Material Safety Data Sheet
Preparation Date: 04-Jan-2010 Revision Date: 29-Dec-2009 Revision Number: 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code L-69-11WHA
Trade Name HB EPOXOLINE II WHITE
Contact Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Emergency Telephone Number 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
DANGER!
COMBUSTIBLE LIQUID AND VAPOR.
HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.
CAUSES SKIN AND EYE BURNS.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT.
MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Potential Health Effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute Effects
Eyes Causes burns.
Skin Causes burns. May cause sensitization by skin contact.
Inhalation Irritating to respiratory system. Respirable crystalline silica (quartz) can cause silicosis, a
fibrosis (scarring) of the lungs.
Ingestion May be harmful if swallowed.
Chronic Effects
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Cancer hazard.
Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure.)
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders.
Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.
Potential Environmental Effects See Section 12 for additional Ecological information
Target Organ Effects Central nervous system, Central Vascular System, Eyes, Lungs, Respiratory system, Skin
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
CAS-No Weight %
Component
14807-96-6 10 - 30
TALC (RESPIRABLE DUST)
13463-67-7 10 - 30
TITANIUM DIOXIDE (TOTAL DUST)
98-56-6 17.9384
BENZENE, 1-CHLORO-4-
(TRIFLUOROMETHYL)-
14808-60-7 13.096
CRYSTALLINE SILICA (QUARTZ)
5 - 10
MODIFIED CYCLOALIPHATIC POLYAMINE
100-51-6 5.1455
BENZYL ALCOHOL
71-36-3 3.8247
N-BUTANOL (SKIN)
2855-13-2 1-5
ISOPHORONE DIAMINE
7631-86-9 1-5
AMORPHOUS SILICA
1344-28-1 1-5
ALUMINUM OXIDES
95-63-6 0.6246
1,2,4-TRIMETHYLBENZENE
1330-20-7 0.3195
XYLENE
108-67-8 0.1561
1,3,5-TRIMETHYLBENZENE
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable Properties Combustible material.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -
Foam - Dry chemical
Hazardous Decomposition Products Oxides of carbon, hydrocarbons. Oxides of nitrogen. Aldehydes. Chlorine. Fluorine.
Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective Equipment and Precautions for Firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier than
air and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system.
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Methods for Cleaning Up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
Other Information Not applicable
7. HANDLING AND STORAGE
Handling
Close container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. If
splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.
When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Storage
Keep away from heat, sparks and flame. Use only in an area containing flame proof equipment. Prevent build-up of vapors by
opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)
TWA: 2 mg/m3 TWA: 2 mg/m3 TWA: 3 mg/m3 TWA: 2 mg/m3 TWA: 2 mg/m3
TALC (RESPIRABLE DUST)
TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3 STEL:
TITANIUM DIOXIDE (TOTAL
15 mg/m3 20 mg/m3
DUST)
TWA: 2.5 mg/m3 TWA: 2.5 mg/m3 TWA: 2.5 mg/m3
BENZENE, 1-CHLORO-4-
(TRIFLUOROMETHYL)-
TWA: 0.025 mg/m3 TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 TWA: 0.10 mg/m3 TWA: 0.1 mg/m3
CRYSTALLINE SILICA
(QUARTZ)
Ceiling: 152 mg/m3 Peak: 150 mg/m3 Peak:
N-BUTANOL (SKIN) TWA: 20 ppm Skin Ceiling: 50 ppm TWA: 20 ppm
Ceiling: 150 mg/m3 Ceiling: 50 ppm Skin 50 ppm
TWA: 100 ppm TWA:
300 mg/m3
TWA: 1 mg/m3 TWA: 10 mg/m3 TWA: 5 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3
ALUMINUM OXIDES
mg/m3 TWA: 15 mg/m3
TWA: 125 mg/m3 TWA:
1,2,4-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA: TWA: 25 ppm TWA:
123 mg/m3 123 mg/m3
25 ppm STEL: 170
mg/m3 STEL: 35 ppm
TWA: 100 ppm STEL: TWA: 435 mg/m3 TWA: TWA: 434 mg/m3 TWA: TWA: 100 ppm TWA: TWA: 435 mg/m3 TWA:
XYLENE
435 mg/m3 STEL: 150
150 ppm 100 ppm STEL: 150 100 ppm STEL: 150 100 ppm STEL: 150
ppm STEL: 655 mg/m ppm STEL: 651 mg/m ppm STEL: 650 mg/m3 ppm STEL: 655 mg/m3
3 3
TWA: 25 ppm TWA: TWA: 125 mg/m3 TWA:
1,3,5-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:
123 mg/m3 123 mg/m3 25 ppm STEL: 170
mg/m3 STEL: 35 ppm
Engineering Measures Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Skin Protection Lightweight protective clothing, Apron, Impervious gloves
Eye/face Protection If splashes are likely to occur, wear Goggles.
Respiratory Protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,
wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.
Follow respirator manufacturer's directions for respirator use.
General Hygiene Handle in accordance with good industrial hygiene and safety practice.
Considerations Avoid breathing dust created by cutting, sanding, or grinding.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point 41癈 / 105.0癋
Boiling Point/Range 116 - 118癈 / 241.0 - 245.0癋
Upper Exposure Limits No information available
Lower Exposure Limits No information available
Evaporation Rate No information available
Vapour Pressure No information available
Vapour Density No information available
Specific Gravity 1.76428
Density 14.68149
VOC Content (lbs/gal) 1.232
% Volatile by Weight 24.2450
% Volatile by Volume 36.7682
10. STABILITY AND REACTIVITY
Chemical stability Stable. Conditions to Avoid Heat, flames and sparks. Epoxy
constituents.
Incompatible Products Strong oxidizing agents. Bases. Possibility of Hazardous None under normal processing
Acids. Cleaning solutions such Reactions
as Chromerge and Aqua Regia.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
TITANIUM DIOXIDE (TOTAL DUST) 10000 mg/kg ( Rat )
BENZENE, 1-CHLORO-4- 13 g/kg ( Rat ) 2 mg/kg ( Rabbit ) 33 mg/L ( Rat ) 4 h
(TRIFLUOROMETHYL)-
CRYSTALLINE SILICA (QUARTZ) 500 mg/kg ( Rat )
BENZYL ALCOHOL 1230 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 8.8 mg/L ( Rat ) 4 h
N-BUTANOL (SKIN) 790 mg/kg ( Rat ) 3400 mg/kg ( Rabbit ) 8000 ppm ( Rat ) 4 h 17.7 mg/L ( Rat
)4h
ISOPHORONE DIAMINE 1030 mg/kg ( Rat )
AMORPHOUS SILICA 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.2 mg/L ( Rat ) 1 h
ALUMINUM OXIDES 5000 mg/kg ( Rat )
18 g/m3 ( Rat ) 4 h
1,2,4-TRIMETHYLBENZENE 3400 mg/kg ( Rat ) 3160 mg/kg ( Rabbit )
XYLENE 4300 mg/kg ( Rat ) 1700 mg/kg ( Rabbit ) 47635 mg/L ( Rat ) 4 h 5000 ppm (
Rat ) 4 h
24 g/m3 ( Rat ) 4 h
1,3,5-TRIMETHYLBENZENE 5000 mg/kg ( Rat )
Irritation No information available
Corrosivity No information available
Sensitization No information available
Chronic Toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component ACGIH IARC NTP OSHA Mexico
TITANIUM DIOXIDE (TOTAL Group 2B X
DUST)
CRYSTALLINE SILICA A2 Group 1 Known X
(QUARTZ)
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Mutagenic Effects No information available
Reproductive Effects No information available
Developmental Effects No information available
Teratogenicity No information available
Target Organ Effects Central nervous system, Central Vascular System, Eyes, Lungs, Respiratory system, Skin.
Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
TALC (RESPIRABLE DUST) LC50> 100 g/L Brachydanio
rerio 96 h
BENZENE, 1-CHLORO-4- EC50 = 11.1 mg/L 5 min EC50 EC50 = 3.68 mg/L 48 h
(TRIFLUOROMETHYL)- = 13.4 mg/L 15 min EC50 =
14.3 mg/L 30 min
BENZYL ALCOHOL EC50 = 35 mg/L 3 h LC50= 460 mg/L Pimephales EC50 = 63.7 mg/L 5 min EC50 EC50 = 23 mg/L 48 h
promelas 96 h LC50= 10 mg/L = 63.7 mg/L 15 min EC50 =
Lepomis macrochirus 96 h 71.4 mg/L 30 min EC50 = 50
mg/L 5 min
N-BUTANOL (SKIN) EC50 > 500 mg/L 96 h EC50 > LC50= 1510 mg/L Pimephales EC50 = 2041.4 mg/L 5 min EC50 = 1983 mg/L 48 h
500 mg/L 72 h promelas 96 h LC50= 1740 EC50 = 2186 mg/L 30 min
mg/L Pimephales promelas 96 EC50 = 4400 mg/L 17 h EC50
h LC50= 1200 mg/L Leuciscus = 3980 mg/L 24 h
idus 96 h
ISOPHORONE DIAMINE EC50 = 37 mg/L 72 h LC50= 110 mg/L Leuciscus EC50 = 42 mg/L 24 h
idus 96 h
AMORPHOUS SILICA EC50 = 440 mg/L 72 h LC50= 5000 mg/L Brachydanio EC50 = 7600 mg/L 48 h
rerio 96 h
1,2,4-TRIMETHYLBENZENE LC50= 7.72 mg/L Pimephales EC50 = 6.14 mg/L 48 h
promelas 96 h
XYLENE LC50= 13.4 mg/L Pimephales EC50 = 0.0084 mg/L 24 h EC50 = 3.82 mg/L 48 h LC50
promelas 96 h LC50= 8.05 = 0.6 mg/L 48 h
mg/L Oncorhynchus mykiss 96
h LC50= 16.1 mg/L Lepomis
macrochirus 96 h LC50= 26.7
mg/L Pimephales promelas 96
h
1,3,5-TRIMETHYLBENZENE LC50= 7.72 mg/L Pimephales EC50 = 50 mg/L 24 h
promelas 96 h LC50= 3.48
mg/L Pimephales promelas 96
h
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in accordance
with local, state and federal regulations.
Contaminated Packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other modes of Transportation.
Proper Shipping Name PAINT IN OIL
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15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Does not Comply
CHINA Does not Comply
ENCS Does not Comply
KECL Does not Comply
PICCS Does not Comply
AICS Does not Comply
Component
XYLENE
U.S. Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - Threshold
Values
N-BUTANOL (SKIN) 71-36-3 3.8247 1.0
1,2,4-TRIMETHYLBENZENE 95-63-6 0.6246 1.0
XYLENE 1330-20-7 0.3195 1.0
SARA 311/312 Hazardous Categorization
Chronic Health Hazard No
Acute Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
Quantities
BENZENE, 1-CHLORO-4- X
(TRIFLUOROMETHYL)-
XYLENE 100 lb X
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs
N-BUTANOL (SKIN) 5000 lb
XYLENE 100 lb
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65
CRYSTALLINE SILICA (QUARTZ) 14808-60-7 Carcinogen
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State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
TALC (RESPIRABLE DUST) X X X X
TITANIUM DIOXIDE (TOTAL X X X X
DUST)
BENZENE, 1-CHLORO-4- X X X
(TRIFLUOROMETHYL)-
CRYSTALLINE SILICA X X X X
(QUARTZ)
BENZYL ALCOHOL X X
N-BUTANOL (SKIN) X X X X
ISOPHORONE DIAMINE X
AMORPHOUS SILICA X X
ALUMINUM OXIDES X X X X
1,2,4-TRIMETHYLBENZENE X X X X X
XYLENE X X X X X
1,3,5-TRIMETHYLBENZENE X X X X X
Other International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
B3 Combustible liquid
D2B Toxic materials
E Corrosive material
Component NPRI
N-BUTANOL (SKIN) Part 1, Group 1 Substance
ALUMINUM OXIDES Part 1, Group 1 Substance (fibrous form)
1,2,4-TRIMETHYLBENZENE Part 1, Group 1 Substance; Part 5 Substance
XYLENE Part 1, Group 1 Substance; Part 5 Substance
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date: 29-Dec-2009
Revision Summary No information available
HMIS Health 0 Flammability 0 Reactivity 1
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any
of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards which exist.
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End of MSDS
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Material Safety Data Sheet
Preparation Date: 04-Jan-2010 Revision Date: 29-Dec-2009 Revision Number: 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code L-69-0069B
Trade Name HB EPOXOLINE II CONVERTER
Contact Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Emergency Telephone Number 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
DANGER!
FLAMMABLE LIQUID AND VAPOR.
HARMFUL IF INHALED.
MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT.
HARMFUL OR FATAL IF SWALLOWED.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Potential Health Effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute Effects
Eyes Moderately irritating to the eyes.
Skin Irritating to skin. May cause sensitization by skin contact.
Inhalation Irritating to respiratory system. Respirable crystalline silica (quartz) can cause silicosis, a
fibrosis (scarring) of the lungs.
Ingestion May be harmful if swallowed.
Chronic Effects
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Cancer hazard.
Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure.)
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders.
Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.
Potential Environmental Effects See Section 12 for additional Ecological information
Target Organ Effects Central nervous system, Central Vascular System, Eyes, Lungs, Respiratory system, Skin
3. COMPOSITION/INFORMATION ON INGREDIENTS
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
CAS-No Weight %
Component
14807-96-6 30 - 60
TALC (RESPIRABLE DUST)
10 - 30
BISPHENOL A TYPE EPOXY RESIN
98-56-6 20.2996
BENZENE, 1-CHLORO-4-
(TRIFLUOROMETHYL)-
25036-25-3 10 - 30
EPOXY RESIN
14808-60-7 5.3028
CRYSTALLINE SILICA (QUARTZ)
540-88-5 3.5761
tert-BUTYL ACETATE
95-63-6 0.5072
1,2,4-TRIMETHYLBENZENE
1330-20-7 0.2639
XYLENE
108-67-8 0.1268
1,3,5-TRIMETHYLBENZENE
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable Properties Flammable.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -
Foam - Dry chemical
Hazardous Decomposition Products Oxides of carbon, hydrocarbons. Aldehydes. Chlorine. Fluorine.
Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective Equipment and Precautions for Firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier than
air and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system.
Methods for Cleaning Up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
Other Information Not applicable
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7. HANDLING AND STORAGE
Handling
Close container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. If
splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.
When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Storage
Keep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.
Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all
vapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)
TWA: 2 mg/m3 TWA: 2 mg/m3 TWA: 3 mg/m3 TWA: 2 mg/m3 TWA: 2 mg/m3
TALC (RESPIRABLE DUST)
TWA: 2.5 mg/m3 TWA: 2.5 mg/m3 TWA: 2.5 mg/m3
BENZENE, 1-CHLORO-4-
(TRIFLUOROMETHYL)-
TWA: 0.025 mg/m3 TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 TWA: 0.10 mg/m3 TWA: 0.1 mg/m3
CRYSTALLINE SILICA
(QUARTZ)
TWA: 950 mg/m3 TWA: TWA: 950 mg/m3 TWA: TWA: 950 mg/m3 TWA: TWA: 950 mg/m3 TWA:
tert-BUTYL ACETATE TWA: 200 ppm
200 ppm 200 ppm 200 ppm 200 ppm STEL: 250
ppm STEL: 1190 mg/m3
TWA: 25 ppm TWA: TWA: 125 mg/m3 TWA:
1,2,4-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:
123 mg/m3 123 mg/m3 25 ppm STEL: 170
mg/m3 STEL: 35 ppm
TWA: 100 ppm STEL: TWA: 435 mg/m3 TWA: TWA: 434 mg/m3 TWA: TWA: 100 ppm TWA: TWA: 435 mg/m3 TWA:
XYLENE
435 mg/m3 STEL: 150
150 ppm 100 ppm STEL: 150 100 ppm STEL: 150 100 ppm STEL: 150
ppm STEL: 655 mg/m3 ppm STEL: 651 mg/m3 ppm STEL: 650 mg/m3 ppm STEL: 655 mg/m3
TWA: 25 ppm TWA: TWA: 125 mg/m3 TWA:
1,3,5-TRIMETHYLBENZENE TWA: 25 ppm TWA: 25 ppm TWA:
3
123 mg/m3
123 mg/m 25 ppm STEL: 170
mg/m3 STEL: 35 ppm
Engineering Measures Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Skin Protection Lightweight protective clothing, Apron, Impervious gloves
Eye/face Protection If splashes are likely to occur, wear Goggles.
Respiratory Protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,
wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.
Follow respirator manufacturer's directions for respirator use.
General Hygiene Handle in accordance with good industrial hygiene and safety practice.
Considerations Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point 35癈 / 95.0癋
Boiling Point/Range 98癈 / 208.0.0癋
Upper Exposure Limits No information available
Lower Exposure Limits No information available
Evaporation Rate No information available
Vapour Pressure No information available
Vapour Density No information available
Specific Gravity 1.49699
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9. PHYSICAL AND CHEMICAL PROPERTIES
Density 12.45721
VOC Content (lbs/gal) .366
% Volatile by Weight 25.9610
% Volatile by Volume 32.4136
10. STABILITY AND REACTIVITY
Chemical stability Stable. Conditions to Avoid Heat, flames and sparks.
Amines.
Incompatible Products Strong oxidizing agents. Bases. Possibility of Hazardous None under normal processing
Acids. Amines. Reactions
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
BENZENE, 1-CHLORO-4- 13 g/kg ( Rat ) 2 mg/kg ( Rabbit ) 33 mg/L ( Rat ) 4 h
(TRIFLUOROMETHYL)-
CRYSTALLINE SILICA (QUARTZ) 500 mg/kg ( Rat )
2230 mg/m3 ( Rat ) 4 h
tert-BUTYL ACETATE 4100 mg/kg ( Rat ) 2 g/kg ( Rabbit )
18 g/m3 ( Rat ) 4 h
1,2,4-TRIMETHYLBENZENE 3400 mg/kg ( Rat ) 3160 mg/kg ( Rabbit )
XYLENE 4300 mg/kg ( Rat ) 1700 mg/kg ( Rabbit ) 47635 mg/L ( Rat ) 4 h 5000 ppm (
Rat ) 4 h
24 g/m3 ( Rat ) 4 h
1,3,5-TRIMETHYLBENZENE 5000 mg/kg ( Rat )
Irritation No information available
Corrosivity No information available
Sensitization No information available
Chronic Toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component ACGIH IARC NTP OSHA Mexico
CRYSTALLINE SILICA A2 Group 1 Known X
(QUARTZ)
Mutagenic Effects No information available
Reproductive Effects No information available
Developmental Effects No information available
Teratogenicity No information available
Target Organ Effects Central nervous system, Central Vascular System, Eyes, Lungs, Respiratory system, Skin.
Endocrine Disruptor Information No information available
Component EU - Endocrine Disrupters EU - Endocrine Disruptors - Japan - Endocrine Disruptor
Candidate List Evaluated Substances Information
BISPHENOL A TYPE EPOXY RESIN Group III Chemical
EPOXY RESIN Group III Chemical
12. ECOLOGICAL INFORMATION
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12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
TALC (RESPIRABLE DUST) LC50> 100 g/L Brachydanio
rerio 96 h
BENZENE, 1-CHLORO-4- EC50 = 11.1 mg/L 5 min EC50 EC50 = 3.68 mg/L 48 h
(TRIFLUOROMETHYL)- = 13.4 mg/L 15 min EC50 =
14.3 mg/L 30 min
tert-BUTYL ACETATE LC50= 327 mg/L Pimephales EC50 = 6.38 mg/L 5 min EC50
promelas 96 h = 8.04 mg/L 15 min EC50 =
11.1 mg/L 30 min
1,2,4-TRIMETHYLBENZENE LC50= 7.72 mg/L Pimephales EC50 = 6.14 mg/L 48 h
promelas 96 h
XYLENE LC50= 13.4 mg/L Pimephales EC50 = 0.0084 mg/L 24 h EC50 = 3.82 mg/L 48 h LC50
promelas 96 h LC50= 8.05 = 0.6 mg/L 48 h
mg/L Oncorhynchus mykiss 96
h LC50= 16.1 mg/L Lepomis
macrochirus 96 h LC50= 26.7
mg/L Pimephales promelas 96
h
1,3,5-TRIMETHYLBENZENE LC50= 7.72 mg/L Pimephales EC50 = 50 mg/L 24 h
promelas 96 h LC50= 3.48
mg/L Pimephales promelas 96
h
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in accordance
with local, state and federal regulations.
Contaminated Packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other modes of Transportation.
Proper Shipping Name UN1263,PAINT,3,PGIII,ERG 128
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Does not Comply
CHINA Does not Comply
ENCS Does not Comply
KECL Does not Comply
PICCS Does not Comply
AICS Does not Comply
Component
XYLENE
U.S. Federal Regulations
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SARA 313
Component CAS-No Weight % SARA 313 - Threshold
Values
1,2,4-TRIMETHYLBENZENE 95-63-6 0.5072 1.0
XYLENE 1330-20-7 0.2639 1.0
SARA 311/312 Hazardous Categorization
Chronic Health Hazard No
Acute Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
Quantities
BENZENE, 1-CHLORO-4- X
(TRIFLUOROMETHYL)-
tert-BUTYL ACETATE X
XYLENE 100 lb X
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs
tert-BUTYL ACETATE 5000 lb
XYLENE 100 lb
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65
CRYSTALLINE SILICA (QUARTZ) 14808-60-7 Carcinogen
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
TALC (RESPIRABLE DUST) X X X X
BENZENE, 1-CHLORO-4- X X X
(TRIFLUOROMETHYL)-
CRYSTALLINE SILICA X X X X
(QUARTZ)
tert-BUTYL ACETATE X X X X
1,2,4-TRIMETHYLBENZENE X X X X X
XYLENE X X X X X
1,3,5-TRIMETHYLBENZENE X X X X X
Other International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
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WHMIS Hazard Class
B2 Flammable liquid
D2B Toxic materials
Component NPRI
1,2,4-TRIMETHYLBENZENE Part 1, Group 1 Substance; Part 5 Substance
XYLENE Part 1, Group 1 Substance; Part 5 Substance
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date: 29-Dec-2009
Revision Summary No information available
HMIS Health 0 Flammability 0 Reactivity 1
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any
of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards which exist.
End of MSDS
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