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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : 5FW90 FLAT BLACK 9702835
IDENTIFICATION NUMBER: V2604 830
DATE PRINTED : 10/23/97
PRODUCT USE/CLASS : DEM-KOTE VOC AEROSOL
SUPPLIER: MANUFACTURER:
Rust-Oleum Corporation Rust-Oleum Corporation
11 Hawthorn Parkway 11 Hawthorn Parkway
Vernon Hills, Illinois Vernon Hills, Illinois
60061 USA 60061 USA
(847) 367-7700 Rust-Oleum Corp. (847) 367-7700 Rust-Oleum Corp.
Mon.-Fri, 8:00 AM-4:30 PM Mon.-Fri, 8:00 AM-4:30 PM
PREPARER: LJW, PHONE: , PREPARE DATE: 06/11/97
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 XYLENE 1330-20-7 30.0 %
02 ACETONE 67-64-1 20.0 %
03 PROPANE 74-98-6 15.0 %
04 COPOLYMER ALKYLD RESIN SOLUTION MIXTURE 10.0 %
05 ETHYLBENZENE 100-41-4 10.0 %
06 Magnesium Silicate 14807-96-6 10.0 %
07 Calcium Carbonate 1317-65-3 10.0 %
08 N-BUTANE 106-97-8 5.0 %
09 ISOBUTANE 75-28-5 5.0 %
10 VM&P NAPHTHA(PETROLEUM DISTILLATES) 8032-32-4 5.0 %
11 Carbon Black 1333-86-4 5.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 100PPM 150PPM 100PPM N.E. N.E. NO
02 750 PPM 1000 PPM 750 PPM N.E. N.E. NO
03 ASPHYXIANT N.E. 1000 PPM N.E. N.E. YES
04 N.E. N.E. N.E. N.E. N.E. NO
05 100 PPM 125 PPM 100 PPM N.E. N.E. NO
06 10mg/m3 N.E. 15mg/m3 N.E. N.E. NO
(Continued on Page 2)
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Product: V2604 830 Preparation Date: 06/11/97 Page 2
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
07 10mg/m3 N.E. 15mg/m3 N.E. N.E. NO
08 800 PPM N.E. N.E. N.E. N.E. NO
09 N.E. N.E. N.E. N.E. N.E. NO
10 300 PPM N.E. 300 ppm N.E. N.E. NO
11 3.5 mg/m3 N.E. 3.5 mg/m3 N.E. N.E. NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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*** EMERGENCY OVERVIEW ***: Harmful if inhaled. Harmful if swallowed.
Extremely flammable liquid and vapor. Vapors may cause flash fire or
explosion.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin
irritation. Prolonged or repeated contact may cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas,
vapor, mist or dust concentrations may be harmful if inhaled. Avoid
breathing vapors or mists. High vapor concentrations are irritating to the
eyes, nose, throat and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if
swallowed. Aspiration hazard if swallowed; can enter lungs and cause
damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous
system disorder (e,g.,narcosis involving a loss of coordination, weakness,
fatigue, mental confusion, and blurred vision) and/or damage. Reports have
associated repeated and prolonged occupational overexposure to solvents
with permanent brain and nervous system damage. Overexposure to xylene in
laboratory animals has been associated with liver abnormalities, kidney,
lung, spleen and eye damage as well as anemia. Effects in humans have
included liver and cardiac
abnormalities. Contains carbon black. Chronic inflammation, lung fibrosis,
and lung tumors have been observed in some rats experimentally exposed
for long periods of time to excessive concentrations of carbon black and
several insoluble fine dust particles. Tumors have not been observed in
other animal species (i.e., mouse and hampster) under similar circumstances
and study conditions. Epidemiological studies of North American workers
show no evidence of clinically significant adverse health effects due to
occupational exposure to carbon black. Carbon black is listed as a Group
2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed
as A4-
(Continued on Page 3)
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Product: V2604 830 Preparation Date: 06/11/97 Page 3
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| SECTION 3 - HAZARDS IDENTIFICATION |
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"not classified as a human carcinogen" by the American Conference of
Govermental Industrial Hygienists. Significant exposure is not
anticipated during brush application or drying. Risk of overexposure
depends on duration and level of exposure to dust from repeated sanding of
surfaces or spray mist and the actual concentration ofcarbon black in the
formula.
PRIMARY ROUTE(S) OF ENTRY: INHALATION EYE CONTACT
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| SECTION 4 - FIRST AID MEASURES |
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FIRST AID - EYE CONTACT: Hold eyelids apart and flush with plenty of water
for at lease 15 minutes. Get medical attention.
FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention
if irritation develops or persists.
FIRST AID - INHALATION: No Information.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give
anything by mouth because this material can enter the lungs and cause
severe lung damage. Get immediate medical attention.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: *** F LOWER EXPLOSIVE LIMIT: 0.9 %
UPPER EXPLOSIVE LIMIT: 12.8 %
AUTOIGNITION TEMPERATURE: ND
EXTINGUISHING MEDIA: DRY CHEMICAL FOAM WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 DEG. F. -
EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective.
Closed containers may explode when exposed to extreme heat due to buildup
of steam. Closed containers may explode when exposed to extreme heat.
Vapors may form explosive mixtures with air. Vapors can travel to a source
of ignition and flash back. Keep containers tightly closed. Isolate from
heat, electrical equipment, sparks and open flame. Perforation of the
pressurized container may cause bursting of the can. Closed containers may
explode when exposed to extreme heat.
SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe
distance.
(Continued on Page 4)
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Product: V2604 830 Preparation Date: 06/11/97 Page 4
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate the
area, remove all sources of ignition and ventilate well. Contain spilled
liquid with sand or earth. DO NOT use combustible materials such as
sawdust. Remove all sources of ignition, ventilate area and remove with
inert absorbent and non-sparking tools. Dispose of according to local,
state (provincial) and federal regulations. Do not incinerate closed
containers.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Wash thoroughly after handling. Wash hands before eating. Use
only in a well-ventilated area. Follow all MSDS/label precautions even
after container is emptied because it may retain product residues. Avoid
breathing vapor or mist.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical
equipment, sparks and open flame. Do not store above 120 degrees F. Store
large quantities in buildings designed and protected for storage of NFPA
Class I flammable liquids. Contents under pressure. Do not expose to heat
or store above 120 degrees F.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation,
or other engineering controls to control airborne levels below recommended
exposure limits. Use explosion-proof ventilation equipment. Prevent
build-up of vapors by opening all doors and windows to achieve
cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying
respirator with an organic vapor cartridge or canister may be permissible
under certain circumstances where airborne concentrations are expected to
exceed exposure limits. Protection provided by air purifying respirators
is limited. Use a positive pressure air supplied respirator if there is
any potential for an uncontrolled release, exposure levels are not known,
or any other circumstances where air purifying respirators may not provide
adequate protection.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and
absorption of this material through the skin. Nitrile or Neoprene gloves
may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of
liquids.
(Continued on Page 5)
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Product: V2604 830 Preparation Date: 06/11/97 Page 5
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial
hygienist for further information regarding personal protective equipment
and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating,
drinking or smoking.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : -44 - 300 F VAPOR DENSITY : Is heavier than air
ODOR : SOLVENT ODOR THRESHOLD : ND
APPEARANCE : LIQUID EVAPORATION RATE: Is faster than Ether
SOLUBILITY IN H2O : SLIGHT
FREEZE POINT : ND SPECIFIC GRAVITY: 0.9818
VAPOR PRESSURE : ND pH @ 0.0 % : ND
PHYSICAL STATE : LIQUID VISCOSITY : ND
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Avoid temperatures above 120 degrees F. Avoid all
possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids
and strong alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: By open flame, carbon monoxide and
carbon dioxide.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
XYLENE RAT 4300MG/KG RAT 5000PPM 4HR
ACETONE RAT 5800MG/KG RAT 50100MG/M^3 8H
PROPANE N.E. N.E.
COPOLYMER ALKYLD RESIN SOLUTION 4300MG/KG RAT 5000PPM 4HR
ETHYLBENZENE RAT 3500MG/KG N.A.
Magnesium Silicate None None
Calcium Carbonate None None
(Continued on Page 6)
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Product: V2604 830 Preparation Date: 06/11/97 Page 6
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
N-BUTANE RAT 658G/M^3 4HR N.E.
ISOBUTANE N.E. N.E.
VM&P NAPHTHA(PETROLEUM DISTILLATES) N.D. N.D.
Carbon Black Rat>10000mg/kg. N.A.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL INFORMATION: Product is a mixture of listed components.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: Dispose of material in accordance to local, state and
federal regulations and ordinances. Do not allow to enter storm drains or
sewer systems.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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No transportation information is available.
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| SECTION 15 - REGULATORY INFORMATION |
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U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD PRESSURIZED
GAS HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
XYLENE 1330-20-7 30.0 %
(Continued on Page 7)
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Product: V2604 830 Preparation Date: 06/11/97 Page 7
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| SECTION 15 - REGULATORY INFORMATION |
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----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
ETHYLBENZENE 100-41-4 10.0 %
1,2,4-TRIMETHYLBENZENE 95-63-6 1.0 %
TOLUENE 108-88-3 0.1 %
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No information is available.
U.S. STATE REGULATIONS: AS FOLLOWS -
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous materials are among the top five ingredients.
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous ingredients are present at greater than 3%.
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
TOLUENE 108-88-3
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: FLAMMABILITY: REACTIVITY:
PREVIOUS MSDS REVISION DATE: 04/10/97
(Continued on Page 8)
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Product: V2604 830 Preparation Date: 06/11/97 Page 8
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| SECTION 16 - OTHER INFORMATION |
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LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
: No Information.
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The information contained on this MSDS has been checked and should be
accurate. However, it is the responsibility of the user to comply with all
Federal, State, and Local laws and regulations.
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