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4
CAS# 1333-86-4
Carbon Black
PCT BY WT: 1.8970
EXPOSURE LIMIT:
ACGIH TLV/TWA: 3.5 mg/M3
OSHA PEL/TWA: 3.5 mg/m3
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5
CAS# 91-20-3
Naphthalene
PCT BY WT: 1.5130 VAPOR PRESSURE: .010 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 10. ppm
OSHA PEL/TWA: 10. ppm
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6
CAS# 95-63-6
Pseudocumene
PCT BY WT: < 5.0 VAPOR PRESSURE: 10.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 25. ppm
OSHA PEL/TWA: 25. ppm
LC50: 18g/m3 (Rat-4H, inh.)
LD50: 5g/kg (Rat-Oral)
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SECTION 3 - HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW:
Primary routes of exposure- inhalation, eye contact and skin contact.
POTENTIAL HEALTH EFFECTS:
EYE:
Liquid and aerosols of this product are irritating and can cause tearing,
reddening, swelling and stinging of the eyes.
SKIN:
Excessive skin contact may cause irritation and redness.
INHALATION:
Excess inhalation may result in headaches, nausea, lung irratation, and
narcosis.
INGESTION:
Moderately toxic by ingestion (unless noted below).
CHRONIC EFFECTS:
Reports have associated repeated and prolonged occupational overexposure
to solvents with permanent brain and nervous system damage.
CARCINOGENICITY:
No Carcinogenic properties known unless noted below. (Note: Items may not
appear in Section 2 above if present in trace amounts only.)
Contains Carbon Black pigment which is listed by IARC as an animal
carcinogen based on the long term, high concentration inhalant exposure of
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JONES BLAIR COMPANY
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MATERIAL SAFETY DATA SHEET
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rats. Other animal testing (mice and hamsters) was negative and there is
inadequate evidence with respect to humans. IARC has designated Carbon
Black as a "Group 2B" or as a "possible" human carcinogen.
Contains low levels of Formaldehyde; which is listed by IARC & NTP as a
suspect carcinogen. There is no current supporting evidence beyond animal
testing that it may cause cancer in humans. Due to the low concentration,
there should be minimal risk with adequate ventilation. See section 8.
Contains low levels of Polyaromatic Hydrocarbons which have been shown to
cause cancer and respiratory damage in laboratory animals.
Contains ethylbenzene which has been classified as possibly carcinogenic
to humans (Group 2B) on the basis of experimental animal studies, while
there is inadequate evidence to show carcingenicity for humans.
Contains solid materials: When subjected to operations such as milling,
sawing or sanding of the cured coating, the resultant dust constitutes a
hazardous dust of the non-volatile noted in Section 2.
TARGET ORGANS:
No Specific data available unless noted below.
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SECTION 4 - FIRST AID MEASURES
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EYE CONTACT:
Flush eyes with water for 15 minutes. If irritation persists, consult
a physician.
SKIN CONTACT:
Wipe area off and wash affected skin areas thoroughly with soap and
water.
Promptly remove contaminated clothing and wash before reuse.
INHALATION:
Move subject to fresh air.
INGESTION:
If ingested, do not induce vomiting. Consult a physician immediately.
NOTE TO PHYSICIAN:
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SECTION 5 - FIRE FIGHTING MEASURES
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FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL:
Containers may rupture due to very high temperature induced pressure.
Flashpoint . . . . . . . . . . . . . : 83.0
Explosion Level . . . . . . . . . . . : Low - .9
High - 7.0
EXTINGUISHING MEDIA:
Foam, CO2, dry chemical, or sand
FIRE-FIGHTING PROCEDURES AND EQUIPMENTS:
General procedures recommended. Avoid the use of water.
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MATERIAL SAFETY DATA SHEET
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
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CLEAN-UP:
Eliminate any ignition sources.
Evacuate nonessential personnel. Ventilate the area of spill. Put on
required personal protective equipment (see section 8). Dike or impound
spilled material and cover with inert absorbant material. Shovel or sweep
into a disposable container. See section 13. See section 15 for SARA
information.
CONTAINMENT:
Dike with inert absorbant material.
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SECTION 7 - HANDLING AND STORAGE
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HANDLING:
Keep containers tightly closed.
STORAGE:
Store in protected area.
SPECIAL COMMENTS:
Ideal storage temperature range for ease of handling is 50F to 85F.
Wash hands thoroughly with soap and water after handling as a standard
hygienic practice.
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SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
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EYE PROTECTION:
Face shield or goggles. Do not wear contact lenses.
RESPIRATORY PROTECTION:
Provide adequate ventilation (see below). For confined areas or when using
spray application, wear appropriate, properly fitted respirator (NIOSH/MESA
approved) during and after application unless air monitoring demonstrates
vapor/mist levels below applicable limits. Follow respirator manufacture's
directions for respirator use.
SKIN PROTECTION:
Wear solvent resistant gloves.
Wear gloves, boots and aprons.
ENGINEERING CONTROLS:
Adequate ventilation in volume and pattern should be provided to keep
vapor concentration below LEL and TLV limits. If spray applied,
respiratory protection is mandatory.
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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Boiling Range . . . . . . . . . . . . : Lower - 275.0
Higher - 425.0
Evaporation Rate . . . . . . . . . . : .800 (n-Butyl Acetate = 1)
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MATERIAL SAFETY DATA SHEET
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Melting Point . . . . . . . . . . . . : -N/A
Mechanical Impact Explosion . . . . . : -N/A
Odor . . . . . . . . . . . . . . . . : -N/A
Odor Threshold . . . . . . . . . . . : -N/A
pH . . . . . . . . . . . . . . . . . : -N/A
Vapor Density . . . . . . . . . . . . : 4.80
Vapor Pressure . . . . . . . . . . . : 10.00
VOC (lbs/gal) . . . . . . . . . . . . : 6.129
Volatile by Volume (%). . . . . . : 84.3681
Volatile by Weight (%). . . . . . : 78.8269
Water Solubility . . . . . . . . . . : -N/A
Wt/Gl . . . . . . . . . . . . . . . . : 7.7748 LB/GL
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SECTION 10 - STABILITY AND REACTIVITY
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INCOMPATIBILITIES:
Strong oxidizing materials.
DECOMPOSITION:
When heated, vapors given off are primarily organic acids and thermal
decomposition products including carbon dioxide,carbon monoxide and mixed
hydrocarbons.
CONDITIONS TO AVOID:
Heat, sparks and open flames.
POLYMERIZATION:
Will not occur (unless noted below).
STABILITY:
This material is stable.
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SECTION 11 - TOXICOLOGICAL INFORMATION
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EYE EFFECTS:
Vapors and mists of this product are irratating to the eyes.
SKIN EFFECTS:
Excessive skin contact may cause irritation and redness.
ORAL EFFECTS:
Toxic by ingestion.
INHALATION EFFECTS:
Excess inhalation may result in headaches, nausea, lung irratation, and
narcosis.
OTHER:
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SECTION 12 - ECOLOGICAL INFORMATION
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ECOTOXICOLOGICAL INFORMATION:
ENVIRONMENTAL FATE:
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JONES BLAIR COMPANY
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MATERIAL SAFETY DATA SHEET
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SECTION 13 - DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL:
Waste must be disposed of in accordance with federal, state, and local
environmental control regulations. Incineration is the preferred method.
Do not heat or cut empty containers with electric or gas torch.
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SECTION 14 - TRANSPORT INFORMATION
---------------------------------------------------------------------------
This section provides basic shipping classification information and does
not contain all regulatory transportation details. Refer to all applicable
regulations for domestic, international, air, vessel and ground
transportation requirements and restrictions.
DOT HAZARD CLASS:
3
DOT SHIPPING NAME:
Adhesive
DOT PACKING GROUP: III
UN/NA NUMBER:
UN 1133
International Shipment or Air DOT:
Same as above.
OTHER:
Not Regulated for non-bulk packaging of 450 liters (119 gallons) or
less (DOT 49CFR 173.150(f)).
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SECTION 15 - REGULATORY INFORMATION
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FEDERAL REGULATIONS:
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning and
Community Right-To-Know Act of 1986 and of 40 CFR 372:
Ethyl Benzene
CAS# 100-41-4 PCT BY WT: 8.0090
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Xylene
CAS# 1330-20-7 PCT BY WT: 48.6240
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Naphthalene
CAS# 91-20-3 PCT BY WT: 1.5130
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Pseudocumene
CAS# 95-63-6 PCT BY WT: < 5.0
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This product is not a marine pollutant. This product is not manufactured
with and does not contain ozone depleting substances(unless noted below).
All ingredients used to manufacture this product are TSCA listed.
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MATERIAL SAFETY DATA SHEET
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Based on the presence of components (02)
which is/are the subject of a TSCA section 4 test rule, a section 5 SNUR
or a section 6 Risk Management Rule. Export of such subject materials
requires that a section 12(b) notice be given to EPA by the exporter.
(See 40 CFR Chapter 1, Part 707, subpart D, Sections 707.60, 707.65
and 707.67).
Based on the presence of components (01,**,03,05)
contains reportable HAPS
STATE REGULATIONS:
Based on the presence of components (01)
Subject to the reporting requirements under California's Proposition 65
in that this product contains Ethylbenzene which appears on the
California Safe Drinking Water and Toxics Enforcement Act List of
chemicals known to cause cancer.
Based on the presence of components (04)
Subject to the reporting requirements under California's Proposition 65
in that this product contains carbon black which appears on the
California Safe Drinking Water and Toxics Enforcement Act List of
cancer causing agents.
Based on the presence of components (05)
Subject to the reporting requirements under California's Proposition 65
in that this product contains naphthalene which appears on the
California Safe Drinking Water and Toxics Enforcement Act List of
cancer causing agents.
Due to the presence of some component(s) (**)
Subject to the reporting requirements under California's Proposition 65
in that this product contains toluene which appears on the
California Safe Drinking Water and Toxics Enforcement Act List of
known reproductive toxins.
Due to the presence of some component(s) (**)
Subject to the reporting requirements under California's Proposition 65
in that this product contains a trace of a chemical(s) which appear on the
California Safe Drinking Water and Toxics Enforcement Act List of
known reproductive toxins or cancer causing agents.
Based on the presence of components (**,03)
Subject to the reporting requirements under California's Proposition 65
in that this product contains a trace of benzene which appears on the
California Safe Drinking Water and Toxics Enforcement Act List of
cancer causing and reproductive toxicity agents.
INTERNATIONAL REGULATIONS:
All ingredients in this product comply with the New Substances
Notification Requirements under the Canadian Enviromental Protection Act
(CEPA).
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SECTION 16 - OTHER INFORMATION
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Prepared by . . . . . . . . . . . . . :
Date of issue . . . . . . . . . . . . : 08/24/2004
Last Revision Date . . . . . . . . . : NONE
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JONES BLAIR COMPANY
8510
MATERIAL SAFETY DATA SHEET