Manus Products, Inc. MANUS-BOND 65-C
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT IDENTIFICATION
Brand Name............................................ MANUS-BOND 65-C
Product Use ............................................ Adhesive / Sealant
Product Identification Number ............... UN 1133
MANUFACTURER EMERGENCY TELEPHONE NUMBER
Manus Products, Inc. CHEMTREC: 800-424-9300
866 Industrial Blvd West
Waconia, MN 55387 Plant Telephone: 952 442-3323
2. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAMEMichael J. Reale Pag CAS NUMBER WEIGHT %
Petroleum naphtha 64742-95-6 <60
Carbon Black 1333-86-4 <1
Titanium Dioxide 13463-67-7 <10
Proprietary non-hazardous ingredients Mixture Balance
See Section 15 of this MSDS for OSHA Regulatory Status
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Thick grey paint with petroleum odor.
Warning - Flammable liquid and vapor. Breathing vapors can cause dizziness, drowsiness,
anesthesia, unconsciousness or other central nervous system effects. May cause skin and eye
irritation. In case of fire, use foam, dry chemical, CO2.
POTENTIAL HEALTH EFFECTS
PRIMARY ROUTE(S) OF ENTRY
Inhalation (breathing); eye and skin contact.
SYMPTOMS OF EXPOSURE
Inhalation: Breathing vapors can be irritating to the respiratory tract. High concentrations can result in
dizziness, drowsiness, anesthesia, unconsciousness or other central nervous system effects.
Eye Contact: Vapors cause eye irritation. Liquid can cause slight irritation, but does not injure eye tissue.
Skin Contact: Can cause loss of natural oils, dermatitis. Symptoms may include redness, drying and cracking of
skin.
Ingestion: Aspirating small amount of this material into the lungs as a result of ingestion or vomiting can
cause mild to severe lung injury, possibly progressing to death.
MANUS-BOND 65-C Page 1 of 6
CHRONIC EFFECTS
Frequent or prolonged contact may cause dermatitis.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Eye or skin disease, breathing or respiratory disorders. Intentional misuse by deliberately concentrating and
inhaling vapors can be harmful or fatal.
REPORTED AS CARCINOGEN OR POTENTIAL CARCINOGEN
Not Applicable OSHA
3 International Agency for Research on Cancer (IARC)
National Toxicology Program (NTP)
(See Section 11)
4. FIRST AID MEASURES
Inhalation: Remove from area to fresh air. If not breathing, clear airway and start mouth-to-mouth
artificial respiration or use a bag-mask respirator. Get immediate medical attention. If
victim is having trouble breathing, transport to medical care and, if available, give
supplemental oxygen.
Eye contact: Hold eye open and flush slowly and gently with plenty of water for several minutes. Remove any
contact lenses, and continue flushing for several more minutes. Seek medical attention if irritation
develops and persists.
Skin Contact: Wash affected areas with plenty of water, and soap if available, for several minutes. Seek medical
attention if irritation develops and persists.
Ingestion: DO NOT induce vomiting. Do not give anything by mouth to an unconscious or convulsing
person. Get immediate medical attention.
NOTE TO PHYSICIAN
Chemical of exposure is petroleum naphtha. Small amounts aspirated during ingestion or vomiting can cause
chemical pneumonitis.
5. FIRE FIGHTING MEASURES
Flash Point and Method............. 108 癋. (Petroleum naphtha)
GENERAL HAZARD
This product and its vapors are flammable. Explosive in a contained area. Vapors are heavier than air and may
travel along the ground or may be moved by ventilation. Vapors may be ignited by open flames, sparks, heaters,
smoking, electric motors or other sources of ignition distant from use.
EXTINGUISHING MEDIA
For small fires, use foam, CO2, or dry chemical. For large fires, use water spray, fog, or foam.
SPECIAL FIREFIGHTING INSTRUCTIONS
Move containers from area if it can be done without risk.
MANUS-BOND 65-C Page 2 of 6
FIREFIGHTING EQUIPMENT
As in any fire, wear NIOSH approved, positive-pressure self-contained breathing apparatus and full protective
gear.
6. ACCIDENTAL RELEASE MEASURES
Wear appropriate protective equipment (See Section 8). Remove all sources of ignition. Ventilate area.
7. HANDLING AND STORAGE
HANDLING
Wear appropriate protective equipment (See Section 8). Avoid breathing vapors. Keep container closed when not
in use. Use with sufficient ventilation to keep area below established exposure levels. Wash thoroughly after
handling.
Product and product vapors are flammable. Keep away from heat, sparks and flame.
STORAGE
Keep container tightly closed. Store in a flammable material area. Isolate from incompatible materials (see
Section 10).
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS
Use local exhaust or general dilution ventilation system.
PERSONAL PROTECTION
Respirator: Use NIOSH approved equipment only. For exposure above the established limits, use a
respirator that has been selected by an industrial hygienist or other technically qualified
person for the specific work conditions. If respirators are used, OSHA requires compliance
with its Respiratory Protection standard (29 CFR 1910.134).
Eye Protection: Wear vented safety goggles.
Gloves: Wear chemical resistant gloves.
Clothing: Wear clothing that will protect the skin from exposure to this chemical. During emergency or
while making repairs, wear clothing that will not allow this chemical to penetrate.
Other: Eye wash; safety shower.
EXPOSURE CONTROLS
COMPONENT OSHA PEL ACGIH TLV
TWA STEL TWA STEL
Carbon Black* 3.5 mg/m3 N/E 3.5 mg/m3 N/E
Petroleum Naphtha N/E N/E N/E N/E
Trimethyl benzene N/E N/E 25 ppm N/E
Xylene 100 ppm N/E 100 ppm 150 ppm
Titanium Dioxide* 15 mg/m3 N/E 10 mg/m3 N/E
MANUS-BOND 65-C Page 3 of 6
* Exposure limits are provided for information only. These chemicals are not in a respirable form in this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
State .....................................Thick paint
Color....................................Grey
Odor.....................................Petroleum
Melting Point 癋 ..................>300
Boiling Point .......................N/E
Vapor Density......................Heavier than air
Reactivity in Water..............Negligible
Density.................................8.29 pounds/gallon
Water Solubility ..................Negligible
pH ........................................NA
10. STABILITY AND REACTIVITY
REACTIVITY
Stable.
INCOMPATIBILITIES
Avoid contact with strong acids and oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
May form oxides of carbon and various unidentified organic compounds.
CONDITIONS TO AVOID
Avoid temperatures above 120 癋.
11. TOXICOLOGICAL INFORMATION
For Product: No information for product
For Carbon Black: IARC ?Group 2B (Possibly carcinogenic to humans)
For Titanium Dioxide
Trochimowicz, et al., J. Appl. Tox., 8, 383-385 (1988).
Oral LD50 (rat) >25 g/kg
Dermal LD50 (rabbit) >10 g/kg
Inhalation LC50 (rat) >6.82 mg/l (4 hr)
E.I. DuPont's Haskel Toxicology Laboratory conducted lifetime inhalation studies of respirable titanium dioxide
at levels up to 250 mg/m3; no compound related clinical signs of toxicity were seen in the exposed animals. Slight
pulmonary fibrosis was seen at 50 to 250 mg/m3 respirable titanium dioxide but not at 10 mg/m3. There was no
evidence of cancer in animals exposed to 10 or 50 mg/m3 respirable titanium dioxide. Microscopic lung tumors
were seen in 17 percent of the rats exposed to 250 mg/m3 respirable titanium dioxide. The lung tumors observed
in the rats were different from common human lung cancers, relative to anatomic type and location, and occurred
only at dust levels which overwhelmed the animals lung clearance mechanism and therefore, are of questionable
biological relevance for man.
MANUS-BOND 65-C Page 4 of 6
Results of a DuPont epidemiology study showed that employees who had been exposed to titanium dioxide
pigments were at no greater risk of developing lung cancer than were employees who had not been exposed to
titanium dioxide pigments. No pulmonary fibrosis was found in any of the employees and no associations were
observed between titanium dioxide pigment exposure and chronic respiratory disease or lung abnormalities.
Based on the results of this study, DuPont concluded that titanium dioxide pigment will not cause lung cancer or
chronic respiratory disease in humans at concentrations experienced in the workplace.
The National Cancer Institute (NCI) conducted a feed study in rats and mice in which either 25,000 or 50,000
parts per million titanium dioxide was given in their diet for two years. Under the condition of the NCI test,
titanium dioxide did not cause cancer by the oral route.
Titanium dioxide has been classified by the American Congress of Governmental Industrial Hygienists (ACGIH)
as an A4 Carcinogen - Not Classifiable as a Human Carcinogen. ("1999 TLVs and BEIs," p. 67). It has been
classified by the International Agency for Research on Cancer (IARC) as Group 3 - Not Classifiable as to Its
Carcinogenicity to Humans. (IARC Monograph 47, 1989).
12. ECOLOGICAL INFORMATION
For Product: ............... No information for Product
13. DISPOSAL CONSIDERATIONS
RCRA Waste Code:..........................D001.
Do not allow material to enter sewer systems. This product , including spill cleanups, is prohibited from land
disposal without prior treatment; see 40 CFR 268.40 for guidance.. Observe all applicable federal, state, and local
regulations.
14. TRANSPORT INFORMATION
DOT Hazard Class............................Not regulated when shipped by ground in non-bulk quantities.
15. REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200)
3 Hazardous Non-Hazardous
CERCLA/SUPERFUND (40 CFR 117, 302)
Chemical Name RQ (lbs)/(kg)
Xylene 100 lb. / 45.4 kg
SARA EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355)
Chemical Name TPQ (lbs) RQ (lbs)
N/A N/A N/A
SARA HAZARD CATEGORIES (40 CFR 370)
3 Acute 3 Chronic 3 Fire Pressure Reactive None
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SARA TOXIC CHEMICALS (40 CFR 372)
Chemical Name CAS Number %
1,2,4-Trimethylbenzene 95-63-6 <25
Xylene 1330-20-7 <5
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (CPR Section (33))
This product has been classified according to the hazard criteria of the Controlled Products Regulations, and the
MSDS contains all required information.
3 Controlled Product; Classification: B2, D2A, D2B Not a Controlled Product
INVENTORY STATUS
The ingredients of this chemical are listed on the US TSCA Chemical Substance Inventory and the Canadian
Domestic Substances List.
TOXIC SUBSTANCES CONTROL ACT
No specific regulations apply.
STATE REGULATIONS
California Proposition 65 ..............................Traces of Formaldehyde
Florida Hazardous Substance List .................Xylene
Massachusetts Right to Know List ................Xylene, 1,2,4-trimethylbenzene, Carbon Black, Titanium Dioxide
Minnesota Hazardous Substance List............Xylene, Carbon Black, Titanium Dioxide
New Jersey Right to Know List.....................Xylene (SN 2014), 1,2,4-trimethylbenzene (SN 2716), Carbon Black
(SN 0342), Titanium Dioxide (SN 1861)
Pennsylvania Right to Know List..................Xylene, 1,2,4-Trimethylbenzene, Carbon Black, Titanium Dioxide
Rhode Island Hazardous Substance List .......Xylene, Carbon Black, Titanium Dioxide
16. OTHER INFORMATION
ABBREVIATIONS
C - Ceiling limit
LCLo - The lowest concentration of a substance in air that will kill a test animal within a certain exposure period.
LC50 - The concentration of a substance in air that will kill 50% of test animals within a certain exposure period.
LD50 - The dose that causes death in 50% of test animals.
N/A - Not applicable
N/D - Not determined
N/E - Not established
N/K - Not known
NAERG - North American Emergency Response Guidebook
RQ - Reportable Quantity
TPQ - Threshold Planning Quantity
PREPARATION INFORMATION
Prepared by: ................. Manus Chemical Safety and Health Department
MSDS No.: ................... MANUS-BOND 65-C
Date Prepared: .............. November 11th, 2009
Date of Issue: ............... November, 2009
Superceded: ..............November 2006
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