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MSDS Material Safety Data Sheet
CAS

67701-23-9 64742-94-5 91-20-3

File Name: 67701-23-9_64742-94-5_91-20.asp

                                                        MATERIAL SAFETY DATA SHEET
Liquid MineralsTM

SECTION 1 ?CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
?br> PRODUCT NAME: LMG-30B
MANUFACTURER/SUPPLIER EMERGENCY TELEPHONE NUMBERS (24 HOUR):

Liquid Minerals Group, Inc.
PO Box 1700 CHEMTREC: 800-424-9300 (US)
New Waverly, TX 77358 703-527-3887 (International)

For information call (936) 291-2424
Preparer: S. D. Smith Date of Last Revision: 06/01/2008
Title: Regulatory Info Group Supercedes MSDS Dated: 07/23/2007

SECTION 2 ?COMPOSITION/INFORMATION ON INGREDIENTS
ITEM HAZARDOUS INGREDIENTS CAS# WT/WT %
01 Magnesium carboxylates 67701-23-9 50-80
02 Heavy Aromatic Naphtha 64742-94-5 10-20
03 Hydrocarbon resin Trade Secret 1-5
04 Naphthalene 91-20-3 0.1 ?1
ITEM ACGIH OSHA COMPANY SKIN
TLV-TWA TLV-STEL PEL-TWA PEL-STEL TLV-TWA
01 N.A. N.A. N.A. N.A. N.E. N
02 N.A. N.A. N.A. N.A. N.E. N
0.5 mg/m3
03 N.A. N.A. N.A. N.E. N
52 mg/m3 hour(s) 79 mg/m3 15 minute(s) 50 mg/m3 8 hour(s) 75 mg/m3 15 minute(s) N.E.
04 N
LEGEND: N.A.: Not available (C): Ceiling Point
N.E.: Not Established Y: Skin absorption is significant to overall exposure
N.D.: Not Determined N: Skin absorption is not significant

SECTION 3 ?HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD CLASSIFICATIONS:

Flammability
2
Reactivity
Health 2 0

Special Hazard


APPEARANCE: Dark gray color liquid ODOR: Hydrocarbon odor

SIGNIFICANT HAZARDS: None determined

COMBUSTIBLE liquid and vapor. Skin and eye irritant. May cause irritation to the respiratory tract. Contains a material which
can cause liver and kidney damage. Contains a material which can cause nervous system effects. Contains a material which may
cause embryo/ferotoxicity based on animal data. Contains a material which may cause effects to the blood and/or bone marrow.

Page 1 of 6
?br> Product Name: LMG-30B Date of Last Revision: 06/01/2008

SECTION 3 ?HAZARDS IDENTIFICATION ?CONTINUED

POTENTIAL HEALTH EFFECTS

EYE CONTACT:
Direct eye contact may cause irritation.

SKIN CONTACT:
Prolonged and repeated skin contact may cause irritation and possibly dermatitis. Repeated skin contact may produce an allergic
sensitization. In such cases, incidental (minor) contact may cause allergic rashes. Sunlight will aggravate or cause irritation
to skin exposed to a component(s) of this product.

INHALATION:
Prolonged, repeated or high exposures may cause irritation to the respiratory m= (nose, mouth, mucous membranes). Prolonged,
repeated or high exposures may cause pneumonitis and in extreme case, pulmonary edema. Prolonged, repeated or high exposures
may cause central nervous system depression leading to headaches, nausea, drowsiness dizziness and possibly narcosis. In extreme
cases, may cause loss of consciousness.

INGESTION:
Harmful if swallowed. May cause severe gastrointestinal disturbance with headache, nausea vomiting and diarrhea Aspiration into
lungs may cause pulmonary chemical pneumonitis. May be readily absorbed through the gastrointestinal tract.

CHRONIC EFFECTS:
Ingestion or inhalation of a large quantity of magnesium oxide may cause a feverish reaction and leukocytosis.

CARCINOGENICITY:
From skin-painting studies of petroleum distillates of similar composition and distillate range, it has been shown that these types of
materials often possess weak carcinogenic activity in laboratory animals. In these tests the material is painted on the shaved backs
of mice twice a week for their lifetime. The material is not washed off between applications. Therefore, there may be a potential
risk of skin cancer from prolonged or repeated skin contact in the absence of good personal hygiene.


SECTION 4 ?FIRST AID MEASURES

EYES:
If material gets into eyes, flush with water immediately for 15 minutes. Consult a physician.

SKIN:
In case of contact, wash skin immediately with soap and water. If rash or irritation develops, consult a physician. Launder clothing
before reuse.

INHALATION:
If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a physician if symptoms persist or exposure was severe.

INGESTION:
Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested. Have die victim drink 8 to 10 ounces (240 - 300 ml)
of water to dilute the material in the stomach. Never give anything by mouth to an unconscious person. If vomiting occurs
naturally, have the victim lean forward to reduce the risk of aspiration into the lungs. Consult a physician immediately.


NOTE TO PHYSICIAN

NOTE TO PHYSICIAN:
Administer activated carbon if indicated.




Page 2 of 6
?br> Product Name: LMG-30B Date of Last Revision: 06/01/2008

SECTION 5 ?FIRE-FIGHTING MEASURES

Flashpoint and Method: 66 C (150 F) SFCC ASTM D-3828 Autoignition Temperature: N.D.

Flammable Limits: LEL: N.D. UEL: N.D.

HAZARDOUS COMBUSTION PRODUCTS:
Carbon monoxide. Carbon dioxide

UNUSUAL FIRE AND EXPLOSION HAZARDS:
Combustible liquid. At elevated temperatures, vapors can form an ignitable mixture with air. Vapors can flow along surfaces to
distant ignition sources and flash back.

EXTINGUISHING MEDIA: CO2, Dry Chemical. Foam, Water Fog

FIRE-FIGHTING INSTRUCTIONS:
Use a self-contained breathing apparatus with full face piece operated in pressure demand or other positive pressure mode.
Combustible. Cool fire-exposed containers using water spray.


SECTION 6 ?ACCIDENTAL RELEASE MEASURES
LEAKS OR SPILLS:
Use personal protective equipment as necessary. Absorb with suitable chemical absorbent. Dispose of material in accordance with
all federal, state and local regulations. Dike to prevent entering any sewer or waterway. Transfer liquid to a holding container.

OTHER:
No known information.

Refer to Section 15 for regulatory reporting requirements in the event of an accidental release.


SECTION 7 ?HANDLING AND STORAGE
HANDLING AND STORAGE:
Combustible liquid. Avoid heat, sparks and open flames. Avoid breathing vapor and contact with eyes, skin and clothing. Keep
container closed when not in use. Use in well ventilated area.


SECTION 8 ?EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT (PPE):
Chemical resistant gloves and chemical goggles should be used to prevent skin and eye contact.

RESPIRATORY PROTECTION:
When concentrations exceed nuisance levels, use appropriate NIOSH-approved respirator. In extreme cases a Self Contained
Breathing Apparatus (SCBA) may be necessary.


SECTION 9 ?PHYSICAL AND CHEMICAL PROPERTIES
Solubility in Water: Insoluble ph @ 5.0% in water: N.D.
Density @ 60 F (16 C): 11.5 ?12.3 lb/USgal Evaporation Rate: Is slower than Ether
Boiling Point ASTM D-86: N.D. Vapor Density: Is heavier than air
Physical Slate: Liquid Vapor Pressure: N.D.


Page 3 of 6
?br> Product Name: LMG-30B Date of Last Revision: 06/01/2008

SECTION 10 ?STABILITY AND REACTIVITY
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.

INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID:
Keep away from strong oxidizing agents, heat and open flames.

HAZARDOUS DECOMPOSITION PRODUCTS:
No known information.


SECTION 11 ?TOXICOLOGICAL INFORMATION
PRODUCT TOXICOLOGICAL INFORMATION
NAPHTHALENE:

This product contains naphthalene. The International Agency for Research on Cancer evaluated naphthalene and concluded that
there was sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in exposed humans.
Accordingly, IARC classified naphthalene as a possible human Carcinogen (Group 2B). The US National Toxicology Program
(NTP) has evaluated naphthalene and found that it may be reasonably anticipated to be a human carcinogen.

OTHER:
No known information

COMPONENT TOXICOLOGICAL INFORMATION:
Component LD 50 Dermal LD 50 Oral LC 50 Inhalation
Magnesium carboxylates N.D. N.D. N.D.
Heavy Aromatic Naphtha Acute: >2000 mg/kg [RB] Acute: >2000 mg/kg [R] N.D.
3200 mg/kg [R]
Hydrocarbon resin N.D. N.D. N.D.
Naphthalene Acute: >20000 mg/kg [RB] Acute: 490 mg/kg [R] N.D.
2600 mg/kg [R]

LEGEND: R = Rat SKIN AND EYE SCORE: 1 = No Effect / Slight Irritant
RB = Rabbit 2 = Moderate Irritant
M = Mouse 3 = Strong Irritant
GP = Guinea Pig 4 = Skin: Extreme Irritant: Eye: Extreme Irritant/Corrosive


SECTION 12 ?ECOLOGICAL INFORMATION

OTHER:
No known information.




SECTION 13 ?DISPOSAL INFORMATION

DISPOSAL INFORMATION:
Responsibility for proper waste disposal rests with the generator of the waste. Dispose of any waste material in accordance with
applicable regulations. Note that these regulations may also apply to empty containers, liners, and rinsate. Processing, use,
dilution, or contamination of this product may cause its physical and chemical properties to change.




Page 4 of 6
?br> Product Name: LMG-30B Date of Last Revision: 06/01/2008

SECTION 14 ?TRANSPORTATION INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION (D.O.T.) INFORMATION
Proper Shipping Name: Combustible liquid, n.o.s (contains Aromatic naphtha and Naphthalene) NA1993 III
D.O.T. Emergency Response Guide: 128 Marine Pollutant N.A.

NON-REGULATED when shipped in containers less than
110 US gallons.

INTERNATIONAL MARITIME ORGANIZATION INFORMATION
Proper Shipping Name: NOT REGULATED by I.M.0. III
IMDG Code Page: N.A. EMS Number: N.A.
MFAG Table Number 1: N.A. MFAG Table Number 2: N.A.
Marine Pollutant: N.A.


SECTION 15 ?REGULATORY INFORMATION
CERCLA HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES:
This Liquid Minerals Group product contains the following components that are subject to the release reporting requirements of the
Comprehensive Environmental Response Compensation and Liability Act. Also listed is the Reportable Quantity (RQ) in pounds for
each such component and the amount of product, in gallons, that must he released or spilled in order to exceed the RQ.

Chemical Name: CAS Number RQ# RQ GAL
Naphthalene 91-20-3 100 1040


SARA TITLE III:
This Liquid Minerals Group product contains the following components that are identified an extremely hazardous substances by the
Superfund Amendments and Reauthorization Act. Also listed is the Reportable Quantity (IQ) in pounds for each such component
and the amount of product, in gallons, that must be released or spilled in order to exceed the RQ; and the Threshold Planning Quantity
(TPQ) in pounds for each such component and the amount of product in gallons that contains the TPQ.

Chemical Name: CAS Number RQ (lbs.) RQ (gal) TPO (lbs) TPO (gal)
No SARA Extremely Hazardous Substances are present in this material.

Liquid Minerals Group has determined that under Sections 311/312 of SARA Title III, the following hazard categories apply to this
product:

Hazard: Immediate Health, Fire.

SARA SECTION 313:
This Liquid Minerals Group product contains the following components that are subject to the annual toxic release inventory reporting
requirements of Section 313 of SARA Title III. Also listed is the concentration of the component in weight percent, in the product. A
component is not listed if its concentration is less than the de minimis level.

Chemical Name CAS Number
Naphthalene 91-20-3




Page 5 of 6
?br> Product Name: LMG-30B Date of Last Revision: 06/01/2008


TOXIC SUBSTANCES CONTROL ACT (TSCA):
This product or its components, if a mixture, are listed on the TSCA inventory.

This Liquid Minerals Group product contains the following components that are subject to the reporting requirements of TSCA
Section 12(b) if exported from the United States.

Chemical Name CAS Number
Trimethylbenzene (C-9 Aromatic/Sec. 4) 95-63-6

SIGNIFICANT NEW USE RULES (SNUR):
This product does not contain any components that are subject to a Significant New Use Rule (SNUR).

PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at greater 3%:

Chemical Name CAS Number
No hazardous ingredients are present in the product at greater than 3%.


INTERNATIONAL REGULATIONS

CANADA All components are compliant with or are exempted from listing on the Canadian Domestic Substance List.

EUROPEAN All components are included on or are exempted from listing on the European Inventory of Existing Commercial
UNION Chemical Substances or the European List of Notified Chemical Substances.




SECTION 16 ?OTHER INFORMATION
NFPA HAZARD CLASSIFICATIONS:
Health: 2 Flammability: 2 Reactivity: 0 Special: N.A.

REVISION HISTORY:
06/01/2008 - New format




The information and recommendations contained hereon are believed to be accurate and reliable as of the date issued. However, we
do not warrant their accuracy or reliability.

We only warrant to you, but no other persons, that the product referenced herein shall conform to our quality assurance specifications
for the product on the date of shipment to you. WE EXPRESSLY DISCLAIM ALL OTHER WARRANTIES, EXPRESS OR
IMPLIED INCLUDING THE IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR
PURPOSE. Any technical advice, information or recommendation given to you is given gratis without any warranty whatsoever as to
the advice, information or recommendation given or results obtained.

You shall assume all risks and shall be solely responsible for the results obtained from the storage, handling or use of the product and
any information or recommendation regarding the product, whether alone or in combination with other substances.

UNDER NO CIRCUMSTANCES SHALL WE BE LIABLE FOR ANY ECONOMIC, CONSEQUENTIAL (INCLUDING LOST
PROFITS OR SAVINGS) OR INCIDENTAL DAMAGES, EVEN IF WE ARE INFORMED OF THEIR POSSIBILITY,
EXEMPLARY OR PUNITIVE DAMAGES, REGARDLESS OF THE FORM OR ACTION, WHETHER IN CONTRACT OR
TORT, INCLUDING OUR SOLE OR JOINT NEGLIGENCE AND STRICT LIABILITY.
Page 6 of 6

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