- D900X170 Revision - 7
Product Identification Number
SPRAnAT
CORPORA T/ON
MATERIAL SAFETY DATA HEET
For Spraylat Liquid Coatings and Associated Liquid Materials
1701 East 122nd Street 716 South Columbus Avenue 3465 South La Cienega Blvd. 3333 North Interstate 35
Chicago, IL 60633 Mount Vernon, NY 10550 Los Angeles, CA 90016 Gainesville, TX 76240
(773) 646-5900 (914) 699-3030 (310) 559-2335 (940) 665-9590
Fax: (~) 836-6094
Fax: (~646-3743 Fax: Fax: (940) 665-8867
~
699-3035
~-
e-mail HSEcoordinator@Spraylat.com
PREPARED BY: Health, Safety and Environmental Coordinator
EMERGENCY PHONE: Chemtrec
1-800-424-9300
INTERNATIONAL TRANSPORTATION ACCIDENTS: Chemtrec
1-703-527-3887
I. CHEMICAL PRODUCT. IDENTIFICATION
Product Name: Sureguard D900X170 Dark Gray Low Lead Rollcoat
Date Printed: 01/02/08
Revision Date: 04/07/05 Revision Number: 7
Supercedes : 11/22/04
-(EXPOSURE -SEE
II. COMPOSITION/INFORMATION ON INGREDIENTS LIMITS SECTION VIII)
INGREDIENTNAME CAS # %
Calciumcarbonate 471-34-1 25.01 - 30.00
n-Butylacetate 123-86-4 10.01 - 15.00
BariumSulfate 7727-43-7 5.01 - 10.00
Isobutylalcohol 78-83-1 5.01 - 10.00
LightAromaticSolventNaphtha 64742-95-6 5.01 - 10.00
1,2,4-Trimethylbenzene 95-63-6 1.01 - 5.00
Stoddardsolvent 8052-41-3 1.01 - 5.00
Talc 14807-96-6 1.01 - 5.00
Titaniumdioxide 13463-67-7 1.01 - 5.00
Lead Cyanamide 20837-86-9 1.01 - 5.00
Zinc oxide 1314-13-2 1.01 - 5.00
CrystallineSilica 14808-60-7 0.10 - 1.00
Carbonblack 1333-86-4 0.10 - 1.00
If ingredient percentages do not total 100%, the balance is due to rounding or applies to ingredient( s) deemed nonhazardous under 29 CFR 1910.1200 (Hazard Communication Standard).
III. HAZARDS IDENTIFICATION
HMIS
HEALTH 2*
FLAMMABILITY 3
REACTIVITY 0
3 = High
0 = Least 1 = Slight 4 = Extreme
2 = Moderate * = Chronic Health Effects
Routes of Entry: Inhalation, Eye contact, Skin contact, Ingestion, Absorption.
Eye disease, Skin disease including eczema and sensitization, Kidney disease, Lung disease,
Medical Conditions Aggravated:
Digestive tract disease.
n__- .. _x,..
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Product Identification Number D900X170 Revision - 7
Immediate (Acute) Health Effects:
Inhalation: Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache.
Breathing high concentrations of vapors or mists may cause irritation of the nose and throat and signs
of nervous system depression (e.g., headache, drowsiness etc.). Exposure to high levels of airborne or
ingested lead may produce symptoms of anemia, insomnia, weakness, constipation, nausea and
abdominal pain. Overexposure may cause damage to blood-forming, nervous, reproductive,
intestinal and urinary systems. This product may cause metal fume fever with resulting flu-like
symptoms. Toxic. Can cause systemic damage, see target organs below. Respiratory failure is
possible at high doses.
Skin Contact: Can cause moderate injury (reddening and swelling). Can be absorbed through the skin to cause
kidney and liver damage. Continued or prolonged contact may irritate the skin and cause a skin rash
(dermatitis). Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause
permanent damage.
Eye Contact: Can cause severe irritation. Eye contact may result in corneal injury. Symptoms may include
discomfort or pain, excess blinking and tear production, with marked redness and swelling of the
conjunctiva. Temporary vision impairment (cloudy or blurred vision) is possible. Contact may cause
eye irritation and transient corneal damage.
May cause irritation and minor systemic damage. Can be absorbed through the skin to cause kidney
Skin Absorption:
and liver damage.
Ingestion: Toxic if swallowed. May cause target organ failure and/or death. Can cause abdominal discomfort,
nausea, vomiting and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis.
Substance is harmful if swallowed. Large exposure may be fatal. Muscular weakness Tremors Loss of
appetite. Anemia Insomnia
Target Organ Acute Toxicity: Eyes, Skin, Respiratory System, Blood, Kidneys, Nervous System, Cardiovascular System, Digestive
Tract, Reproductive System, Gingival Tissue, Bone Marrow, Lymphatic System.
Long-Term (Chronic) Health Effects:
Inhalation: Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness,
weakness, fatigue, nausea and headache. Upon prolonged or repeated exposure this product may
cause sensitization. Avoid prolonged or repeated exposure. If sensitized, exposure below the TLV or
PEL, or at low levels can result in respiratory irritation and shortness of breath. These asthma-type
symptoms may develop immediately or be delayed up to several hours. Respiratory tract sensitization,
characterized by asthma-like symptoms such as tightness in the chest, difficulty breathing, and
wheezing may result from prolonged or repeated inhalation of dust/processing fumes ofthis product.
Pulmonary edema (fluid build-up in the lungs)
Skin Contact: Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis: Not
likely to cause permanent damage. Continued or prolonged contact may irritate the skin and cause a
skin rash (dermatitis). May cause sensitization. Upon prolonged or repeated contact, may lead to a
metallic taste in mouth.
Eye Contact: Upon prolonged or repeated contact, can cause severe irritation. Eye contact may result in corneal
injury. Symptoms may include discomfort or pain, excess blinking and tear production, with marked
redness and swelling of the conjunctiva. Temporary vision impairment (cloudy or blurred vision) is
possible.
Upon prolonged or repeated exposure, harmful if absorbed through the skin. May cause minor
Skin Absorption
systemic damage.
Carcinogenicity: IARC: Yes NTP: Yes OSHA: No
Target Organ Chronic Toxicity: Respiratory System, Nervous System, Eyes, Skin, Blood, Kidneys, Cardiovascular System, Digestive
Tract, Reproductive System, Gingival tissue, Lymphatic System.
NOTICE - Reports have associated repeated and prolonged occupational overexposure to solvents
with brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling
the contents may be harmful or fatal.
This product contains pigments which may become a dust nuisance when removed by abrasive
blasting, sanding or grinding.
- -7
Product Identification Number D900X170 Revision
IV. FIRST AID
Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not
Inhalation:
breathing, give artificial respiration and have a trained individual administer oxygen. Get medical
attention immediately.
Eyes: Immediately flush eyes with plenty of luke warm water for at least 20 minutes retracting eyelids often.
Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical
attention and monitor the eye daily as advised by your physician.
Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if
Skin Contact:
irritation develops or persists.
Seek medical advice immediately. Provide ingredients information from Section II of this MSDS to
Ingestion:
the medical care provider. Contact your local Poison Control Center (listed in the telephone book), or
dial the local "Emergency" (911) number for additional information. Do not induce vomiting unless
instructed to do so by a physician or other competent medical personnel. Never give anything by
mouth to an unconscious person.
v. FIRE FIGHTING MEASURES
Flammability Summary: Flammable
Flash Point: 27癈; 81 of
Autoignition Temperature: 420癈; 788 OF
Lower FlammablelExplosive Limit, % in air: 0.8 Upper FlammablelExplosive Limit, % in air: 6.0
Flammable Empty containers that retain product residue (liquid, solid/sludge, or vapor) can be
Fire Hazards:
dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or crush used containers. Do not
expose containers or product to heat, flame, sparks, static electricity, or other sources of ignition. Any
of these actions can potentially cause an explosion that may lead to injury or death. Vapors may be
ignited by sparks, flames or other sources of ignition if material is above the flash point giving rise to a
fire (Class B). Vapors are heavier than air and may travel to a source of ignition and flash back. This
product, when dried or cured, may support combustion when subj ected to sources of ignition or heat in
sufficient amount.
Extinguishing Media: Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water may be
ineffective but water spray can be used to extinguish a fire if swept across the base of the flames. Water
can absorb heat and keep exposed material from being damaged by fire.
Fire Fighting Instructions: Do not enter fire area without proper protection including self-contained breathing apparatus and full
protective equipment. Fight fire from a safe distance and a protected location due to the potential of
hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter
than water and burn while floating on the surface.
Carbon dioxide, Carbon monoxide, Toxic fumes, Toxic gases.
Hazardous Combustion Products:
VI. ACCIDENTAL RELEASE MEASURES
Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment
Health Consideration for Spill Response:
recommendations found in Section VIII of this MSDS. Additional precautions may be necessary based
on special circumstances created by the spill including: the material spilled, the quantity of the spill,
and the area in which the spill occurred. Also consider the expertise of employees in the area
responding to the spill.
Spill Mitigation Procedures:
General Methods: Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so.
Wear complete and proper personal protective equipment following the recommendation of Section
VIII at a minimum. For liquid spills, dike with suitable absorbent material like granulated clay. Gather
and store in a sealed container pending a waste disposal evaluation.
Ventilate the area by opening door and/or turning on fans and blowers.
Air Release:
Retain all contaminated water for treatment.
Water Release:
Avoid runoff into storm sewers and ditches that lead to waterways.
Land Spills:
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- D900X170 Revision - 7'
Product Identification Number
VII. HANDLING AND STORAGE
Hannful or irritating; avoid overexposure to the material. Use only in a well ventilated area. As with
Handling:
all chemicals, good industrial hygiene practices should be followed when handling this material.
Minimize dust generation and accumulation. Use spark-proof tools and explosion-proof equipment.
Do not get in eyes, on skin and clothing. Avoid breathing material. Ground and bond containers when
transferring material. "Empty" containers retain product residue (liquid and/or vapor) and can be
dangerous. Guard against dust accumulation of this material. Remove contaminated clothing and
wash before reuse.
Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep
Storage:
container(s) closed when not in use. Keep away from sources of ignition. Limit quantity of material
stored.
VIII. ENGINEERING CONTROLS, PERSONAL PROTECTIVE EQUIPMENT, AND EXPOSURE LIMITS
Engineering Controls: Local exhaust ventilation or other engineering controls are normally required when handling or using
this product to avoid overexposure. See table at the end ofthis Section VIII below for exposure limits.
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Engineering controls must be designed to meet any
relevant OSHA chemical specific standards in 29 CFR 1910. If user operations generate dust, fume, or
mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Protective Equipment:
If general or local exhaust ventilation is not available or sufficient to reduce exposure to below
Respiratory Tract:
acceptable levels, then respiratory protection is required to avoid overexposure when handling this
product. A supplied air type respiratory will be required.
Wear safety glasses with side shields when handling this product. When the possibility exists for eye
Eyes:
contact with splashing or spraying liquid, or airborne material, wear additional eye protection such as
chemical splash goggles and/or face shield. Do not wear contact lenses. Have an eye wash station
available.
Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals.
Skin:
Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water
before eating, drinking, and when leaving work.
Wear chemically resistant gloves and apron. (Consult your safety equipment supplier).
Protective Clothing:
IDLH
OSHA PEL
ACGIH TLV
CAS
CHEMICAL NAME
#
Not determined.
No PEL established
NoTLV
Calcium carbonate 471-34-1
150ppm TWA 1700 ppm IDLH
150 ppm TWA; 710 mg/m3 TWA
n-Butyl acetate 123-86-4
200 ppm STEL
Not determined.
15 mg/m3 TWA (total dust); 5 mg/m3
10 mg/m3 TWA
Barium Sulfate 7727-43-7
TW A (respirable traction)
50ppm TWA 1600 ppm IDLH
100 ppm TWA; 300 mg/m3 TWA
Isobutyl alcohol 78-83-1
Not determined.
Light Aromatic Solvent No PEL established
No TL V
64742-95-6
Naphtha
Not determined.
No PEL established
1,2,4- Trimethylbenzene No TL V
95-63-6
20000 mg/m3 IDLH
500 ppm TW A; 2900 mg/m3 TW A
100 ppm TWA
Stoddard solvent 8052-41-3
1000 mg/m3 IDLH
Not containing asbestos; containing
2 mg/m3 TW A (respiralble traction,
Talc 14807-96-6
particulate matter containing no asbestos less than I % quartz: 20 mppcf
and
5000 mg/m3 IDLH
15 mg/m3 TW A (total dust)
Titanium dioxide 10 mg/m3 TWA
13463-67-7
Not determined.
As Pb: 50 ug/m3 8hr- TW A
as Pb: 0.05 mg.m3 TW A
Lead Cyanamide 20837-86-9
-7
- D900X170 Revision
Product Identification Number
500 mglm3 IDLH (fume)
5 mglm3 TWA(fume); 10 mglm3 TWA 5 mglm3 TWA (fume); 15 mglm3
Zinc oxide 1314-13-2
(dust) TWA (total dust); 5 mglm3 TWA
(respirable fraction)
10 mglm3 STEL (fume)
(250)/(%Si02 + 5) mppcf(respirable); IDLH (respirable dust)
Crystalline Silica 50 mglm3
0.05 mglm3 TWA (respirable fraction)
14808-60-7
(10 mglm3)/(%Si02 + 2) (respirable);
(30 mglm3)/(%Si02 + 2) (Total Dust)
1750 mglm3 IDLH
Carbon black 3.5 mglm3 TWA
3.5 mglm3 TWA
1333-86-4
IX. PHYSICAL DATA
Grey Liquid.
Appearance:
Grey
Color:
N/A
pH:
Not Detennined.
Octanol/Water Coeff:
Partial.
Solubility in Water:
Heavier than air. Vapors that evolve from this product will tend to settle and accumulate near the floor.
Vapor Density:
Slower than n-Butyl Acetate.
Evaporation Rate:
1.451 / 12.11 Lbs.lGl.
Specific GravitylDensity:
3.7 Lbs/Glless water & 444 g/lless water & 3.7 Lbs/Gl as
V.O.C.
exempt solvent; exempt solvent; packed
The VOC content is detennined by using a percent solids basis, less water and exempt solvents, for adhesives, coatings and inks and the calculations of EPA
Reference Method 24 or equivalent ASTM method approved by the executive office.
203 OF
95癈;
Initial Boiling Point:
N/A
Initial Freezing Point:
X. STABILITY AND REACTIVITY
Stable under nonnal conditions.
Stability Information:
None known unless listed here. Contamination.
Conditions to Avoid:
Strong alkalies, Strong oxidizing agents, Chlorine, Strong acids, Chlorinated compounds.
Chemical Incompatibility:
Carbon dioxide, Carbon monoxide, Sulfur containing gases, Toxic fumes, Toxic gases.
Hazardous Decomposition Products:
XI. TOXICOLOGICAL INFORMATION
Chemical Name LD50/LC50
Carbonic acid, calcium salt 1:1 Oral LD50 Rat: 6450 m
Inhalation LC50 Rat: 2000 ppm/4H; Inhalation LC50 Mouse: 6 gm/m3/2H; Oral LD50 Rat: 10768 mg/kg; Oral
Acetic acid, butyl ester
LD50 Mouse: 6 ; Dennal LD50 Rabbit: > 17600 m
Oral LD50 Rat: 2460 m ; Dennal LD50 Rabbit: 3400 m
Oral LD50 Rat: 8400 m
Inhalation LC50 Rat: 18 m3/4H; Oral LD50 Rat: 5 m/k
Inhalation LC50 Mouse: 2500 m m3; Oral LD50 Mouse: 7950 m
Oral LD50 Rat: > 15400 m ; Dennal LD50 Rabbit: >3
XII. ECOLOGICAL INFORMATION
Care should be taken to minimize releases of any industrial chemicals to the environment.
Overview:
XIII. DISPOSAL CONSIDERATIONS
Spent or discarded material is a hazardous waste.
Waste Description for Unused Product:
Infonnation in this MSDS is provided only as a guide. Consult with competent authority to detennine
Disposal Methods:
proper waste disposal procedures. Clean up and dispose of waste and clean-up materials in accordance
with all federal, state, and local environmental regulations.
D001, .
Potential EPA Waste Codes:
Some Components Possibly Subjected to USEP A Land Disposal Restrictions:
When disposing of unused products or any waste, the preferred options are to send to a licensed reclaimer or to permitted incinerators. There may be some other ingredients subject to LOR categories.
Isobutyl alcohol 78-83-1
XIV. TRANSPORTATION INFORMATION
Agency Basic Description and Label
DOT Paint, 3, UN1263, PG ill
Hazardous Substance
RQ = 5000 pounds (2270 kg)
n-Butyl acetate
RQ = 5000 pounds (2270 kg); also listed as I-Propanol,
Isobutyl alcohol 2-methyl-
XV. REGULATORY INFORMATION
Regulation
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-7
- D900X170 Revision
Product Identification Number
1,2,4-Trimethylbenzene, Lead Compounds (Inorganic), Zinc Compounds
SARA 313 Reportable:
All components of this product are listed in, or exempt from, the TSCA 8(b) Inventory.
TSCA Inventory :
Lead Compounds.
M.S.D.S. Reportable HAP(s) :
The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986-
California Proposition 65 :
Proposition 65: "WARNING: This product contains chemical(s) known to the State of California to cause cancer and birth defects or
other reproductive harm."
N/A
SARAICERCLA Section 302 :
XVI. ADDITIONAL INFORMATION
VENDOR'S MSDS's, PAINT & COATINGS HANDBOOK, EPA's LIST OF LISTS, AND OTHER PUBLISHED MATERIALS.
Major References:
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, THEY ARE PROVIDED
FOR YOUR GUIDANCE ONLY. MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION OR USE, INCLUDING USE OF THIS MATERIAL IN COMBINATION WITH OTHER MATERIAI,S
OR PROCESSES. YOU THEREFORE SHOULD, AND THIS MATERIAL IS SUPPLIED ON THE CONDITION THAT YOU, PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF THE
MATERIAL PRIOR TO USE, AND YOU ACCEPT RESPONSIBILITY FOR SATISFYING YOURSELF THAT THE MATERIAL IS SUITABLE AND THE COMPLETENESS OF THIS INFORMATION IS
SUFFICIENT FOR YOUR USE. ALTHOUGH CERTAIN HAZARDS MAY BE DESCRIBED HEREIN, OTHER HAZARDS MAY ALSO EXIST NO WARRANTIES OF ANY KIND, EITHER EXPRESSED
OR IMPLIED, INCLUDING FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA, OR INFORMATION SET FORTH. IN NO CASE SHALL THE
DESCRIPTIONS, INFORMATION, OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE, AND WE DISCLAIM LIABILITY FOR LOSS OR INJURY
ARISING FROM YOUR USE OF THIS MATERIAL, DATA OR INFORMATION. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED HERE ARE GIVEN GRATIS. NO
OBLIGATIONS NOR LIABILITIES FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
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