Page: 1
Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
WS 165 T-25 RESIN 682315 Version: 1.2
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Ashland Regulatory Information Number 1-800-325-3751
P.O. Box 2219 Telephone 614-790-3333
Columbus, OH 43216 Emergency telephone 1-800-ASHLAND
(1-800-274-5263)
Product name TAP Bond Coat Resin
Product code 682315
Product Use Description No data
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance: liquid
DANGER! FLAMMABLE LIQUID AND VAPOR. MAY AFFECT THE CENTRAL
NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY BE
HARMFUL. MAY CAUSE SEVERE BURNS OF RESPIRATORY AND DIGESTIVE
TRACTS. MAY BE FATAL IF SWALLOWED. MAY CAUSE ALLERGIC SKIN OR
RESPIRATORY REACTION. CAUSES SEVERE BURNS OF THE EYES AND
SKIN.
Potential Health Effects
Routes of exposure
Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion
Eye contact
Can cause permanent eye injury. Symptoms include stinging, tearing, redness,
and swelling of eyes. Can injure the cornea and cause blindness. Additional symptoms of
eye exposure may include: blurred vision
Skin contact
Can cause permanent skin damage. Symptoms may include redness, burning, and
swelling of skin, burns, and other skin damage. Individuals with direct skin contact with
methyl methacrylate have experienced temporary loss of feeling and mild nerve damage
in the fingers. Additional symptoms of skin contact may include: Blistering allergic skin
reaction (delayed skin rash which may be followed by blistering, scaling and other skin
effects) peeling of the skin
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Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
Ingestion
Swallowing this material may be harmful or fatal. Symptoms may include severe
stomach and intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and
vomiting of blood. Swallowing this material may cause burns and destroy tissue in the
mouth, throat,and digestive tract. Low blood pressure and shock may occur as a result of
severe tissue injury. This material can get into the lungs during swallowing or vomiting.
This results in lung inflammation and other lung injury.
Inhalation
Breathing of vapor or mist is possible. Breathing this material may be harmful or
fatal. Symptoms may include severe irritation and burns to the nose, throat, and
respiratory tract.
Aggravated Medical Condition
Preexisting disorders of the following organs (or organ systems) may be
aggravated by exposure to this material:, respiratory tract, skin, lung (for example,
asthma-like conditions), liver, kidney, central nervous system, Heart, thyroid, blood-
forming system, male reproductive system, auditory system, eye, Individuals with
preexisting heart disorders maybe more susceptible to arrhythmias (irregular heartbeats)
if exposed to high concentrations of this material.
Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing,
and/or passage of the material through the skin may include:, metallic taste, redness of
the skin, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat,
airways), discomfort in the chest, central nervous system excitation (giddiness, liveliness,
light-headed feeling) followed by central nervous system depression (dizziness,
drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central
nervous system effects, irritability, effects on memory, loss of appetite, sleep
disturbances, lowered blood pressure, respiratory depression (slowing of the breathing
rate), shortness of breath, loss of coordination, confusion, pain in the hands and feet,
difficult breathing, irregular heartbeat, high blood sugar, narcosis (dazed or sluggish
feeling), kidney damage, liver damage, coma, Exposure to this product (or a component)
may cause an allergic reaction (narrowing of the air passages of the lungs resulting in
difficult breathing, tightness in the chest, coughing and wheezing) in some sensitive
individuals. Other symptoms of an allergic reaction may include itchy and watery eyes,
runny and stuffy nose, sweating, flushing, hives, rapid heart rate, and lowered blood
pressure.
Target Organs
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Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
Prolonged inhalation of cobalt dust, or metal dust, fume or mist containing cobalt
may cause respiratory illness., Overexposure to cobalt compounds has been shown to
cause blood, thyroid and heart effects in man., Overexposure to this material (or its
components) has been suggested as a cause of the following effects in laboratory
animals:, blood abnormalities, liver abnormalities, anemia, nasal damage, spleen damage,
kidney damage, respiratory tract damage (nose, throat, and airways), effects on hearing,
nasal damage, testis damage, kidney damage, liver damage, Overexposure to this material
(or its components) has been suggested as a cause of the following effects in humans:,
central nervous system effects, mild effects on color vision, blood effects, blood
abnormalities, anemia, effects on hearing, respiratory tract damage (nose, throat, and
airways), central nervous system effects
Carcinogenicity
Cobalt and certain cobalt compounds have been shown to cause cancer in
laboratory animals. The relevance of this finding to humans is uncertain. Cobalt and
certain cobalt compounds are listed as carcinogenic by the International Agency for
Research on Cancer (IARC). There was no increase in cancer in rats exposed to styrene
by inhalation. However, there was an increase in lung cancer in styrene-exposed mice.
The relevance of the mouse lung cancer to humans is uncertain. Styrene did not cause
cancer in mice in studies in which the chemical was placed in the stomachs through a
feeding tube, or in a study in which styrene was given by injection. Epidemiological
studies do not provide a basis for concluding that styrene causes cancer. Styrene is listed
as a possible human carcinogen by the International Agency for Research on Cancer
(IARC). Dimethylaniline has been shown to cause cancer in laboratory animals. The
relevance of this finding to humans is uncertain. Dimethylaniline is not listed as a
carcinogen by the International Agency for Research on Cancer (IARC), the National
Toxicology Program (NTP), or the Occupational Safety and Health Administration
(OSHA). Dimethyl methylphosphonate caused an increased incidence of kidney tumors
in male rats, but not in female rats or in mice of either sex. The relevance of this finding
to humans is uncertain. Vinyl toluene is not expected to cause cancer in humans since it
did not cause cancer in laboratory animals.
Reproductive hazard
This material (or a component) may be harmful to the human fetus based on
positive test results with laboratory animals.
Other information
Styrene readily reacts with low concentrations of halogens (for example, fluorine,
chlorine, bromine, or iodine) to form a tear-producing substance.
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Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS-No. Concentration
STYRENE 100-42-5 >=50-<60%
DIVINYLBENZENE 1321-74-0 >=5-<10%
VINYL TOLUENE 25013-15-4 >=5-<10%
1-METHOXY-2-PROPANOL 107-98-2 >=1.5-<5%
METHYLMETHACRYLATE 80-62-6 >=1.5-<5%
MINERAL SPIRITS ODORLESS 8052-41-3 >=1.5-<5%
(BASE DATA)
SOLVENT NAPHTHA 64742-95-6 >=1.5-<5%
(PETROLEUM), LIGHT
AROMATIC
TRIMETHYLBENZENE 1,2,4- 95-63-6 >=1.5-<5%
XYLENE 1330-20-7 >=1.5-<5%
PROPYLENE GLYCOL 108-65-6 >=1-<1.5%
MONOMETHYL ETHER ACETATE
PARA-TERTIARY BUTYL 98-29-3 >=1-<1.5%
CATECHOL
ETHYL ACETATE 141-78-6 >=1-<1.5%
POTASSIUM 2- 3164-85-0 >=1-<1.5%
ETHYLHEXANOATE
BENZYLTRIMETHYLAMMONIUM 56-93-9 >=1-<1.5%
CHLORIDE
HYDROTREATED LIGHT 64742-55-8 >=1-<1.5%
PARAFFINIC DISTILLATE
ZINC 2-ETHYLHEXOATE 136-53-8 >=1-<1.5%
METHACRYLIC ACID 79-41-4 >=1-<1.5%
DIALLYL PHTHALATE 131-17-9 >=1-<1.5%
MONOMER
ESTER NJTS# 800986-5136P >=1-<1.5%
PENTANEDIONE 2,4 123-54-6 >=1-<1.5%
PARAFFIN WAX NJTS# 254504001-5235 >=1-<1.5%
DIETHYL ANILINE 91-66-7 >=1-<1.5%
ALPHA METHYL STYRENE 98-83-9 >=1-<1.5%
DIMETHYL 756-79-6 >=1-<1.5%
METHANEPHOSPHONATE
DIMETHYLANILINE 121-69-7 >=1-<1.5%
SILICA COLLOIDAL 112945-52-5 >=1-<1.5%
AMORPHOUS
POLYOL ESTER NJTS# 254504001-5429 >=1-<1.5%
POLYALKOXYLATE
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Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
NAPHTHOQUINONE-1,4 130-15-4 >=1-<1.5%
ETHYL VANILLIN 121-32-4 >=1-<1.5%
DIMETHYL-N,N P-TOLUIDINE 99-97-8 >=1-<1.5%
COBALT 2-ETHYLHEXANOATE 136-52-7 >=0.5-<1%
COBALT NEODECANOATE 27253-31-2 >=0.5-<1%
ETHYL BENZENE 100-41-4 >=0.1-<0.5%
COBALT HYDROXIDE 21041-93-0 >=0.1-<0.5%
NAPHTHALENE 91-20-3 >=0.1-<0.5%
4. FIRST AID MEASURES
Eyes
If material gets into the eyes, immediately flush eyes gently with water for at least
15 minutes while holding eyelids apart. If symptoms develop as a result of vapor
exposure, immediately move individual away from exposure and into fresh air before
flushing as recommended above. Seek immediate medical attention.
Skin
Immediately flush skin with water for at least 15 minutes while removing
contaminated clothing and shoes. Seek immediate medical attention. Wash clothing
before reuse and discard contaminated shoes.
Ingestion
Seek immediate medical attention. Do not induce vomiting. Vomiting will cause
further damage to the mouth and throat. If individual is conscious and alert, immediately
rinse mouth with water and give milk or water to drink. If possible, do not leave
individual unattended.
Inhalation
If symptoms develop, immediately move individual away from exposure and into
fresh air. Seek immediate medical attention; keep person warm and quiet. If person is
not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.
Notes to physician
Hazards: Inhalation of high concentrations of this material, as could occur in
enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias.
Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this
material. This material is an aspiration hazard. Potential danger from aspiration must be
weighed against possible oral toxicity (See Section 2 - Swallowing) when deciding
whether to induce vomiting.
Treatment: No information available.
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Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Dry chemical, Foam, Water spray, Carbon dioxide (CO2)
Hazardous combustion products
May form:, carbon dioxide and carbon monoxide, chlorine compounds, copper
compounds, nitrogen oxides, toxic fumes, various hydrocarbons
Precautions for fire-fighting
Material is volatile and readily gives off vapors which may travel along the
ground or be moved by ventilation and ignited by pilot lights, flames, sparks, heaters,
smoking, electric motors, static discharge or other ignition sources at locations near the
material handling point. Never use welding or cutting torch on or near drum (even empty)
because product (even just residue) can ignite explosively. During a fire, irritating or
toxic decomposition products may be generated.Wear full firefighting turn-out gear (full
Bunker gear), and respiratory protection (SCBA). Polymerization will take place under
fire conditions. If polymerization occurs in a closed container, there is a possibility it
will rupture violently. Cool storage container with water, if exposed to fire.
Flammability Class for Flammable Liquids
Flammable Liquid Class IC
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
For personal protection see section 8. Persons not wearing protective equipment
should be excluded from area of spill until clean-up has been completed.
Environmental precautions
Prevent run-off to sewers, streams or other bodies of water. If run-off occurs,
notify proper authorities as required, that a spill has occurred.
Methods for cleaning up
Absorb liquid on vermiculite, floor absorbent or other absorbent material.
7. HANDLING AND STORAGE
Handling
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Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
Containers of this material may be hazardous when emptied. Since emptied
containers retain product residues (vapor, liquid, and/or solid), all hazard precautions
given in the data sheet must be observed. Avoid prolonged or frequently repeated skin
contact with this material. Skin contact can be minimized by wearing impervious
protective gloves. As with all products of this nature, good personal hygiene is essential.
Hands and other exposed areas should be washed thoroughly with soap and water after
contact, especially before eating and/or smoking. Regular laundering of contaminated
clothing is essential to reduce indirect skin contact with this material. Static ignition
hazard can result from handling and use. Electrically bond and ground all containers,
personnel and equipment before transfer or use of material. Special precautions may be
necessary to dissipate static electricity for non-conductive containers. Use proper bonding
and grounding during product transfer as described in National Fire Protection
Association document NFPA 77.
Storage
Store in closed containers in a dry, well-ventilated area. Do not store near extreme
heat, open flame, or sources of ignition.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
STYRENE 100-42-5
ACGIH time weighted average 20 ppm
ACGIH Short term exposure limit 40 ppm
NIOSH Recommended exposure limit 50 ppm
(REL):
NIOSH Recommended exposure limit 215 mg/m3
(REL):
NIOSH Short term exposure limit 100 ppm
NIOSH Short term exposure limit 425 mg/m3
OSHA Z2 time weighted average 100 ppm
OSHA Z2 Ceiling Limit Value: 200 ppm
OSHA Z2 Maximum concentration: 600 ppm
DIVINYLBENZENE 1321-74-0
ACGIH time weighted average 10 ppm
NIOSH Recommended exposure limit 10 ppm
(REL):
NIOSH Recommended exposure limit 50 mg/m3
(REL):
VINYL TOLUENE 25013-15-4
ACGIH time weighted average 50 ppm
ACGIH Short term exposure limit 100 ppm
NIOSH Recommended exposure limit 100 ppm
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Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
(REL):
NIOSH Recommended exposure limit 480 mg/m3
(REL):
OSHA Z1 Permissible exposure limit 100 ppm
OSHA Z1 Permissible exposure limit 480 mg/m3
1-METHOXY-2-PROPANOL 107-98-2
ACGIH time weighted average 100 ppm
ACGIH Short term exposure limit 150 ppm
NIOSH Recommended exposure limit 100 ppm
(REL):
NIOSH Recommended exposure limit 360 mg/m3
(REL):
NIOSH Short term exposure limit 150 ppm
NIOSH Short term exposure limit 540 mg/m3
OSHA Z1A time weighted average 100 ppm
OSHA Z1A time weighted average 360 mg/m3
OSHA Z1A Short term exposure limit 150 ppm
OSHA Z1A Short term exposure limit 540 mg/m3
US CA OEL Time Weighted Average (TWA) 100 ppm
Permissible Exposure Limit (PEL):
US CA OEL Time Weighted Average (TWA) 360 mg/m3
Permissible Exposure Limit (PEL):
US CA OEL Short term exposure limit 150 ppm
US CA OEL Short term exposure limit 540 mg/m3
METHYLMETHACRYLATE 80-62-6
ACGIH time weighted average 50 ppm
ACGIH Short term exposure limit 100 ppm
NIOSH Recommended exposure limit 100 ppm
(REL):
NIOSH Recommended exposure limit 410 mg/m3
(REL):
OSHA Z1 Permissible exposure limit 100 ppm
OSHA Z1 Permissible exposure limit 410 mg/m3
MINERAL SPIRITS ODORLESS 8052-41-3
(BASE DATA)
ACGIH time weighted average 100 ppm
NIOSH Recommended exposure limit 350 mg/m3
(REL):
NIOSH Ceiling Limit Value and Time 1,800 mg/m3
Period (if specified):
OSHA Z1 Permissible exposure limit 500 ppm
OSHA Z1 Permissible exposure limit 2,900 mg/m3
OSHA Z1A time weighted average 100 ppm
OSHA Z1A time weighted average 525 mg/m3
US CA OEL Time Weighted Average (TWA) 100 ppm
Permissible Exposure Limit (PEL):
US CA OEL Time Weighted Average (TWA) 525 mg/m3
Permissible Exposure Limit (PEL):
TRIMETHYLBENZENE 1,2,4- 95-63-6
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Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
NIOSH Recommended exposure limit 25 ppm
(REL):
NIOSH Recommended exposure limit 125 mg/m3
(REL):
ACGIH time weighted average 25 ppm
OSHA Z1A time weighted average 25 ppm
OSHA Z1A time weighted average 125 mg/m3
US CA OEL Time Weighted Average (TWA) 25 ppm
Permissible Exposure Limit (PEL):
US CA OEL Time Weighted Average (TWA) 125 mg/m3
Permissible Exposure Limit (PEL):
XYLENE 1330-20-7
ACGIH time weighted average 100 ppm
ACGIH Short term exposure limit 150 ppm
OSHA Z1 Permissible exposure limit 100 ppm
OSHA Z1 Permissible exposure limit 435 mg/m3
NIOSH Recommended exposure limit 100 ppm
(REL):
NIOSH Recommended exposure limit 435 mg/m3
(REL):
NIOSH Short term exposure limit 150 ppm
NIOSH Short term exposure limit 655 mg/m3
ETHYL ACETATE 141-78-6
ACGIH time weighted average 400 ppm
NIOSH Recommended exposure limit 400 ppm
(REL):
NIOSH Recommended exposure limit 1,400 mg/m3
(REL):
OSHA Z1 Permissible exposure limit 400 ppm
OSHA Z1 Permissible exposure limit 1,400 mg/m3
DIMETHYLANILINE 121-69-7
NIOSH Recommended exposure limit 5 ppm
(REL):
NIOSH Recommended exposure limit 25 mg/m3
(REL):
NIOSH Short term exposure limit 10 ppm
NIOSH Short term exposure limit 50 mg/m3
OSHA Z1 Permissible exposure limit 5 ppm
OSHA Z1 Permissible exposure limit 25 mg/m3
ACGIH time weighted average 5 ppm
ACGIH Short term exposure limit 10 ppm
SILICA COLLOIDAL AMORPHOUS 112945-52-5
Z3 time weighted average 0.8 mg/m3
ALPHA METHYL STYRENE 98-83-9
ACGIH time weighted average 50 ppm
ACGIH Short term exposure limit 100 ppm
NIOSH Recommended exposure limit 50 ppm
(REL):
NIOSH Recommended exposure limit 240 mg/m3
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Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
(REL):
NIOSH Short term exposure limit 100 ppm
NIOSH Short term exposure limit 485 mg/m3
OSHA Z1 Ceiling Limit Value: 100 ppm
OSHA Z1 Ceiling Limit Value: 480 mg/m3
ACGIH NIC time weighted average 20 ppm
METHACRYLIC ACID 79-41-4
ACGIH time weighted average 20 ppm
NIOSH Recommended exposure limit 20 ppm
(REL):
NIOSH Recommended exposure limit 70 mg/m3
(REL):
HYDROTREATED LIGHT 64742-55-8
PARAFFINIC DISTILLATE
ACGIH time weighted average 5 mg/m3 Mist.
ACGIH Short term exposure limit 10 mg/m3 Mist.
ACGIH NIC time weighted average 0.2 mg/m3 Inhalable fraction.
General advice
These recommendations provide general guidance for handling this product.
Personal protective equipment should be selected for individual applications and should
consider factors which affect exposure potential, such as handling practices, chemical
concentrations and ventilation. It is ultimately the responsibility of the employer to
follow regulatory guidelines established by local authorities.
Exposure controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to
maintain exposure below TLV(s). OSHA has formally endorsed a styrene industry
proposal for a voluntary 50 ppm workplace limit on styrene. Members of the Styrene
Information and Research Council (SIRC), Composites Institute (CI), Composite
Fabricators Association (CFA), International Cast Polymers Association (ICPA) and
National Marine Manufacturers Association (NMMA) have agreed to use either
engineering controls, work practices or respiratory protection to achieve this voluntary
limit for styrene.
Eye protection
Chemical splash goggles and face shield (8" min.) in compliance with OSHA
regulations are advised; however, OSHA regulations also permit other type safety
glasses. (Consult your industrial hygienist.) Maintain eye wash station near work area.
Skin and body protection
Wear impervious gloves (consult your safety equipment supplier).
To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Wear normal work clothing covering arms and legs.
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MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
Other protective equipment: eyewash station, emergency shower.
Wear resistant gloves such as:
polyvinyl alcohol
Respiratory protection
If workplace exposure limit(s) of product or any component is exceeded (see
exposure guidelines), a NIOSH-approved air supplied respirator is advised in absence of
proper environmental control. OSHA regulations also permit other NIOSH respirators
(negative pressure type) under specified conditions (see your industrial hygienist).
Engineering or administrative controls should be implemented to reduce exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
liquid
Physical state
No data
Form
No data
Colour
No data
Odour
No data
Boiling point/boilingrange
No data
pH
79.0 癋 / 26.1 癈
Flash point
> 1 (Ethyl Ether)
Evaporation rate
1.1 %(V) 12.5 %(V)
Explosion limits
No data
Vapour pressure
No data
Vapour density
No data
Density
No data
insoluble in water
Solubility
No data
Partition coefficient: n-
octanol/water
No data
Autoignition temperature
10. STABILITY AND REACTIVITY
Stability
This material is unstable at elevated temperatures and pressures.
Conditions to avoid
Avoid heat, open flame, and prolonged storage at elevated temperatures., Avoid
contact with:, excessive heat
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MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
Incompatible products
Avoid contact with:, acids, aluminum chloride, Amines, chlorinated rubber,
halogenated hydrocarbons, halogens, iron chloride, lithium, metal salts, perchloric acid,
peroxides, reducing agents, strong alkalis, strong bases, strong oxidizing agents, UV light
Hazardous decomposition products
May form:, carbon dioxide and carbon monoxide, chlorine compounds, copper
compounds, nitrogen oxides (NOx), toxic fumes, various hydrocarbons
Hazardous reactions
Product can undergo hazardous polymerization., Avoid exposure to excessive
heat, peroxides and polymerization catalysts.
Thermal decomposition
No data
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity
STYRENE LD 50 Rat: 2,650 mg/kg
DIVINYLBENZENE LD 50 Rat: 9.3 g/kg
VINYL TOLUENE LD 50 Rat: 2,255 mg/kg
1-METHOXY-2-PROPANOL LD 50 Rat: 7,200 mg/kg
METHYLMETHACRYLATE LD 50 Rat: 7,800 mg/kg
MINERAL SPIRITS ODORLESS LD 50 Rat: > 5 g/kg
(BASE DATA)
SOLVENT NAPHTHA (PETROLEUM), LD 50 Rat: > 5,600 mg/kg
LIGHT AROMATIC
TRIMETHYLBENZENE 1,2,4- LD 50 Rat: 6 g/kg
XYLENE LD 50 Rat: 4,300 mg/kg
PROPYLENE GLYCOL LD 50 Rat: 8,532 mg/kg
MONOMETHYL ETHER ACETATE
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MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
PARA-TERTIARY BUTYL LD 50 Rat: 2,820 mg/kg
CATECHOL
ETHYL ACETATE LD 50 Rat: 5,600 mg/kg
METHACRYLIC ACID LD 50 Rat: 1,060 mg/kg
DIALLYL PHTHALATE MONOMER LD 50 Rat: 656 mg/kg
ESTER LD 50 Rat: 1,311 mg/kg
PENTANEDIONE 2,4 LD 50 Rat: 970 mg/kg
DIETHYL ANILINE LD 50 Rat: 782 mg/kg
ALPHA METHYL STYRENE LD 50 Rat: 4,900 mg/kg
DIMETHYL LD 50 Rat: > 5,000 mg/kg
METHANEPHOSPHONATE
DIMETHYLANILINE LD 50 Rat: 951 mg/kg
SILICA COLLOIDAL AMORPHOUS LD 50 Rat: 3,160 mg/kg
POLYOL ESTER LD 50 Rat: 40,590 mg/kg
POLYALKOXYLATE
NAPHTHOQUINONE-1,4 LD 50 Rat: 190 mg/kg
ETHYL VANILLIN LD 50 Rat: 1,590 mg/kg
DIMETHYL-N,N P-TOLUIDINE LD 50 Rat: 1,650 mg/kg
ETHYL BENZENE LD 50 Rat: 3,500 mg/kg
NAPHTHALENE LD 50 Rat: 490 mg/kg
Acute inhalation toxicity
STYRENE LC 50 Rat: 2800 ppm, 4 h
VINYL TOLUENE LC 50 Mouse: 3,020 mg/m3 , 4 h
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SAFETY DATA SHEET
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MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
1-METHOXY-2-PROPANOL LC 50 Rat: > 10000 ppm, 4 h
METHYLMETHACRYLATE LC 50 Rat: 3750 ppm, 8 h
SOLVENT NAPHTHA (PETROLEUM), LC 50 Rat: > 10,200 mg/m3 , 4 h
LIGHT AROMATIC
TRIMETHYLBENZENE 1,2,4- LC 50 Rat: 18 g/m3 , 4 h
PROPYLENE GLYCOL LC 50 Rat: > 5344 ppm, 4 h
MONOMETHYL ETHER ACETATE
ETHYL ACETATE LC 50 Rat: 16000 ppm, 6 h
METHACRYLIC ACID LD 50 Rat: 7.1 mg/l , 4 h
ESTER LC 50 Rat: > 2.05 mg/l , 6 h
PENTANEDIONE 2,4 LC 50 Rat: 1224 ppm, 4 h
DIETHYL ANILINE LC 50 Rat: 1,920 mg/m3 , 4 h
ALPHA METHYL STYRENE LC Lo Rat: 3000 ppm, 4 h
DIMETHYL LD 50 Rat: > 26.1 mg/l , 4 h
METHANEPHOSPHONATE
DIMETHYLANILINE LD L0 Rat: 250 mg/m3 , 4 h
SILICA COLLOIDAL AMORPHOUS LC 50 Rat: 154 mg/m3 , 4 h
DIMETHYL-N,N P-TOLUIDINE LC 50 Rat: 1,400 mg/m3 , 4 h
ETHYL BENZENE LC Lo Rat: 4000 ppm, 4 h
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SAFETY DATA SHEET
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MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
Acute dermal toxicity
VINYL TOLUENE LD Lo Rat: 4,500 mg/kg
1-METHOXY-2-PROPANOL LD 50 Rabbit: 13,000 mg/kg
MINERAL SPIRITS ODORLESS LD 50 Rabbit: > 3 g/kg
(BASE DATA)
SOLVENT NAPHTHA (PETROLEUM), LD 50 Rabbit: > 4,000 mg/kg
LIGHT AROMATIC
XYLENE LD 50 Rabbit: > 2,000 mg/kg
PROPYLENE GLYCOL LD 50 Rabbit: > 5,000 mg/kg
MONOMETHYL ETHER ACETATE
METHACRYLIC ACID LD 50 Rabbit: 500 mg/kg
DIALLYL PHTHALATE MONOMER LD 50 Rabbit: 3.8 g/kg
ESTER LD 50 Guinea pig: > 21,400 mg/kg
PENTANEDIONE 2,4 LD 50 Rabbit: 4,875 mg/kg
ALPHA METHYL STYRENE LD Lo Rabbit: 14.6 g/kg
DIMETHYL LD 50 Rabbit: > 2,000 mg/kg
METHANEPHOSPHONATE
DIMETHYLANILINE LD 50 Rabbit: 1,692 mg/kg
NAPHTHOQUINONE-1,4 LD 50 Rat: 202 mg/kg
ETHYL BENZENE LD 50 Rabbit: 15,433 mg/kg
Page 15 / 18
Page: 16
Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
NAPHTHALENE LD 50 Rat: > 20,000 mg/kg
12. ECOLOGICAL INFORMATION
Aquatic toxicity
Acute and Prolonged Toxicity to Fish
No data
Acute Toxicity to Aquatic Invertebrates
No data
Environmental fate and pathways
No data
13. DISPOSAL CONSIDERATIONS
Waste disposal methods
For assistance with your waste management needs - including disposal, recycling
and waste stream reduction, contact Ashland Distribution's Environmental Services
Group at 800-637-7922.
14. TRANSPORT INFORMATION
CNDG:
, SHIPMENT IS FORBIDDEN 0,
MXDG:
, SHIPMENT IS FORBIDDEN 0,
TDG_ROAD:
, SHIPMENT IS FORBIDDEN 0,
TDG_RAIL:
, SHIPMENT IS FORBIDDEN 0,
TDG_INWTR:
, SHIPMENT IS FORBIDDEN 0,
RID:
, SHIPMENT IS FORBIDDEN 9,
IMDG:
Page 16 / 18
Page: 17
Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
, SHIPMENT IS FORBIDDEN 9,
CFR_ROAD:
UN1866, Resin solution 3, III
CFR_RAIL:
UN1866, Resin solution 3, III
CFR_INWTR:
UN1866, Resin solution 3, III
ADR:
, SHIPMENT IS FORBIDDEN 9,
ADNR:
, SHIPMENT IS FORBIDDEN 9,
Dangerous goods descriptions (if indicated above) may not reflect package size, quantity,
end-use or region-specific exceptions that can be applied. Consult shipping documents for
descriptions that are specific to the shipment.
15. REGULATORY INFORMATION
California Prop. 65
WARNING! This product contains a chemical known in the State of California to cause
cancer.
ETHYLENE OXIDE
1,4-DIOXANE
ACETALDEHYDE
BENZENE
CATECHOL
NAPHTHALENE
ETHYL BENZENE
WARNING! This product contains a chemical known in the State of California to cause
birth defects or other reproductive harm.
TOLUENE
BENZENE
ETHYLENE GLYCOL MONOETHYL ETHER
ETHYLENE GLYCOL MONOMETHYL ETHER
ETHYLENE OXIDE
Reactivity Hazard
SARA Hazard Classification
Fire Hazard
Acute Health Hazard
Page 17 / 18
Page: 18
Revision Date: 01/25/2008
SAFETY DATA SHEET
Print Date: 4/30/2009
MSDS Number: R0336452
TAP BOND COAT RESIN Version: 1.2
Chronic Health Hazard
SARA 313 Component(s)
STYRENE 100-42-5 50.1149%
METHYLMETHACRYLATE 80-62-6 4%
TRIMETHYLBENZENE 95-63-6 1.7046%
1,2,4-
XYLENE 1330-20-7 1.5608%
DIMETHYLANILINE 121-69-7 1%
COBALT 2- 136-52-7 0.65%
ETHYLHEXANOATE
COBALT NEODECANOATE 27253-31-2 0.58%
COBALT HYDROXIDE 21041-93-0 0.2%
ETHYL BENZENE 100-41-4 0.3922%
NAPHTHALENE 91-20-3 0.1039%
ZINC 2-ETHYLHEXOATE 136-53-8 1%
Health Flammability Reactivity Other
2* 3 2
HMIS
2 3 2
NFPA
16. OTHER INFORMATION
The information accumulated herein is believed to be accurate but is not warranted to be
whether originating with the company or not. Recipients are advised to confirm in advance
of need that the information is current, applicable, and suitable to their circumstances. This
MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-
800-325-3751).
Page 18 / 18
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