MATERIAL SAFETY DATA SHEET
______________________________________________________________________________________
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: CCW-704
Product Use: Mastic
Manufacturer/Supplier Phone Numbers
Carlisle Coatings & Waterproofing Incorporated
Medical Emergency:
8810 West 100th Street South, P.O. Box 1600CHEMTREC(USA): (800) 424-9300
Sapulpa, OK 74067-1600 CHEMTREC(International): (703) 527-3887
Internet Address: www.Carlisle-CCW.com MSDS Assistance: (918) 227-5435
Fax Number: (918) 227-0603 Fax On Demand: NA
Technical Assistance: (918) 227-5435
Customer Service: (918) 227-4533
______________________________________________________________________________________
2. COMPONENT INFORMATION
Component CAS No. Percent Range Hazardous in Blend
Asphalt 64742-93-4 40 - 60
Aromatic 64742-95-6 10 - 20
Hydrocarbons
Crystalline Silica (in 14808-60-7 0.3 ?.4
organic and inorganic
salts)
This product is hazardous according OSHA 29 CFR 1910.1200.
Hazards:
Flammable/Combustible X Acute Toxin X Chronic Toxin X Carcinogen X
Pressure X Reactive No Exposure Limit Target Organ Other
______________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency and Hazards Overview:
Mixture contains flammable components and the vapors may ignite explosively. Vapors are heavier than
air and may travel to distance sources of ignition and flash back. Harmful if swallowed or inhaled.
Overexposure to vapors may cause dizziness, headache or central nervous depression. May cause irritation
to eyes, skin and respiratory tract.
Ratings
Health 2 Flammability 2 Reactivity 0
x Inhalation x Eye x Ingestion x
Primary Route of Exposure: Skin
Health Effect Information
Eye Contact: May cause eye irritation if wiped or rubbed into eyes.
Skin Contact: May cause skin irritation if wiped or left on the skin.
Inhalation: May cause irritation of the nose, throat, and respiratory tract. At very high concentrations,
breathing vapors may cause dizziness, drowsiness, weakness, fatigue, nausea, headache, and
unconsciousness.
Issued: 12/21/00
Supersedes: 10/14/99
CCW-704 Page 1 of 7
Ingestion: Ingestion may cause symptoms similar to those of inhalation. Single dose oral toxicity is
low. If a large amount is swallowed do not induce vomiting. If the individual is drowsy or
unconscious, place on left side with the head down. Seek medical attention.
Medical Conditions Aggravated by Exposure: Prolonged skin contact with this product may defat skin
leading to irritation or dermatitis resulting in itching,
redness and rash. Over exposure may aggravate mild
reversible liver effects, mild reversible kidney effects,
blood abnormalities, cataracts.
4. FIRST AID INFORMATION
Eye Contact: Immediately flush with plenty of water for at least 15 minutes. Call a physician.
Skin Contact:. Wash promptly with soap and water, waterless hand cream or abrasive soap. Clean under
fingernails. See a physician if irritation develops.
Inhalation: Get fresh air if symptoms develop due to inhalation. Give oxygen if breathing is difficult. If
not breathing give artificial respiration and get medical attention immediately.
Ingestion:. If swallowed contact a physician immediately. Decision to induce vomiting should only be
made by a physician. Never give anything by mouth to an unconscious person.
Notes to Physician: This product contains asphalt, aromatic hydrocarbons.
5. FIRE AND EXPLOSION INFORMATION
Flammable Properties
Flash Point: 108篎 Test Method: TCC
Flame extension: NA Test Method: NA
Flammable Limits in Air
Upper Percent: 12.6
Lower Percent: 1.9
Autoignition Temperature: 880篎 Test Method: NA
NFPA Classification: H 2 F2 R0
Extinguishing Media: CO2, regular foam or dry chemical.
Fire Fighting Measures
Special Fire Fighting Procedures and Equipment: Firemen must wear full-face air-supplied mask and
full protective clothing. Containers should be kept
cool with water spray. Liquid or vapor may settle in
low areas or travel along ground to ignition sources
where they may ignite or explode and flash back.
Unusual Fire and Explosion Conditions: Vapors may be ignited by heat or sparks. Material may
collect static charges which can cause an incendiary electrical
discharge. Empty container contains product residues. Do
not pressurize, cut, weld, drill, grind or expose containers to
heat, flame, sparks, static electricity or other sources of
ignition. They may explode and cause injury or death.
Issued: 12/21/00
Supersedes: 10/14/99
CCW-704 Page 2 of 7
Hazardous Combustion By-Products: CO, CO2, unburned hydrocarbons.
______________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Personnel Safeguards: Immediately evacuate all non-essential personnel to safe areas. Emergency
responders should wear proper protective gears before entering the affected area.
Observe all precautions noted above.
Regulatory Notifications: Waste of this product is defined as hazardous according to U.S. EPA. Spill
reporting requirements and reportable quantities vary by region. Consult all
applicable state and local regulations. For Canada, observe all precautions
noted above.
Containment and Clean up: Remove all sources of ignition. Do not use metal shovels or other tools
which could create sparks. Prevent liquids from entering sewers, drains or
waterways by diking with sand or earth. Absorb with vermiculite or other
absorbent material and remove for disposal. Use adequate ventilation to
promote drying. Wash area with mild detergent and water.
.
7. HANDLING AND STORAGE INFORMATION
Handling: Avoid prolonged contact with the skin. Use solvent resistant gloves. Avoid rubbing eyes while
handling. Use only in areas with adequate ventilation. Do not take internally. Keep out of
reach of children. Avoid breathing vapors. Wash hands thoroughly after each use especially
before eating or smoking.
Storage: Store in cool ventilated space away from direct sunlight. Keep away from heat, sparks, open
flames, electrical equipment, welding torches, pilot lights, etc. Keep containers tightly closed and
upright when not in use. Keep below 110篎.
Empty Container Warnings
Drums: Do not reuse empty drums or containers. Do not cut, drill, grind or weld on or near the empty
drums.
Plastic: Not applicable.
______________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION INFORMATION
Exposure Limits and Guidelines
Component CAS No. Exposure Limit
5 mg/m3 TWA
Asphalt 64742-93-4
Aromatic Hydrocarbons 64742-95-6 50 ppm TWA
Personal Protective Equipment
Eye/Face Protection: Wear safety goggles.
Skin Protection: Use solvent resistant rubber gloves.
Respiratory Protection: Provide adequate ventilation to maintain vapors below TLV/TWA. If vapor
levels are exceeded, use NIOSH approved respirator, both during and
immediately after application, until vapor levels are below limits.
Issued: 12/21/00
Supersedes: 10/14/99
CCW-704 Page 3 of 7
Personal Hygiene: Avoid rubbing eyes during handling. Use good personal hygiene practices to avoid
incidental ingestion.
Engineering Controls / Work Practices
Ventilation: Provide local exhaust or area ventilation to maintain concentration of vapors below
TLV/TWA. Use explosion proof ventilation equipment. Take care not to draw vapors into
non-explosion proof or spark generating equipment.
Other: Source of clean water should be available in the work area for flushing eyes and skin. Wash
thoroughly with soap and water after use and before eating and/or smoking.
______________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Black paste Vapor Pressure: 3 mm Hg @ 20篊
Odor: Petroleum odor
Physical state: paste Vapor Density (air=1): 4.2
pH: Not applicable Percent Volatile by Volume: 10 ?20
DOT Corrosivity: NA Volatile Organic Content: 200 g/liter
Boiling Point: 308 to 355篎 Molecular Weight: NA
Melting Point: NA Average Carbon Number: NA
Specific Gravity: 1.24 Viscosity @ 100 F: NA
Pour Point: NA Viscosity @ 40 C: NA
Solubility in Water: Negligible
Octanol / Water Coefficient: Log Kow = NA
______________________________________________________________________________________
10. STABILITY AND REACTIVITY INFORMATION
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: Avoid contact with heat, sparks, open flame and fire.
Incompatible Materials to Avoid: Strong oxidizers.
______________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION (will only print available data)
Primary Eye Irritation: Irritating
Primary Skin Irritation: Irritating
Acute Dermal Toxicity: NA
Subacute Dermal Toxicity: NA
Dermal Sensitization: NA
Inhalation Toxicity: Product toxicity has not been determined. Following are component data:
LC50
Cumene (a component in aromatic hydrocarbons):
Mouse 2,000 ppm 7 hr
Inhalation Sensitization: NA
Issued: 12/21/00
Supersedes: 10/14/99
CCW-704 Page 4 of 7
Oral Toxicity: Product toxicity has not been determined. Following are component data:
LD50
Cumene (a component in aromatic hydrocarbons):
Mouse 12,750 mg/kg
Rat 1,400 mg/kg
Mutagenicity: NA
Carcinogenicity: California Proposition 65 Chemicals lists crystalline silica as a cancer causing agent.
The filler may contains small amount of crystalline silica.
Reproductive Toxicity: NA
Teratogenicity: NA
Immunotoxicity: NA
Neurotoxicity: NA
Other:
No other toxicological information available
______________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Aquatic Toxicity: Not known
Terrestrial Toxicity: Not known
Chemical Fate and Transport: Not known
No other ecological information available.
______________________________________________________________________________________
13. DISPOSAL INFORMATION
Regulatory Information: Consult all regulations (federal, state, provincial, local etc.) or a qualified waste
disposal firm when characterizing waste for disposal.
Waste Disposal Methods: Dispose of waste in accordance with all applicable regulations. Waste which
results from the clean-up of spilled product, absorbed by a noncombustible
absorbing media, would not be considered a hazardous waste once aromatic
hydrocarbons have evaporated.
______________________________________________________________________________________
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation (DOT)
Highway / Rail (Bulk): Combustible liquid N.O.S.(contains heavy aromatic hydrocarbons) NA1993
Highway / Rail (Non-Bulk): PGIII, Combustible liquid N.O.S., NA1993
The DOT description is provided to assist in the proper shipping classification of this product and
may not be suitable for all shipping descriptions.
Issued: 12/21/00
Supersedes: 10/14/99
CCW-704 Page 5 of 7
International Information
Class 3.3
Vessel: IMDG Regulated: IMDG Not Regulated
Class 3
Air: ICAO Regulated: ICAO Not Regulated
Other: No other information available.
______________________________________________________________________________
15. Regulatory Information
Regulatory Lists
U.S. TSCA Inventory: All components of this material are on the US TSCA Inventory or exempt from
listing on the TSCA Inventory.
Sara Section 313: This product contains the following Sara, Title III, Section 313 Chemicals:
Chemical CAS Number Percent in Product
1,2,4 -Trimethylbenzene 95-63-6 4?
Regulatory Lists Searched
Health & Safety: NA
Environmental: NA
International: NA
State: FL, CA, MA, MN, PA, RI
National Inventories: NA
SARA 311 / 312 Categories
Yes Yes Yes Yes No
Acute: Chronic: Fire: Pressure: Reactive:
Not Regulated:
California Proposition 65 Information: Warning! This product contains substances known to the State
of California to cause cancer.
Canadian WHMIS Classification
Class: B
Division: 3
This product has been classified in accordance with hazard criteria of the Controlled Products
Regulations (CPR). This MSDS contains all the information required by the CPR.
European Union Classification
Hazard Symbol:
Highly Harmful
Flammable
Risk Phrases: R10, R65
Safety Phrases: S51, S24/25, S37/39, S62
Other Regulations: No other information available.
Issued: 12/21/00
Supersedes: 10/14/99
CCW-704 Page 6 of 7
______________________________________________________________________________________
16. OTHER INFORMATION
Health and Environmental Label Language
All ingredients contained in this product are included on the US EPA Toxic Substances Control Act
(TSCA) inventory or exempt from listing on the TSCA inventory. All ingredients contained in this
product comply with the requirements of the Canadian Environmental Protection Act (CEPA) and are
listed on the Domestic Substance List (DSL) or Non-Domestic Substance List (NDSL)
MSDS Revisions
Previous Version Date: 10/14/99
Section
Old Information:
New Information:
Prepared By: Paul Cheng Date: 10/30/00
Disclaimer of Warranty: The information contained herein is based upon data and information available
to us, and reflects our best professional judgement. This product may be formulated in part with
components purchased from other companies. In many instances, especially when proprietary or trade
secret materials are sued, Pennzoil Products company must rely upon the hazard evaluation of such
components submitted by that product's manufacturer or importer. No warranty of merchantability, fitness
for any use, or any other warranty is expressed or implied regarding the accuracy of such data or
information. The results to be obtained from the use thereof, or that any such use does not infringe any
patent, since the information contained herein may be applied under conditions of use beyond our control
and with which we may be unfamiliar, we do not assume responsibility for the results of such application.
This information is furnished upon the condition that the person receiving it shall make his own
determination of the suitability of the material for his particular use.
Issued: 12/21/00
Supersedes: 10/14/99
CCW-704 Page 7 of 7
|