HMIS
H =2
MATERIAL SAFETY DATA SHEET F =2
R =0
PPE = See Section 8
VOC: 250 grams per liter or less
Section I
Manufacturer: Siplast, an Icopal Group Company
(800) 643-1591 or (800) 922-8800
Address: 1000 E. Rochelle Blvd., Irving, TX 75062-3940
Emergency Phone No.: CHEMTREC, (800) 424-9300 (U.S.), (703) 527-3887 (outside of U.S.)
Product Class: Petroleum Hydrocarbon Adhesive
Trade Name: PA-311 LS
Section II - Ingredients
OSHA PEL ACGIH TLV
Ingredient Percent TWA TWA
5 mg/m3 0.5 mg/m3
Asphalt, Oxidized 50 - 70
CAS #64742-93-4
5 mg/m3 0.5 mg/m3
Asphalt Fumes <1
CAS #8052-42-4
15 mg/m3 10 mg/m3
Limestone 5 - 15
CAS #1317-65-3
10 mg/m3 15 mg/m3
Cellulose <5
CAS #9004-34-6
5 mg/m3
Fullers Earth <5 No Data
CAS #8031-18-3
Emulsifiers <1 No Data No Data
CAS #61789-77-3
Light Aromatic Solvent 10-30 No Data No Data
CAS # 64742-95-6
1,2,4-Trimethyl benzene 5-8 No Data 25 ppm
CAS #95-63-6
Xylene <1 100 ppm 100 ppm
CAS #1330-20-7
Section IV - Fire and Explosion Data
Section III - Physical Data
Appearance & Odor: Black asphalt mastic, The description shown may not apply to all shipping
hydrocarbon solvent odor. situations. Consult 49CFR, or appropriate
Vapor Pressure: 2.09 mmHg@68癋 Dangerous Goods Regulations, for additional
Vapor Density (Air = 1): 4+ description information.
Specific Gravity (H2O=1, at 4癈): 0.9 - 1.0
Solubility in H2O: Negligible DOT Shipping Name: Tars, Liquid
Solvent Boiling Point: 300 - 350癋 DOT Hazard Class: 3
Evaporation Rate: (Butyl Acetate = 1) 0.30 DOT Category: UN1999
% Volatile: 25% vol. DOT Packing Group: III
VOC lb/gal: 1.90 Hazardous Label: Flammable Liquid
Flash Point: 108癋
Flash Point Method: PMCC
Autoignition Temperature: No Data
LEL %: 0.5 UEL %: 6.0
Trade Name: PA-311 LS
Page Two
Flammability Classification: Class II Combustible Carcinogenicity: There is inadequate evidence that
Liquid bitumens alone are carcinogenic to humans. There
Extinguishing Media: Extinguish with dry chemical, is sufficient evidence for the carcinogenicity of
CO2, foam, and water fog. Solid streams of water extracts of steam-refined bitumens, air-refined
may be ineffective. Cool affected containers with bitumens, and pooled mixtures of steam- and air-
flooding quantities of water. Apply water from as refined bitumens in experimental animals. There is
great a distance as possible. Water or foam may inadequate evidence for the carcinogenicity of
cause frothing. Keep run-off water out of sewers and undiluted air-refined bitumens in experimental
water sources. Minimize breathing of gases, vapor, animals. There is limited evidence for the
fumes, or decomposition products. Use self- carcinogenicity of undiluted steam-refined bitumens
contained breathing apparatus for enclosed or and for cracking-residue bitumens in experimental
confined spaces or as otherwise needed. animals. (bitumens) IARC-3
Unusual Fire or Explosion Hazards: Flammable - Do
not store near strong oxidants or open flame. Smoke Emergency and First Aid Procedures:
from fire may be hazardous. SKIN: DO NOT try to dissolve with solvents or
Hazardous Combustion Products: Under fire thinners, wash with soap and water.
conditions - May form toxic materials: carbon dioxide EYES: Flush with large amounts of water for at least
and monoxide, oxides of sulfur, H2S, and other 15 minutes. Seek Medical Attention.
decomposition products, in the case of incomplete INHALATION: Move to fresh air. Use artificial
combustion. respiration if necessary. Seek Medical Attention.
Fire-Fighting Instructions: INGESTION: Do Not Induce Vomiting, because of
Special Fire-Fighting Procedures: Use air supplied danger of aspiration into lungs, causing serious
rescue equipment. Cool exposed containers with damage and chemical pneumonitis. If spontaneous
water. vomiting occurs, keep head below hips to prevent
aspiration into lungs and monitor fore breathing
difficulty. Seek Medical Attention.
Section V - Health Hazard Data
After first aid, get appropriate in-plant,
WARNING! Flammable liquid and vapor. Keep
paramedic, or community medical support.
away from heat, sparks, and flame. Keep container
closed when not in use. Use only with adequate
Section VI - Reactivity Data
ventilation. May cause skin irritation, wash
thoroughly after handling.
Stability: Stable X Unstable ______
Conditions to Avoid: Do not store near open flames.
Primary Entry Routes: Inhalation of fumes, skin
Chemical Incompatibilities: Do not store near strong
contact, eye contact.
oxidants.
Target Organs: Eyes, skin, respiratory system,
Hazardous Decomposition Products: Under fire
central nervous system, and kidneys.
conditions - May form toxic materials: carbon dioxide
and monoxide, oxides of sulfur, H2S, and other
Effects of Overexposure:
decomposition products, in the case of incomplete
SKIN: Irritation and dermatitis.
combustion.
EYES: Exposure to the mists, vapors, or fumes may
Hazardous Polymerization:
cause irritation.
May occur Will not occur X
INHALATION: Breathing of the mists, vapors, or fumes
may cause irritation of respiratory tract, dizziness,
headaches, and nausea. Section VII - Spill or Leak Procedures
INGESTION: May cause gastrointestinal disturbances,
irritation, nausea, vomiting, and diarrhea. Steps to be Taken: Shut off sources of ignition. Shut
Chronic Effects: Absorption from prolonged or off leak, if possible without risk.
repeated skin contact may cause systemic toxicity. Small Spills: Allow material to cool, and then scrape
up material for disposal.
Large Spills: Dike ahead of spill to contain, and then
take up with sand or other non-combustible,
absorbent material. Dispose in accordance with
local, state, and federal regulations.
Waste Disposal Method: Local, state, and federal
disposal regulations must be followed.
Trade Name: PA-311 LS
Page Three
Container Cleaning and Disposal: "Empty" Container Storage Requirements:
Warning: "Empty" containers retain product residue Do not store near strong oxidants and void water
(liquid and/or vapor) and can be dangerous. DO contamination.
NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS Section IX - Other
TO HEAT, FLAME, SPARKS, STATIC Regulator Information:
ELECTRICITY, OR OTHER SOURCES OF EPA Regulations:
IGNITION. THEY MAY EXPLODE AND CAUSE SARA 311/312 CODES (40 CFR 370 /29 CFR
INJURY OR DEATH. 1910.1200):
Fire: Yes
Section VIII - Special Protection Information Pressure: No
Reactivity: No
Engineering Controls: Immediate (acute): Yes
Ventilation: General mechanical with local exhaust; Delayed (chronic): Yes
sufficient to maintain exposure levels below
recommended ACGIH TLVs and OSHA PELs. TSCA (40 CFR 710): All components of this product
Protection Clothing/Equipment: are listed on the TSCA Inventory.
Gloves: Use chemical resistant gloves to avoid
prolonged or repeated skin contact. State Regulations: The following chemicals are
Goggles: Chemical-type goggles or face shield. specifically listed by individual states, for details on
Respiratory: Self-contained, positive-pressure each state's regulatory requirements you should
breathing apparatus when used in confined or contact the appropriate agency in that state:
enclosed space or when exposure limits are
exceeded or hydrogen sulfide is unknown or exceeds CAS
Compound Number States
20 ppm. Organic vapor respirators can be used with
Asphalt Fumes 8052-42-4 CA, CA65, MA,
good ventilation when organic vapors are less than TX, FL, IL, PA
1000 ppm or ten (100) times permissible exposure Asphalt, Oxidized 64742-93-4
limit, whichever is less. For emergency or non- Limestone 1317-65-3 CA2, MA, PA,
TX
routine operations (cleaning spills or storage tanks),
Cellulose 9004-34-6 CA2, MA, IL, PA,
wear a SCBA. Warning! Air-purifying respirators do
TX
not protect workers in oxygen-deficient atmospheres. Fullers Earth 8031-18-3
If respirators are used, OSHA requires a written Emulsifiers 61789-77-3
respiratory protection program that includes: Light Aromatic Solvent 64742-95-6
1,2,4,-Trimethyl benzene 95-63-6 MA, TX, FL, PA
procedures for selecting respirators, medical
Xylene 1330-20-7 CA, MA, NY NJ,
evaluations, fit testing, use in routine and emergency
TX, FL, IL, PA
situations, cleaning, disinfecting, storing, inspecting
and maintaining respirators, breathing air quality, CA - California State Superfund Hazardous Substance
quantity and flow, training in respiratory hazards, and CA1 - California OSHA Directors List of Hazardous
evaluation of effectiveness of respiratory program. Substances
Contaminated Clothing: Launder or dry clean CA2 - California OSHA Workplace Airborne Contaminants
CA65 - California Proposition 65 Carcinogens or
contaminated clothing before reuse.
Reproductive Toxins
Hygiene: Never eat, drink, or smoke in work areas.
MA - Massachusetts Substance List
Practice good personal hygiene after using this
TX - Texas Air Contaminants with Health Effects Screening
material, especially before eating, drinking, and
Level
smoking. FL - Florida Toxic Substance List
IL - Toxic Substance Disclosure to Employees List
Section IX - Special Precautions PA - Pennsylvania Hazardous Substance List
NY - New York Hazardous Substance Bulk Storage List
NJ - New Jersey Right to Know Hazardous Substance
Handling Precautions:
Stay up wind to avoid vapors. Do not store near
open flames. Ground lines and equipment used
during transfer.
The information and recommendations contained herein are, to the best of Siplast's knowledge and belief, accurate and reliable as of the date
issued. Siplast does not warrant or guarantee their accuracy or reliability, and should not be liable for any loss or damage arising out of the use
thereof. User should satisfy himself that he has all current data relevant to his particular use.
Rev 10/07
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