 70-2010-3691-3, 70-2010-3692-1, 70-2010-3693-9, 70-2010-3694-7, 70-2010-
3695-4, 70-2010-3696-2, 70-2010-3697-0, 70-2010-3698-8, 70-2010-3699-6, 70-2010-3700-2, 70-2010-3701-0, 70-2010-3702-8,
70-2010-3723-4
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) FILTEK(TM) SUPREME UNIVERSAL RESTORATIVE 06/29/2004
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the
FDA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) FILTEK(TM) SUPREME UNIVERSAL RESTORATIVE 06/29/2004
Revision Changes:
Section 16: NFPA hazard classification heading was modified.
Section 15: 311/312 hazard categories heading was modified.
Section 15: International regulations information was modified.
Section 15: State regulations information was modified.
Section 15: US federal regulations information was modified.
Section 10: Hazardous polymerization heading was modified.
Section 2: Ingredient table was modified.
Section 16: NFPA explanation was modified.
Section 15: Inventories information was modified.
Section 12: Ecotoxicological information heading was modified.
Section 12: Chemical fate information heading was modified.
Section 16: NFPA hazard classification for special hazards was modified.
Section 8: Exposure guidelines information - none - was modified.
Section 12: Ecotoxicological phrase was modified.
Section 12: Chemical Fate phrase was modified.
Section 2: Ingredient phrase was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
_________________________________________________________________________________________________
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