MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: AUTOMOTIVE AFTERMARKET
TRADE NAME:
3M(TM) Super Duty Rubbing Compound, P.N. 05954, 05955, 05956
ID NUMBER/U.P.C.:
60-9800-1132-8 00-51131-05954-2 60-9800-1527-9 00-51131-05956-6
60-9898-3201-3 00-51144-05955-3 CN-1006-9453-4 - - -
XC-0616-7891-5 - - -
ISSUED: January 02, 2001
SUPERSEDES: April 14, 2000
DOCUMENT: 10-2844-8
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1. INGREDIENT C.A.S. NO. PERCENT
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TRIPOLI (CRYSTALLINE SILICA)............ 1317-95-9 40.0 - 50.0
WATER................................... 7732-18-5 10.0 - 30.0
KEROSENE................................ 8008-20-6 10.0 - 30.0
STODDARD SOLVENT........................ 8052-41-3 5.0 - 10.0
SOLVENT-REFINED HEAVY PARAFFINIC
PETROLEUM DISTILLATES................. 64741-88-4 1.0 - 5.0
OLEIC ACID.............................. 112-80-1 1.0 - 5.0
1,2,4-TRIMETHYLBENZENE.................. 95-63-6 0.1 - 1.0
The components of this product are in compliance with the chemical
notification requirements of TSCA. All applicable chemical
ingredients in this material are listed on the European Inventory of
Existing Chemical Substances (EINECS), or are exempt polymers whose
monomers are listed on EINECS.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
1,2,4-TRIMETHYLBENZENE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super Duty Rubbing Compound, P.N. 05954, 05955, 05956
January 02, 2001 PAGE 2
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2. PHYSICAL DATA
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BOILING POINT:................. 212 F
VAPOR PRESSURE:................ N/D
VAPOR DENSITY:................. > 1.00 Air=1
EVAPORATION RATE:.............. > 1.00 Ether=1
SOLUBILITY IN WATER:........... DILUTABLE
SPECIFIC GRAVITY:.............. 1.280 Water=1
PERCENT VOLATILE:.............. 50 % by wt
pH:............................ 9.4-9.6
VISCOSITY:..................... 7-12K CPS
MELTING POINT:................. N/D
APPEARANCE AND ODOR:
Liquid, viscous, tan colored, slight pine odor
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... 133 F PENSKY-MARTIN CLOSED CUP
FLAMMABLE LIMITS - LEL:........ 1.60 %
FLAMMABLE LIMITS - UEL:........ 6.00 %
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
None known.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 2 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Strong Oxidizing Agents.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super Duty Rubbing Compound, P.N. 05954, 05955, 05956
January 02, 2001 PAGE 3
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4. REACTIVITY DATA (continued)
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HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Hydrocarbons.
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Contain spill. Evacuate unprotected personnel
from hazard area. Cover with inorganic absorbent material. Cover
spill area with Light Water Brand or other ATC foam. (For further
information on ATC foam usage, contact 3M Fire Protection Systems.)
Collect using non-sparking tools. Clean up residue with water.
Place in an approved metal container. Seal the container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator. Disposal
alternative: Dispose of waste product in a facility permitted to
accept chemical waste.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 2.69 lb/gal calculated per SCAQMD rule 443.1.
Volatile Organic Compounds: 323 gms/liter calculated per SCAQMD rule
443.1.
VOC Less H2O & Exempt Solvents: 431 gms/liter calculated per SCAQMD rule
443.1.
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifies as a
reportable quantity. U.S. EPA Hazardous Waste Number = D001
(Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super Duty Rubbing Compound, P.N. 05954, 05955, 05956
January 02, 2001 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. Wear vented goggles.
SKIN PROTECTION:
Avoid prolonged or repeated skin contact. Wear appropriate gloves
when handling this material. A pair of gloves made from the
following material(s) are recommended: nitrile rubber, polyvinyl
alcohol, fluoroelastomer (Viton).
RECOMMENDED VENTILATION:
Use in a well-ventilated area. Provide sufficient ventilation to
maintain emissions below recommended exposure limits. If exhaust
ventilation is not adequate, use appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors. Avoid breathing of dust created by
cutting, sanding or grinding. Select one of the following NIOSH
approved respirators based on airborne concentration of contaminants
and in accordance with OSHA regulations: Half-mask organic vapor
respirator with dust/mist prefilter, full-face organic vapor
respirator with dust/mist prefilter
Continuous spurring of dry buff pads may produce dust conditions in
excess of the OSHA Permissible Exposure Limit (PEL) or the Threshold
Limit Value (TLV) for crystaline silicia.
When cleaning or spurring a dry buff pad used with this product, use
appropiate local exhaust to control dust, or use appropiate
respiratory protection to avoid inhalation of dusts.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super Duty Rubbing Compound, P.N. 05954, 05955, 05956
January 02, 2001 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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RECOMMENDED STORAGE:
Keep container closed when not in use. Keep container in well-
ventilated area. Keep out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed. Keep away from heat, sparks, open
flame, and other sources of ignition. Combustible liquid and vapor.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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TRIPOLI (CRYSTALLINE SILICA)......... 0.1 MG/M3 TWA ACGIH
RESPIRABLE
TRIPOLI (CRYSTALLINE SILICA)......... 0.1 MG/M3 TWA OSHA
RESPIRABLE
WATER................................ NONE NONE NONE NONE
KEROSENE............................. 500 PPM TWA CMRG
STODDARD SOLVENT..................... 100 PPM TWA ACGIH
STODDARD SOLVENT..................... 100 PPM TWA OSHAV
STODDARD SOLVENT..................... 500 PPM TWA OSHA
SOLVENT-REFINED HEAVY PARAFFINIC
PETROLEUM DISTILLATES.............. 5 MG/M3 TWA CMRG
OLEIC ACID........................... 10 MG/M3 TWA OSHA
as mist
OLEIC ACID........................... 10 MG/M3 TWA ACGIH
as mist
1,2,4-TRIMETHYLBENZENE............... NONE NONE NONE NONE
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
regulatory authority.
- NONE: None Established
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super Duty Rubbing Compound, P.N. 05954, 05955, 05956
January 02, 2001 PAGE 6
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Mild Eye Irritation: signs/symptoms can include redness, swelling,
pain, and tearing.
SKIN CONTACT:
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
May be absorbed through the skin and produce effects similiar to
those caused by inhalation and/or ingestion.
INHALATION:
May be harmful if inhaled.
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness.
Silicosis: signs/symptoms can include shortness of breath and
persistent coughing.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
IF SWALLOWED:
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, muscular weakness,
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super Duty Rubbing Compound, P.N. 05954, 05955, 05956
January 02, 2001 PAGE 7
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8. HEALTH HAZARD DATA (continued)
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incoordination, slowed reaction time, fatigue, blurred vision,
slurred speech, giddiness, tremors and convulsions.
CANCER:
WARNING: Contains a chemical which can cause cancer. (1317-95-9)
(IARC 1 - human carcinogen, Calif. Proposition 65)
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SECTION CHANGE DATES
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INGREDIENTS SECTION CHANGED SINCE April 14, 2000 ISSUE
PRECAUTIONARY INFO. SECTION CHANGED SINCE April 14, 2000 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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