Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification
Product ID: PS ?ACRYLIC ENAMEL PRIMER SEALER
Product Name: ACRYLIC ENAMEL PRIMER SEALER
Product Use: Paint product.
Date Published: 12/21/2006
Company Identification
TCP Global
6695 RASHA STREET
SAN DIEGO, CA 92121
Manufacturer's Phone: 1-858-909-2110
24-Hour Medical Emergency
US Phone (CHEMTREC): 1-800-424-9300
International Phone (CHEMTREC): 1-703-527-3887
2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name Approx Chemical name
CAS # Wt%
BUTYL ACETATE 10 - 15 n-Butyl acetate
123-86-4
TALC 10 - 15 TALC (MG3H2(SI03)4)
14807-96-6
AROMATIC NAPHTHA, LIGHT 10 - 15 Petroleum naphtha, light aromatic
64742-95-6
DIMETHYL KETONE 5 - 10 ACETONE
67-64-1
1,2,4-TRIMETHYLBENZENE 5 - 10 PSEUDO CUMENE
95-63-6
ZINC PHOSPHATE 1-5 Trizinc diphosphate
7779-90-0
CRYSTALLINE SILICA .1 - 1 QUARTZ (Si02)
14808-60-7
If this section is blank there are no hazardous components per OSHA guidelines.
3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health
effects:
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Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness,
headache, nausea or respiratory irritation.
Eye Contact:
Causes eye irritation.
Skin Contact:
May cause moderate skin irritation.
Acute Ingestion:
None known
Other Effects:
May cause kidney damage. May cause liver damage.
This product contains ingredients that may contribute to the following potential chronic health
effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with
permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and
inhaling the contents may be harmful or fatal. Prolonged exposure to respirable crystalline quartz silica
may cause delayed chronic injury (silicosis).Prolonged and/or repeated contact can result in skin irritation.
May cause skin drying with prolonged exposure.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.
4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention. If inhaled,
remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is
difficult give oxygen. Get medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation
persists get medical attention.
Ingestion:
If swallowed, get medical attention immediately. If swallowed, do not induce vomiting. Give large
quantities of water. If available, give several glasses of milk. Never give anything by mouth to an
unconscious person. Get medical attention immediately.
Medical conditions aggravated by exposure: Any respiratory or skin condition.
5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit): -4?F ( -20?C) TCC/PM
Lower explosive limit: 1%
Upper explosive limit: 13 %
Autoignition temperature: Not available.?F ( ?C)
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Sensitivity to impact: No.
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.
Hazardous combustion products: See Section 10.
Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.
6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large
spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal.
See section 5, "Unusual Fire and Explosion Hazards", for proper container and storage procedures.
Remove sources of ignition. Remove with inert absorbent and non sparking tools. Avoid contact with
eyes.
7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above
120 degrees F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be
provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty
containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or
weld on or near container. All label warnings must be observed until the container has been commercially
cleaned or reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be
present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may
also present an ignition hazard. Please ensure containers and other interconnected equipment are
properly bonded and grounded at all times.
8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the
eye.
Skin protection:
Appropriate chemical resistant gloves should be worn. To prevent skin contact wear protective clothing
covering all exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator
such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator
manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all
respirator manufacturer's instructions.
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Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof.
Eliminate ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name Approx TWA (final) Ceilings limits Skin
CAS # Wt% (final) designations
BUTYL ACETATE 10 - 15 150 ppm TWA;
123-86-4 710 mg/m3 TWA
TALC 10 - 15 see Table Z-3
14807-96-6
1,2,4-TRIMETHYLBENZENE 5 - 10 25 PPM
95-63-6
CRYSTALLINE SILICA .1 - 1 see Table Z-3
14808-60-7
ACGIH Threshold Limit Value (TLV's)
Common Name Approx TWA STEL Ceiling Skin
CAS # Wt% limits designations
BUTYL ACETATE 10 - 15 150 ppm TWA 200 ppm
123-86-4 STEL
TALC 10 - 15 2 mg/m3 TWA (this TLV
14807-96-6 is for the respirable
fraction of dust for Talc
containing no asbestos
and <1% crystalline
silica)
AROMATIC NAPHTHA, 10 - 15 100 PPM
LIGHT
64742-95-6
DIMETHYL KETONE 5 - 10 750 PPM
67-64-1
1,2,4- 5 - 10 25 PPM
TRIMETHYLBENZENE
95-63-6
ZINC PHOSPHATE 1-5 10 MG/M3
7779-90-0
CRYSTALLINE SILICA .1 - 1 0.05 mg/m3 TWA (this
14808-60-7 TLV is for the respirable
fraction of dust)
If this section is blank, no information is available.
9. PHYSICAL PROPERTIES
Odor: Normal for this product type.
Physical State: Liquid
pH: Not determined.
Vapor pressure: 182 mmHG @ 68?F ( 20?C)
Vapor density (air = 1.0): 4.3
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Boiling point: 133?F ( 56?C)
Solubility in water: Insoluble.
Coefficient of water/oil distribution: Not determined.
Density (lbs per US gallon): 10.42
Specific gravity (water = 1): 1.25
Evaporation rate (butyl acetate = 1.0): 5.6
10. STABILITY AND REACTIVITY
Stability: This product is stable.
Conditions to Avoid: None known.
Incompatibility: Strong oxidizers.
Hazardous Polymerization: None anticipated.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Metal oxide fumes.
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.
11. TOXICOLOGICAL INFORMATION
Contains crystaline silica. The IARC has determined that crystaline silica inhaled in the form of quartz or
cristobablite from occupational sources is carcinogenic to humans (group 1). Refer to IARC monograph
68 in conjunction with the use of these materials. Risk of cancer depends on the duration and level of
exposure. In coatings products, risk is due primarily to inhalation of sanding dusts or respirable particles
in spray mists. The NTP has also determined that crystaline silica is a known human carcinogen in the
form of fine, breathable particles. Risk of cancer depends on duration and level of exposure in coatings
products, risk is due primarily to inhalation of sanding dust or respirable particles in spray mist.
Common Name Approx IARC Group 1 - Human IARC Group 2A - IARC Group 2b -
CAS # Wt% Evidence limited human sufficient animal
data data
CRYSTALLINE SILICA .1 - 1 Monograph 68, 1997;
14808-60-7 (inhaled in the form of
quartz or cristobalite
from occupational
sources)
Monograph 68, 1997; (inhaled in the form of quartz or cristobalite from occupational sources)
Common Name Approx NTP Known NTP Suspect NTP Evidence of
CAS # Wt% carcinogens carcinogens carcinogenicity
TALC 10 - 15 male rat-some evidence;
14807-96-6 female rat-clear evidence;
male mice-no evidence;
female mice-no evidence
CRYSTALLINE SILICA .1 - 1 Known Carcinogen
14808-60-7
Common Name Approx OSHA Select OSHA Possible ACGIH Carcinogens
CAS # Wt% carcinogens select carcinogens
CRYSTALLINE SILICA .1 - 1 A2 - Suspected
14808-60-7 Human Carcinogen
If this section is blank, no information is available.
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12. ECOLOGICAL DATA
Not available at this time.
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name: PAINT
Hazard Class: 3
UN ID Number: UN1263
Packing Group: II
49 CFR Hazardous Material Regulations Parts 100-180
The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not
sustain combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR
Parts 100-180 to determine if the use of these exceptions applies to your shipments when re-shipping our
products.
International Air Transport Association:
Proper Shipping Name: PAINT
Hazard Class: 3
UN ID Number: UN1263
Packing Group: II
International Maritime Organization:
Proper Shipping Name: PAINT
Hazard Class: 3
UN ID Number: UN1263
Packing Group: II
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
Common Name Approx SARA 302 SARA 313 CERCLA RQ IN
CAS # Wt% LBS.
BUTYL ACETATE 10 - 15 5000
123-86-4
1,2,4- 5 - 10 form R reporting
TRIMETHYLBENZENE required for 1.0%
95-63-6 de minimis
concentration
ZINC PHOSPHATE 1-5 YES
7779-90-0
SARA 311/312 Hazard Class:
Acute: Yes
Chronic: Yes
Flammability: Yes
Reactivity: No
Sudden Pressure: No
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U.S. STATE REGULATIONS:
Pennsylvania Right To Know:
BUTYL ACETATE 123-86-4
TALC 14807-96-6
AROMATIC NAPHTHA, LIGHT 64742-95-6
DIMETHYL KETONE 67-64-1
ZINC PHOSPHATE 7779-90-0
1,2,4-TRIMETHYLBENZENE 95-63-6
Additional Non-Hazardous Materials
RESIN COMPONENT 68122-96-3
PROPRIETARY INERT Trade Secret
California Proposition 65:
WARNING: This product contains a chemical known to the State of California to cause cancer.
Rule 66 status of product Photochemically reactive.
INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory: All components of this product are in compliance with U.S. TSCA
Chemical Substance Inventory Requirements.
Canada Domestic Substances List: Not all components in this product are listed on the Domestic
Substances List.
16. OTHER INFORMATION
HMIS Codes
Health: 2
Flammability: 3
Reactivity: 1
PPE: X - See Section 8 for Personal Protective Equipment (PPE).
Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on
Cancer, NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology
Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast
Air Quality Management District, TSCA ?Toxic Substances Control Act, IATA - International Air Transport
Association, IMO - International Maritime Organization, DOT - Department of Transportation, NA - Not
applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ - Reportable quantity, WT - Weight,
MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, MPPCF - Millions of
particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup /
Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL -
Short term exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product
performance, this information should serve only as a general guide. TCP Global assumes no obligation or
liability for use of this information.
UNLESS TCP GLOBAL AGREES OTHERWISE IN WRITING, TCP GLOBAL MAKES NO
WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM
FROM PATENT INFRINGEMENT. TCP GLOBAL WILL NOT BE LIABLE FOR ANY SPECIAL,
INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the
replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains
additional information required by the state of Pennsylvania.
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