2006 MSDS Catalog
MSDS
Catalog Index
AUSTIN POWDER
A TRADITION OF SAFETY, STRENGTH AND SERVICE.
MSDS Name Reference Number Catalog Page Numbers
Ammonium Nitrate A1 1-2
Austinite 15 and 30 B1 3-4
Austinite 15 HE Series B2 5-6
Austinite WR Series B3 7-8
Cast Boosters P1 9-10
Coalmex 14E E1 11-12
DES Pentolite Charges P4 13-14
Detonating Cord C1 15-16
Dynamite Series D3 17-18
Electric Detonators ED1 19-20
Emulex Series E3 21-22
Emutrench E6 23-24
FS Seismic Detonating Cord C2 25-26
Fuse Caps ED3 27-28
Gelatin and Semi-Gelatin Dynamites D2 29-30
HEET E2 31-32
Hydromite 400 Series S5 33-34
Hydromite HE-25 S6 35-36
Hydromite E4 37-38
Hydrox Bulk Emulsions E5 39-40
Non-Electric Detonators ED5 41-42
Oil Star Electric Detonators ED2 43-44
Permissible Dynamite Series D1 45-46
Non-Incendive Sheathed Explosive Unit
(Rockbuster II) D7 47-48
Shock Star Shock Tubing C3 49-50
Slurmex S4 51-52
AMMONIUM NITRATE
DATE MAY 2004 MSDS NO. A-1 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Ammonium Nitrate Prills
CLEVELAND, OHIO 44122
EMERGENCY PHONE
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3 CAS No. 6484-52-2
SECTION III PHYSICAL DATA
o o
VAPOR PRESSURE (mm Hg) N/A
BOILING POINT, 356 F (180 C )
o
VAPOR DENSITY (Air = 1) N/A
SPECIFIC GRAVITY (H2O = 1) 1.73 @ 25 C
EVAPORATION RATE: N/A
PERCENT VOLATILE BY VOL. (%) N/A o o
MELTING POINT: 169 C (336 F)
o
SOLUBILITY IN WATER: 118.3 g/100cc @ 0 C
White to beige,
APPEARANCE AND ODOR:
1/8" diameter prills. Odorless
DECOMPOSES AT 210 o C (410 oF)
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: Large quantities of water.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self contained breathing apparatus and fight fire only during initial
stages.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flood melted or burning ammonium nitrate with large volumes of water. Do
not smother or confine fire or explosion may result. Do not fight fire in
advanced stages. Evacuate to a safe distance.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: None
OSHA : None
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse,
vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water for at least 15 minutes.
Skin: Slight irritant. Wash with mild soap and water.
AMMONIUM NITRATE
DATE MAY 2004 MSDS NO. A-1 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or the shock of an adjacent detonation,
especially when confined and in large quantities.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid contamination with oxidizable materials.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and ammonia.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required for normal conditions. Slight skin irritant.
EYE PROTECTION: Not required under normal conditions. Slight eye irritant.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥? WARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Ammonium Nitrate Fertilizers, 5.1, UN2067 (or UN1942), PG II
This product should be kept dry and the oldest material used first.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
AUSTINITE
DATE JUNE 2004 MSDS NO. B-1 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Ammonium Nitrate-Fuel Oil Mixture, ANFO
CLEVELAND, OHIO 44122 Austinite 15
EMERGENCY PHONE Austinite 30
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3 CAS No. 6484-52-2 (92 to 97%)
Fuel Oil: Combustible Liquid, CAS No. 68476-30-2 (3 to 8%)
The mixture is classified by DOT as a Blasting Agent Type B or Blasting Explosive, Type B.
SECTION III PHYSICAL DATA
349 (0F) 176 (0C) 0.4 @ 680F
BOILING POINT, VAPOR PRESSURE (mm Hg)
SPECIFIC GRAVITY (H2O = 1) 0.85 to 1.10 VAPOR DENSITY (Air = 1) 4.7
EVAPORATION RATE: (Water=1) Slower
PERCENT VOLATILE BY VOL. (%) Approx. 6
SOLUBILITY IN WATER: NH4NO3 118.3 g/100cc @ 00 C
APPEARANCE AND ODOR: Granular beige-white, pink or
orange ( Canada), material with hydrocarbon ( fuel oil) odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: Fuel Oil 1250F Minimum P.M.
FLAMMABLE LIMITS: Fuel Oil Lower 0.7% Upper 5.0%
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn itself
out. Avoid toxic fumes from fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and in
large quantities.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: Ammonium Nitrate - None Oil mist, mineral, 5 MG/M3
OSHA : Ammonium Nitrate - None Oil mist, mineral, 5 MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse,
vomiting, abdominal pain, rapid heartbeat, rapid breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water.
Skin: Slight irritant. Wash with mild soap and water.
AUSTINITE
DATE JUNE 2004 MSDS NO. B-1 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides and chlorates.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so that
the energy is utilized as originally intended. This material may become a hazardous waste under certain conditions. Call Austin
Powder for recommendations and assistance. It must be collected, labeled and disposed of under direct supervision of a qualified
person according to local, state and federal regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required for normal conditions. Slight skin irritant.
EYE PROTECTION: Not required under normal conditions. Slight eye irritant.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT proper shipping description for Domestic transportation: Ammonium Nitrate-Fuel Oil Mixture, 1.5D, NA0331, PG II.
DOT or IMDG proper shipping description for Domestic or International transportation: Explosive, Blasting, Type B or Agent,
Blasting, Type B, 1.5D, UN0331, PG II. Exemption DOT-E11156 authorizes shipment of multi-wall, stitch top closure, water -
resistant bags.
This product should be kept dry and the oldest material used first. Use only proper primers. Avoid wet holes and inadequate
confinement. If these restrictions are observed, the formation of toxic fumes from detonation will be minimized.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
AUSTINITE 15 HE SERIES
DATE MAY 2004 MSDS NO. B-2 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE HE-1 Through HE-12
CLEVELAND, OHIO 44122 Aluminized ANFO
EMERGENCY PHONE
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3 CAS No. 6484-52-2 (80-96%)
Fuel Oil: Combustible Liquid, CAS No. 68476-30-2 (3-8%)
Aluminum: AL, CAS No. 7429-90-5 (1-12%)
SECTION III PHYSICAL DATA
Oil 349 (F0) 176 (C0) 0.4 @ 680F
BOILING POINT, VAPOR PRESSURE (mm Hg)
SPECIFIC GRAVITY (H2O = 1) 0.85 to 1.00 VAPOR DENSITY (Air=1) 4.7
PERCENT VOLATILE BY VOL. (%) Approx. 6 EVAPORATION RATE: (Water=1) Slower
SOLUBILITY IN WATER: NH4NO3 118.3 g/100cc @ 00C
APPEARANCE AND ODOR: White prills or granules with coarse gun metal grey particles. Hydrocarbon (fuel oil) odor is
noticeable. .
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: Fuel Oil 1250F Minimum P.M.
FLAMMABLE LIMITS: Fuel Oil Lower 0.7% Upper 5.0%
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn itself out.
Avoid toxic fumes from fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and in
large quantities.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: Oil mist, mineral, 5 MG/M3 , Al metal & oxide, 10 MG/M3
OSHA : Oil mist, mineral, 5 MG/M3, Al metal & oxide, none
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse,
vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water.
Skin: Slight irritant. Wash with mild soap and water.
AUSTINITE 15 HE SERIES
DATE MAY 2004 MSDS NO. B-2 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides and chlorates.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so that
the energy is utilized as originally intended. This material may become a hazardous waste under certain conditions. Call Austin
Powder for recommendations and assistance. It must be collected, labeled and disposed of under direct supervision of a qualified
person according to local, state and federal regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required for normal conditions. Slight skin irritant.
EYE PROTECTION: Not required under normal conditions. Slight eye irritant.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosive, Blasting, Type B, or Agent, Blasting, Type B, 1.5D, UN0331, PG II
This product should be kept dry and the oldest material used first. Use only proper primers. Avoid wet holes and inadequate
confinement. If these restrictions are observed, the formation of toxic fumes from detonation will be minimized.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
AUSTINITE WR SERIES
DATE MAY 2004 MSDS NO. B-3 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Austinite WR 300
CLEVELAND, OHIO 44122 Water Resistant ANFO
EMERGENCY PHONE
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3 CAS No. 6484-52-2 (86 to 94%)
Fuel Oil: Combustible Liquid, CAS No. 68476-30-2 (2 to 6%)
Guar Gum CAS No. 9000-30-0 (3 to 8%)
SECTION III PHYSICAL DATA
Oil 349 (F0) 176 (C0) 0.4 @ 680F
BOILING POINT, VAPOR PRESSURE (mm Hg)
SPECIFIC GRAVITY (H2O = 1) 0.85 to 1.10 VAPOR DENSITY (Air=1) 4.7
PERCENT VOLATILE BY VOL. (%) 2 to 5 EVAPORATION RATE: (Water=1) Slower
SOLUBILITY IN WATER: NH4NO3 118.3 g/100cc @ 00C Although in excess of 80% of the materials are readily soluble in
water, the Austinite WR Series provides good water resistance.
APPEARANCE AND ODOR: Granular grey to black material with hydrocarbon (fuel oil) odor.
.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: Fuel Oil 1250 F Minimum P.M.
FLAMMABLE LIMITS: Fuel Oil Lower 0.7% Upper 5.0%
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn itself out.
Avoid toxic fumes from fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and in
large quantities.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: Ammonium Nitrate-None. Oil mist, mineral, 5 MG/M3
OSHA : Ammonium Nitrate-None. Oil mist, mineral, 5 MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse,
vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water.
Skin: Slight irritant. Wash with mild soap and water.
AUSTINITE WR SERIES
DATE MAY 2004 MSDS NO. B-3 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides and chlorates.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides, carbon oxides, sulfur oxides
and hydrogen sulfide: Toxic decomposition products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so that
the energy is utilized as originally intended. This material may become a hazardous waste under certain conditions. Call Austin
Powder for recommendations and assistance. It must be collected, labeled and disposed of under direct supervision of a qualified
person according to local, state and federal regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required for normal conditions. Slight skin irritant.
EYE PROTECTION: Not required under normal conditions. Slight eye irritant.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosive, Blasting, Type B, or Agent, Blasting, Type B, 1.5D, UN0331, PG II
This product should be kept dry and the oldest material used first. Use only proper primers. Use in dewatered blast holes. Avoid
inadequate confinement. If these restrictions are observed, the formation of toxic fumes from detonation will be minimized.
Before blasting near inhabited buildings contact an Austin Powder Technical Representative.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
CAST BOOSTERS
DATE OCTOBER 2006 MSDS NO. P-1 PAGE 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
TRADE NAME AND SYNONYMS
AUSTIN POWDER COMPANY ACP Boosters: Orange Cap, Orange Cap R, Red Cap, Black Cap, Brown Cap,
25800 SCIENCE PARK DRIVE Green Cap, Purple Cap, White Cap, Gray Cap, etc.
CLEVELAND, OHIO 44122 NDS Boosters, ADP Boosters, Gold Nugget, Silver Nugget, Diamond Nugget,
EMERGENCY PHONE
DES Series, DES Pentolite Charges, Rock Crushers, 60 Gram, 90 Gram, 110
DAY 216-464-2400
Gram, DES Shaped Charges, Prime Gel*, Renforcatuers, HDP 150, HDP 400,
NIGHT 216-464-2407
HDP 400LP, HDP 450, Doubledet, Ringprime and Snow Launcher Series,
Hornet Series, Enviroprime Series and Electro Star Series.
SECTION II HAZARDOUS INGREDIENTS
Formulated with TNT and an explosive sensitizer such as PETN, RDX and/or HMX.
TNT, Trinitrotoluene, C7H5N3O6, CAS No. 118-96-7 30% to 80% TNT
PETN, Pentaerythritol tetranitrate, C5H8N4O12, CAS No. 78-11-5 20% to 70% PETN, RDX, and/or
HMX.
HMX, Cyclotetramethylene tetranitramine, Octogen, C4H8N8O8, CAS No. 261-41-0
RDX, Cyclotrimethylene trinitramine, Cyclonite, C3H6N6O6, CAS No. 121-82-4
Aluminum, AL CAS No. 7429-90-5 0% to 20% Aluminum
Pentolite is a 50/50 mixture of PETN and TNT. CAS No. 8066-33-9
Orange Cap R and Electro Star boosters contain a brass sleeve.
SECTION III PHYSICAL DATA
BOILING POINT Decomposes VAPOR PRESSURE (mm Hg) Negligible at 20掳C
SPECIFIC GRAVITY (H2O = 1) 1.65 VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: 0.15%
APPEARANCE AND ODOR: Solid yellow-buff cast crystalline material. No odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow
fire to burn itself out. Avoid toxic fumes from fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: TNT-Skin, 0.1 MG/M3 PETN-None RDX-Skin, 1.5 MG/M3 AL-10MG/M3
OSHA : TNT-Skin, 1.5 MG/M3 PETN-None RDX-None AL-15MG/M3
EFFECTS OF OVEREXPOSURE: TNT ingestion may cause headache, weakness, anemia, or liver damage. Excessive
skin contact may cause dermatitis and sensitization. PETN is a vasodilator. Ingestion of RDX may cause nervous
system disorders or epiliptiform seizures.
EMERGENCY AND FIRST AID PROCEDURES:
FUMES: Remove to fresh air.
IF INGESTED: Obtain medical attention immediately.
CAST BOOSTERS
DATE OCTOBER 2006 MSDS NO. P-1 PAGE 2 OF 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire shock or friction.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid contact with strong acids or alkalies.
Do not exceed 150掳F (66掳C).
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic
decomposition products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all
spilled material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state
and federal regulations. Call Austin Powder for recommendations and assistance. This material may become a
hazardous waste under certain conditions and must be collected, labeled and disposed of per state and federal
hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S.
dial the U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Avoid breathing fumes from detonation.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required for normal handling of boosters.
EYE PROTECTION: Not required under normal conditions.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Boosters, Without Detonator, 1.1D, UN 0042, PG II
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A, or 2B as a known, probable or possible
carcinogen, nor are they listed in the NTP annual report on carcinogens.
The Enviroprime Series contains 4 to 7 % of a bioremediation inoculant consisting of natural food products and a trace of
a naturally occurring non-pathogenic bacterium.
*Prime Gel contains both a Cast Booster and Hydromite. Also see the Hydromite MSDS.
COALMEX 14 E
DATE JUNE 2004 MSDS NO. E-1 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Coalmex 14 E (Permissible Emulsion)
CLEVELAND, OHIO 44122 Red-D Lite AXE 129
EMERGENCY PHONE
Enviroseis Surface
DAY 216-464-2400
Note: Enviroseis Surface includes a continuous
NIGHT 216-464-2407
length of Detonating Cord. See Detonating Cord
MSDS.
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3, CAS No. 6484-52-2 (60 - 90%)
Sodium Nitrate, NaNO3, CAS No. 7631-99-4 (6 - 15%)
EDDN: Ethylenediamine Dinitrate, C2H10N4 O6, CAS No. 505-71-5 (0 - 10%)
Petroleum Hydrocarbons, CAS No. 68476-30-2 (3 - 9%)
An emulsified water in oil mixture of ammonium nitrate, sodium nitrate, mineral oil, emulsifiers, EDDN and hollow microspheres.
SECTION III PHYSICAL DATA
BOILING POINT None VAPOR PRESSURE (mm Hg) Less than 0.1
SPECIFIC GRAVITY (H2O = 1) 1.1 to 1.2 VAPOR DENSITY (Air=1)
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Although in excess of 80% of the materials are readily soluble in water, the products have
excellent water resistance for long periods of time.
APPEARANCE AND ODOR: Semi-solid cohesive material. Negligible odor.
SECTION IV FIRE AND EXPLOSION DATA
Mineral oil, 2500F. ( 1210C) PMCC
FLASH POINT:
FLAMMABLE LIMITS: Not available
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn
itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and
in large quantities. Avoid toxic fumes from fires.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: NH4 NO3 - None, EDDN - None
OSHA: NH4 NO3 - None, EDDN - None
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse,
vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Flush with large amounts of water for at least 15 minutes and consult a physician.
Skin: Wash with mild soap and water.
COALMEX 14 E
DATE JUNE 2004 MSDS NO. E-1 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities. Avoid temperatures above 2120F.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides and chlorates.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so that
the explosive energy is utilized as originally intended. Dispose of under direct supervision of a qualified person according to local,
state and federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Ventilate storage magazine.
PROTECTIVE GLOVES: Avoid skin contact. Wear impervious gloves when handling
material.
EYE PROTECTION: Safety glasses.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosives, Blasting, Type E, 1.1D, UN0241, PG II
Coalmex 14E is approved for use as a Permissible Explosive by the USDL and MSHA when used in conformance with the
requirements of 30 CFR 15.
This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and
federal hazardous waste regulations.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
DES PENTOLITE CHARGES
DATE JUNE 2004 MSDS NO. P-4 PAGE 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE DES series, DES Shaped Charges,
CLEVELAND, OHIO 44122 Seismic Directional Energy System
EMERGENCY PHONE
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
TNT, Trinitrotoluene, C7H5N3O6, CAS No. 118-96-7 (40% to 50%)
PETN, Pentaerythritoltetranitrate, C5H8N4O12, CAS No. 78-11-5 (50% to 60%)
Pentolite is a mixture of PETN and TNT. CAS No. 8066-33-9 (50/50)
SECTION III PHYSICAL DATA
BOILING POINT Decomposes VAPOR PRESSURE (mm Hg) Negligible at 20 oC
SPECIFIC GRAVITY (H2O = 1) 1.65 VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: 0.15%
APPEARANCE AND ODOR: Solid yellow-buff cast crystalline material. No odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fire. Withdraw personnel immediately. Allow
fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock. Avoid toxic
fumes from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: TNT - Skin, 0.1 MG/M3, PETN - None
OSHA: TNT - Skin, 1.5 MG/M3, PETN - None
EFFECTS OF OVEREXPOSURE: TNT ingestion may cause headache, weakness, anemia, or liver damage. Excessive
skin contact may cause dermatitis and sensitization. PETN is a vasodilator.
EMERGENCY AND FIRST AID PROCEDURES:
FUMES: Remove to fresh air.
IF INGESTED: Obtain medical attention immediately.
DES PENTOLITE CHARGES
DATE JUNE 2004 MSDS NO. P-4 PAGE 2 OF 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire, shock, or friction.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid contact with strong acids or alkalies.
Do not exceed 150 F (66 C).
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic
decomposition products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all
spilled material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state
and federal regulations. Call Austin Powder for recommendations and assistance. This material may become a
hazardous waste under certain conditions and must be collected, labeled and disposed of per state and federal
hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S.
dial the U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Avoid breathing fumes from detonation.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required for normal handling of boosters.
EYE PROTECTION: Not required under normal conditions.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Boosters without Detonator, 1.1D, UN0042, PG II
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible
carcinogens, nor are they listed in the NTP annual report on carcinogens.
DETONATING CORD
DATE SEPTEMBER 2004 MSDS NO. C-1 PAGE 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Lite Line, Scotch Cord, A-Cord, Tuff-Kote, No. 40, No. 50
CLEVELAND, OHIO 44122 No. 60, etc. Seismic Detonating Cord, Slide Line Series,
EMERGENCY PHONE Heavy Duty Series, Cordeau Detonant Fuse, Cord,
DAY 216-464-2400 Detonating, Flexible, Fine Line, Trim Line, Special 18, 25,
NIGHT 216-464-2407 30,40 and 50.Detonating Cord C3
SECTION II HAZARDOUS INGREDIENTS
PETN, Pentaerythritol tetranitrate, C5H8N4O12, CAS No. 78-11-5
SECTION III PHYSICAL DATA
VAPOR PRESSURE (mm Hg) Negligible at 200C
BOILING POINT N/A
SPECIFIC GRAVITY (H2O = 1) 1.76 VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Negligible
APPEARANCE AND ODOR: Flexible cord with an explosive core of PETN protected within a textile casing
covered by a seamless polyethylene jacket. PETN is a white crystalline solid. No odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below
SPECIAL FIREFIGHTING PROCEDURES: Do not fight fire. Withdraw personnel immediately. Allow
fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
May explode when subjected to fire or shock. Avoid toxic
fumes from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: PETN-None
OSHA : PETN-None
EFFECTS OF OVEREXPOSURE: Ingestion of PETN may cause headache and nausea. PETN is a vasodilator and
produces dilation of blood vessels.
EMERGENCY AND FIRST AID PROCEDURES:
FUMES: Remove to fresh air.
IF INGESTED: Obtain medical attention immediately.
DETONATING CORD
DATE SEPTEMBER 2004 MSDS NO. C-1 PAGE 2 OF 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid contact with strong acids or alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic
decomposition products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATON WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all
spilled material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state
and federal regulations. Call Austin Powder for recommendations and assistance. This material may become a
hazardous waste under certain conditions and must be collected, labeled and disposed of per state and federal
hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S.
dial the U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required except to prevent abrasive injuries.
EYE PROTECTION: Not required under normal conditions.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS" AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Cord, Detonating, Flexible, 1.1D, UN0065, PG II
May be offered for transportation domestically and transported as Cord, Detonating (UN 0289), Division 1.4 compatibility
group D (1.4D) Explosives, if the explosive content does not exceed 100 grains per linear foot (21.3 grams per meter)
and the gross weight of all packages of detonating cord does not exceed (45 KG) 99 pounds per vehicle. See 49 CFR
173.63
The maximum recommended temperature for detonating cord is 1600F (710C). None of the components are listed in the
1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens, nor are they listed in the NTP
annual report on carcinogens.
DYNAMITE SERIES
DATE JULY 2004 MSDS NO. D-3 Page 1 0F 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Extra Dynamite Series
CLEVELAND, OHIO 44122 AXD 500 Series
EMERGENCY PHONE Red-E Split Series
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Nitroglycerin, NG, C3H5O3 (NO2)3, CAS No. 55-63-0, 1-20%
Ethylene Glycol Dinitrate, EGDN, C2H4O2 (NO2)2, CAS No. 628-96-6 8-76%
Nitrocellouse, NC, C12H14N6O22 CAS No. 9004-70-0 0-6%
Ammonium Nitrate, AN, NH4NO3, CAS No. 6484-52-2, 0-75%
Sodium Nitrate, SN, NaNO3 CAS No. 7631-99-4 0-50%
Sulfur, S CAS No .7704-34-9 0-4%
SECTION III PHYSICAL DATA
BOILING POINT None VAPOR PRESSURE (mm Hg) 0.038-0.050
SPECIFIC GRAVITY (H2O = 1) 0.8 to 1.48 VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
EXPLOSION POINT: 237oF
SOLUBILITY IN WATER: Salts are soluble in water, but the nitric esters (NG and EGDN) are only slightly soluble.
APPEARANCE AND ODOR: A mixture of absorbants, white oxidizing salts. Tan color with white granules. Slightly sweet odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: Not Applicable
FLAMMABLE LIMITS: Not Applicable
EXTINGUISHING MEDIA: See below
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Immediately withdraw personnel for 2500 feet in all
directions. Allow fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire, impact or shock, especially when confined
or in large quantities. Avoid toxic fumes from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH TWA: NG 0.05 PPM*, EGDN; 0.05 PPM*, AN; None
OSHA: NG CEILING; 0.2 PPM*, 2 MG/M3 EGDN CEILING; 0.2 PPM, 1 MG/M3*, AN; None
*Skin
EFFECTS OF OVEREXPOSURE: Ingestion, inhalation or absorption through skin contact may cause headache, nausea, blood
vessel dilation, vomiting, and convulsions. In extreme cases, death may result.
EMERGENCY AND FIRST AID PROCEDURES:
EYES: Slight irritant. Hold eyelid open and flush with large amounts of water for 15 minutes.
SKIN: Slight irritant. Absorbs through skin. Wash with mild soap and water.
INGESTION: Consult a physician if persistent headaches or chest pains develop. The nitric esters are coronary vasodilators.
DYNAMITE SERIES
DATE JULY 2004 MSDS NO. D-3 Page 2 0F 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire, impact or shock.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially acids or alkalies, peroxides
and chlorates. Do not exceed 1500F ( 660C).
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides, hydrogen sulfide and carbon oxides: Toxic
decomposition products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all spilled
material immediately using non-sparking tools. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state and
federal regulations. Call Austin Powder for recommendations and assistance. This material may become a hazardous waste under
certain conditions and must be collected, labeled and disposed of per state and federal hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Ventilate magazines before entering.
PROTECTIVE GLOVES: Wear absorbent cotton or chemical resistant (nitrile) gloves.
EYE PROTECTION: Not required under normal conditions.
WARNING: Minimize inhalation and skin contact. Prevent contact
with food, and chewing or smoking materials.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES. STORE IN COOL, DRY, WELL-VENTILATED LOCATION.
DOT or IMDG proper shipping description: Explosive, Blasting, Type A, 1.1D, UN0081, PG II.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
MATERIAL SAFETY DATA SHEET
庐
ELECTRIC DETONATORS
DATE MARCH 2006 MSDS NO. ED-1 PAGE 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
TRADE NAME AND SYNONYMS
AUSTIN STAR DETONATOR COMPANY
Rock* Star, Time* Star, Coal Mine Delays,
901 CANTU ROAD
Seismic* Star, Static*Star, 3-D Star Seismic Detonators,
BROWNSVILLE, TX 78520 Electro*Star Electronic Detonators
Electric Blasting Caps
24 HOUR PHONE: 956-831-7751
SECTION II HAZARDOUS INGREDIENTS
Explosive components are PETN (possibly TNT) and lead compounds sealed in a metal shell.
PETN, Pentaerythritol tetranitrate, C5H8 N4 O12 CAS No. 78-11-5
Lead Azide, Pb (N3)2 CAS No. 13424-46-9
Lead Styphnate, Lead Trinitroresorcinate, C6H3N3O9Pb CAS No. 15245-44-0
TNT, Trinitrotoluene, C7H5N3O6 CAS No. 118-96-7 (May be included in some detonators)
SECTION III PHYSICAL DATA
BOILING POINT N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1) N/A VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Insoluble
APPEARANCE AND ODOR: Aluminum or copper shells with attached PVC or polyethylene coated copper or iron leg
wires. No odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below
SPECIAL FIREFIGHTING PROCEDURES: Do not fight fire. Withdraw personnel immediately. Allow
fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to flame, heat, impact,
friction, electric current, electrostatic or radio frequency
energy. Do not exceed 150 F (66 C). Avoid toxic fumes
from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: 0.05 mg/M3 TWA, lead, elemental, and inorganic compounds, as Pb.
OSHA : 50 g/M3 PEL as Pb. For additional information, see 29 CFR 1910.1025
EFFECTS OF OVEREXPOSURE: None likely when safe blasting practices are employed.
EMERGENCY AND FIRST AID PROCEDURES: Improper handling or misuse may cause detonation resulting in
injuries from shrapnel. Lead and lead compounds are listed in the 1987 IARC Monographs as possible human
carcinogens (Group 2B). Lead is not listed in the NTP annual report on carcinogens.
MATERIAL SAFETY DATA SHEET
庐
ELECTRIC DETONATORS
Austin Star Detonator Company
901 Cantu Road
Brownsville, TX 78520
DATE MARCH 2006 MSDS NO. ED-1 PAGE 2 OF 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance
Dept.
STABILITY: May explode when subjected to flame, heat, impact, friction, electric currents, electrostatic or radio
frequency energy. Avoid static charge build up. Keep lead wires shunted until wiring into circuit.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid contact with acids or alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and lead fumes.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up containers or units by
hand. Avoid conditions affecting stability. DO NOT use damaged detonators.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state
and federal regulations. Call Austin Powder for recommendations and assistance. This material may become a
hazardous waste under certain conditions and must be collected, labeled and disposed of per state and federal
hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires, or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S.
dial the U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Avoid breathing fumes from detonation.
VENTILATION: Not required.
PROTECTIVE GLOVES: Not required.
EYE PROTECTION: Not required.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Detonators, Electric, 1.4B, UN0255, PGII or Detonators, Electric, 1.1B,
UN0030 PG ll
Consult IME Safety Library Publication No. 20, SAFETY GUIDE FOR THE PREVENTION OF RADIO FREQUENCY
RADIATION HAZARDS IN THE USE OF COMMERCIAL ELECTRIC DETONATORS, and Publication No. 22,
RECOMMENDATIONS FOR THE SAFE TRANSPORTATION OF DETONATORS IN A VEHICLE WITH CERTAIN
OTHER EXPLOSIVE MATERIALS AND THE GUIDE FOR THE USE OF THE IME 22 CONTAINER.
EMULEX SERIES
DATE JUNE 2004 MSDS NO. E-3 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Seismex MH Red-D Prime
CLEVELAND, OHIO 44122 Emulex 500, 700 & 900 Series Enviroseis Emulsions
EMERGENCY PHONE AXE 100 to 499 Emuline and Emuline 33
DAY 216-464-2400 Pyroline Emuseis
NIGHT 216-464-2407 Primegel Red-D Lite-E
Coalmex (Permissible Emulsion) Enviroseis
Emuline and Pyroline are Emulex Products that incorporate a continuous length
of Detonating Cord. See MSDS. Primegel contains a Cast Booster. See
MSDS. Emuseis products are packaged in threaded plastic tubes.
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3, CAS No. 6484-52-2, (60 - 90%)
Sodium Nitrate, NaNO3, CAS No. 7631-99-4, (0 - 17%)
Petroleum Hydrocarbons, (3 to 9%)
Aluminum, Al, CAS No. 7429-90-5, (0 to 10%)
An emulsified water in oil mixture of ammonium nitrate, mineral oil, and emulsifiers.
SECTION III PHYSICAL DATA
BOILING POINT N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1) 1.14 to 1.35 VAPOR DENSITY (Air=1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Although in excess of 80% of the materials are readily soluble in water, the products have
excellent water resistance.
APPEARANCE AND ODOR: Viscous emulsion. If aluminum is present, gray metal particles will be visible. Slight
odor of oil.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT:
Oil 1140C (PMCC)
FLAMMABLE LIMITS:
Not available
EXTINGUISHING MEDIA:
See below.
SPECIAL FIRE FIGHTING PROCEDURES:
Do not fight fires. Withdraw personnel immediately. Allow fire to burn
itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and
in large quantities.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: Oil Mist, mineral, 5 MG/M3, Aluminum metal dust, 10 MG/M3
OSHA: Oil Mist, mineral, 5 MG/M3, Aluminum metal dust, 15 MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse,
vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water for at least 15 minutes and consult a physician.
Skin: Slight irritant. Wash with mild soap and water.
EMULEX SERIES
DATE JUNE 2004 MSDS NO. E-3 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities. Avoid temperatures above 2120F, (1000C).
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides and chlorates.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so
that the explosive energy is utilized as originally intended. Dispose of under direct supervision of a qualified person
according to local, state and federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Slight skin irritant.
EYE PROTECTION: Slight eye irritant.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosives, Blasting, Type E, 1.1D, UN0241, PG II.
Coalmex is approved for use as a Permissible Explosive by the USDL and MSHA when used in conformance with the requirements
of 30 CFR 15.
This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and
federal hazardous waste regulations.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
EMUTRENCH
DATE JUNE 2004 MSDS NO. E-6 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE
CLEVELAND, OHIO 44122 Emutrench
EMERGENCY PHONE
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3, CAS No. 6484-52-2 (60 - 90%)
Sodium Nitrate, NaNO3, CAS No. 7631-99-4 (6 - 15%)
EDDN: Ethylenediamine Dinitrate, C2H10N4 O6, CAS No. 505-71-5 (0 - 10%)
Petroleum Hydrocarbons, CAS No. 68476-30-2 (3 - 9%)
Aluminum, CAS No. 7429-90-5 (2 - 10%)
An emulsified water in oil mixture of ammonium nitrate, sodium nitrate, petroleum hydrocarbons, emulsifiers, EDDN, aluminum and
hollow microspheres.
SECTION III PHYSICAL DATA
BOILING POINT None VAPOR PRESSURE (mm Hg) Less than 0.1
SPECIFIC GRAVITY (H2O = 1) 1.1 to 1.2 VAPOR DENSITY (Air=1) N/A
PERCENT VOLATILE BY VOL. (%) N/A VAPORATION RATE: N/A
SOLUBILITY IN WATER: Although in excess of 80% of the materials are readily soluble in water, the product has
excellent water resistance for long periods of time.
APPEARANCE AND ODOR: Semi-solid cohesive material. Negligible odor. Grayish white color.
SECTION IV FIRE AND EXPLOSION DATA
Mineral oil, 4510F.
FLASH POINT:
FLAMMABLE LIMITS: Not available
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn
itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and
in large quantities. Avoid toxic fumes from fires.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: NH4 NO3 - None, EDDN - None, Aluminum metal dust, 10 MG/M3
OSHA: NH4 NO3 - None, EDDN - None, Aluminum metal dust, 15 MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse,
vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Flush with large amounts of water for at least 15 minutes and consult a physician.
Skin: Wash with mild soap and water. Launder contaminated clothing before reuse.
EMUTRENCH
DATE JUNE 2004 MSDS NO. E-6 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities. Avoid temperatures above 2120F, (1000C).
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides and chlorates.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so that
the explosive energy is utilized as originally intended. Dispose of under direct supervision of a qualified person according to local,
state and federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U.S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Ventilate storage magazine.
PROTECTIVE GLOVES: Avoid skin contact. Wear impervious gloves when handling
material.
EYE PROTECTION: Safety glasses.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosives, Blasting, Type E, 1.1D, UN0241, PG II.
This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and
federal hazardous waste regulations.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
FS SEISMIC DETONATING CORD
DATE MAY 2004 MSDS NO. C-2 PAGE 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE FS Seismic
CLEVELAND, OHIO 44122 Cordeau Detonate Fuse
EMERGENCY PHONE Cord, Detonating, Flexible
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
PETN, Pentaerythritol tetranitrate, C5H8N4O12 CAS No. 78-11-5
PVC: Polyvinylchloride, C2H3CI, CAS No. 9002-86-2
SECTION III PHYSICAL DATA
BOILING POINT N/A VAPOR PRESSURE (mm Hg) Negligible
SPECIFIC GRAVITY (H2O = 1) 1.76 VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) None EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Negligible
APPEARANCE AND ODOR: Flexible cord with an explosive core of PETN protected within a textile casing
covered by a seamless polyvinylchloride jacket. PETN is a white crystalline
solid. No odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below
SPECIAL FIREFIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow
fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
May explode when subjected to fire, heat or shock. Avoid
toxic fumes from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: PETN-None PVC - None
OSHA: PETN-None PVC - None
EFFECTS OF OVEREXPOSURE: Ingestion of PETN may cause headache and nausea. PETN is a vasodilator and
produces dilation of blood vessels.
EMERGENCY AND FIRST AID PROCEDURES:
FUMES: Remove to fresh air.
IF INGESTED: Obtain medical attention immediately.
FS SEISMIC DETONATING CORD
DATE MAY 2004 MSDS NO. C-2 PAGE 2 OF 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid contact with strong acids or alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides. The PVC resin
will also liberate hydrogen chloride. Toxic decomposition products including carbon monoxide (CO) may migrate to off
blast-site areas.
HAZARDOUS POLYMERIZATON WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all
spilled material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state
and federal regulations. Call Austin Powder for recommendations and assistance. This material may become a
hazardous waste under certain conditions and must be collected, labeled and disposed of per state and federal
hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S.
dial the U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required except to prevent abrasive injuries.
EYE PROTECTION: Not required under normal conditions.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥滱S ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Cord, Detonating, Flexible 1.1D, UN0065, PG II.
May be offered for transportation domestically and transported as Cord, Detonating (UN 0289), Division 1.4 compatibility
group D (1.4D) Explosives, if the explosive content does not exceed 100 grains per linear foot (21.3grams per
meter)and the gross weight of all packages of detonating cord does not exceed (45 KG) 99 pounds per vehicle. See 49
CFR 173.63
The maximum recommended temperature for detonating cord is 1600F (710C).
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible
carcinogens, nor are they listed in the NTP annual report on carcinogens
FUSE CAPS
DATE SEPTEMBER 2004 MSDS NO. ED-3 PAGE 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE FUSE CAPS NO. 6, NO. 8
CLEVELAND, OHIO 44122 Non-Electric Caps
EMERGENCY PHONE
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
All explosive components are sealed in a metal shell.
PETN, Pentaerythritol Tetranitrate, CAS No. 78-11-5
Lead Azide, Pb (N3)2, CAS No. 13424-46-9
Lead Styphnate, Lead Trinitroresorcinate, C6H3N3O9Pb CAS No. 15245-44
TNT, Trinitrotoluene, C7H5N306 CAS No. 118-96-7 (May be included in some Detonators)
SECTION III PHYSICAL DATA
BOILING POINT N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1) N/A VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Insoluble
APPEARANCE AND ODOR: Aluminum or copper shells. No odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below
SPECIAL FIREFIGHTING PROCEDURES: Do not fight fire. Withdraw personnel immediately . Allow
fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to flame, heat, impact, friction,
electric current or electrostatic energy. Do not exceed
150 F (66 C). Avoid toxic fumes from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: 0.05 MG/M3, TWA, lead, elemental, and inorganic compounds as Pb.
OSHA : 50 G/M3 PEL as Pb. For additional information, see 29 CFR 1910.1025
OSHA: 1.5 MG/M3 TNT-Skin ACGIH: 0.5 MG/M3 TNT-Skin
EFFECTS OF OVEREXPOSURE: None likely when safe blasting practices are employed.
EMERGENCY AND FIRST AID PROCEDURES: Improper handling or misuse may cause detonation resulting in injuries
from shrapnel. Lead and lead compounds are listed in the 1987 IARC Monographs as possible human carcinogens
(Group 2B). Lead is not listed in the NTP annual report on carcinogens.
FUSE CAPS
DATE SEPTEMBER 2004 MSDS NO. ED-3 PAGE 2 OF 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance
Dept.
STABILITY: May explode when subjected to flame, heat, impact, friction, electric currents or electrostatic energy.
INCOMPATIBILITY (MATERIALS TO AVOID): DO NOT exceed 150 F (66 C). Avoid contact with acids or
alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous Nitrogen Oxides, Carbon Oxides, and lead
fumes.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up containers or units by
hand. Avoid conditions affecting stability. DO NOT use damaged detonators.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state
and federal regulations. Call Austin Powder for recommendations and assistance. This material may become a
hazardous waste under certain conditions and must be collected, labeled and disposed of per state and federal
hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S.
dial the U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Avoid breathing fumes from detonation.
VENTILATION: Not required.
PROTECTIVE GLOVES: Not required.
EYE PROTECTION: Not required.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT CLASSIFICATION: IMO HAZARD CLASS:
Detonators, Non-Electric, 1.4B PGII UN NUMBER; 0267 1.4B
Detonators, Non-Electric, 1.1B PGII UN NUMBER; 0029 1.1B
Consult IME Safety Library Publication No. 22, RECOMMENDATIONS FOR THE SAFE TRANSPORTATION OF
DETONATORS IN A VEHICLE WITH CERTAIN OTHER EXPLOSIVE MATERIALS AND THE GUIDE FOR THE USE
OF THE IME 22 CONTAINER.
GELATIN AND SEMI-GELATIN DYNAMITES
DATE JULY 2004 MSDS NO. D-2 Page 1 0F 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Extra Gelatin Series
CLEVELAND, OHIO 44122 Apcogel Series
EMERGENCY PHONE 60% Seis Gel HELIX PNG 80
DAY 216-464-2400 AL Series HELIX PNG 90
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Nitroglycerin, NG, C3H5O3 (NO2)3 CAS No. 55-63-0 1-20%
Ethylene Glycol Dinitrate, EGDN, C2H4O2 (NO2)2 CAS No. 628-96-6 8-76%
Nitrocellulose, NC, C12H14N6O22 CAS No. 9004-70-0 0-6%
Ammonium Nitrate, AN, NH4NO3 CAS No. 6484-52-2, 0-75%
Sodium Nitrate, SN, NaNO3 CAS No. 7631-99-4 0-50%
Sulfur, S CAS No. 7704-34-9 0-4%
SECTION III PHYSICAL DATA
BOILING POINT None VAPOR PRESSURE (mm Hg) 0.038-0.050
SPECIFIC GRAVITY (H2O = 1) 0.8 to 1.48 VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
EXPLOSION POINT: 2370F
SOLUBILITY IN WATER: Salts are soluble in water, but the nitric esters (NG and EGDN) are only slightly soluble.
APPEARANCE AND ODOR: A mixture of absorbants, white oxidizing salts. Tan color with white granules. Slightly sweet odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: Not Applicable
FLAMMABLE LIMITS: Not Applicable
EXTINGUISHING MEDIA: See below
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Immediately withdraw personnel for 2500
feet in all directions. Allow fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire, impact or shock especially
when confined and in large quantities. Avoid toxic fumes from
. fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH TWA: NG; 0.05 PPM*, EGDN; 0.05PPM*, AN; None
OSHA: NG CEILING; 0.2 PPM, 2 MG/M3*, EGDN CEILING; 0.2 PPM, 1 MG/M3*, AN; None
* Skin
EFFECTS OF OVEREXPOSURE: Ingestion, inhalation or absorption through skin contact may cause headache, nausea, blood
vessel dilation, vomiting and convulsions. In extreme cases, death may result.
EMERGENCY AND FIRST AID PROCEDURES:
EYES: Slight irritant. Hold eyelid open and flush with large amounts of water for 15 minutes.
SKIN: Slight irritant. Absorbs through skin. Wash with mild soap and water.
INGESTION: Consult a physician if persistent headaches or chest pains develop. The nitric esters are coronary vasodilators.
GELATIN AND SEMI-GELATIN DYNAMITE
DATE JULY 2004 MSDS NO. D-2 Page 2 0F 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire, impact or shock.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination especially acids or alkalies, peroxides and chlorates.
Do not exceed 1500F ( 660C).
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides, hydrogen sulfide and carbon oxides: Toxic
decomposition products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all spilled material
immediately using non-sparking tools. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state and federal
regulations. Call Austin Powder for recommendations and assistance. This material may become a hazardous waste under certain
conditions and must be collected, labeled and disposed of per state and federal hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the U. S. access number
followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Ventilate magazines before entering.
PROTECTIVE GLOVES: Wear absorbent cotton or chemical resistant (nitrile) gloves.
EYE PROTECTION: Not required under normal conditions.
WARNING: Minimize inhalation and skin contact. Prevent contact with food, and
chewing or smoking materials.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥? WARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES. STORE IN COOL, DRY, WELL-VENTILLATED LOCATION.
DOT or IMDG proper shipping description: Explosive, Blasting, Type A, 1.1D, UN0081, PG II.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
HEET
DATE JUNE 2004 MSDS NO. E-2 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE HEET 10 SERIES
CLEVELAND, OHIO 44122 HEET 100 SERIES
EMERGENCY PHONE
Examples: HEET 30 HEET 50
DAY 216-464-2400
HEET 130 HEET 150
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3, CAS No. 6484-52-2 (70 - 90%)
Fuel Oil/Mineral Oil Blend, CAS No. 68476-30-2 (3 - 9%)
Aluminum: Al, CAS No. 7429-90-5 (0 - 12%)
A blend of ANFO (ammonium nitrate/fuel oil) and an emulsified mixture of ammonium nitrate solution, fuel oil, mineral oil and
polymeric surfactant (emulsifier). May also contain aluminum.
SECTION III PHYSICAL DATA
BOILING POINT, Oil 3200F, 1600C, VAPOR PRESSURE (mm Hg) 0.4 at 680F
SPECIFIC GRAVITY (H2O = 1) 1.1 to 1.3 VAPOR DENSITY (Air=1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Although in excess of 80% of the materials are readily soluble in water, the products have
excellent water resistance.
APPEARANCE AND ODOR: A blend of ANFO (round white to tan granules) and a white to light tan colored thick cream. Slight
odor of fuel oil. If aluminum is present, gray metal particles will be visible.
SECTION IV FIRE AND EXPLOSION DATA
Oils, 1250F Minimum PMCC
FLASH POINT:
FLAMMABLE LIMITS: Not available
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn
itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and
in large quantities.
SECTION V HEALTH HAZARD DATA
ACGIH: Oil mist, mineral, 5 MG/M3, Aluminum metal dust, 10 MG/M3
THRESHOLD LIMIT VALUE:
OSHA: Oil mist, mineral, 5 MG/M3,Aluminum metal dust, 15 MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse,
vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water for at least 15 minutes and consult a physician.
Skin: Slight irritant. Wash with mild soap and water.
HEET
DATE JUNE 2004 MSDS NO. E-2 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides and chlorates.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so that
the explosive energy is utilized as originally intended. Dispose of under direct supervision of a qualified person according to local,
state and federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Slight skin irritant.
EYE PROTECTION: Slight eye irritant.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosive, Blasting, Type E, 1.5D, UN0332, PG II
This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and
federal hazardous waste regulations.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
HYDROMITE 400 SERIES
DATE JUNE 2004 MSDS NO. S-5 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Hydromite 415 Hydromite 415 AWS 5
CLEVELAND, OHIO 44122 Hydromite 415 AW (All Weather) Hydromite 415 AWS 10
EMERGENCY PHONE Hydromite 415 B (Bulk) Hydromite 416
DAY 216-464-2400 Hydromite 415 BAW (Bulk, All Weather) Hydromite 416 AW
NIGHT 216-464-2407
Hydromite 415 AWS Hydromite 416 AW 4
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3 CAS No. 6484-52-2 60 to 80%
Hexamine, Hexamethylenetetramine, HMT, C6H12N4 CAS No. 100-97-0 4 to 15%
Nitric Acid, HNO3, CAS No 7697-37-2 2 to 10%
Ammonium Perchlorate, NH4 C104 CAS No. 7790-98-9 0 to 5%
Sodium Perchlorate, NaC104, CAS No. 7601-89-0 0 to 5%
Aluminum, Al, CAS No. 7429-90-5 0 to 15%
Ethylene Glycol, C2H6O2, CAS No. 107211 0 to 2%
Only all weather formulations will contain perchlorates.
SECTION III PHYSICAL DATA
BOILING POINT, N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1) 1.15-1.20 VAPOR DENSITY (Air=1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Although in excess of 90 % of the materials are readily soluble in water, the gel structure provides
excellent water resistance.
APPEARANCE AND ODOR: A white, gelled material containing prills or granules of ammonium nitrate.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn itself
out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and in
large quantities.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: HNO3: 2 PPM, Aluminum metal dust, 10 MG/M3
OSHA: HNO3: 5 MG/M3, Aluminum metal dust, 15 MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse, methemoglobinemia,
vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water for at least 15 minutes and consult a physician.
Skin: Slight irritant. Wash with mild soap and water.
HYDROMITE 400 SERIES
DATE JUNE 2004 MSDS NO. S-5 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities. Avoid temperatures above 2120 F, (1000 C ).
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially amines, strong alkalines, acids,
peroxides, and chlorates. Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous Nitrogen Oxides and Carbon Oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate underground to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so
that the explosive energy is utilized as originally intended. Dispose of under direct supervision of a qualified person according to
local, state and federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTON INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Maintain adequate ventilation.
PROTECTIVE GLOVES: Slight skin irritant. Avoid skin contact. Wear protective
gloves when handling material.
EYE PROTECTION: Slight eye irritant. Wear safety glasses.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥? WARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosive, Blasting, Type E, 1.5D, UN0332, PG II
This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and
federal hazardous waste regulations.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
HYDROMITE HE-25
DATE JUNE 2004 MSDS NO. S-6 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Hydromite HE-25
CLEVELAND, OHIO 44122
EMERGENCY PHONE
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3, CAS No. 6484-52-2 (40 - 60%)
Sodium Nitrate: Na NO3, CAS No. 7631-99-4 (5 - 15%)
Aluminum: Al, CAS No. 7429-90-5, (20 - 30%)
Petroleum Hydrocarbon, CAS No. 68476-30-2 (3 - 9%)
SECTION III PHYSICAL DATA
BOILING POINT, N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1) 1.40-1.45 VAPOR DENSITY (Air=1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Although in excess of 70% of the materials are readily soluble in water, the gel structure provides
excellent water resistance.
APPEARANCE AND ODOR: A gray, gelled material containing prills or granules of ammonium nitrate.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT:
N/A
FLAMMABLE LIMITS:
N/A
EXTINGUISHING MEDIA:
See below.
SPECIAL FIRE FIGHTING PROCEDURES:
Do not fight fires. Withdraw personnel immediately. Allow fire to burn
itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and
in large quantities.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: Aluminum metal dust: 10MG/M3
OSHA: Aluminum metal dust: 15MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse, vomiting, abdominal
pain, rapid heartbeat and breathing. Coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water for at least 15 minutes, and consult a physician.
Skin: Slight irritant. Wash with mild soap and water.
HYDROMITE HE-25
DATE JUNE 2004 MSDS NO. S-6 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides. Alkaline
contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so that
the explosive energy is utilized as originally intended. Dispose of under direct supervision of a qualified person according to local,
state and federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required under normal conditions. Slight skin irritant.
EYE PROTECTION: Not required under normal conditions. Slight eye irritant.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥? WARNING AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosive, Blasting, Type E, 1.5D, UN0332, PG II
This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and
federal hazardous waste regulations.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
HYDROMITE EMULSIONS
DATE JUNE 2004 MSDS NO. E-4 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Hydromite 600 Series
CLEVELAND, OHIO 44122 Hydromite 800 Series
EMERGENCY PHONE Hydromite 1000 Series
DAY 216-464-2400 Hydromite 2000 Series
NIGHT 216-464-2407
Hydromite 3000 Series
Hydromite 4000 Series
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3, CAS No. 6484-52-2 (65 - 90%)
Fuel Oil/ Mineral Oil Blend, CAS No. 68476-30-2 (3 - 9%)
Aluminum: Al, CAS No. 7429-90-5, (0 - 10%)
Polymeric Surfactant Not Applicable for Mixtures (0.5 鈥? 2%)
An emulsified mixture of ammonium nitrate solution, fuel oil, mineral oil and polymeric surfactant (emulsifier). May also contain
ammonium nitrate prills (granules) and/or aluminum.
SECTION III PHYSICAL DATA
BOILING POINT: N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1): 1.20 to 1.30 VAPOR DENSITY (Air=1) N/A
PERCENT VOLATILE BY VOL. (%): N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Although in excess of 80% of the materials are readily soluble in water, the products have
excellent water resistance.
APPEARANCE AND ODOR: White to tan colored thick cream. If aluminum is present, gray metal particles will be visible. If
ammonium nitrate prill is present, white to tan colored granules will be visible. Slight odor of fuel oil.
SECTION IV FIRE AND EXPLOSION DATA
1650 F ( 740 C) (PMCC)
FLASH POINT:
FLAMMABLE LIMITS: Not available
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn
itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and
in large quantities.
SECTION V HEALTH HAZARD DATA
ACGIH: Oil mist, mineral, 5 MG/M3, Aluminum metal dust, 10 MG/M3
THRESHOLD LIMIT VALUE:
OSHA: Oil mist, mineral, 5 MG/M3, Aluminum metal dust, 15 MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse, vomiting, abdominal
pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water for at least 15 minutes and consult a physician.
Skin: Slight irritant. Wash with mild soap and water.
HYDROMITE EMULSIONS
DATE JUNE 2004 MSDS NO. E-4 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities. Avoid temperatures above 2120F, (1000C).
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides and chlorates.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so that
the explosive energy is utilized as originally intended. Dispose of under direct supervision of a qualified person according to local,
state and federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Slight skin irritant.
EYE PROTECTION: Slight eye irritant.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosive, Blasting, Type E, 1.5D, UN0332, PG II
This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and
federal hazardous waste regulations.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
HYDROX Bulk Emulsions
DATE JUNE 2005 MSDS NO. E-5 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Hydrox 501
CLEVELAND, OHIO 44122 Hydrox 503
EMERGENCY PHONE
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3, CAS No. 6484-52-2, (70 - 82%)
Fuel Oil/ Mineral Oil Blend, CAS No. 68476-30-2 ( 6 - 9%)
Mineral Oil ( Florida Products)* CAS No. 64742-46-7 ( 6 - 9%)
Polymeric Surfactant, Not Applicable for Mixtures ( 0.5 鈥? 2%)
An emulsified mixture of ammonium nitrate solution, fuel oil, mineral oil, and polymeric surfactant (emulsifier).
*Hydrox products made and used in Florida contain only this oil and do not contain the fuel oil/mineral oil blend.
SECTION III PHYSICAL DATA
BOILING POINT: N/A VAPOR PRESSURE (mm Hg): N/A
SPECIFIC GRAVITY (H2O = 1): 1.32 to 1.36 VAPOR DENSITY (Air=1): N/A
PERCENT VOLATILE BY VOL. (%): N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Although in excess of 90% of the materials are readily soluble in water, the products have
excellent water resistance.
APPEARANCE AND ODOR: Tan to amber thick cream. Slight odor of oil.
SECTION IV FIRE AND EXPLOSION DATA
1650F (740 C) (PMCC)
FLASH POINT:
FLAMMABLE LIMITS: Not available
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn
itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and
in large quantities.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: Oil mist, mineral, 5 MG/M3
OSHA: Oil mist, mineral, 5 MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse,
vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water for at least 15 minutes and consult a physician.
Skin: Slight irritant. Wash with mild soap and water.
HYDROX Bulk Emulsions
DATE JUNE 2005 MSDS NO. E-5 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities. Avoid temperatures above 2120F, (1000C).
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially peroxides and chlorates.
Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state and
federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION Not required under normal conditions.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required under normal conditions. Slight skin irritant.
EYE PROTECTION: Not required under normal conditions. Slight eye irritant.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO 4. 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Oxidizing Liquid, n.o.s. 5.1, UN3139, PG II
(Ammonium Nitrate/Fuel Aqueous Emulsion)
This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and
federal hazardous waste regulations.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
MATERIAL SAFETY DATA SHEET
庐
SHOCK *STAR
NON-ELECTRIC DETONATORS
DATE MAY 2006 MSDS NO. ED-5 PAGE 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
TRADE NAME AND SYNONYMS
AUSTIN STAR DETONATOR COMPANY
901 CANTU ROAD
Shock*Star: Twin* Star Detonators, In-Hole Delays,
BROWNSVILLE, TX 78520 Detonators, Surface Delay Connectors, Quick-Relay
Connectors, Dual-Delays, Shorty, Long Period, STD (Shock
24 HOUR PHONE; 956-831-7751 Tube with Detonators) and MS Connector.
Non-Electric Blasting Caps
SECTION II HAZARDOUS INGREDIENTS
Explosive components are PETN and lead compounds sealed in a metal shell.
PETN, Pentaerythritol tetranitrate, C5H8N4O 12 CAS No. 78-11-5
Lead Azide, Pb (N3)2 CAS No. 13424-46-9
Lead Styphnate, Lead Trinitroresorcinate, C6H3N3O9Pb CAS No. 15245-44-0
SECTION III PHYSICAL DATA
BOILING POINT N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1) N/A VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Insoluble
APPEARANCE AND ODOR: Aluminum or copper shells with Shock Tube attached. See the Shock Tube MSDS. No
odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below
SPECIAL FIREFIGHTING PROCEDURES: Do not fight fire. Withdraw personnel immediately. Allow
fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to flame, heat, impact or
friction. Safe from extraneous electric currents except for
high energy discharges such as lightening. Do not exceed
150掳F (66掳C). Avoid toxic fumes from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH: 0.05 mg/M3 TWA, lead, elemental, and inorganic compounds, as Pb.
OSHA : 50 碌g/M3 PEL as Pb. For additional information, see 29 CFR 1910.1025
EFFECTS OF OVEREXPOSURE: None likely when safe blasting practices are employed.
EMERGENCY AND FIRST AID PROCEDURES: Improper handling or misuse may cause detonation resulting in injuries
from shrapnel. Lead and lead compounds are listed in the 1987 IARC Monographs as possible human carcinogens
(Group 2B). Lead is not listed in the NTP annual report on carcinogens.
MATERIAL SAFETY DATA SHEET
庐
SHOCK*STAR
NON ELECTRIC DETONATORS
Austin Star Detonator Company
901 Cantu Road
Brownsville, TX 78520
DATE MAY 2006 MSDS NO. ED-5 PAGE 2 OF 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: May explode when subjected to flame, heat, impact or friction. Shock*Star and non-electric detonators
are safe from extraneous electric currents except for high energy discharges such lightening.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid contact with acids or alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and lead fumes.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up containers or units by
hand. Avoid conditions affecting stability. DO NOT use damaged detonators.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state
and federal regulations. Call Austin Powder for recommendations and assistance. This material may become a
hazardous waste under certain conditions and must be collected, labeled and disposed of per state and federal
hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires, or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S.
dial the U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Avoid breathing fumes from detonation.
VENTILATION: Not required.
PROTECTIVE GLOVES: Not required.
EYE PROTECTION: Not required.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
THESE DETONATORS MAY BE SHIPPED UNDER ONE OF THE FOLLOWING DOT CLASSIFICATIONS:
DOT or IMDG proper shipping description:
Detonator Assemblies, Non-Electric, 1.1B, UN0360, PGII Detonator Assemblies, Non-Electric,1.4B, UN0361, PGII
Consult IME Safety Library Publication No. 22, RECOMMENDATIONS FOR THE SAFE TRANSPORTATION OF
DETONATORS IN A VEHICLE WITH CERTAIN OTHER EXPLOSIVE MATERIALS AND THE GUIDE FOR THE USE
OF THE IME 22 CONTAINER.
OIL STAR ELECTRIC DETONATORS
DATE JULY 2005 MSDS NO. ED-2 PAGE 1 OF 2
SECTION I Issued by the Safety and Compliance Dept.
TRADE NAME AND SYNONYMS
AUSTIN POWDER COMPANY
25800 SCIENCE PARK DRIVE
OIL STAR DETONATORS
CLEVELAND, OHIO 44122 Electric Blasting Caps
Emergency Phone A2b, A84, A85, A95, A96, A98, A105, A140
Day 216-464-2400 Oil and Gas Detonator Type A-140F, A-140S
Night 216-464-2407 Oil and Gas Detonator Type A-161
Manufactured by: AUSTIN DETONATOR s.r.o.
Vsetin, Czech Republic
SECTION II HAZARDOUS INGREDIENTS
Explosive components are RDX and lead compounds sealed in a metal shell.
Lead Azide, Pb (N3)2, CAS No. 13424-46-9
Lead Styphnate, Lead Trinitroresorcinate, C6H3N3O9Pb CAS No. 15245-44-0
RDX, Cyclotrimethylene Trinitramine, C3H6N6O6 CAS No. 121-82-4
HNS, Hexanitrostilbene, C14H6N6O12 CAS No. 20062-22-0
SECTION III PHYSICAL DATA
BOILING POINT N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1) N/A VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Insoluble
APPEARANCE AND ODOR: Aluminum or copper shells with Teflon or high temperature polymer coated copper leg
wires. No odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below.
SPECIAL FIREFIGHTING PROCEDURES: Do not fight fire. Withdraw personnel immediately. Allow
fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to flame, heat, impact, friction,
electric current, electrostatic or radio frequency energy.
Avoid toxic fumes from fire. Do not exceed 3500F (1770C)
for 1 hour. With Type A-161 detonators which contain HNS
do not exceed 475oF (246oC) for 1 hour.
SECTION V HEALTH HAZARD DATA
ACGIH: 0.05 MG/M3 TWA, Lead, Elemental, and Inorganic Compounds, as Pb.
THRESHOLD LIMIT VALUE:
OSHA: 50 碌G/M3 PEL as Pb. For additional information, see 29CFR1910.1025
EFFECTS OF OVEREXPOSURE: None likely when safe blasting procedures are employed.
EMERGENCY AND FIRST AID PROCEDURES: Improper handling or misuse may cause detonation resulting in injuries
from shrapnel. Lead and lead compounds are listed in the 1987 IARC Monographs as possible human carcinogens
(Group 2B). Lead is not listed in the NTP annual report on carcinogens.
OIL STAR ELECTRIC DETONATORS
DATE JULY 2005 MSDS NO. ED-2 PAGE 2 OF 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: May explode when subjected to flame, heat, impact, friction, electric currents, electrostatic or radio
frequency energy. Avoid static charge build up. Keep lead wires shunted until wiring into circuit.
INCOMPATIBILITY (MATERIALS TO AVOID): Do not exceed 350 F (177 C) for more than 1 hour. With Type
A-161 detonators do not exceed 475oF (246oC) for more than 1 hour. Avoid contact with acids or alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and lead fumes.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up containers or units by
hand. Avoid conditions affecting stability. DO NOT use damaged detonators.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state
and federal regulations. Call Austin Powder for recommendations and assistance. This material may become a
hazardous waste under certain conditions and must be collected, labeled, and disposed of per state and federal
hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S.
dial the U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Avoid breathing fumes from detonation.
VENTILATION: Not required.
PROTECTIVE GLOVES: Not required.
EYE PROTECTION: Not required.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT CLASSIFICATION: IMO HAZARD CLASS:
Detonators, Electric, 1.4B PGII UN NUMBER 0255 1.4B
Detonators, Electric, 1.1B PGII UN NUMBER 0030 1.1B
Consult IME Safety Library Publication No. 20, SAFETY GUIDE FOR THE PREVENTION OF RADIO FREQUENCY
RADIATION HAZARDS IN THE USE OF COMMERCIAL ELECTRIC DETONATORS, and Publication No. 22,
RECOMMENDATIONS FOR THE SAFE TRANSPORTATION OF DETONATORS IN A VEHICLE WITH CERTAIN
OTHER EXPLOSIVE MATERIALS AND THE GUIDE FOR THE USE OF THE IME 22 CONTAINER.
PERMISSIBLE DYNAMITE SERIES
MSHA APPROVED EXPLOSIVES
DATE JULY 2004 MSDS NO D-1 Page 1 0F 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Red Diamond Series
CLEVELAND, OHIO 44122 Red-D-Gel Series
EMERGENCY PHONE
DAY 216-464-2400
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Nitroglycerin, NG, C3H5O3 (NO2)3, CAS No. 55-63-0 1-10%
Ethylene Glycol Dinitrate, EGDN, C2H4O2 (NO2)2 CAS No. 628-96-6 5-25%
Nitrocellulose, NC, C12H14N6O22 CAS No. 9004-70-0 0-6%
Ammonium Nitrate, AN, NH4NO3, CAS No. 6484-52-2 40-70%
Sodium Nitrate, SN, NaNO3 CAS No. 7631-99-4 0-50%
SECTION III PHYSICAL DATA
BOILING POINT None VAPOR PRESSURE (mm Hg) 0.038-0.050
SPECIFIC GRAVITY (H2O = 1) 0.64 to 1.35 VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
EXPLOSION POINT: 237oF
SOLUBILITY IN WATER: Salts are soluble in water, but the nitric esters (NG and EGDN) are only slightly soluble.
APPEARANCE AND ODOR: A mixture of absorbants, white oxidizing salts, and a non-organic flame suppressant. Tan color
with white granules. Slightly sweet odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: Not Applicable
FLAMMABLE LIMITS: Not Applicable
EXTINGUISHING MEDIA: See below
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Immediately withdraw personnel for
2500 feet in all directions. Allow fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire, impact or shock,
especially when confined or in large quantities.. Avoid
toxic fumes from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH TWA: NG; 0.05 PPM*, EGDN; 0.05 PPM*, AN; None
*Skin OSHA: NG CEILING; 0.2 PPM, 2 MG/M3*, EGDN CEILING; 0.2 PPM, 1 MG/M3*, AN; None
EFFECTS OF OVEREXPOSURE: Ingestion, inhalation or absorption through skin contact may cause headache, nausea, blood
vessel dilation, vomiting and convulsions. In extreme cases, death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
EYES: Slight irritant. Hold eyelid open and flush with large amounts of water for 15 minutes.
SKIN: Slight irritant. Absorbs through skin. Wash with mild soap and water.
INGESTION: Consult a physician if persistent headaches or chest pains develop. The nitric esters are coronary vasodilators.
PERMISSIBLE DYNAMITE SERIES
MSHA APPROVED EXPLOSIVES
DATE JULY 2004 MSDS NO. D-1 Page 2 0F 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination especially acids or alkalies, peroxides
and chlorates. DO NOT exceed 1500F ( 660C).
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all spilled
material immediately using non-sparking tools. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state and federal
regulations. Call Austin Powder for recommendations and assistance. This material may become a hazardous waste under certain
conditions and must be collected, labeled and disposed of per state and federal hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Ventilate magazines before entering.
PROTECTIVE GLOVES: Wear absorbent cotton or chemical resistant (nitrile) gloves.
EYE PROTECTION: Not required under normal conditions.
WARNING: Minimize inhalation and skin contact. Prevent contact with food, and chewing or smoking materials.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥? WARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES. STORE IN COOL, DRY, WELL-VENTILATED LOCATION
DOT or IMDG proper shipping description: Explosive, Blasting, Type A, 1.1D, UN0081, PG II.
Permissible Explosive: Approved as Permissible by the USDL, MSHA when used in conformance with requirements 30 CFR 15.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
NON-INCENDIVE SHEATHED EXPLOSIVE UNIT
(ROCKBUSTER II)
DATE JUNE 2004 MSDS NO. D-7 Page 1 0F 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE Rock-Buster II
CLEVELAND, OHIO 44122
EMERGENCY PHONE
DAY 216-464-2400
MSHA APPROVED SHEATHED EXPLOSIVE UNIT
NIGHT 216-464-2407
SECTION II HAZARDOUS INGREDIENTS
Nitroglycerin, NG, C3H5O3 (NO2)3 CAS No. 55-63-0, 3-9%
Ethylene Glycol Dinitrate, EGDN, C2H4O2 (NO2)2 CAS No. 628-96-6 21-27%
Ammonium Nitrate, AN, NH4NO3 CAS No. 6484-52-2 40-50%
1,2 Propylene Glycol, C3H8O2 CAS No. 57-55-6 10-15% of Flame Suppressant Gel
Sodium Bisulfate, NaHSO4 CAS No. 7681-38-1 1 to 5% of Flame Suppressant Gel
Sodium Metaborate, NaBO2 CAS No. 10555-76-7 0.5 to 4% of Flame Suppressant Gel
SECTION III PHYSICAL DATA
BOILING POINT None VAPOR PRESSURE (mm Hg) 0.038-0.050
SPECIFIC GRAVITY (H2O = 1) 0.64 to 1.35 VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
EXPLOSION POINT: 2370F
SOLUBILITY IN WATER: Salts are soluble in water, but the nitric esters (NG and EGDN) are only slightly soluble.
APPEARANCE AND ODOR: The explosive is a mixture of absorbants, white oxidizing salts, and a non-organic flame suppressant.
Tan color with white granules. Slightly sweet odor. One and one half pounds of a MSHA approved explosive is surrounded by a
flame suppressing water gel composed of a freezing point depressant, water, yellow dye and thickeners.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: Not Available Not Available
FLAMMABLE LIMITS: Not Available Not Available
EXTINGUISHING MEDIA: See below See below
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow
fire to burn itself out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock. Avoid toxic
fumes from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: ACGIH TWA: NG; 0.05 PPM*, EGDN; 0.05 PPM*, AN; NONE
*Skin OSHA: NG CEILING; 0.2 PPM, 2 MG/M3*, EGDN CEILING; O.2 PPM, 1 MG/M3*, AN; None
EFFECTS OF OVEREXPOSURE: Ingestion, inhalation or absorption of the explosives through skin contact may cause headache,
nausea, blood vessel dilation, vomiting and convulsions. In extreme cases, death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
EYES: Slight irritant. Hold eye lid open and flush with large amounts of water for 15 minutes.
SKIN: Slight irritant. Absorbs through skin. Wash with mild soap and water.
INGESTION: Consult a physician if persistent headaches or chest pains develop. The nitric esters are coronary vasodilators.
NON-INCENDIVE SHEATHED EXPLOSIVE UNIT
(ROCKBUSTER II)
DATE JUNE 2004 MSDS NO. D-7 Page 2 0F 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination especially acids or alkalies, peroxides
and chlorates. Do not exceed 1500F (660C)
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all spilled
material immediately using non-sparking tools. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state and federal
regulations. Call Austin Powder for recommendations and assistance. This material may become a hazardous waste under certain
conditions and must be collected, labeled and disposed of per state and federal hazardous waste regulations.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Ventilate magazines before entering.
PROTECTIVE GLOVES: Wear absorbent cotton gloves.
EYE PROTECTION: Not required under normal conditions.
WARNING: Minimize inhalation and skin contact. Prevent contact with food,
and chewing or smoking materials.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO .4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosive, Blasting, Type A, 1.1D, UN0081, PG II
Permissible Explosive: Approved as Permissible by the USDL and MSHA when used in conformance with the requirements of 30
CFR 15.
The minimum firing temperature using a No. 8 Detonator is 00F
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
MATERIAL SAFETY DATA SHEET
庐
SHOCK STARTM SHOCK TUBING
DATE MAY 2004 MSDS NO. C-3 PAGE 1 OF 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN STAR DETONATOR COMPANY
TRADE NAME AND SYNONYMS
901 CANTU ROAD
Signal Transmission Tubing
BROWNSVILLE, TX 78520 Shock Tube
24 HOUR PHONE: 956-831-7751 LEAD-IN-LINE (L-I-L)
SECTION II HAZARDOUS INGREDIENTS
The explosive components of this device (HMX and Aluminum Powder) are less than 0.4 percent by weight of the shock
tube and are totally enclosed in the tubing.
SECTION III PHYSICAL DATA
BOILING POINT N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1) N/A VAPOR DENSITY (Air = 1) N/A
PERCENT VOLATILE BY VOL. (%) None EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Negligible
APPEARANCE AND ODOR: Flexible ionomer resin plastic tubing with a minute amount of an extremely fine, silver
colored explosive composition on the interior walls of the tube. No odor.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: Water, CO2 , foam, dry chemical fire extinguisher.
SPECIAL FIREFIGHTING PROCEDURES: Not determined.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid toxic fumes from fire.
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: Not determined.
EFFECTS OF OVEREXPOSURE: Not determined.
EMERGENCY AND FIRST AID PROCEDURES:
FUMES: Remove to fresh air.
MATERIAL SAFETY DATA SHEET
庐
SHOCK STARTM SHOCK TUBING
Austin Star Detonator Company
901 Cantu Road
Brownsville, TX 78520
DATE MAY 2004 MSDS NO. C-3 PAGE 2 OF 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable.
INCOMPATIBILITY (MATERIALS TO AVOID): None known.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic
decomposition products including carbon monoxide (CO) may migrate to off blast-site areas.
HAZARDOUS POLYMERIZATON WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up containers or units by
hand.
WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state
and federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U.S.
dial the U.S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Avoid breathing fumes from detonation.
VENTILATION: Not required under normal conditions.
PROTECTIVE GLOVES: Not required.
EYE PROTECTION: Not required.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥? WARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS,
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
Avoid any situation that may cause entanglement with machinery or moving equipment. Jerking and breaking Shock
Tubing may lead to a premature detonation known as "Snap and Shoot". Do not drive equipment over Shock Tubing.
DOT or IMDG proper shipping description:
1) Standard packaging: Articles, Explosive, n.o.s., (contains HMX/Aluminum), 1.4S, UN0349, PGII.
2) Not regulated as an explosive when packaged on production or large volume shipping spools with end caps. May be
shipped as: Plastic Tubing.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible
carcinogens, nor are they listed in the NTP annual report on carcinogens.
SLURMEX SERIES
DATE JUNE 2004 MSDS NO. S-4 Page 1 of 2
SECTION I Issued by the Safety and Compliance Dept.
AUSTIN POWDER COMPANY TRADE NAME AND SYNONYMS
25800 SCIENCE PARK DRIVE SLURMEX 300
CLEVELAND, OHIO 44122 SLURMEX 500
EMERGENCY PHONE
AQUALINE
DAY 216-464-2400
EMULINE SE
NIGHT 216-464-2407
Aqualine and Emuline SE are Slurmex products that
include a continuous length of Detonating Cord.
See MSDS.
SECTION II HAZARDOUS INGREDIENTS
Ammonium Nitrate: NH4 NO3 CAS No. 6484-52-2, 50 To 65%
Sodium Nitrate, NaNO3 CAS No. 7631-99-4, 10 To 20%
Nitric Acid, HNO3 CAS No. 7697-37-2, 2 To 6%
Aluminum: Al, CAS No. 7429-90-5, 4 To 8%
Sodium Perchlorate, NaClO4 CAS No. 7601-89-0, 2 To 7%
Hexamine, Hexamethylenetetramine, HMT, C6H12 N4 CAS No. 100-97-0, 5 To 15%
SECTION III PHYSICAL DATA
BOILING POINT, N/A VAPOR PRESSURE (mm Hg) N/A
SPECIFIC GRAVITY (H2O = 1) 1.20 VAPOR DENSITY (Air=1) N/A
PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A
SOLUBILITY IN WATER: Although in excess of 90 % of the materials are readily soluble in water, this product provides
excellent water resistance.
APPEARANCE AND ODOR: A highly cohesive gel, gray/white color. Negligible odor. Packaged in polyethylene cartridges.
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A
EXTINGUISHING MEDIA: See below.
SPECIAL FIRE FIGHTING PROCEDURES: Do not fight fires. Withdraw personnel immediately. Allow fire to burn itself
out.
UNUSUAL FIRE AND EXPLOSION HAZARDS: May explode when subjected to fire or shock, especially when confined and in
large quantities.
SECTION V HEALTH HAZARD DATA
ACGIH: Nitric Acid, 2 MG/M , Aluminum metal dust, 10 MG/M3
3
THRESHOLD LIMIT VALUE:
OSHA: Nitric Acid, 5 MG/M3, Aluminum metal dust , 15 MG/M3
EFFECTS OF OVEREXPOSURE: Acute: Ingestion of large amounts may cause cyanosis, nausea, collapse, methemoglobinemia,
Vomiting, abdominal pain, rapid heartbeat and breathing, coma, convulsions, and death may occur.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: Slight irritant. Flush with large amounts of water for at least 15 minutes and consult a physician.
Skin: Slight irritant. Wash with mild soap and water.
SLURMEX SERIES
DATE JUNE 2004 MSDS NO. S-4 Page 2 of 2
SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept.
STABILITY: Stable under normal conditions. May explode when subjected to fire or shock, especially when confined and in
large quantities.
INCOMPATIBILITY (MATERIALS TO AVOID): Avoid all contamination, especially amines, strong alkalines, acids,
peroxides and chlorates. Alkaline contamination may liberate ammonia fumes.
HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition
products including carbon monoxide (CO) may migrate to off blast- site areas
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Pick up and dispose of all spilled
material immediately. Do not permit smoking or open flames near spill site.
WASTE DISPOSAL METHOD: Uncontaminated material may be placed in large diameter boreholes and detonated so that
the explosive energy is utilized as originally intended. Dispose of under direct supervision of a qualified person according to local,
state and federal regulations. Call Austin Powder for recommendations and assistance.
TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States:
CALL CHEMTREC for emergencies only: 1-800-424-9300. For calls originating outside the U. S. dial the
U. S. access number followed by: 1-703-527-3887. All calls are recorded.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION: Not required under normal conditions.
VENTILATION: Maintain Adequate Ventilation.
PROTECTIVE GLOVES: Slight Skin Irritant, Avoid Skin Contract, Wear Protective
Gloves When Handling Material.
EYE PROTECTION: Slight Eye Irritant, Wear Safety Glasses.
SECTION IX SPECIAL PRECAUTIONS
COMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 鈥淲ARNINGS AND INSTRUCTIONS鈥? AS ADOPTED BY
THE INSTITUTE OF MAKERS OF EXPLOSIVES.
TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS
29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS
BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND
ORDINANCES.
DOT or IMDG proper shipping description: Explosive, Blasting, Type E, 1.1D, UN0241, PG II
This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and
federal hazardous waste regulations.
None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens,
nor are they listed in the NTP annual report on carcinogens.
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