3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) CLINPRO SEALANT 06/11/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) ESPE(TM) CLINPRO SEALANT
MANUFACTURER: 3M
DIVISION: 3M ESPE Dental Products
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 06/11/2004
Supercedes Date: 06/07/2004
Document Group: 16-0386-9
Product Use:
Limitations on Use: For use only by dental professionals
Specific Use: Dental sealant
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
TRIETHYLENE GLYCOL DIMETHACRYLATE 109-16-0 40 - 50
BISPHENOL A DIGLYCIDYL ETHER DIMETHACRYLATE 1565-94-2 40 - 50
TETRABUTYLAMMONIUM TETRAFLUOROBORATE 429-42-5 1 - 10
SILANE TREATED SILICA 68611-44-9 1- 7
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Clear to slight yellow, characteristic odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) CLINPRO SEALANT 06/11/2004
Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
Skin Contact:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Prolonged or repeated exposure may cause:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:
Prolonged or repeated exposure may cause:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness,
and nose and throat pain.
Ingestion:
Ingestion may cause:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) CLINPRO SEALANT 06/11/2004
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Non-flammable: ordinary combustible material.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Ventilate the area with fresh air. Clean up residue. Place in a closed container
approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid eye contact. Avoid skin contact. A no-touch technique is recommended. If skin contact occurs, wash skin with soap and water.
Acrylates may penetrate commonly-used gloves. If product contacts glove, remove and discard glove, wash hands immediately with
soap and water and then re-glove.
7.2 STORAGE
Store out of direct sunlight. Keep container in well-ventilated area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Not applicable.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid skin contact. See section 7.1 for skin protection information.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) CLINPRO SEALANT 06/11/2004
8.2.3 Respiratory Protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
8.2.4 Prevention of Swallowing
Do not ingest.
8.3 EXPOSURE GUIDELINES
None Established
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Clear to slight yellow, characteristic odor
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
>=95 潞F
Boiling point
No Data Available
Vapor Density
<=27 psia [@ 131.0 潞F]
Vapor Pressure
1.2 [Ref Std: WATER=1]
Specific Gravity
No Data Available
pH
Not Applicable
Melting point
No Data Available
Solubility In Water
No Data Available
Evaporation rate
No Data Available
Volatile Organic Compounds
No Data Available
Percent volatile
No Data Available
VOC Less H2O & Exempt Solvents
Approximately 1000 centistoke
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) CLINPRO SEALANT 06/11/2004
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of waste product in a facility permitted to accept chemical waste. As a disposal alternative,
incinerate in an industrial or commercial facility in the presence of a combustible material.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
70-2009-2353-3, 70-2010-3009-8, 70-2010-3011-4, 70-2010-3148-4, 70-2010-3149-2, 70-2010-3150-0, 70-2010-3151-8, 70-
2010-3152-6, 70-2010-3153-4, 70-2010-3154-2, 70-2010-3208-6, 70-2010-3505-5
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - No
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) CLINPRO SEALANT 06/11/2004
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the
FDA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 1: Product name was modified.
Section 14: ID Number(s) was modified.
Page Heading: Product name was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) CLINPRO SEALANT 06/11/2004
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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