SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHEMICAL PRODUCT IDENTIFICATION:
PRODUCT ID ...................... ?HR2410099-01
. : SILICONE ALKYD PAINT, SOLVENT BASED
PRODUCT CLASS . .
TRADE NAME ....
- HEAT RESISTANT SILICONE ALKYD - WHITE
MSDS PREPARATION DATE ............. 08/07/2008
?br>
MANUFACTURER IDENTIFICATION:
NAME ................... COMPLEMENTARY COATINGS CORP
dba INSL-X/CORONADO/LENMAR/TRINITY
ADDRESS . . 50 HOLT DRIVE
? 0 . . . . . . . .
STONY POINT, NY 10980
TELEPHONE (800) 225-5554
EMERGENCY CONTACT .............. ?CHEMTREC
EMERGENCY TELEPHONE . . . (US). ... : (800) 424-9300
EMERGENCY TELEPHONE (OUTSIDE US): (703) 527-3887
SECTION 2 - COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
1
CAS# 136-52-7
COBALT 2-ETHYLHEXANOATE
PCT BY WT: .1920
EXPOSURE LIMIT:
ACGIH TLV/TWA: NOT ESTAB.
ACGIH CEILING:
NOT ESTAB.
2 MINERAL SPIRITS
CAS# 8052-41-3
ALIPHATIC HYDROCARBONS (STODDARD TYPE)
.540 MMHG @ 20C
PCT BY WT: 15 - 40 VAPOR PRESSURE:
EXPOSURE LIMIT:
ACGIH TLV/TWA: 100 ppm TWA
OSHA PEL/TWA: 500 ppm TWA
LC50: Inhalation (rat) 5500 ppm, 4h Oral(Rat)-
LD50: 5000mg/kg Dermal(Rabbit)-3000mg/kg
3
CAS# 1330-20-7
XYLENE (MIXED ISOMERS
PCT BY WT: .05 - 1.5
VAPOR PRESSURE: 5.100 MMHG 0 20C
EXPOSURE LIMIT:
ACGIH TLV/TWA: 100 ppm TWA
ACGIH TLV/STEL: 150 ppm STEL
OSHA PEL/TWA: 100 ppm TWA
LC50:
LD50: Inhalation (Rat) - 6700 ppm/4H
CA PROPOSITION 65:
Oral (Rat) - 4.3 g/kg
NO
4
CAS# 95-63-6 1,2,4-
TRIMETHYLBENZENE
PCT BY WT: .05 - 1.5
EXPOSURE LIMIT:
ACGIH TLV/TWA: TWA 25 ppm
COMPLEMENTARY COATINGS CORP
MATERIAL SAFETY DATA SHEET
HR2410099-01
OSHA PEL/TWA: TWA 25 ppm
LC50: Inhalation - 18 g/cu m (Rat/4H)
LD50: Oral,Rat - 5 g/kg
5
CAS# 100-41-4
ETHYLBENZENE
PCT BY WT: .3660 VAPOR PRESSURE: 7.000 MMHG @ 20C
EXPOSURE LIMIT:
ACGIH TLV/TWA: TWA 100 ppm
ACGIH TLV/STEL: STEL 25 ppm
OSHA PEL/TWA: TWA 100 ppm
OSHA STEL: 125 ppm
LD50: Oral, Rat - 3500 mg/kg
CA PROPOSITION 65: Yes
6
CAS# 13463-67-7
TITANIUM DIOXIDE
PCT BY WT: 10 - 30
EXPOSURE LIMIT:
ACGIH TLV/TWA:
OSHA PEL/TWA: 10 mg/cu m(Total Dust) - TWA
LD50: 10 mg/cu m(Total Dust) - TWA
Oral (Rat)- >7500 mg/kg (TiO2)
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This product contains one or more reported carcinogens or suspected
carcinogens which are noted in Section 3, Hazards Identification,
CARCINOGENICITY.
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This product contains one or more Hazardous Air Pollutants.
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This product contains pigments, which may become a dust nuisance when
removed by abrasive blasting, sanding, or grinding.
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This product contains one or more reported or suspected reproductive
toxins.
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SECTION 3 - HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
EYES: Exposure to liquid may cause mild eye irritation. Symptoms
may include stinging, tearing, and redness.
SKIN: May cause skin defatting with prolonged exposure. Exposure may
cause skin irritation. Prolonged or repeated exposure may dry
the skin.
COMPLEMENTARY COATINGS CORP
MATERIAL SAFETY DATA SHEET
HR2410099-01
INHALATION: Causes mild respiratory irritation. Breathing large
amounts may be harmful. Symptoms of exposure may
include irritation (nose, throat, respiratory tract)
and CNS depression.
INGESTION: Swallowing small amounts of this product during normal
handling is not likely to cause harmful effects, but
swallowing large amounts may be harmful.
CHRONIC EFFECTS
NOTICE: Reports have associated repeated and prolonged occupational
exposure to solvents with permanent brain and nervous system damage.
Intentional misuse by deliberately concentrating and inhaling the contents
may be harmful or fatal. May cause respiratory and/or skin sensitization.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Pre-existing eye, skin and respiratory disorders may be aggravated by
exposure to this product.
POSSIBLE ROUTES OF ENTRY
Inhalation, ingestion, skin absorption.
CARCINOGENICITY
Ethylbenzene has been shown to cause cancer in laboratory animals.
The relevance of this finding to humans is uncertain. IARC has classified
ethylbenzene as a possible human carcinogen, Group 2B.
IARC lists cobalt and cobalt compounds as possible human carcinogens
(Group 2B). However, there is inadequate evidence of the carcinogenicity
of cobalt and cobalt compounds in humans.
ACGIH has given cobalt a rating of A3, animal carcinogen. They state
that available epidemiological studies do not confirm an increased risk
of cancer in exposed humans.
SECTION 4 - FIRST AID MEASURES
EMERGENCY FIRST AID:
EYE CONTACT
If irritation or redness develops, move victim away from exposure and into
fresh air. Flush eyes with clean water, holding eyelids apart. If
symptoms persist, seek medical attention.
SKIN CONTACT
Remove contaminated shoes and clothing, and flush affected area with large
amounts of water. If skin surface is damaged, apply a clean dressing and
seek medical attention. If skin surface is not damaged, cleanse affected
area thoroughly by washing with mild soap and water. If irritation or
redness develops, seek medical attention. Launder clothing before reuse.
INHALATION
If respiratory symptoms develop, move victim away from source of exposure
and into fresh air. If symptoms persist, seek medical attention. If
victim is not breathing, immediately begin artificial respiration. If
breathing difficulties develop, oxygen should be administered by qualified
COMPLEMENTARY COATINGS CORP
MATERIAL SAFETY DATA SHEET
HR2410099-01
personnel. Seek immediate medical attention. Keep person warm & quiet.
INGESTION: Aspiration hazard. Do not induce vomiting or give anything by
mouth because this material can enter the lungs and cause severe
lung damage. If the victim is drowsy or unconcious, place on
left side with head down. If possible, do not leave victim
unattended. Seek immediate medical attention.
NOTE TO PHYSICIAN:
Not Applicable.
SECTION 5 - FIRE FIGHTING MEASURES
FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL:
Flammability Classification . . Combustible Liquid-Class II
Flashpoint ............................. 104.0 癋
Explosion Level ....................... Low .9
High - 6.8
EXTINGUISHING MEDIA
Use National Fire Protection Association (NFPA) Class B extinguisher
(carbon dioxide, dry chemical or foam).
FIRE-FIGHTING INSTRUCTIONS
During fire, a water spray can scatter flames and should be used
by experienced firefighters. Firefighters should wear self-contained
breathing apparatus with a full face piece operated in the positive
pressure mode when fighting fires. Isolate damage area, keep
unauthorized personnel out. Avoid spreading burning liquid with water
used for cooling purposes.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Combustible liquid. Forms combustible mixtures with air at or above
the flash point. This product can accumulate static charges, which can
cause fire or explosion. This liquid is volatile and gives off invisible
vapors. Either the liquid or vapor may settle in low areas or travel
some distance along the ground or surface to ignition sources where
they may ignite or explode and flash back.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Eliminate all ignition sources. Spilled material may be absorbed into
an appropriate absorbent material. Prevent spilled material from entering
sewers, storm drains, other authorized treatment drainage systems, and
natural waterways. Stop spill/release if it can be done, and stay away
from spill. Isolate danger and keep unauthorized personnel out.
Use non-sparking tools and explosion-proof equipment.
CLEAN-UP
COMPLEMENTARY COATINGS CORP
MATERIAL SAFETY DATA SHEET
HR2410099-01
Warn occupants in surrounding and downwind areas of fire and explosion
hazard to stay clear. Remove from surface with suitable absorbents. If
allowed by local authorities, sinking and/or suitable dispersants may be
used in non-confined waters.
SECTION 7 - HANDLING AND STORAGE
HANDLING
Keep container closed. Handle and open container with care. Open
container slowly to relieve any pressure. Do NOT cut, weld or puncture
on or near container.
STORAGE
Keep container(s) tightly closed. Use and store this product in a
cool, dry, well-ventilated area away from heat, direct sunlight, hot metal
surfaces, and all sources of ignition. Keep away from any incompatible
material. Protect container(s) against physical damage.
SPECIAL COMMENTS
WARNING: Sudden release of hot organic chemical vapors or mists from
process equipment operating at elevated temperatures and pressures, or
sudden ingress of air into vacuum equipment, may result in ignitions
without the presence of obvious ignition sources.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
VENTILATION
Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below TLV(s).
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH for protection against chemicals in Sections (2 &/or 15).
EYE PROTECTION
Wear safety glasses or goggles to protect against exposure. Chemical
splash goggles in compliance with OSHA regulations are advised; however,
OSHA regulations also permit other types of safety glasses.
PROTECTIVE GLOVES
Appropriate disposable gloves are acceptable, such as, Nutrile rubber
gloves.
COMPLEMENTARY COATINGS CORP
MATERIAL SAFETY DATA SHEET
HR2410099-01
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
. ... . . . LIQUID
:
Physical State . .
Vapor Pressure ........ 7.00
Vapor Density . . . . . . . . . . . . : 4.90
Boiling Point Range ... - Lower - 277.0 癋
Higher - 400.0 癋
Specific Gravity . .
. . : 1.146
Weight per Volume ..... 9.5381 LB/GL
VOC - Total (lb/gal) 3.346
.860 (n-Butyl Acetate = 1)
Evaporation Rate ......
Volatile by Weight . .... . 35.0893
Volatile by Volume ...... .... . 52.4360
SECTION 10 - STABILITY AND REACTIVITY
STABILITY
This product is stable.
INCOMPATIBILITIES (Materials to Avoid)
This product can react violently with strong oxidizing agents such
as chlorine, oxygen, or strong oxidizing acids, such as, nitric and
sulfuric.
HAZARDOUS POLYMERIZATION
Will not occur.
CONDITIONS TO AVOID
Avoid heat, sparks, open flames and other sources of ignition.
HAZARDOUS PRODUCTS OF DECOMPOSITION
Heating to decomposition, as in a fire or welding, may produce
hazardous fumes. Fumes may contain carbon monoxide, carbon dioxide
and oxides of nitrogen.
SECTION 11 - TOXICOLOGICAL INFORMATION
No data at this time.
SECTION 12 - ECOLOGICAL INFORMATION
No data at this time.
COMPLEMENTARY COATINGS CORP
MATERIAL SAFETY DATA SHEET
HR2410099-01
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL
Dispose of this product in accordance with applicable local,
county, state and federal regulations, by incinerating, or treating and
disposing in approved facility. Do not incinerate closed containers.
SECTION 14 - TRANSPORT INFORMATION
DOT HAZARD CLASS NOT REGULATED (In containers less
-
than 119 gallons or 450 liters via surface transportation).
COMBUSTIBLE LIQUID (In containers of more than 119 gallons capacity)
for surface shipments within the U.S. and Canada, and apply the DOT
information, listed below:
DOT PACKAGING GROUP ...... . : PG III
DOT LABEL . . . . ........ NONE
DOT SHIPPING NAME .................- PAINT
DOT PLACARD . . . ... . . . : NONE
UN/NA NUMBER .................... UN1263
SECTION 15 - REGULATORY INFORMATION
U.S. FEDERAL REGULATORY INFORMATION
TSCA SECTION 8(b) - INVENTORY STATUS:
All components of this product are either listed on the U.S. Toxic
Substances Control Act (TSCA) inventory of chemicals or are otherwise
compliant with TSCA Regulations.
SARA 313 TOXIC CHEMICALS:
This product contains the following substances subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
COBALT 2-ETHYLHEXANOATE
CAS# 136-52-7 PCT BY WT: .1920
XYLENE (MIXED ISOMERS)
CAS# 1330-20-7 PCT BY WT: .05- 1.5
1,2,4-TRIMETHYLBENZENE
CAS# 95-63-6 PCT BY WT: .05- 1.5
ETHYLBENZENE
CAS# 100-41-4 PCT BY WT: .3660
COMPLEMENTARY COATINGS CORP
MATERIAL SAFETY DATA SHEET
HR2410099-01
SECTION 16 - OTHER INFORMATION
Prepared by .........................
Date of issue ....................... - 08/07/2008
Last Revision Date .. . : 08/23/2007
MSDS Prepared for .
MSDS Last Prepared .....................?NONE
HMIS Rating: Health- 2* Flammability- 2
Reactivity- 0
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This Material Safety Data Sheet conforms to the Hazard Communication
Standard, 29 CFR 1910.1200(g)(4).
The above information pertains to this product as currently formulated
and is based on the information available, as of this date. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are out-
side our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
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Abbreviations used: int.- interior; ext.- exterior; MSDS - Material Safety
Data Sheet; HMIS - Hazardous Materials Information System; CAS - Chemical
Abstracts Services; pct - percent; wt - weight; mm Hg - millimeters of
mercury; F - Fahrenheit; ACGIH - American Conference of Governmental
Industrial Hygienists; TLV - Threshold Limit Value; OSHA - Occupational
Safety and Health Administration; PEL - Permissible Exposure Limit; TWA -
Time-Weighted Average; STEL- Short Term Exposure Limit; N/A- Not applicable
IARC - International Agency for Research on Cancer; NE - Not established
NTP - National Toxicological Program; CFR - Code of Federal Regulations;
OSHA - Z 29CFR 1910, Subpart Z; VOC - Volatile Organic Compounds; TCC -
Tag Closed Cup; LEL - Lower Explosive Limit; Mg/m3 or Mg/Cu M - milligram
per cubic meter; mppcf - millions of particles per cubic foot; ppm - parts
per million; NIOSH - National Institute of Occupational Safety and Health;
MSHA - Mine Safety and Health Administration; CNS - Central Nervous System.
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