23379 Issue Date: July 2009 Page 1 of 9
EXHAUST GAS RECIRCULATION 3 (AEROSOL)
Material Safety Data Sheet
SECTION 1 IDENTIFICATION OF THE MATERIAL
AND SUPPLIER
Product Name Wynn's Exhaust Gas Recirculation 3 (Aerosol)
Other Names 23379 200ml
AEROSOLS / ADG
Recommended Use Cleaner for vehicle engine throttle bodies in aerosol form
Supplier Name Wynn's Australia Pty Ltd
An (ITW), Illinois Tool Works Company
ABN 73 000 370 150
Address 100 Hassall Street, Wetherill Park NSW 2164
Private Bag 35, Wetherill Park DC NSW 2164
Telephone Number (02) 9828 0900
Email: wynnsaus@wynns.net
Website: www.wynns.net
Emergency Phone Number (02) 9828 0900 Monday-Friday 8.00am ?5.00pm
13 11 26 (24 hours Australia) Poisons Information Centre (PIC)
0800 764 766 (New Zealand) Poisons Information Centre (PIC)
SECTION 2 HAZARDS IDENTIFICATION
Hazard Classification HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
Classified as hazardous according to the criteria of NOHSC.
Classified as Dangerous Goods according to the criteria of the ADG
Code.
Risk Phrase R 20/21 Harmful by inhalation and in contact with skin.
R 36/37/38 Irritating to the eyes, respiratory system and the skin.
R 51/53 Toxic to aquatic organisms and may cause long term
adverse effects in the aquatic environment.
R 65 May cause lung damage if swallowed.
R 66 Repeated exposure may cause drying and cracking of the skin.
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Safety Phrase S 2 Keep out of reach of children.
S 14 Keep away from heat, ignition sources and oxidisers.
S 23 Do not breathe vapour.
S 24/25 Avoid contact with skin or eyes.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face
protection.
S 60 This material and its container must be disposed of as
hazardous wastes.
SECTION 3 COMPOSITION/INFORMATION ON
INGREDIENTS
NAME CAS NO EINICS / MIN/MAX SYMBOL R-PHRASES
ELINCS
1,2,4-trimethylbenzene 95-63-6 202-436-9 3
, R51/53
4-methyl-2-pentanol 108-11-2 203-551-7 3
Solvent naphtha (petroleum), light 64742-95-6 265-199-0 25
aromatic, low boiling point naphtha - R65, R66, R67
unspecified
Benzene, mono-C4-9-alkyl 68784-56-5 272-258-4 0.1
derivatives
Butane 106-97-8 203-448-7 15
Cumene 98-82-8 202-704-5 1
R65
Mesitylene; 1,3,5-trimethylbenzene 108-67-8 203-604-4 2.5
Propane 74-98-6 200-827-9 10
Xylene 1330-20-7 215-535-7 1
SECTION 4 FIRST AID MEASURES
Ingestion Do NOT induce vomiting. Rinse mouth with water. If symptoms
persist, seek prompt medical assistance.
Skin Remove contaminated clothing and footwear (while under safety
shower if appropriate). Flush affected area with water for 3-5
minutes followed by washing gently with soap and water for a further
5 minutes. Rinse well and pat dry. If symptoms persist, seek
prompt medical attention.
Eye Immediately: Hold eye open and flush with clean water for at least
15 minutes. While flushing, gently pull upper and lower eyelids
away from eyes and ensure carefully flushed. If symptoms persist,
seek prompt medical attention.
Inhalation Remove the patient (while wearing SCBA if concentrations are high)
to fresh air. Allow to rest. Rinse mouth and nose with water.
Provide artificial respiration if breathing stops. Seek prompt medical
attention unless recovery is virtually immediate. Inhaling
concentrated vapours ("Chroming") may prove fatal. Cases of
"chroming" must be medically examined even if patient has
apparently recovered.
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First Aid Facilities Provide normal industrial first aid facilities including eye-wash stations
and safety showers as appropriate.
Advice to Doctor Prolonged or repeated skin exposure may lead to dermatitis. Prolong
exposure to high vapour concentrations may lead to CNS effects and
liver or kidney disorders. "Chroming" may cause heart failure or
damage, and brain damage through CNS effects. Aspiration of
vomitus may cause chemical pneumonitis. A few unconfirmed cases
of skin sensitisation after prolonged or repeated exposures have been
reported.
Asthmatics and sufferers of other bronchial disorders should exercise
particular care when working with aerosols. Provide supportive care
and treatment based on the patient's reactions to the exposure.
Contains 50 g/kg 1, 2, 4 trimethyl benzene
Contains 25 g/kg Xylene.
Contains 500 g/kg Liquid Hydrocarbons.
SECTION 5 FIRE FIGHTING MEASURES
Foam, dry chemical, water delivered as fine spray or fog. Water may
Suitable Extinguishing
be ineffective due to low flash point of material.
Media
Carbon dioxide, carbon monoxide, complex hydrocarbons may be
Hazards From
formed on combustion. Vapour highly flammable. Fire may produce
Combustion Products
irritating or poisonous gases. Heat may cause violent rupture of
containers. Vapours may travel significant distances to a source of
ignition and flash back to the point of origin. Vapours may "pool" in
low-lying areas. In storage fires, aerosol cans may "bleve",
spreading burning liquid in their travel thus spreading fires.
Avoid bodily contact with substance or run-off. Contain run-off for
Precautions For Fire
later collection and controlled disposal. Be aware of potential for
Fighters
"mini-bleves".
Wear SCBA and full turn out clothing.
Special Protective
Equipment
None allocated.
Hazchem Code
SECTION 6 ACCIDENTAL RELEASE MEASURES
Switch off or remove all potential ignition sources. Prevent material
Emergency Procedures
entering drains or waterways. Send unnecessary personnel out of
area. Wear full protective clothing including rubber boots and
respirator. If ventilation is poor, use SCBA.
Spread sand, soil or other inert absorbent over liquid. When
Methods and Materials
saturated, collect into pails or drums, fit lids, label and place in a safe
for Containment and
area to await disposal. Collect undamaged cans for return to store.
Clean Up Procedures
Collect damaged or leaking cans, place in recovery drums for return to
supplier or disposal under local authority approval.
23379 Issue Date: July 2009 Page 4 of 9
SECTION 7 HANDLING AND STORAGE
Wear suitable protective clothing. Ensure appropriate fire prevention
Precautions for Safe
measures are in place.
Handling
Store in accordance with AS/NZS 3833 or AS 1940 and local
Conditions for Safe
regulations. Note that many authorities require that aerosols are
Storage
housed in caged enclosures to prevent the travel of "bleves". Keep
away from incompatibles in accordance with the Australian Standards.
SECTION 8 EXPOSURE CONTROLS/PERSONAL
PROTECTION
National Exposure Name ES-TWA ES-STEL ES-Peak
Standards
None established for - - -
product.
Established for ingredients
1800 mg/m3
Hydrocarbon Gas None Allocated -
Xylene 80 ppm 150 ppm -
350 mg/m3 655 mg/m3
VME/VLE
VlE (mg/m3)
PRODUCT NAME VME (PPM) VME VlE (ppm)
(MG/M3)
1, 2, 4- 20 100
trimethylbenzene
100 mg/m3
4-methyl-2-pentanol 25 ppm - -
xylene 50 221 100 442
MAC (MG/M3)
MAC PRODUCT MAC MAC SHORT MAC SHORT TIME
TIME (MG/M3)
NAME (PPM) (PPM)
100 mg/m3
4-Methyl-2-pentanol
MAK (MG/M3)
MAK PRODUCT MAK MAK SKIN MAK
NAME (PPM) RESORPTION CARCINOGENICITY
85 mg/m3
Methylpentan-2-ol 20 ppm
TLV PRODUCT TLV-TWA TLV-TWA TLV-STEL TLV-STEL (PPM)
(MG/M3) (MG/M3)
NAME (PPM)
Methyl isobutyl 25 ppm 40 ppm
carbinol
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Biological Limit Values No biological limit allocated.
Engineering Controls Use in well ventilated areas and ensure ventilation is adequate to
maintain air concentrations below TWAs. Use local exhaust
ventilation (flame-proof) in enclosed areas if necessary.
Personal Protective
Equipment
Not usually required. If exposure standards may be exceeded, use an
Respiratory Protection
organic vapour respirator to AS 1715 & 1716. Use SCBA in confined
spaces.
Use safety glasses with side shields or goggles to AS 1337.
Eye / Face Protection
Use butyl rubber or PVA gloves to AS 2161. Wear Tyvec or cotton
Skin Protection
coveralls fastened at the neck and wrists. Supplement with PVA
apron if required.
None required.
Thermal Hazards
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear pale yellow aerosol spray
Odour Aromatic
pH Value Not applicable
Vapour Pressure 1820 mm Hg @ 25篊 (Gas)
Vapour Density > 1 (air = 1) @ 20篊
Boiling Point/Range -43篊 to 149篊
Freezing Point Not applicable
Melting Point Not applicable
Solubility Insoluble in water
Density 0.88 @ 15篊 (Concentrate)
Flash Point 4篊 (PMCC) as concentrate.
-60篊 as gas.
Flammable Limits 1.9 to 8.5% (Gas)
Ignition Temperature 287篊 (Gas)
Volatiles 100.0% volume
SECTION 10 STABILITY AND REACTIVITY
Under all normal conditions of use at normal temperatures and
Chemical Stability
pressure the product is stable.
Heat and ignition sources.
Conditions to Avoid
Oxidising substances.
Incompatible Materials
Oxides of carbon.
Hazardous
Decomposition Products
No hazardous polymerisation will occur.
Hazardous Reactions
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SECTION 11 TOXICOLOGICAL INFORMATION
Hydrocarbon Gas: LC50 Inhal Rat 4 hr 658 g/m3
Toxicology Information
Harmful by inhalation. Harmful if swallowed.
Acute Health Effects
Ingestion Harmful if swallowed. May cause chemical pneumonia if aspirated
into the bronchial system during vomiting. Will cause central nervous
system depression.
Inhalation High concentration of solvent vapours can be harmful in enclosed
spaces. Vapours are harmful if inhaled. Irritant to upper respiratory
tract. May cause dizziness, nausea, vomiting.
Eye Solvent vapours will cause irritation to eyes. Severe irritant to eyes.
Will cause burning of eyes, blurred vision, watery eyes.
Skin Irritant to skin. Skin contact may produce a burning sensation,
redness, defatting of skin. Can be absorbed through skin. Repeated
exposures may cause drying and cracking of the skin.
Vapours in a confined area in high concentrations are anesthetic.
Other Effects of
Prolonged/Repeated
Overexposure may result in light headiness, dizziness, nausea.
Overexposure
Prolonged and repeated over-exposure to solvents may result in
permanent brain and nervous system damage. May cause kidney
and liver damage.
SECTION 12 ECOLOGICAL INFORMATION
Ecotoxicity Toxic to aquatic organisms.
Persistence/ May have long term adverse effects in the aquatic environment.
Degradability
Mobility Not available.
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal must be in accordance with local regulations for hazardous
Disposal Methods
industrial wastes.
None allocated.
Special Precautions for
Landfill or Incineration
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SECTION 14 TRANSPORT INFORMATION
UN Number 1950
Proper Shipping Name AEROSOLS
Class and Subsidiary 2.1 and 3
Risk
Packing Group None allocated.
Special Precautions None allocated.
for User
Hazchem Code None allocated.
23379 Issue Date: July 2009 Page 8 of 9
SECTION 15 REGULATORY INFORMATION
Poisons Schedule Not scheduled under SUSDP.
Hazard Category Harmful / NOHSC : 10005 (1999).
AEROSOLS / ADG Code Sixth Edition (1998).
SECTION 16 OTHER INFORMATION
Acronyms
ABN Australian Business Number
ACGIH American Conference of Governmental Industrial Hygienists
ADG Australian Dangerous Goods
AICS Australian Inventory of Chemical Substances
AS Australian Standard
CAS Chemical Abstracts Service (USA)
COC Cleveland Open Cup
EPA Environment Protection Agency (Australian States)
IARC International Agency for Research on Cancer
IP Institute of Petroleum (UK)
NIOSH National Institute for Occupational Safety and Health (USA)
NOHSC National Occupational Health and Safety Commission
(Australia)
NTP National Toxicology Program (USA)
NZS New Zealand Standard
OSHA Occupational Safety and Health Administration (USA)
PEL Permissible Exposure Level
PMCC Pensky ?Martens Closed Cup
SCBA Self-Contained Breathing Apparatus
STEL Short Term Exposure Limit
SUSDP Standard for the Uniform Scheduling of Drugs and Poisons
(Australia)
TLV Threshold Limit Valve
TWA Time Weighted Average
UN United Nations
Abbreviations
cP centiPoise
cSt centiStoke
g gram
Hg Mercury
kPa kiloPascal
L litre
m3 cubic metre
mg milligram
mL millilitre
mm millimetre
篊 degrees of temperature in Celsius (Centigrade)
% percent(age)
23379 Issue Date: July 2009 Page 9 of 9
Note This form has been prepared in accordance with the National Code of
Practice for the Preparation of Material Safety Data Sheets 2nd Edition
[NOHSC:2011 (2003)] issued by the National Occupation Health and
Safety Commission April 2003.
All information contained in this form is as accurate as possible at the
time of issue. The data contained herein is not to be taken as an
expressed or implied warranty or representation, for which Wynn's
Australia Pty Ltd assumes legal responsibility. No responsibility for
damages resulting from use of the information is given, other than
those implied mandatorily by Federal or State Government
Legislation.
END OF MATERIAL SAFETY DATA SHEET
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