MATERIAL SAFETY DATA SHEET
ICI Paints North America
DEVGUARD 4160 MULTI-PURPOSE TANK & STRUCTURAL PRIMER
Paints prepared 08/06/02
HAZARDS IDENTIFICATION (ANSI Section 3) ACCIDENTAL RELEASE MEASURES (ANSI Section 6)
Primary route(s) of exposure : Inhalation, skin contact, eye contact, ingestion. Steps to be taken in case material is released or spilled : Comply with all applicable health and
environmental regulations. Eliminate all sources of ignition. Ventilate area. Spills may be collected
Effects of overexposure :
with absorbent materials. Evacuate all unnecessary personnel. Place collected material in proper
Inhalation : Irritation of respiratory tract. Prolonged inhalation may lead to mucous membrane
container. Complete personal protective equipment must be used during cleanup. Large spills - shut
irritation, fatigue, drowsiness, dizziness and/or lightheadedness, headache, uncoordination,
off leak if safe to do so. Dike and contain spill. Pump to storage or salvage vessels. Use absorbent
nausea, vomiting, diarrhea, blurred vision, coughing, difficulty with speech, central nervous
to pick up excess residue. Keep salvageable material and rinse water out of sewers and water
system depression, intoxication, metallic taste, anesthetic effect or narcosis, difficulty of
courses. Small spills - use absorbent to pick up residue and dispose of properly.
breathing, bronchitis, fever and chills, dehydration, tremors, liver damage, kidney damage,
925 Euclid Avenue Cleveland, Ohio 44115
pulmonary edema, loss of consciousness, respiratory failure, asphyxiation, death.
HANDLING AND STORAGE (ANSI Section 7)
Skin contact : Irritation of skin. Prolonged or repeated contact can cause dermatitis, defatting,
blistering. Handling and storage : Store below 100f (38c). Keep away from heat, sparks and open flame. Keep
Eye contact : Irritation of eyes. Prolonged or repeated contact can cause conjunctivitis, blurred vision, away from direct sunlight, heat and all sources of ignition.
tearing of eyes, redness of eyes, severe eye irritation. Other precautions : Use only with adequate ventilation. Do not take internally. Keep out of reach of
Ingestion : Ingestion may cause lung inflammation and damage due to aspiration of material into children. Avoid contact with skin and eyes, and breathing of vapors. Wash hands thoroughly after
lungs, mouth and throat irritation, mucous membrane irritation, fatigue, dizziness and/or handling, especially before eating or smoking. Keep containers tightly closed and upright when not
lightheadedness, headache, nausea, vomiting, diarrhea, gastro-intestinal disturbances, central in use. Empty containers may contain hazardous residues. Ground equipment when transferring to
nervous system depression, anesthetic effect or narcosis, difficulty of breathing, liver damage, prevent accumulation of static charge.
kidney damage, pulmonary edema, convulsions, loss of consciousness.
Medical conditions aggravated by exposure : Eye, skin, respiratory disorders respiratory disorders EXPOSURE CONTROLS/PERSONAL PROTECTION (ANSI Section 8)
Respiratory protection : Control environmental concentrations below applicable exposure standards
FIRST-AID MEASURES (ANSI Section 4) when using this material. When respiratory protection is determined to be necessary, use a
Inhalation : Remove to fresh air. Restore and support continued breathing. Get emergency medical NIOSH/MSHA (Canadian z94.4) Approved elastomeric sealing- surface facepiece respirator
attention. Have trained person give oxygen if necessary. Get medical help for any breathing outfitted with organic vapor cartridges and paint spray (dust/mist) prefilters. Determine the proper
difficulty. Remove to fresh air if inhalation causes eye watering, headaches, dizziness, or other level of protection by conducting appropriate air monitoring. Consult 29CFR1910.134 For selection
discomfort. of respirators (Canadian z94.4).
Skin contact : Wash thoroughly with soap and water. If any product remains, gently rub petroleum Ventilation : Provide dilution ventilation or local exhaust to prevent build-up of vapors. Use explosion-
EMERGENCY TELEPHONE NO. (800) 545-2643
jelly, vegetable or mineral/baby oil onto skin. Repeated applications may be needed. Remove proof equipment.
contaminated clothing. Wash contaminated clothing before re-use. Personal protective equipment : Eye wash, safety shower, safety glasses or goggles. Impervious
Eye contact : Flush immediately with large amounts of water, especially under lids for at least 15 gloves, impervious clothing, face shield.
minutes. If irritation or other effects persist, obtain medical treatment.
Ingestion : If swallowed, obtain medical treatment immediately. STABILITY AND REACTIVITY (ANSI Section 10)
Under normal conditions : Stable see section 5 fire fighting measures
FIRE-FIGHTING MEASURES (ANSI Section 5) Materials to avoid : Oxidizers, acids, reducing agents, bases, amines, aluminum, nitric acid,
Fire extinguishing media : Dry chemical or foam water fog. Carbon dioxide. Closed containers may magnesium, mineral acids.
explode when exposed to extreme heat or fire. Vapors are heavier than air and may travel long Conditions to avoid : Elevated temperatures, contact with oxidizing agent, sparks, open flame, ignition
distances to a source of ignition and flash back. Vapors can form explosive mixtures in air at elevated sources.
temperatures. Closed containers may burst if exposed to extreme heat or fire. May decompose under Hazardous polymerization : Will not occur
fire conditions emitting irritant and/or toxic gases.
Fire fighting procedures : Water may be used to cool and protect exposed containers. Firefighters TOXICOLOGICAL INFORMATION (ANSI Section 11)
should use full protective clothing, eye protection, and self-contained breathing apparatus. Self-
Supplemental health information : Contains a chemical that is readily absorbed through skin.
contained breathing apparatus recommended.
Excessive inhalation of fumes may lead to metal fume fever characterized by a metallic taste in
Hazardous decomposition or combustion products : Carbon monoxide, carbon dioxide, acrid fumes,
mouth, excessive thirst, coughing, weakness, fatigue, muscular pain, nausea, chills and fever.
oxides of phosphorus, toxic gases, smoke and soot.
Notice - reports have associated repeated and prolonged occupational overexposure to solvents
with permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal. Other effects of overexposure
may include toxicity to liver, kidney, central nervous system.
4160
The information contained herein is based on data available at the time of preparation of this data sheet which ICI Paints believes to be reliable. However, no warranty is expressed or implied regarding the accuracy of this
data. ICI Paints shall not be responsible for the use of this information, or of any product, method or apparatus mentioned and you must make your own determination of its suitability and completeness for your own use,
for the protection of the environment, and the health and safety of your employees and the users of this material.
Complies with OSHA hazard communication standard 29CFR1910.1200.
Carcinogenicity : Inhalation of non-asbestiform cosmetic grade talc for 2 years at 6 and 18 mg/m3 produced Mutagenicity : No mutagenic effects are anticipated
clear evidence of carcinogenicity in female rats (lung and adrenal tumors) and some evidence of Teratogenicity : No teratogenic effects are anticipated
carcinogenicity in male rats (adrenal tumors). No evidence of carcinogenicity was demonstrated in male
and female mice exposed under the same conditions. Microscopic examination of the lungs of rats and ECOLOGICAL INFORMATION (ANSI Section 12)
mice exposed to talc revealed additional exposure related effects primarily associated with the
No ecological testing has been done by ICI paints on this product as a whole.
inflammatory response. Contains crystalline silica which is considered a hazard by inhalation. IARC
has classified crystalline silica as carcinogenic to humans (group 1). Crystalline silica is also a known
DISPOSAL CONSIDERATIONS (ANSI Section 13)
cause of silicosis, a noncancerous lung disease. The national toxicology program (NTP) has classified
crystalline silica as a known human carcinogen. The international agency for research on cancer (IARC) Waste disposal : Dispose in accordance with all applicable regulations. Avoid discharge to natural waters.
has evaluated ethylbenzene and classified it as a possible human carcinogen (group 2b) based on
sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in
REGULATORY INFORMATION (ANSI Section 15)
exposed humans. In a 2 year inhalation study conducted by the national toxicology program (NTP),
As of the date of this MSDS, all of the components in this product are listed (or are otherwise exempt from
ethylbenzene vapor at 750 ppm produced kidney and testicular tumors in rats and lung and liver tumors
listing) on the TSCA inventory. This product has been classified in accordance with the hazard criteria of the
in mice. Genetic toxicity studies showed no genotoxic effects. The relevance of these results to humans
CPR (controlled products regulations) and the MSDS contains all the information required by the CPR.
is not known.
Reproductive effects : High exposures to xylene in some animal studies, often at maternally toxic levels, have
affected embryo/fetal development. The significance of this finding to humans is not known.
Physical Data (ANSI Sections 1, 9, and 14)
Product VOC % Volatile Flash Boiling
Description Wt. / Gal. HMIS DOT, proper shipping name
Code gr. / ltr. by Volume Point Range
4160-1000 devguard 4160 multi purpose tank & structura l primer - white 11.99 408.48 47.84 108 f 277-415 *220 paint, combustible liquid, UN 1263, PGIII
4160-6120 devguard 4160 multi-purpose tank & structura l primer - gray 11.77 411.95 48.25 108 f 277-415 *220 paint, combustible liquid, UN 1263, PGIII
4160-7100 devguard 4160 multi-purpose tank & structural primer - red 11.99 409.61 47.98 108 f 277-415 *220 paint, combustible liquid, UN 1263, PGIII
Ingredients Product Codes with % by Weight (ANSI Section 2)
Chemical Name Common Name CAS. No. 4160-1000 4160-6120 4160-7100
benzene, ethyl- ethylbenzene 100-41-4 .1-1.0 .1-1.0 .1-1.0
1,3,5-trimethylbenzene 1,3,5-trimethylbenzene 108-67-8 1-5 1-5 1-5
2-heptanone methyl amyl ketone 110-43-0 5-10 5-10 5-10
antigorite antigorite 12135-86-3 5-10 5-10 5-10
iron oxide ferric oxide 1309-37-1 5-10
zinc oxide zinc oxide 1314-13-2 1-5 1-5 1-5
benzene, dimethyl- xylene 1330-20-7 1-5 1-5 1-5
titanium oxide titanium dioxide 13463-67-7 5-10 1-5
tremolite, nonasbestiform tremolite 14567-73-8 10-20 10-20 10-20
talc talc 14807-96-6 10-20 10-20 10-20
quartz quartz 14808-60-7 .1-1.0 .1-1.0 .1-1.0
anthophyllite, nonasbestiform anthophyllite 17068-78-9 1-5 1-5 1-5
ethanol ethyl alcohol 64-17-5 .1-1.0 .1-1.0 .1-1.0
naphtha (petroleum), heavy alkylate heavy solvent naphtha 64741-65-7 1-5 1-5 1-5
solvent naphtha (petroleum), light aromatic light aromatic solvent naphtha 64742-95-6 5-10 5-10 5-10
phosphoric acid, zinc salt zinc phosphate 7779-90-0 1-5 1-5 1-5
benzene,1,2,4-trimethyl- pseudocumene 95-63-6 5-10 5-10 5-10
alkyd resin alkyd resin Sup. Conf. 10-20 10-20 10-20
long oil alkyd resin long oil alkyd resin Sup. Conf. 5-10 5-10 5-10
Form: 4160, Page 2 of 3, prepared 08/06/02
Chemical Hazard Data (ANSI Sections 2, 8, 11, and 15)
ACGIH-TLV OSHA-PEL S.R.
S2 S3 CC
Std.
Common Name CAS. No. 8-Hour TWA STEL C S 8-Hour TWA STEL C S H M N I O
ethylbenzene 100-41-4 100 ppm 125 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n y n
1,3,5-trimethylbenzene 108-67-8 25 ppm 35 ppm not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
methyl amyl ketone 110-43-0 50 ppm not est. not est. not est. 100 ppm not est. not est. not est. not est. n n n n n n n n
antigorite 12135-86-3 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
ferric oxide 1309-37-1 5 mg/m3 not est. not est. not est. 10 mg/m3 not est. not est. not est. not est. n n n n n n n n
zinc oxide 1314-13-2 5 mg/m3 10 mg/m3 not est. not est. 5 mg/m3 not est. not est. not est. not est. n y n n n n n n
xylene 1330-20-7 100 ppm 150 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n n n
titanium dioxide 13463-67-7 10 mg/m3 not est. not est. not est. 10 mg/m3 not est. not est. not est. not est. n n n n n n n n
tremolite 14567-73-8 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
talc 14807-96-6 2 mg/m3 not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
quartz 14808-60-7 .05 mg/m3 not est. not est. not est. 0.1 mg/m3 not est. not est. not est. not est. n n n n n y y n
anthophyllite 17068-78-9 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
heavy solvent naphtha 64741-65-7 100 ppm not est. not est. not est. 500 ppm not est. not est. not est. not est. n n n n n n n n
light aromatic solvent naphtha 64742-95-6 not est. not est. not est. not est. 500x ppm not est. not est. not est. not est. n n n n n n n n
zinc phosphate 7779-90-0 10 mg/m3 not est. not est. not est. 15 mg/m3 not est. not est. not est. not est. n y n n n n n n
pseudocumene 95-63-6 25 ppm not est. not est. not est. not est. not est. not est. not est. not est. n y n n n n n n
Footnotes: H=Hazardous Air Pollutant, M=Marine Pollutant
C=Ceiling - Concentration that S=Skin - Additional exposure, n/a=not applicable ppm=parts per million S2=Sara Section 302 EHS P=Pollutant, S=Severe Pollutant
should not be exceeded, over and above airborn exposure, not est=not established mg/m3=milligrams per cubic meter S3=Sara Section 313 Chemical Carcinogenicity Listed By:
even instantaneously. may result from skin absorption. CC=CERCLA Chemical Sup Conf=Supplier Confidential S.R.Std.=Supplier Recommended Standard N=NTP, I=IARC, O=OSHA, y=yes, n=no
Form: 4160, Page 3 of 3, prepared 08/06/02
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