MATERIAL SAFETY DATA SHEET
Page: 1
BLANKET & ROLLER WASH V-133
Revised: January 2, 2003
PRODUCT CODE: B010007 HMIS CODES: H F R P
220X
SECTION 1 - MANUFACTURER IDENTIFICATION
MANUFACTURER'S NAME: Day International Chemical Products Div.
ADDRESS : 905 South Westwood Avenue
Addison, Illinois 60101
EMERGENCY PHONE: 800-424-9300 INFORMATION PHONE: 800-336-8276
NAME OF PREPARER: DAY Chemical Prod. Div. DATE PRINTED: 01/02/03
REASON REVISED: Update; Supersedes All Previous Revisions.
SECTION 2 - HAZARDOUS INGREDIENTS/SARA III INFORMATION
VAPOR PRESSURE WEIGHT
REPORTABLE COMPONENTS CAS NUMBER MM HG @ TEMP PERCENT
---------------------------------------------------------------------------------------------
Petroleum Naphtha 64742-47-8 2.8 68癋 75
OSHA PEL: 500ppm TWA, ACGIH TLV: N/E
* Dichloremethane 75-09-2 355 68癋 15.02
OSHA PEL: 25ppm, ACGIH TLV: 50ppm, STEL: 125ppm
Hazardous Air Pollutant
Petroleum Naphtha 64742-95-6 2.7 68癋 6
OSHA PEL: N/E, ACGIH TLV: N/E, Mfg: 50ppm
* 1,2,4-Trimethyl Benzene 95-63-6 2
p-mentha-1,8-diene 5989-27-5 2.0 68癋 2
OSHA PEL: N/E, ACGIH TLV: N/E, Mfg: 125ppm
* Indicates toxic chemical(s) subject to the reporting requirements of Section 313 of SARA Title III and of 40 CFR 372. All
ingredients are listed on the EPA TSCA Inventory.
SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING RANGE/POINT: 104癋 - 338癋 SPECIFIC GRAVITY (H2O=1): .83
VAPOR DENSITY: Heavier than air.
EVAPORATION RATE: Faster than n-Butyl Acetate.
V.O.C. (EPA METHOD 24): 5.88 lb/gl
VAPOR PRESSURE (MM HG @ 20癈): 2.3
SOLUBILITY IN WATER: Less Than 5%
APPEARANCE AND ODOR: Clear Liquid - Petroleum Odor
SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: 118癋 METHOD USED: TAG CC
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: 1.0% UPPER: 23.0%
EXTINGUISHING MEDIA:
Foam, CO2, Dry Chemical.
SPECIAL FIREFIGHTING PROCEDURES:
As in any fire, wear self-contained breathing apparatus (MSHA/NIOSH approved) and full protective gear. Water may not be
effective to extinguish fire. Use water spray to cool fire-exposed containers and to protect personnel.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Treat as Petroleum Fire. Burning will produce hydrogen chloride and traces of phosgene.
MATERIAL SAFETY DATA SHEET
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BLANKET & ROLLER WASH V-133
Revised: January 2, 2003
SECTION 5 - REACTIVITY DATA
STABILITY:
Stable
CONDITIONS TO AVOID:
Avoid heat, sparks, flame and other sources of ignition.
INCOMPATIBILITY (MATERIALS TO AVOID):
Avoid mixing with strong oxidizing agents.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
Burning will produce oxides of carbon, hydrogen chloride and traces of phosgene.
HAZARDOUS POLYMERIZATION:
Will Not Occur.
SECTION 6 - HEALTH HAZARD DATA
INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
Breathing vapors above established exposure limits may cause nose and throat irritation; signs of central nervous system
depression such as headache, drowsiness, dizziness and carbon monoxide-like effects (Carboxyhemoglobinemia).
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
Skin contact may cause irritation and burning. Eye contact will cause stinging, tearing, redness and swelling.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
Can be absorbed through the skin and may contribute to the overall exposure to the chemical Dichloromethane.
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
Ingestion of this product will cause nausea, gastro-intestinal irritation, diarrhea and possible damage to vital organs. Follow
first aid procedures.
HEALTH HAZARDS (ACUTE AND CHRONIC):
Breathing vapors above established exposure limits may cause nausea, vomiting, lightheadedness, numbness, changes in
blood enzyme levels, breathing problems leading to bronchitis & pulmonary edema, unconsciousness and even death.
Chronic exposure to dichloromethane has been demonstrated to produce liver toxicity in animals. Repeated skin contact will
dry out and crack skin. Aspiration hazard if swallowed; aspiration into the lungs can cause chemical pneumonitis.
CARCINOGENICITY: NTP CARCINOGEN: Yes IARC MONOGRAPHS: Yes OSHA REGULATED: Yes
Product contains dichloromethane, a chemical which has caused cancer in certain laboratory animal tests.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
Skin contact may aggravate pre-existing dermatitis. Inhalation of vapors may aggravate pre-existing asthma like conditions.
EMERGENCY AND FIRST AID PROCEDURES:
INHALATION: Remove victim to fresh air. Give oxygen if breathing is labored. Apply artificial respiration if not breathing. Seek
medical help. SKIN: Remove all contaminated clothing and shoes. Wash with soap and water. Do not reuse clothing and
shoes until cleaned. EYES: Flush eyes with plenty of water while removing any contact lenses. Hold eyelids open and continue
flushing for at least 15 minutes. INGESTION: DO NOT INDUCE vomiting. If vomiting occurs spontaneously, keep head below
hips to prevent aspiration of liquid into the lungs. Seek medical attention immediately.
MATERIAL SAFETY DATA SHEET
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BLANKET & ROLLER WASH V-133
Revised: January 2, 2003
SECTION 7 - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Eliminate all ignition sources. Spills should be diked and must be kept from entering the sewer. Soak up with absorbent or
transfer liquid into a closed container for later disposal. Use spark-proof tools and explosion proof equipment.
WASTE DISPOSAL METHOD:
If this product becomes a waste, it is regulated by RCRA as Spent Halogenated Solvent Mixture, EPA I.D. #F002. Suitable
methods of disposal include reclamation or fuel blending. Contact a Licensed Hazardous Waste Hauler for more information.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Containers should be grounded and bonded before transferring product. Store in the original closed container away from
sunlight, excess heat, sparks, flames and other sources of ignition. Avoid skin or eye contact. Avoid breathing vapors. When
transferring or using this product, wear proper personal protective equipment. Store and handle as a Combustible Liquid.
OTHER PRECAUTIONS/DOT INFORMATION:
DOT Proper Shipping Name: Combustible Liquid n.o.s. (Naphtha), ID No.: NA1993, Packing Group: III, RQ Dichloromethane:
1000 Lbs. Non-bulk packagings not Regulated as per 49CFR 173.150 (f)(2). IMDG Code: Flammable Liquid n.o.s. (petroleum
naphtha, dichloromethane) Class 3, UN1993, PG III Flash Point 48癈. California Proposition 65: The following statement is
made in order to comply with the California Safe Drinking Water And Toxic Enforcement Act Of 1986: WARNING: This product
contains a chemical known to the State of California to cause cancer. (See Section VI of this MSDS for details on
carcinogenicity).
SECTION 8 - CONTROL MEASURES
RESPIRATORY PROTECTION:
The use of respiratory protection is required when concentrations exceed the established OSHA PEL limits in SECTION 2. Wear
a supplied air respirator (SABA or SCBA) (NIOSH approved). Respirators equipped with organic vapor cartridges are
authorized for emergency escape only.
VENTILATION:
If current ventilation practices are not adequate to maintain airborne concentrations below the established OSHA PEL limits in
SECTION 2, additional general ventilation or local exhaust system or the use of SABA or SCBA is required.
PROTECTIVE GLOVES:
Wear solvent resistant gloves made of polyvinyl alcohol (PVA) or others rated for protection from dichloromethane.
EYE PROTECTION:
Wear safety glasses with side shields.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
A personal protective rating of X means you must see your supervisor for guidance. OSHA regulations (29CFR Part 1910,
Subpart I) require employers to evaluate Personal Protective Equipment requirements in the workplace.
WORK/HYGIENIC PRACTICES:
Wash with soap and water after product contact with skin. Launder contaminated clothing before reuse.
SECTION 9 - DISCLAIMER
The information on this MSDS is believed to be accurate as of the date shown in SECTION 1. Since the use of this product is not
under the control of DAY Chemical Products Division, it is the user's responsibility to determine what constitutes safe usage for
a particular product. This form may be reproduced in quantities necessary to meet your requirements.
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