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MSDS Material Safety Data Sheet
CAS

68476-34-6 68476-30-2 64741-45-3 64741-56-6 64741-61-3 64741-59-9 64741-62-4 1330-20-7 95-63-6 111-84-2 7704-34-9 91-20-3

File Name: 68476-34-6_68476-30-2_64741-45-3_64741-56-6_64741-61-3_64741-59.asp

                           MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 ?DSL2,
Off-Road, On-Road, HS璂yed, LS璂yed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel
Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy Dyed; Diesel Fuel ?Premium, Super, Supreme,
Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10 and ?5 F pour point
depressed diesel; Lago; Burner Oil; Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine ?Marine
Gas Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30
to IF-460; IMF; RR Diesel Fuel - No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel -
On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA - LS Diesel Fuel Dyed, Undyed, Off-
Road HS Dyed - Ultra Low Sulfur Diesel

GENERAL USE: Fuel
PRODUCT DESCRIPTION: Liquid. Color varies, clear, yellow (pale to straw), red, blue, blue-green
color. Petroleum odor.

MANUFACTURER'S NAME DATE PREPARED: September 16, 2004
Page 1 of 5
Tesoro Petroleum Companies, Inc. SUPERSEDES: May 23, 2002
ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION
300 Concord Plaza Drive Tesoro Call Center (877) 783-7676
(CITY, STATE AND ZIP CODE) COUNTRY EMERGENCY TELEPHONE NUMBER
San Antonio, TX 78216-6999 USA Chemtrec (800) 424-9300
DISTRIBUTOR'S NAME
Same
ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION

(CITY, STATE AND ZIP CODE) COUNTRY EMERGENCY TELEPHONE NUMBER

SECTION 2 - HAZARDOUS INGREDIENTS
OSHA PEL ACGIH TWA
% SARA RQ
HAZARDOUS COMPONENTS CAS # TITLE III LBS
(by volume) PPM MG/M3 PPM MG/M3
Contains or May Contain:
Diesel Fuel #2 68476-34-6 0 - 100 not established
Fuel Oil #2 68476-30-2 0 - 100 not established
Tower Residues, atmospheric 64741-45-3 0 - 100 not established
Residues (petroleum), Vacuum 64741-56-6 0 - 100 not established
Heavy catalytically cracked distillate (e,f,g) 64741-61-3 0 - 100 0.2 0.2
Light thermally cracked distillate (h) 64741-59-9 0 - 100 not established
Catalytically cracked clarified oil (e,g) 64741-62-4 0 - 100 0.2 0.2
Xylene (mixed) (a,b,c) 1330-20-7 0 - 1.1 100 435 100 Yes 1000
Trimethylbenzene 1,2,4 (a) 95-63-6 0 - 1.2 25 125 Yes
Nonane 111-84-2 0 - 1.1 200 1050 200
Sulfur, precipitated 7704-34-9 0 - 5.0 15
Naphthalene (a,b,c,d) 91-20-3 0-1 10 50 10 Yes 100
Red Dye not specified Trace
(a,c) See Section 15
(b) Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled
according to regulations in 40 CFR 260-281.
(d) Product is listed or defined as a marine pollutant in IMDG Code or 49 CFR 172.101 Appendix B, List of Marine Pollutants and must be classified as an
Environmentally Hazardous Substance, Class 9, in addition to any other defined hazards for this product.
(e) California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986, chemicals known to the state to cause cancer or reproductive toxicity. A
person in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical.
(f) IARC has determined that residual fuels are possibly carcinogenic to humans. Handling procedures and safety precautions in the MSDS should be followed
to minimize employee's exposure.
(g) IARC has determined there is sufficient evidence for the carcinogenicity of catalytically cracked oils.

(h) Kidney damage may result following aspiration pneumonitis. The results of animal bioassays on middle distillate fuels show that prolonged dermal contact
produces a weak to moderate carcinogenic activity.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 ?DSL2, Off-Road, On-Road, Page 2 of 5
HS璂yed, LS璂yed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy
Dyed; Diesel Fuel ?Premium, Super, Supreme, Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10
and ?5 F pour point depressed diesel; Lago; Burner Oil; Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine ?Marine Gas
Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30 to IF-460; IMF; RR Diesel Fuel -
No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel - On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA -
LS Diesel Fuel Dyed, Undyed, Off-Road HS Dyed - Ultra Low Sulfur Diesel
September 16, 2004
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Various colored liquid, potentially hazardous vapors. Flammable as defined by DOT and TDG. May be classified by DOT as Combustible.
Classified as Combustible by OSHA. Can cause eye and skin irritation upon contact. Inhalation of vapors can cause anesthetic effect
leading to death in poorly ventilated areas. Hazard symbols for this product - Xn Risk Phrases - R10 20 36/38


POTENTIAL HEALTH EFFECTS
INHALATION: High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting and malaise.


SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate irritation or dermatitis.


EYES: High vapor concentration or contact may cause irritation and discomfort.


INGESTION: May result in vomiting; aspiration of vomitus into the lungs must be avoided; DO NOT induce vomiting. Minute amounts
aspirated into the lungs can produce severe lung injury, chemical pneumonitis, pulmonary edema or death.

CARCINOGENICITY No No No
NTP? IARC MONOGRAPHS? OSHA REGULATED?
This product contains a mixture of petroleum hydrocarbons called middle distillates. Because of this broad description, many products are
considered middle distillates yet they are produced by a variety of different petroleum refining processes. Toxicology data developed on some
middle distillates found that they caused positive responses in some mutagenicity tests and caused skin cancer when repeatedly applied to
mice over their lifetime.

SECTION 4 - FIRST AID MEASURES
INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR
and seek emergency medical attention.

SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation
persists, seek medical attention.

EYES: Remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation persists, seek
medical attention.

INGESTION: DO NOT induce vomiting; if vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs; seek
immediate medical attention. Vomiting may be induced only under the supervision of a physician.

SECTION 5 - FIRE FIGHTING MEASURES
FLAMMABLE LIMITS LEL: 0.3% UEL: 10.0%
FLASH POINT (METHOD USED)
AUTOIGNITION TEMPERATURE: 350?- 625?F NFPA CLASS:
100?- 199?F ( 38?- 93?C) TCC II
GENERAL HAZARDS: Product is considered combustible. Products of combustion include compounds of carbon, hydrogen and oxygen,
including carbon monoxide.


EXTINGUISHING MEDIA
Carbon dioxide, water fog, dry chemical, chemical foam

FIRE FIGHTING PROCEDURES
Firefighters must wear full facepiece self - contained breathing apparatus in positive pressure mode. Do not use solid stream of water since
stream will scatter and spread fire. Fine water spray can be used to keep fire - exposed containers cool.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers can explode due to buildup of pressure when exposed to extreme heat. Do not use direct stream of water on pool fires as
product may reignite on water surface. Caution - Material is combustible!
HAZARDOUS COMBUSTION PRODUCTS
Smoke, fumes, oxides of carbon
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 ?DSL2, Off-Road, On-Road, Page 3 of 5
HS璂yed, LS璂yed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy
Dyed; Diesel Fuel ?Premium, Super, Supreme, Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10
and ?5 F pour point depressed diesel; Lago; Burner Oil; Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine ?Marine Gas
Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30 to IF-460; IMF; RR Diesel Fuel -
No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel - On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA -
LS Diesel Fuel Dyed, Undyed, Off-Road HS Dyed - Ultra Low Sulfur Diesel
September 16, 2004
SECTION 6 - ENVIRONMENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: COMBUSTIBLE. Evacuate and ventilate area; confine and absorb
into absorbent; place material into approved containers for disposal; for spills in excess of allowable limits (RQ) notify the National Response
Center (800) 424 - 8802; refer to CERCLA 40 CFR 302 and SARA Title III, Section 313 40 CFR 372 for detailed instructions concerning
reporting requirements. Do not discharge into lakes, ponds, streams or public waters.


SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: This material is combustible. It should be stored in tightly closed containers
in a cool, well ventilated area. Vapor may form explosive mixtures in air. All sources of ignition should be controlled. This material may be
classified as COMBUSTIBLE by DOT unless transported by vessel or aircraft. Refer to 49 CFR 173.120. Keep this and other chemicals out
of reach of children. Avoid inhaling concentrated fumes or vapors.




SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation of confined spaces.
Use explosion-proof ventilation equipment. See Section 2 for Component Exposure Guidelines.


PERSONAL PROTECTION:
RESPIRATORY PROTECTION (SPECIFY TYPE): None required while threshold limits (Section 2) are kept below maximum allowable
concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149
for complete regulations.

PROTECTIVE GLOVES: Neoprene or rubber gloves with cuffs.
EYE PROTECTION: Protective eyeglasses or chemical safety goggles. Refer to 29 CFR 1910.133 or European Standard EN166.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyebath nearby
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.


SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
VAPOR PRESSURE (PSIA) VAPOR DENSITY (AIR = 1)
< 0.5 PSIA @ 100?F >1
SPECIFIC GRAVITY @ 60?F (WATER = 1) EVAPORATION RATE (WATER = 1)
0.78 - 0.955 <1
SOLUBILITY IN WATER FREEZING POINT
Negligible, below 1.0% - 51?F (- 46?C)
pH APPEARANCE AND ODOR
Not determined Liquid, clear, yellow (pale to straw), red, blue, blue-green, petroleum odor.
BOILING RANGE PHYSICAL STATE
30 - 806?F (1.1 - 430?C) Liquid
VISCOSITY VOLATILE ORGANIC COMPOUNDS (Total VOC's)
1.7 - 40.0 cS @ 100癋 6.75 lbs / gallon
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Extreme temperatures, open flames
STABILITY UNSTABLE:
STABLE: XXX
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides
of carbon, hydrocarbons, fumes, and smoke may be produced.
CONDITIONS TO AVOID: None
HAZARDOUS POLYMERIZATION MAY OCCUR:
WILL NOT OCCUR: XXX
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 ?DSL2, Off-Road, On-Road, Page 4 of 5
HS璂yed, LS璂yed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy
Dyed; Diesel Fuel ?Premium, Super, Supreme, Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10
and ?5 F pour point depressed diesel; Lago; Burner Oil; Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine ?Marine Gas
Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30 to IF-460; IMF; RR Diesel Fuel -
No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel - On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA -
LS Diesel Fuel Dyed, Undyed, Off-Road HS Dyed - Ultra Low Sulfur Diesel
September 16, 2004
SECTION 11 - TOXICOLOGICAL INFORMATION
LD50 of Ingredient LC50 of Ingredient
Hazardous Ingredients (All products may not be
CAS # EINECS # (Species and Route) (Species)
listed if information is not available)
Contains or May Contain:
Not established Not established
Diesel Fuel #2 68476-34-6 270-676-1
Not determined Not determined
Fuel Oil #2 68476-30-2 270-671-4
Not established Not established
Tower Residues, atmospheric 64741-45-3 265-045-2
Not established Not established
Residues (petroleum), Vacuum 64741-56-6 265-057-8
Not established Not established
Heavy catalytically cracked distillate (e,f,g) 64741-61-3 265-063-0
Not established Not established
Light thermally cracked distillate (h) 64741-59-9 265-060-4
Not established Not established
Catalytically cracked clarified oil (e,g) 64741-62-4 265-064-6
4300 mg / kg 5000 ppm / 4H
Xylene (mixed) (a,b,c) 1330-20-7 215-535-7
Oral - rat Inhalation - rat
5 gm / kg 18 gm / m3 / 4H
Trimethylbenzene 1,2,4 (a) 95-63-6 202-436-9
Oral - mouse Inhalation - rat
218 mg / kg 3200 ppm / 4H
Nonane 111-84-2 203-913-4
Oral - mouse Inhalation - rat
Not available Not available
Sulfur, precipitated 7704-34-9 231-722-6
1780 mg / kg Not established
Naphthalene (a,b,c,d) 91-20-3 202-049-5
Oral - rat
Not determined Not determined
Red Dye not specified not specified

SECTION 12 - ECOLOGICAL INFORMATION
No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Release of this
product should be prevented from contaminating soil and water and from entering drainage and sewer systems. U.S.A. regulations require
reporting spills of this material that could reach any surface waters. The toll free number for the U.S. Coast Guard National Response Center
is (800) 424-8802. Naphthalene (91-20-3) one of the ingredients in this mixture is classified as a Marine Pollutant.


SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of in accordance with Local, State, and Federal Regulations. This product may produce hazardous
vapors or fumes in a closed disposal container creating a dangerous environment. Refer to "40 CFR Protection of Environment Parts 260 -
299" for complete waste disposal regulations. Consult your local, state, or Federal Environmental Protection Agency before disposing of any
chemicals. Do not flush to sanitary sewer or waterway.

SECTION 14 - TRANSPORT INFORMATION
PROPER SHIPPING NAME: Diesel Fuel
DOT HAZARD CLASS / Pack Group: 3 / III IATA HAZARD CLASS / Pack Group: Not applicable
REFERENCE: 49 CFR 173.150, .203, .242 IMDG HAZARD CLASS: Not applicable
UN / NA IDENTIFICATION NUMBER: NA 1993 RID/ADR Dangerous Goods Code: Not applicable
LABEL: Flammable UN TDG Class / Pack Group: Not applicable
HAZARD SYMBOLS: F
Note: Transportation information provided is for reference only. Client is urged to consult CFR 49 parts 100 - 177, IMDG, IATA, EC, United
Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes,
packaging materials and methods of shipping.
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 ?DSL2, Off-Road, On-Road, Page 5 of 5
HS璂yed, LS璂yed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy
Dyed; Diesel Fuel ?Premium, Super, Supreme, Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10
and ?5 F pour point depressed diesel; Lago; Burner Oil; Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine ?Marine Gas
Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30 to IF-460; IMF; RR Diesel Fuel -
No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel - On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA -
LS Diesel Fuel Dyed, Undyed, Off-Road HS Dyed - Ultra Low Sulfur Diesel
September 16, 2004
SECTION 15 - REGULATORY INFORMATION
TSCA (Toxic substance Control Act)
All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory) or are exempted
from listing because a Low Volume Exemption has been granted in accordance with 40 CFR 723.50.
SARA TITLE III (Superfund Amendments and Reauthorization Act)
311/312 Hazard Categories
Acute health, flammable
313 Reportable Ingredients:
(a) A "Yes" in the SARA TITLE III column in Section 2 indicates a toxic chemical subject to annual reporting requirements of Section 313 of
the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372.
CERCLA (Comprehensive Response Compensation and Liability Act)
(c) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or
spills to the environment of the Reportable Quantity (RQ for this mixture > 24,000 lbs) or greater amounts, according to 40 CFR 302.

CPR (Canadian Controlled Products Regulations)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all
the information required by the Controlled Products Regulations.
IDL (Canadian Ingredient Disclosure List)
Components of this product identified by CAS number are listed on the Canadian Ingredient Disclosure List are shown in Section 2.
DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List)
Components of this product identified by CAS number are listed on the DSL or NDSL and may or may not be listed in Section 2 of this
document. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicated.
EINECS (European Inventory of Existing Commercial Chemical Substances)
Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances.
EC Risk Phrases SYMBOL(S) REQUIRED EC Safety Phrases
FOR LABEL
R10 Flammable S23 Do not breathe vapor
R20 Harmful by inhalation S25 Avoid contact with eyes
R36/38 Irritating to eyes and skin. Harmful S28 After contact with skin, wash immediately with
plenty of soap and water.
R51 Toxic to aquatic organisms.
R65 Damaging to lungs when swallowed S29 Do not empty into drains
S62 If swallowed, do not induce vomiting; seek
medical advice immediately and show this label.

SECTION 16 - OTHER INFORMATION
Values do not reflect absolute minimums and maximums; these values are typical which may vary from time to time.

HMIS HAZARD RATINGS HEALTH 0 = INSIGNIFICANT 3 = HIGH
1
FLAMMABILITY 1 = SLIGHT 4 = EXTREME
2
PHYSICAL HAZARD 2 = MODERATE
0
PERSONAL PROTECTIVE EQUIPMENT Safety Glasses, Gloves
B

Section 1, add name; Section 3, Hazard Symbols; Section 11, add
REVISION SUMMARY:
EINECS #; Section 15, TSCA text, add symbol; Section 16, HMIS Text
This MSDS has been revised in the following
sections:

MSDS Prepared by: Chem-Tel, Inc.
1305 N. Florida Ave.
Tampa, Florida USA 33602
(800) 255-3924 Outside USA (813) 248-0573
DISCLAIMER: The information supplied in this data sheet is obtained from currently available sources, which are believed to be reliable. HOWEVER, THE
INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THE INFORMATION OR THE RESULTS
TO BE OBTAINED FROM ITS USE.
Handling, storage, use or disposal of the above-referenced product is beyond our control and may occur under conditions with which we are unfamiliar. FOR THESE
AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM ANY LIABILITY FOR DAMAGE, INJURY AND COST ARISING
FROM OR RELATED TO THE USE OF THE PRODUCT.
PRODUCT NUMBER (s): BHPP-1052, BHPP-1054, MSDS-1054, 2, 3, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 39, 46, 75, 88, 89, 90, 94, 97, 98, 99, 100, 101,
102, 103, 104, 105, 106, 108, 109, 111, 116, 117, 118, 282, 290, 291, 294, 304, 319, 351, 352, 1000, 1001, 1071,1076
MATERIAL SAFETY DATA SHEET
Manufacturer: Schaeffer Mfg. Company Emergency Response Number:
Address: 102 Barton Street 314-865-4105 (24hr emergency number) or
Address St. Louis, MO 63104 800-325-9962
SECTION 1 ?PRODUCT INFORMATION
Chemical Family: Petroleum Hydrocarbons Trade Name: #137B Diesel Treat 2000
Formula: Proprietary Mixture.
SECTION 2 ?HAZARDOUS INGREDIENTS
COMPONENTS-CHEMICAL NAMES AND COMMON CAS Exposure Limits
NAMES Number % TVL PEL
3 3
ppm mg/m ppm mg/m
Heavy Aromatic Naphtha 64742-95-6 2.8-4.2 50
1,2,4-Trimethylbenzene 95-63-6 2.46 25 25
Aromatic Solvent Naphtha 64742-94-5 14-15 100
Heavy Aromatic Distillate 64742-48-9 38-40 NE NE
Avetic Acid Ethynel Ester 24937-78-8 14-15 NE NE
2-Butoxyethanol 111-76-2 7-9 25 121 50 240
Benzene 71-43-6 0.039 10 32 10
Diethylene Glycol Monoethyl Ether 111-77-3 0.425 NE
Tall Oil Fatty Acids 61790-12-3 3-4 NE
Cumene 98-82-6 0.154 50 246 50 246
Ethylbenzene 100-41-4 3-4 100 434 100 435
2-Ethylhexyl Nitrate 27247-96-7 4-6 8
Amines, polyethylene poly-reaction products with succinic 84605-20-9 9-12 NE NE
anhydride isobutylene derivatives
Xylene 1330-20-7 2-3 100 434 100
Naphthalene 91-20-3 0.1521 100 434 100 435
Section 3 ?PHYSICAL DATA
Boiling Point: Specific Gravity: .8641
300癋/148.8癈
Vapor Pressure (mm, Hg): Not Determined % Volatile: >75%
Vapor Density (Air = 1): Not Determined Evaporation Rate: (=1) Not Determined
Solubility in Water: Negligible pH: Not Applicable
Appearance and Odor: Tan Color, aromatic odor.
SECTION 4 ?FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method) 癋/癈: 129癋/54癈 Flammability Limits UEL & LEL ----Not Determined
PMCC
Extinguishing Media: Carbon dioxide foam, dry chemical foam, sand, earth, waterfog.
Special Fire Fighting Procedures: For fires involving this material, do not enter any enclosed or confined space without protective
equipment including self-contained breathing apparatus. Cool exposed containers with waterspray. Avoid breathing fumes.
Unusual Fire & Explosion Hazards: Toxic fumes, gases or vapors may evolve on burning. Vapors may be heavier than air and may
travel along the ground to distant ignition source and flash back. Container may rupture on heating. The 2 Ethylhexyl Nitrate contained in
this product may undergo a self accelerating exothermic reaction if heated above 212癋 (100癈).
SECTION 5 - REACTIVITY HAZARD DATA
STABILITY [X] STABLE [ ]UNSTABLE Hazardous Decomposition [ ] WILL [X] WILL NOT OCCUR
Conditions to Avoid: High heat, high energy ignition sources
Incompatibility (Mat. to avoid): Strong oxidizing agents, amines, phenols, halogen compounds.
Hazardous Decomposition Products: Oxides of carbon and nitrogen.
Conditions to Avoid: None.
SECTION 6 - HEALTH HAZARD DATA
Threshold Limit Value and Sources: None established.
Acute Effects of Overexposure:
Ingestion: Irritation of the gastrointestinal lining, nausea, vomiting, diarrhea and abdominal pain. This material if ingested can
directly enter the lungs or if subsequently swallowed. Once in the lungs it is very difficult to remove and can cause
severe injury or death.
Eye Contact: Liquid contact produces irritation and redness to the eyes.
Skin Contact: Prolonged and repeated contact with the skin can cause redness or severe irritation.
Inhalation: Inhalation of vapors can cause headache, dizziness, nausea, or decreased blood pressure.
CHRONIC EFFECTS OF OVEREXPOSURE: Repeated overexposure may cause destruction of red blood cells with anemia, fever,
jaundice and kidney and liver damage.
Emergency and First Aid Procedures:
Swallowing: If a large amount of this material is swallowed give a large amount of water to drink. Do not induce vomiting. Seek
medical attention immediately.
Skin: Wash skin thoroughly with soap and water. Launder contaminated clothing.
Inhalation: Remove victim to fresh air. If breathing is labored, administer oxygen. If breathing has stopped start artificial
respiration immediately.
Eyes: Flush eyes with clear, cool, clean water for 15 minutes. Seek medical attention immediately




Date Prepared: 10/13/04 OF-1049 Rev. (1999)
#137B
Page 2

SECTION 7 ?SPILL OR LEAK PROCEDURES
Environmental Impact: This material is not expected to present any environmental problems other than those associated with oil spills.
If spilled into a watercourse, call the Coast Guard Toll Free No. 800-424-8802.
Procedures To Be Taken If Material Is Released or Spilled: Eliminate all sources of ignition. Absorb spills with absorbent clay.
Ventilate confined spaces. Keep out of sewers and watercourses.
Waste Disposal Method: Dispose of at an approved waste or disposal site facility in accordance with all applicable federal, state and
local laws and regulations. This product is considered to be an RCRA hazardous waste due to the presence of Benzene CAS#71-43-2
DO18 and its flammability D001.

SECTION 8 ?SPECIAL PROTECTION INFORMATION
Respiratory Protection: Use NIOSH/MSHA approved fullface respirator with an organic vapor cartridge if the recommended
exposure limits are exceeded.
Ventilation: Use local exhaust ventilation to control mists or vapors.
Eye Protection: Goggles of face shield.
Protective Clothing: Long sleeve shirt is recommended. Wear either a chemical protective suit or apron when potential for
contact with material exists. Use neoprene and nitrile rubber boots when necessary to avoid contaminating
shoes. Wear nitrile or neoprene gloves.
SECTION 9 ?SPECIAL PRECAUTIONS
Precautions To Be Taken In Handling and Storage: Do not store near heat, spark, flame or strong oxidizers. Keep containers closed
when not in use. Adequate ventilation required. Electrostatic charge may accumulate and create a hazardous condition when handling
this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all
operations which have the potential of generating an accumulation of electrostatic charge and/or a flammable atmosphere (including tank
and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing and vacuum truck operations) and
use appropriate mitigating procedures.
Special Comments: This product is a DOT Class 3 flammable liquid. Avoid breathing vapors. Avoid prolonged or repeated skin contact.
Remove contaminated shoes and clothing. Throw away shoes. Launder clothing before reuse. Wash thoroughly with soap and water
after use and before eating, drinking, smoking, and using toilet facilities.
SECTION 10 ?ADDITIONAL HEALTH AND TOXICOLOGICAL DATA

HMIS & NFPA Ratings: Health = 2 Fire = 2 Reactivity = 1

Contaminated clothing should be disposed of properly and/or decontaminated before reuse. Under no circumstance should vomiting be
induced. Vomiting can cause aspiration of the product into the lungs. If aspirated into the lungs, chemical pneumonia, which may cause
death in spite of treatment with oxygen and antibiotics, may result.

Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and
convulsion may be needed.

This product contains 0.039% of Benzene which is listed as potential cancer causing agents as determined by the National Toxicology
Programs Annual Reports, OSHA's Subpart Z list, the International Agency for Cancer Research's Monographs.

Proposition 65 State of California Warning: This product contains .0039% of Benzene CAS#71-43-2 which has been found by the State
of California to be a potential reproductive toxin and/or cancer-causing agent.

This product is an IRC (ignitable, reactive, corrosive) substance under CERCLA. If 2,779 gallons of the material is spilled which will
release 100lbs of 2-Ethylhexyl Nitrate into the environment and unless the material is cleaned up immediately for reprocessing, recycling
or reuse this may trigger the reporting requirements of CERCLA Section 103.


For SARA Title III Information, see last page

The materials in this product are listed on the US TSCA Inventory and are in compliance with the Canadian Environmental Protection
Act.

DOT Non Bulk Description: Flammable liquids, N.O.S., (Heavy Aromatic Naphtha,2-Butoxyethanol , Hydrotreated Heavy Naphtha),3,
UN1993, PGIII

Bulk: Flammable Liquids: N.O.S., (Heavy Aromatic Naphtha,2-Butoxyethanol, Hydrotreated Heavy Naphtha),3, UN1993, PG III
#137B
Page 3
SARA TITLE III INFORMATION

I. Section 302/304 Extremely Hazardous
Component CAS# % RQ (lbs.) RQ (gal.)*
Benzene 71-43-2 .0039 10 35,638

II. Section 102(a) CERCLA Hazardous Substance
Component CAS# % RQ (lbs.) RQ (gals.)
Cumene 98-82-6 0.154 5000 42,3621
Xylene 1330-20-7 2-3 100 6,352
Benzene 71-43-2 .0039 10 35,638
Ethylbenzene 100-41-4 3.7 1000 3,775
Naphthalene 91-20-3 0.1521 100 9,138
*Product RQ for Stationary Sources in case of spill in order to release Regulatory Requirements RQ as specified by
CERCLA
III. Title Section 311 Hazardous Categorization
Acute Chronic Fire Pressure Reactivity
X X X X
IV. Section 313 Toxic Chemical
Component CAS# %
Xylene 1330-20-7 32-34
Benzene 71-43-2 .000385
Vinyl Acetate 108-05-4 0.14
2-Butoxyethanol 104-76-7 9-11
Ethylbenzene 100-41-4 0.91
Cumene 98-82-6 0.77
Diethylene Glycol Monoethyl Ether 111-77-3 0.425

Although the information and recommendations set forth herein (hereafter referred to as information) are presented in
good faith and believed to be accurate and factual as of the date hereof, Schaeffer Mfg. Company makes no
representation as to the completeness or accuracy thereof. Information is supplied upon the condition that the person
receiving the same will make their own determination as to its safety and suitability for their purposes prior to use. In
no event will Schaeffer Mfg. Company be responsible for damages of any natures whatsoever resulting from the use
or reliance upon information. No representation or warranty, either expressed or implied, of merchantability or
fitness for a particular purpose is made with respect to information of the product to which the information
refers.

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100-42-5_1321-74-0_25013-15-4_107-98-2_80-62-6_8052-41-3_64742-95.asp 100-42-5 1321-74-0 25013-15-4 107-98-2 80-62-6 8052-41-3 64742-95-6 95-63-6 1330-20-7 108-65-6 98-29-3 141-78-6 3164-85-0 56-93-9 64742-55-8 136-53-8 79-41-4 131-17-9 123-54-6 91-66-7 98-83-9 756-79-6 121-69-7 112945-52-5 130-15-4 121-32-4 99-97-8 136-52-7 27253-31-2 100-41-4 21041-93-0 91-20-3
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1330-20-7_108-88-3_95-63-6_100-41.asp 1330-20-7 108-88-3 95-63-6 100-41-4
115-10.asp 115-10-6
64742-95-6_95-63-6_1330-20-7_6846-50-0_98-82.asp 64742-95-6 95-63-6 1330-20-7 6846-50-0 98-82-8
110613563.asp N/A
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1330-20-7_28182-81-2_110-43-0_53880-05-0_64742-95-6_4098-71.asp 1330-20-7 28182-81-2 110-43-0 53880-05-0 64742-95-6 4098-71-9 95-63-6
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68476-85-7_1330-20-7_100-41-4_64742-95-6_111-76-2_13463-67.asp 68476-85-7 1330-20-7 100-41-4 64742-95-6 111-76-2 13463-67-7 95-63-6 108-67-8
95-63-6_108-11-2_64742-95-6_68784-56-5_106-97-8_98-82-8_108-67.asp 95-63-6 108-11-2 64742-95-6 68784-56-5 106-97-8 98-82-8 108-67-8 74-98-6 1330-20-7
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64742-95-6_96-29-7_95-63-6_8052-41-3_64742-47-8_1330-20-7_100-41.asp 64742-95-6 96-29-7 95-63-6 8052-41-3 64742-47-8 1330-20-7 100-41-4 34590-94-8
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123-86-4_7779-90-0_1330-20-7_98516-30-4_1314-13-2_64742-95.asp 123-86-4 7779-90-0 1330-20-7 98516-30-4 1314-13-2 64742-95-6 100-41-4 95-63-6 108-67-8 103-65-1
1330-20-7_100-41-4_64742-95-6_95-63-6_7727-43-7_110-43-0_123-86-4.asp 1330-20-7 100-41-4 64742-95-6 95-63-6 7727-43-7 110-43-0 123-86-4
101-68-8_64742-94-5_64742-95-6_8052-41-3_9016-87-9_95-63-6_6846-50-0.asp 101-68-8 64742-94-5 64742-95-6 8052-41-3 9016-87-9 95-63-6 6846-50-0
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14807-96-6_110-43-0_14808-60-7_64742-95-6_141-78-6_95-63-6_108-67.asp 14807-96-6 110-43-0 14808-60-7 64742-95-6 141-78-6 95-63-6 108-67-8 67-64-1 1330-20-7 26471-62-5 100-41-4
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64742-47-8_64742-89-8_95-63-6_64742-95-6_8052-41-3_108-38.asp 64742-47-8 64742-89-8 95-63-6 64742-95-6 8052-41-3 108-38-3 95-47-6 100-41-4 106-42-3 108-88-3 71-43-2
1330-20-7_95-63-6_64742-47-8.asp 1330-20-7 95-63-6 64742-47-8
60207-90-1_64742-95-6_91-20-3_95-63-6.asp 60207-90-1 64742-95-6 91-20-3 95-63-6
108-88-3_78-93-3_108-10-1_67-56-1_110-82-7_8052-41-3_95-63-6.asp 108-88-3 78-93-3 108-10-1 67-56-1 110-82-7 8052-41-3 95-63-6 8002-05-9
822-06-0_28182-81-2_64742-95-6_123-86-4_95-63-6_108-88.asp 822-06-0 28182-81-2 64742-95-6 123-86-4 95-63-6 108-88-3
67701-23-9_64742-94-5_91-20.asp 67701-23-9 64742-94-5 91-20-3
64742-95-6_107-96-2_25551-13-7_103-65.asp 64742-95-6 107-96-2 25551-13-7 103-65-1
100-41-4_64742-94-5_1330-20-7_1333-86-4_91-20-3_95-63.asp 100-41-4 64742-94-5 1330-20-7 1333-86-4 91-20-3 95-63-6
115-29-7_64742-95-6_91-20-3_95-63-6_12-17-0.asp 115-29-7 64742-95-6 91-20-3 95-63-6 12-17-0
41-52-6_108-65-6_95-63-6_1085-98-9_731-27-1_103-65-1_108-67.asp 41-52-6 108-65-6 95-63-6 1085-98-9 731-27-1 103-65-1 108-67-8
8052-41-3_64742-47-8_64742-48-9_111-84-2_95-63-6_71-43-2_108-88-3.asp 8052-41-3 64742-47-8 64742-48-9 111-84-2 95-63-6 71-43-2 108-88-3
8052-41-3_64742-94-5_91-20-3_95-63-6_108-67-8_1330-20-7_100-41.asp 8052-41-3 64742-94-5 91-20-3 95-63-6 108-67-8 1330-20-7 100-41-4 25973-55-1 45-51-2 7631-86-9 7440-36-0 7727-43-7 7440-39-3 1306-23-6 1306-24-7 1333-86-4 7440-47-3 7440-50-8 64-46-1 7782-42-5 1309-37-1 7439-96-5 108-78-1 12001-26-2 7447-02-0 112-02-7 1503-48-6 1314-13-2 1314-98-3


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