Page: 1
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: SUPER PRO CLEAR SPOT & PANEL ?PART B HMIS CODES: H F R P
PRODUCT CODE: 2699 CATALYST 2*2 0 X
================== SECTION I - MANUFACTURER IDENTIFICATION =================
MANUFACTURER'S NAME: PCL
ADDRESS : 3150 E. PICO BLVD.
LOS ANGELES, CA 90023-3683
EMERGENCY PHONE(CHEMTREC) : (800) 424-9300 DATE PRINTED : 4/29/2009
INFORMATION PHONE : (800) 672-4900 NAME OF PREPARER :
========== SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION =========
VAPOR PRESSURE
REPORTABLE COMPONENTS CAS NUMBER mmHG @TEMP(F)
--------------------------------------------------------------------------------
1,6-HEXAMETHYLENE DIISOCYANATE, HDI 28182-81-2
~ PARACHLOROBENZOTRIFLUORIDE 98-56-6 5.3 68
OSHA PEL: NE, ACGIH TLV: NE
UCAR N-PENTYL PROPIONATE 624-54-4 1.5 68
WHITE SPIRITS 64742-82-1 3 68
OSHA PEL: NE, ACGIH TLV: NE
~ 1,2,4-TRIMETHYLBENZENE 95-63-6 1.7 68
OSHA PEL: 400 ppm, ACGIH TLV: 50 ppm
~Indicates toxic chemical(s) subject to the reporting requirements of section
313 of Title III and of 40 CFR 372.
=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============
BOILING RANGE (Deg F): 282 - 329 DENSITY: 9.19 lb/gal
VAPOR DENSITY: HEAVIER THAN AIR SPECIFIC GRAVITY (H2O=1): 1.1
COATING V.O.C.: 2.92 lb/gal MATERIAL V.O.C.: 2.32 lb/gal
COATING V.O.C.: 350 g/l MATERIAL V.O.C.: 278 g/l
SOLUBILITY IN WATER: Insoluble EVAPORATION RATE: SLOWER THAN ETHER
APPEARANCE AND ODOR: Pale yellow liquid with mild odor
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============
FLASH POINT (Deg F): 104 METHOD USED: TOC
FLAMMABLE LIMITS IN AIR BY % VOLUME- LOWER: .9 UPPER: 10.5
EXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL
SPECIAL FIREFIGHTING PROCEDURES
Full emergency equipment with self-contained breathing apparatus and full
protective clothing should be worn by fire fighters. During fire, HDI vapors and
other irritating , highly toxic gases may be generated by thermal decomposition.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Isolate from heat, electrical equipment, sparks and open flame. Closed container
MATERIAL SAFETY DATA SHEET
2699 Page: 2
may explode when exposed to extreme heat or burst when contaminated with water.
Solvent vapors may be heavier than air. Stagnant air may cause vapors to
accumulate and travel along the ground to an ignition source which may result in
a flash back to the source of the vapor.
======================== SECTION V - REACTIVITY DATA =======================
STABILITY: STABLE
CONDITIONS TO AVOID
Excessive heat, sparks or open flames.
INCOMPATIBILITY (MATERIALS TO AVOID)
Water, amines, strong bases, alcohols, metal compounds and surface active
materials
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
Carbon dioxide, carbon monoxide, oxides of nitrogen, traces of HCN and HDI
HAZARDOUS POLYMERIZATION: MAY OCCUR WILL NOT OCCUR
May occur if in contact with moisture or other materials which react with
isocyanates. May occur at temperatures over 400 癋.
==================== SECTION VI - HEALTH HAZARD DATA =======================
INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
May cause irritation of the mucous membranes in the respiratory tract (nose,
throat, lungs) causing runny nose, sore throat, coughing, chest discomfort,
shortness of breath and reduced lung function (breathing obstruction).
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE
Skin contact may cause irritation. Symptoms of skin irritation may be reddening,
swelling, scaling or blistering. Eye contact may cause tearing, reddening and
swelling of the eyes.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
Skin absorption may cause systemic effects similar to those identified under
inhalation effects.
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
Ingestion may result in irritation and possible corrosive action in the mouth,
stomach and digestive tract.
HEALTH HAZARDS (ACUTE AND CHRONIC)
Acute: May cause irritation of the mucous membranes, eyes, skin and throat.
Other symptoms are headache, nausea, fatigue and loss of appetite. Ingestion may
cause vomiting which may result in aspiration of the solvent resulting in
chemical pneumonitis. Chronic: May cause lung damage, skin sensitization and
neurotoxic effects including permanent brain and nervous system damage.
CARCINOGENICITY: NTP CARCINOGEN: No IARC MONOGRAPHS: No OSHA REGULATED: No
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Asthma and any other respiratory disorders (bronchitis, emphysema, hyper-
reactivity), skin allergies and eczema.
MATERIAL SAFETY DATA SHEET
2699 Page: 3
EMERGENCY AND FIRST AID PROCEDURES
INHALATION: REMOVE TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION IF NECESSARY.
SPLASH(EYES): FLUSH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. SPLASH(SKIN): WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND WASH THOROUGHLY BEFORE REUSE. FOR SEVERAL
EXPOSURES GET UNDER SAFETY SHOWER AFTER REMOVING CLOTHING, THEN GET MEDICAL
ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GIVE 1 TO 2 CUPS OF MILK OR WATER
TO DRINK. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING PERSON.
CONSULT PHYSICIAN IMMEDIATELY.
=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
REMOVE ALL SOURCES OF IGNITION AND PROVIDE VENTILATION. COVER THE SPILL WITH
SAWDUST, VERMICULITE OR OTHER ABSORBENT MATERIAL. COLLECT MATERIAL IN OPEN
CONTAINERS. REMOVE CONTAINERS TO A SAFE PLACE AND ALLOW TO STAND FOR 24 TO 48
HOURS.
WASTE DISPOSAL METHOD
Waste must be disposed of in accordance with federal, state and local
environmental control regulations. Incineration is the preferred method. Empty
containers must be handled with care due to product residue and flammable
solvent vapor. Decontaminate containers prior to disposal. DO NOT HEAT OR CUT
EMPTY CONTAINER WITH ELECTRIC OR GAS TORCH.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Keep away from heat, sparks and open flame. Ground containers during storage and
transfer operations. Store in tightly closed containers to prevent moisture
contamination. Do not reseal if contamination is suspected. Avoid contact with
skin and eyes.
OTHER PRECAUTIONS
If container is exposed to high heat, it can be pressurized and possibly rupture
explosively. HDI reacts slowly with water to form carbon dioxide (CO2) gas. This
gas can cause sealed containers to expand and possibly rupture explosively.
===================== SECTION VIII - CONTROL MEASURES ======================
RESPIRATORY PROTECTION
Use self-contained breathing apparatus where vapor concentration may be above
TLV limits. Below TLV limits, use a combination vapor and particulate respirator
for spray application or a vapor respirator for non-spray applications.
VENTILATION
Exhaust ventilation sufficient to keep the airborne concentration of the
solvents, HDI and polyisocyanate below their respective TLV must be utilized.
PROTECTIVE GLOVES
Chemical resistant gloves: Cover as much of the skin area as possible with
appropriate clothing.
MATERIAL SAFETY DATA SHEET
2699 Page: 4
EYE PROTECTION
Safety glasses, splash goggles or face shield. Contact lenses should not be
worn.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
Safety showers and eyewash stations should be provided.
WORK/HYGIENIC PRACTICES
Wash hands thoroughly before eating or using the washroom. Smoke in smoking
areas only.
===================== SECTION IX - TRANSPORT INFORMATION ====================
DOT (GROUND)
1.3 gallons (5 liters) or less:
UN1263,Paint,3,PGIII, "Ltd. Qty."
Greater than 1.3 gallons (5 liters):
UN1263, Paint,3,PGIII
AIR
UN1263,Paint,3,PGIII
==================== SECTION X - REGULATORY INFORMATION ====================
CALIFORNIA PROPOSITION 65
None
========================= SECTION XI - DISCLAIMER ===========================
The information contained herein is based on the data available to us and is
believed to be correct. However, PCL makes no warranty expressed or implied
regarding the accuracy of these data or the results to be obtained from the use
thereof. PCL assumes no responsibility for injury from the use of the product
described herein.
|