Aviation Products Systems, Inc./Superflite Division
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification
Product ID: T-170.000SF2200-1.170LAB
Product Name: BLACK AIRCRAFT ENGINE ENAMEL
Product Use: Paint product.
Date Published: 2004/08/04
Revision Date: 2004/08/04
Company Identification
Aviation Products Systems, Inc./Superflite Division
905 Industrial Dr.
West Chicago, IL 60185
Manufacturer's Phone: 1-800-323-0611
24-Hour Medical Emergency 1-888-345-5732
Phone:
2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name Approx Chemical name
CAS # Wt%
XYLENE 20 - 25 Xylenes (o-, m-, p- isomers)
1330-20-7
TALC 10 - 15 TALC (MG3H2(SI03)4)
14807-96-6
VM&P NAPHTHA-HI 5 - 10 Solvent naphtha (petroleum), light aliphatic
FLASH 64742-89-8
AROMATIC NAPHTHA, 5 - 10 Petroleum naphtha, light aromatic
LIGHT
64742-95-6
ETHYLBENZENE 1-5 Ethyl benzene
100-41-4
1,2,4- 1-5 Pseudocumene
TRIMETHYLBENZENE
95-63-6
MINERAL SPIRITS 1-5 Petroleum distillates, hydrotreated light
64742-47-8
TOLUENE 1-5 Toluene
108-88-3
CARBON BLACK 1-5 Carbon black
1333-86-4
CRYSTALLINE SILICA .1 - 1 QUARTZ (Si02)
14808-60-7
If this section is blank there are no hazardous components per OSHA guidelines.
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3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache,
nausea or respiratory irritation.
Eye Contact:
Corneal Injury/eye damage.
Skin Contact:
May cause moderate skin irritation.
Acute Ingestion:
None known
Other Effects:
May cause central nervous system depression. May cause liver damage. May cause kidney damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent
brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents
may be harmful or fatal. Prolonged exposure to respirable crystalline quartz silica may cause delayed chronic
injury (silicosis). Possible birth defects hazard. Contains ingredients which may cause birth defects based on
animal data. May cause liver damage. Possible cancer hazard. Contains ingredients which may cause cancer
based on animal data. Risk of cancer depends on duration and level of exposure. May cause kidney damage.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.
4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and
get medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation
persists get medical attention.
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Ingestion:
If swallowed, do not induce vomiting. Give large quantities of water. If available, give several glasses of milk.
Never give anything by mouth to an unconscious person. Get medical attention immediately.
Medical conditions aggravated by exposure: Any respiratory or skin condition.
5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit): 83?F ( 28?C) TCC/PM
Lower explosive limit: 1%
Upper explosive limit: 7%
Autoignition temperature: Not available. ?F ( ?C)
Sensitivity to impact: No.
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding
information in Section 7.
Hazardous combustion products: See Section 10.
Unusual fire and explosion hazards:
Contaminated rags, wipes, saw dust, etc., may catch fire spontaneously. Store waste under water in
closed metal containers until disposed of in compliance with applicable regulations. Contains oxidizable
materials.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.
6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5,
"Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition.
Remove with inert absorbent and non sparking tools. Avoid contact with eyes.
7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120
degrees F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in
accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may
contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near
container. All label warnings must be observed until the container has been commercially cleaned or
reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be present. Activities,
uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition
hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all
times.
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8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing
covering all exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as
an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's
literature to ensure that the respirator will provide adequate protection. Read and follow all respirator
manufacturer's instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate
ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name Approx TWA (final) Ceilings limits (final) Skin designations
CAS # Wt%
XYLENE 20 - 25 100 ppm TWA; 435
1330-20-7 mg/m3 TWA
TALC 10 - 15 see Table Z-3
14807-96-6
ETHYLBENZENE 1-5 100 ppm TWA; 435
100-41-4 mg/m3 TWA
1,2,4- 1-5 25 PPM
TRIMETHYLBENZENE
95-63-6
MINERAL SPIRITS 1-5 100 PPM
64742-47-8
TOLUENE 1-5 200 ppm TWA; C 300 C 300 ppm
108-88-3 ppm
CARBON BLACK 1-5 3.5 mg/m3 TWA
1333-86-4
CRYSTALLINE SILICA .1 - 1 see Table Z-3
14808-60-7
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ACGIH Threshold Limit Value (TLV's)
Common Name Approx TWA STEL Ceiling limits Skin
CAS # Wt% designations
XYLENE 20 - 25 100 ppm TWA 150 ppm STEL
1330-20-7
TALC 10 - 15 2 mg/m3 TWA
14807-96-6 (this TLV is for
the respirable
fraction of dust
for Talc
containing no
asbestos and
<1% crystalline
silica)
VM&P NAPHTHA-HI 5 - 10 300 PPM
FLASH 64742-89-8
AROMATIC NAPHTHA, 5 - 10 100 PPM
LIGHT
64742-95-6
ETHYLBENZENE 1-5 100 ppm TWA 125 ppm STEL
100-41-4
1,2,4- 1-5 25 PPM
TRIMETHYLBENZENE
95-63-6
MINERAL SPIRITS 1-5 100 PPM
64742-47-8
TOLUENE 1-5 50 ppm TWA skin - potential
for
108-88-3 cutaneous
absorption
CARBON BLACK 1-5 3.5 mg/m3
TWA
1333-86-4
CRYSTALLINE SILICA .1 - 1 0.05 mg/m3
14808-60-7 TWA (this TLV
is for the
respirable
fraction of dust)
If this section is blank, no information is available.
9. PHYSICAL PROPERTIES
Odor: Normal for this product type.
Physical State: Liquid
pH: Not determined.
Vapor pressure: 28 mmHG @ 68?F ( 20?C)
Vapor density (air = 1.0): 5.1
Boiling point: 230?F ( 110?C)
Solubility in water: Insoluble.
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Coefficient of water/oil distribution: Not determined.
Density (weight per gallon): 8.69
Specific gravity (water = 1): Not determined.
Evaporation rate (butyl acetate = 1.0): 2
10. STABILITY AND REACTIVITY
Stability: This product is stable.
Conditions to Avoid: None known.
Incompatibility: Strong oxidizers.
Hazardous Polymerization: None anticipated.
Hazardous Decomposition Products: Silicon dioxide. Carbon monoxide and carbon dioxide. Metal oxide fumes.
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.
11. TOXICOLOGICAL INFORMATION
Common Name Approx Calif- Prop. 65. Developmental California Prop 65 - reproductive
CAS # Wt% Toxicity male
TOLUENE 1-5 developmental toxicity; initial date
108-88-3 1/1/91
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance
to humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient
evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans. Contains
crystaline silica. The IARC has determined that crystaline silica inhaled in the form of quartz or cristobablite from
occupational sources is carcinogenic to humans (group 1). Refer to IARC monograph 68 in conjunction with the
use of these materials. Risk of cancer depends on the duration and level of exposure. In coatings products, risk
is due primarily to inhalation of sanding dusts or respirable particles in spray mists. The NTP has also determined
that crystaline silica is a known human carcinogen in the form of fine, breathable particles. Risk of cancer
depends on duration and level of exposure in coatings products, risk is due primarily to inhalation of sanding dust
or respirable particles in spray mist.
Common Name Approx IARC Group 1 - IARC Group 2A - IARC Group 2b -
CAS # Wt% Human Evidence limited human data sufficient animal
data
ETHYLBENZENE 1-5 Monograph 77, 2000
100-41-4
CARBON BLACK 1-5 Monograph 65, 1996
1333-86-4
CRYSTALLINE SILICA .1 - 1 Monograph 68, 1997;
14808-60-7 (inhaled in the form of
quartz or cristobalite
from occupational
sources)
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Common Name Approx NTP Known NTP Suspect NTP Evidence of
CAS # Wt% carcinogens carcinogens carcinogenicity
TALC 10 - 15 male rat-some
14807-96-6 evidence; female rat-
clear evidence; male
mice-no evidence;
female mice-no
evidence
ETHYLBENZENE 1-5 male rat-clear
100-41-4 evidence; female rat-
some evidence; male
mice-some evidence;
female mice-some
evidence
TOLUENE 1-5 MALE RAT - NO
108-88-3 EVIDENCE; FEMALE
RAT - NO
EVIDENCE; MALE
MICE - NO
EVIDENCE; FEMALE
MICE - NO
EVIDENCE.
CRYSTALLINE SILICA .1 - 1 Known Carcinogen
14808-60-7
Common Name Approx OSHA Select OSHA Possible ACGIH Carcinogens
select
CAS # Wt% carcinogens carcinogens
ETHYLBENZENE 1-5 Monograph 77, 2000
100-41-4 IARC - Group 2B
(Possibly carcinogenic
to humans)
TOLUENE 1-5 A4 - Not Classifiable
as a Human
108-88-3
Carcinogen
CARBON BLACK 1-5 Monograph 65, 1996 A4 - Not Classifiable
as
1333-86-4 IARC - Group 2B a Human Carcinogen
(Possibly carcinogenic
to
humans)
CRYSTALLINE SILICA .1 - 1 A2 - Suspected
14808-60-7 Human Carcinogen
If this section is blank, no information is available.
12. ECOLOGICAL DATA
Not available at this time.
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13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name: PAINT
Hazard Class: 3
UN ID Number: UN1263
Packing Group: III
49 CFR Hazardous Material Regulations Parts 100-180
The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain
combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180
to determine if the use of these exceptions applies to your shipments when re-shipping our products.
International Air Transport Association:
Proper Shipping Name: PAINT
Hazard Class: 3
UN ID Number: UN1263
Packing Group: III
International Maritime Organization:
Proper Shipping Name: PAINT
Hazard Class: 3
UN ID Number: UN1263
Packing Group: III
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
Common Name Approx SARA 302 SARA 313 CERCLA RQ IN LBS.
CAS # Wt%
XYLENE 20 - 25 form R reporting 100
1330-20-7 required for 1.0% de
minimis concentration
ETHYLBENZENE 1-5 form R reporting 1000
100-41-4 required for 1.0% de
minimis concentration
1,2,4- 1-5 form R reporting
TRIMETHYLBENZENE required for 1.0% de
95-63-6 minimis concentration
TOLUENE 1-5 form R reporting 1000
108-88-3 required for 1.0% de
minimis concentration
SARA 311/312 Hazard Class:
Acute: Yes
Chronic: Yes
Flammability: Yes
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Reactivity: No
Sudden Pressure: No
U.S. STATE REGULATIONS:
Pennsylvania Right To Know:
TOLUENE 108-88-3
VM&P NAPHTHA-HI FLASH 64742-89-8
MINERAL SPIRITS 64742-47-8
ETHYLBENZENE 100-41-4
1,2,4-TRIMETHYLBENZENE 95-63-6
AROMATIC NAPHTHA, LIGHT 64742-95-6
XYLENE 1330-20-7
CARBON BLACK 1333-86-4
TALC 14807-96-6
Additional Non-Hazardous Materials
PROPRIETARY RESIN Trade Secret
PROPRIETARY RESIN Trade Secret
PROPRIETARY INERT Trade Secret
PROPRIETARY RESIN Trade Secret
California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or
other reproductive harm.
Rule 66 status of product Photochemically reactive.
INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory: All components of this product are in compliance with U.S. TSCA
Chemical Substance Inventory Requirements.
Canada Domestic Substances List: All components of this product are listed on the Domestic Substances
List.
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16. OTHER INFORMATION
HMIS Codes
Health: 3
Flammability: 3
Reactivity: 1
PPE: X - See Section 8 for Personal Protective Equipment (PPE).
Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer,
NIOSH National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH -
American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management
District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International
Maritime Organization, DOT Department of Transportation, NA - Not applicable, NOT ESTAB - Not established,
N.A.V. - Not available, RQ Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L -
Grams per liter, MM - Millimeters, MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT -
parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level,
TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product
performance, this information should serve only as a general guide. AVIATION PRODUCTS SYSTEMS assumes
no obligation or liability for use of this information. UNLESS AVIATION PRODUCTS SYSTEMS AGREES
OTHERWISE IN WRITING, AVIATION PRODUCTS SYSTEMS MAKES NO WARRANTIES, EXPRESS OR
IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY
OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. AVIATION
PRODUCTS SYSTEMS WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL
DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a
refund of its purchase price, at our option. This MSDS contains additional information required by the state of
Pennsylvania.
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