MATERIAL SAFETY DATA SHEET
Page 1 of 6
WP-049
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards MSDS Revision: 2.0 MSDS Revision Date: 06/01/2007
34
1. PRODUCT IDENTIFICATION CHEMICAL RESPONSE CARD:
DIESEL PURGE
1.1
RESPONSE
Product Name:
TEAM PPE:
1.2 Chemical Name: See ingredients listed in section 2
1.3 Synonyms: P/N LM2005
WHMIS:
1.4 Trade Names: Diesel Purge
2
1.5
HEALTH:
Product Use: Automotive Cleaner
2
FLAMMABILITY:
1.6 Manufacturer's Name: Liqui Moly GmbH
0
REACTIVITY:
1.7 Manufacturer's Address: Jerg-Wielandstrae 4, 89081 Ulm, Germany
B
PERSONAL PROTECTION:
1.8 Business Phone: +49 (731) 1420-52
CHEMTREC 1-+1 (800) 424-9300/1-+1 (703) 527-3887
1.9 Emergency Phone:
2. HAZARD IDENTIFICATION
2.1 Hazard Identification:
This product is classified as a hazardous substance but not as dangerous goods according to the classification criteria of NOHSC and
ADG Code (Australia).Flammable liquid.
2.2 Routes of Entry: Inhalation: YES Absorption: YES Ingestion: NO
2.3 Effects of Exposure:
EYES: May cause irritation, redness and tearing. Vapors may be irritating to the eyes.
SKIN: May cause irritation, defatting, drying and cracking of skin. Prolonged and repeated contact may lead to dermatitis.
INGESTION: May cause a burning sensation of the mouth and throat, abdominal pain, gastrointestinal irritation, nausea, vomiting and
diarrhea. May also cause kidney damage, cardiac arrhythmia and Central Nervous System effects (see inhalation). Aspiration of
material into the lungs may cause chemical pneumonitis, which can be fatal. Can be fatal if inhaled or ingested.
INHALATION: Vapors may be irritating to nose, throat and respiratory tract. Excessive inhalation of vapors may cause kidney
damage, cardiac arrhythmia and Central Nervous System effects including dizziness, weakness, fatigue, nausea, headache and
possible unconsciousness.
2.4 Symptoms of Exposure:
EYES: Irritation, redness, swelling and tearing.
SKIN: Irritation, defatting, drying and cracking of skin.
INGESTION: Burning sensation of the mouth and throat, abdominal pain, gastrointestinal irritation, nausea, vomiting and diarrhea.
INHALATION: Irritation to nose, throat and respiratory tract, dizziness, coughing, wheezing, weakness, fatigue, nausea, headache and
possible unconsciousness.
2.5 Acute Health Effects:
EYES: May cause irritation, redness and tearing. Vapors may be irritating to the eyes. Risk of conjunctivitis
SKIN: May cause irritation, defatting, drying and cracking of skin. Prolonged and repeated contact may lead to dermatitis.
INGESTION: May cause a burning sensation of the mouth and throat, abdominal pain, gastrointestinal irritation, nausea, vomiting and
diarrhea. May also cause kidney damage, cardiac arrhythmia and Central Nervous System effects (see inhalation). Aspiration of
material into the lungs may cause chemical pneumonitis, which can be fatal. Can be fatal if inhaled or ingested.
INHALATION: Vapors may be irritating to nose, throat and respiratory tract. Excessive inhalation of vapors may cause kidney
damage, cardiac arrhythmia and Central Nervous System effects including dizziness, weakness, fatigue, nausea, headache and
possible unconsciousness.
2.6 Chronic Health Effects:
Prolonged or repeated skin contact may lead to dermatitis.
2.7 Target Organs:
None reported by the manufacturer.
See Section 16 for Additional Definitions of Terms Used.
NOTE: All WHMIS required information is included ?it is located in appropriate sections based on the ANSI Z400.1-2004 format.
MATERIAL SAFETY DATA SHEET
Page 2 of 6
WP-049
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards MSDS Revision: 2.0 MSDS Revision Date: 06/01/2007
3. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH - ppm OSHA - ppm OTHER
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. % TLV STEL PEL STEL IDLH
DIESEL FUEL 68476-34-6 LS9142500 270-676-1 65.0 100 NE 100 NE NA
2-ETHYLHEXYL NITRATE 27247-96-7 QU792500 248-363-6 25.0 100 NE 100 NE NA
PETROLEUM DISTILLATES 64742-54-7 PY8035500 NA 10.0 100 NA 100 NA NA
1,2,4-TRIMETHYLBENZENE DC3325000 202-436-9 1.0 25 NA 25 NA NA
95-63-6
4. FIRST AID MEASURES
4.1 First Aid:
EYES: Immediately flush eyes with plenty of running water for at least 15 minutes, lifting upper and lower lids, occasionally. If irritation
persists, repeat flushing. Get medical attention.
SKIN: Wash thoroughly with soap and water. If irritation persists, seek medical attention. Remove contaminated clothing and wash
before reuse.
INGESTION: Do not include vomiting. Have conscious person rise out mouth with water, then drink 1 or 2 glasses of water. Never give
an unconscious person anything to ingest. If vomiting spontaneously occurs, have victim lean forward with head down to avoid
breathing in the vomitus (vapors from vomit) into the lungs. Rinse out mouth and administer more water. Guard against aspiration
into the lungs. Aspiration of material into lungs due to vomiting may cause chemical pneumonitis which can be fatal. Get
immediate medical attention.
INHALATION: Remove affected person to fresh air. If breathing if difficult, administer oxygen. If breathing stops give artificial
respiration. Keep person warm, quiet and get medical attention.
HEALTH 2
4.2 Medical Conditions Aggravated by Exposure:
None reported by the manufacturer.
FLAMMABILITY 2
REACTIVITY 0
PROTECTIVE EQUIPMENT B
EYES SKIN
5. FIREFIGHTING MEASURES
5.1 Flashpoint & Method:
63 癈 (144.5 癋), UNK
5.2 Autoignition Temperature:
NA
6.5
5.3 Flammability Limits: Lower Explosive Limit (LEL): 0.6 Upper Explosive Limit (UEL):
5.4 Fire & Explosion Hazards:
This material can burn but will not readily ignite. This material will release vapors when heated above the
flash point temperature that can ignite when exposed to a source of ignition. In enclosed spaces, heated
vapor can ignite with explosive force. Mists or sprays may burn at temperatures below the flash point.
Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and trace oxides of sulfur
and nitrogen. Also, depending upon the conditions of use, low concentrations of hydrogen sulfide can be
released.
5.5 Extinguishing Methods:
Dry chemical, foam, carbon dioxide, and water fog.
5.6 Firefighting Procedures:
Keep containers cool until well after the fire is out. Use water spray to cool fire-exposed surfaces and to
protect personal. Avoid spraying water directly into storage containers because of danger of boilover.
Prevent runoff from fire control or dilution from entering sewers, drains, drinking water supply, or any
natural waterway. Firefighters must use full bunker gear including NIOSH-approved positive pressure self-
contained breathing apparatus to protect against potential hazardous combustion or decomposition
products and oxygen deficiencies.
MATERIAL SAFETY DATA SHEET
Page 3 of 6
WP-049
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards MSDS Revision: 2.0 MSDS Revision Date: 06/01/2007
6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
When accidentally discharged, prevent the product from flowing. Contain spillage with sand or inert absorbent and arrange safe
disposal. Prevent from fire and explosion risk. Eliminate any possible cause of fire. Absorb in earth or sand, skim on water surface.
Elimination treatment will have to be made by an agreed collector.
7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Wear gloves, glasses and self-contained mask. Warn about risk of vapor inhalation. Wash hands with water and soap immediately
after handling then rinse in case of contact. When using, do not eat, drink or smoke.
7.2 Storage & Handling:
Use and keep away from flame, heat sources and functioning electrical devices. Use in a well ventilated area. Store in original
packaging. Keep out of reach of children. Do not store in temperatures above 50癈. Keep out of direct sunlight.
7.3 Special Precautions:
Do not spray on a naked flame or any incandescent material. When using do not smoke. Avoid breathing vapors or spray mists.
Avoid any contact.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Ventilation & Engineering Controls:
Avoid breathing the vapors generated by this product. Use in a well-ventilated location (e.g., local exhaust ventilation, fans. Do not
eat, drink, or smoke while handling this product. Ensure that safety shower, hand washing sink and eye bath are near work area.
8.2 Respiratory Protection:
Use respiratory protection (e.g., organic vapor-acid gas cartridge respirator). Use only protection authorized by 29 CFR ?910.134,
applicable U.S. State regulations, or the Canadian CAS Standard Z94.4-93 and applicable standards of Canadian Provinces, EC
member states, or Australia.
8.3 Eye Protection:
Safety goggles.
8.4 Hand Protection:
Solvent resistant or other impervious gloves. Wear boots, clothing with long sleeves, etc. as appropriate.
8.5 Body Protection:
Wear protective clothing (e.g., apron)
9. PHYSICAL & CHEMICAL PROPERTIES
0.86 @ 15 癈
9.1 Density:
NA
9.2 Boiling Point:
ND
9.3 Melting Point:
NA
9.4 Evaporation Rate:
NA
9.5 Vapor Pressure:
NA
9.6 Molecular Weight:
Amber liquid
9.7 Appearance & Color:
Petroleum odor
9.8 Odor Threshold:
Insoluble
9.9 Solubility:
NA
9.10 pH
NA
9.11 Viscosity:
NA
9.12 Other Information:
10. STABILITY & REACTIVITY
This product is chemically stable under normal conditions of storage and use.
10.1 Stability:
10.2 Hazardous Decomposition Products: Fumes, smoke, carbon monoxide, and trace hydrocarbons.
10.3 Hazardous Polymerization: Will not occur.
10.4 Conditions to Avoid: Do not exposure this product to temperatures above 140癈.
10.5 Incompatible Substances: Strong oxidizing agents.
MATERIAL SAFETY DATA SHEET
Page 4 of 6
WP-049
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards MSDS Revision: 2.0 MSDS Revision Date: 06/01/2007
11. TOXICOLOGICAL INFORMATION
11.1 Toxicity Data:
None reported by the manufacturer.
11.2 Acute Toxicity:
None reported by the manufacturer.
11.3 Chronic Toxicity:
None reported by the manufacturer.
11.4 Suspected Carcinogen:
No
11.5 Reproductive Toxicity:
Mutagenicity: This product is not reported to cause mutagenic effects in humans.
Embryotoxicity: This product is not reported to cause embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive harm in humans.
11.6 Irritancy of Product: See section 2.3
11.7 Biological Exposure Indices: NA
11.8 Physician Recommendations: Treat symptomatically.
12. ECOLOGICAL INFORMATION
12.1 Environmental Stability:
Analysis for ecological effects has not been conducted on this product. However, if spilled, this product and any contaminated soil or
water may be harmful to human, animal, and aquatic life. Also, the coating action associated with petroleum and petroleum
products can be harmful or fatal to aquatic life and waterfowl.
12.2 Effect on Plants & Animals:
An environmental fate analysis has not been conducted on this specific product. However, plants and animals may experience
harmful or fatal effects when coated with petroleum-based products.
12.3 Effect on Aquatic Life:
Petroleum-based (mineral) lube oils will normally float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large
surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not
removed, oxygen depletion in the waterway can result in a loss of marine life or create an anaerobic environment. This material
contains phosphorus which is a controlled element for disposal in effluent waters in most sections of North America. Phosphorus is
known to enhance the formation of algae. Severe algae growth can reduce oxygen content in the water possibly below levels
necessary to support marine life.
13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Dispose of in a safe matter, in accordance with local and national regulations.
13.2 Special Considerations:
U.S. EPA Characteristic Waste (Ignitable) ?D001
14. TRANSPORTATION INFORMATION
The basic description (proper shipping name, hazard class & division, ID Number, packing group) is shown for each mode of transportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
NOT REGULATED
14.2 IATA (AIR):
NOT REGULATED
14.3 IMDG (OCN):
NOT REGULATED
14.4 TDGR (Canadian GND):
NOT REGULATED
14.5 ADR/RID (EU):
NOT REGULATED
14.6 MEXICO (SCT):
NOT REGULATED
MATERIAL SAFETY DATA SHEET
Page 5 of 6
WP-049
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards MSDS Revision: 2.0 MSDS Revision Date: 06/01/2007
15. REGULATORY INFORMATION
15.1 SARA Reporting Requirements:
This product does not contain any substances subject to SARA reporting requirements.
15.2 SARA Threshold Planning Quantity:
NA
15.3 TSCA Inventory Status:
The components of this product are listed on the TSCA inventory.
15.4 CERCLA Reportable Quantity (RQ):
NA
15.5 Other Federal Requirements:
NA
15.6 Other Canadian Regulations
All chemical substances of this product are listed on the CEPA DSL/NDSL or are exempt from list
requirements. This product has been classified according to the hazard criteria of the CPR and
the MSDS contains all of the information required by the CPR.
15.7 State Regulatory Information:
NA
15.8 67/548/EEC (European Union) Requirements:
The primary components of this product are not listed in Annex I of EU Directive 67/548/EEC.
Diesel Fuel: Flammable (F). R: 10-65 - Flammable. Harmful ?may cause lung damage if
swallowed. S: 23-24-62 - Do not inhale gas, fumes, vapor or spray. Avoid contact with skin. If
swallowed, do not induce vomiting - Seek medical advice immediately and show this
container or label.
16. OTHER INFORMATION
16.1 Other Information:
NA
16.2 Terms & Definitions:
Please see last page of this Material Safety Data Sheet.
16.3 Disclaimer:
This Material Safety Data Sheet complies with U.S. OSHA's Hazard Communication Standard, 29 CFR ?910.1200 & Health Canada's
Workplace Hazardous Materials Information System (WHMIS). To the best of ShipMate's or Worldpac's knowledge, the information
contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no
warranties of any type, either expressed or implied, are provided. The information contained herein relates only to the specific
product. Contact the manufacturer for additional information.
Prepared for:
16.4
WorldPac, Inc.
37137 Hickory Street
Newark, CA 94560
510-608-5525 phone
510-742-9262 fax
http://www.worldpac.com/
Prepared by:
16.5
Steven Charles Hunt
ShipMate, Inc.
18436 Hawthorne Blvd, Suite 201
Torrance, CA 90504 USA
Phone: +1 (310) 370-3600
Fax: +1 (310) 370-5700
e-mail: shipmate@shipmate.com
MATERIAL SAFETY DATA SHEET
Page 6 of 6
WP-049
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards MSDS Revision: 2.0 MSDS Revision Date: 06/01/2007
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
GENERAL INFORMATION:
NATIONAL FIRE PROTECTION ASSOCIATION: NFPA
CAS No. Chemical Abstract Service Number
FLAMMABILITY LIMITS IN AIR:
EXPOSURE LIMITS IN AIR:
Autoignition Minimum temperature required to initiate combustion
Temperature in air with no other source of ignition
ACGIH American Conference on Governmental Industrial Hygienists
LEL Lower Explosive Limit - lowest percent of vapor in air, by
TLV Threshold Limit Value
volume, that will explode or ignite in the presence of
OSHA U.S. Occupational Safety and Health Administration
an ignition source
PEL Permissible Exposure Limit
UEL Upper Explosive Limit - highest percent of vapor in air,
IDLH Immediately Dangerous to Life and Health
by volume, that will explode or ignite in the presence of
an ignition source
FIRST AID MEASURES:
CPR Cardiopulmonary resuscitation - method in which a person HAZARD RATINGS:
whose heart has stopped receives manual chest
compressions and breathing to circulate blood and provide 0 Minimal Hazard
oxygen to the body. 1 Slight Hazard
FLAMMABILITY
2 Moderate Hazard REACTIVITY
HMIS?br>
HAZARDOUS MATERIALS IDENTIFICATION
3 Severe Hazard
SYSTEM: HMIS
4 Extreme Hazard
HEALTH ACD Acidic
HEALTH, FLAMMABILITY & REACTIVITY RATINGS:
ALK Alkaline
0 Minimal Hazard COR Corrosive
FLAMMABILITY
1 Slight Hazard W Use No Water SPECIAL
HEALTH
2 Moderate Hazard OX Oxidizer PRECAUTIONS
REACTIVITY
3 Severe Hazard
4 Extreme Hazard PERSONAL PROTECTION
TOXICOLOGICAL INFORMATION:
NCCHL44T ?NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808
PERSONAL PROTECTION RATINGS:
LD50 Lethal Dose (solids & liquids) which kills 50% of the
exposed animals s
A G LC50 Lethal concentration (gases) which kills 50% of the
exposed animal
B H ppm Concentration expressed in parts of material per
million parts
TDlo Lowest dose to cause a symptom
C I TCLo Lowest concentration to cause a symptom
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or
D J TC, TCo, LClo, & LCo toxic effects
IARC International Agency for Research on Cancer
NTP National Toxicology Program
E K
RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
Consult your supervisor or S.O.P. for
F X TLm Median threshold limit
special handling directions.
log KOW or log KOC Coefficient of Oil/Water Distribution
REGULATORY INFORMATION:
Face Shield &
Safety Glasses Splash Goggles Gloves
Eye Protection
WHMIS Canadian Workplace Hazardous Material Information System
DOT U.S. Department of Transportation
TC Transport Canada
EPA U.S. Environmental Protection Agency
Boots Synthetic Apron Full Suit Dust Respirator
DSL Canadian Domestic Substance List
NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
Full Face
Dust & Vapor Half- Airline Hood/Mask
Full Face Respirator Respirator
Mask Respirator or SCBA TSCA U.S. Toxic Substance Control Act
EU European Union (European Union Directive 67/548/EEC)
Note: the dotted circle indicates that this respiratory protective
equipment is required for high concentrations or for large
volume spills or releases of product. EC INFORMATION:
OTHER STANDARD ABBREVIATIONS:
NA Not Available
NR No Results
NE Not Established
C E F N O T+ Xi Xn
ND Not Determined
ML Maximum Limit Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
SCBA Self-Contained Breathing Apparatus
|