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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 10.02.2009 Revision: 10.02.2009
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: Pico Fluor 40
?Article number: 6013349
?Application of the substance / the preparation Laboratory chemicals
?Manufacturer/Supplier:
PerkinElmer Life & Analytical Sciences B.V.
Rigaweg 22
9723 TH Groningen
The Netherlands
P.O. Box 5205
9700 GE Groningen
The Netherlands
Phone: 0031 50 5445900
Fax: 0031 50 5445950
www.perkinelmer.com
?Further information obtainable from:
Environment, Safety and Health (ESH)
Jack.VanderWeele@perkinelmer.com
2 Hazards identification
?Hazard description:
Xn Harmful
N Dangerous for the environment
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 10 Flammable.
R 20 Harmful by inhalation.
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
?GHS label elements
Danger
3.3/1 - Causes serious eye damage.
3.2/2 - Causes skin irritation.
Warning
2.6/3 - Flammable liquid and vapour.
Warning
3.1/4 - Harmful if inhaled.
3.8/3 - May cause respiratory irritation.
(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 10.02.2009 Revision: 10.02.2009
Trade name: Pico Fluor 40
(Contd. of page 1)
4.1/2 - Toxic to aquatic life with long lasting effects.
?Prevention:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/ equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
?Response:
IF ON SKIN: Wash with plenty of soap and water.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/
shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
Call a POISON CENTER or doctor/physician if you feel unwell.
Specific treatment (see label).
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.
In case of fire: Use for extinction: CO2, powder or water spray.
Collect spillage.
?Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
?Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture: consisting of the following components.
?Dangerous components:
CAS: 95-63-6 1,2,4-trimethylbenzene 40-60%
EINECS: 202-436-9 Xn, Xi, N; R 10-20-36/37/38-51/53
Index number: 601-043-00-3 Warning: 2.6/3; 3.1.I/4, 3.2/2, 3.3/2A, 3.8/3
4.1.C/2
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 10.02.2009 Revision: 10.02.2009
Trade name: Pico Fluor 40
(Contd. of page 2)
CAS: 73070-48-1 Diethanolaminephosphoric acid ester, Ammonium Salt 10-20%
EINECS: 277-274-5 Xi; R 38-41
Danger: 3.3/1, 3.2/2
CAS: 37205-87-1 Polymer based on nonylphenolethoxylate 10-20%
Xi, N; R 36/38-51/53
Warning: 3.2/2, 3.3/2A
4.1.C/2
CAS: 78-40-0 Triethyl phosphate 2.5-10%
EINECS: 201-114-5 Xn; R 22
Index number: 015-013-00-7 Danger: 3.1.O/3
CAS: 577-11-7 Sodium dioctyl sulphosuccinate 2.5-10%
EINECS: 209-406-4 Xi; R 36/38
Warning: 3.2/2, 3.3/2A
2.5%
Polymer Polymer based on alkylphenolethoxylate (EO=7)
Xn, Xi, N; R 36/38-48/22-51/53
Warning: 3.9/2; 3.2/2, 3.3/2A
4.1.C/2
?Non-dangerous components
2.5%
CAS: 92-71-7 2,5-Diphenyloxazole (PPO)
EINECS: 202-181-3
2.5%
CAS: 13280-61-0 1,4-Bis-(2-methylstyryl)-benzene (MSB)
EINECS: 236-285-5
?Additional information: For the wording of the listed risk phrases refer to section 16.
4 First-aid measures
?General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
?After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
?Information for doctor:
?The following symptoms may occur: Headache
5 Fire-fighting measures
?Suitable extinguishing agents:
Foam
Fire-extinguishing powder
Carbon dioxide
?For safety reasons unsuitable extinguishing agents: Water with full jet
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 10.02.2009 Revision: 10.02.2009
Trade name: Pico Fluor 40
(Contd. of page 3)
?Protective equipment: Mount respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Do not allow to enter sewers/ surface or ground water.
Inform respective authorities in case of seepage into water course or sewage system.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
7 Handling and storage
?Handling:
?Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Protect from heat and direct sunlight.
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
95-63-6 1,2,4-trimethylbenzene
WEL Long-term value: 125 mg/m? 25 ppm
ILV
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
?Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 10.02.2009 Revision: 10.02.2009
Trade name: Pico Fluor 40
(Contd. of page 4)
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Fluid
Form:
Colourless
Colour:
Aromatic
Odour:
?Change in condition
Boiling point/Boiling range: 170癈 (338癋)
48癈 (118癋)
?Flash point:
520癈 (968癋)
?Ignition temperature:
Product is not selfigniting.
?Self-igniting:
Product is not explosive. However, formation of explosive air/vapour
?Danger of explosion:
mixtures are possible.
?Explosion limits:
1.1 Vol %
Lower:
7.0 Vol %
Upper:
0.930 g/cm?br>
?Density at 20癈 (68癋):
?Solubility in / Miscibility with
Not miscible or difficult to mix.
water:
?Solvent content:
60-80 %
Organic solvents:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
(Contd. on page 6)
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Safety Data Sheet
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Trade name: Pico Fluor 40
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?Dangerous decomposition products: Carbon monoxide and carbon dioxide
11 Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
12 Ecological information
?Ecotoxical effects:
?Remark: Toxic for fish
?General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
13 Disposal considerations
?Recommendation Delivery of waste oil to offically authorized collectors only.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
3 Flammable liquids.
?ADR/RID class:
?Danger code (Kemler): 30
1993
?UN-Number:
III
?Packaging group:
(Contd. on page 7)
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Safety Data Sheet
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Printing date 10.02.2009 Revision: 10.02.2009
Trade name: Pico Fluor 40
(Contd. of page 6)
3
?Hazard label
?Maritime transport IMDG:
3
?IMDG Class:
1993
?UN Number:
3
?Label
III
?Packaging group:
F-E,S-E
?EMS Number:
Yes
?Marine pollutant:
?Proper shipping name: FLAMMABLE LIQUID, N.O.S. (1,2,4-trimethylbenzene)
?Air transport ICAO-TI and IATA-DGR:
3
?ICAO/IATA Class:
1993
?UN/ID Number:
3
?Label
III
?Packaging group:
?Proper shipping name: FLAMMABLE LIQUID, N.O.S. (1,2,4-trimethylbenzene)
?UN "Model Regulation": UN1993, FLAMMABLE LIQUID, N.O.S., 3, III
?Environmental hazards: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID
15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Code letter and hazard designation of product:
Xn Harmful
N Dangerous for the environment
?Hazard-determining components of labelling:
1,2,4-trimethylbenzene
?Risk phrases:
10 Flammable.
20 Harmful by inhalation.
37/38 Irritating to respiratory system and skin.
41 Risk of serious damage to eyes.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
39 Wear eye/face protection.
(Contd. on page 8)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 10.02.2009 Revision: 10.02.2009
Trade name: Pico Fluor 40
(Contd. of page 7)
57 Use appropriate container to avoid environmental contamination.
?National regulations:
?Technical instructions (air):
Class Share in %
NK 66.7
?Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
20 Harmful by inhalation.
22 Harmful if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
36/38 Irritating to eyes and skin.
38 Irritating to skin.
41 Risk of serious damage to eyes.
48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Department issuing MSDS: Environment, Safety and Health (ESH)
?Contact: J. van der Weele
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
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