MSDS ID: 2003098 03/09
JELMAR
MATERIAL SAFETY DATA SHEET
CLR BATH & KITCHEN CLEANER
ENHANCED FORMULA
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Manufacturer: Jelmar LLC Emergency Phone Number: 1(800) 323-5497 (USA)
Address: 5550 W. Touhy Ave. Monday Friday 8:30 A.M. 4:30 P.M. CST
Skokie, IL 60077 Emergency Contact: Chemtrec 1(800) 424-9300
MSDS ID: 200309
Product Name: CLR Bath & Kitchen Cleaner Enhanced Formula
Chemical Family: Aqueous Acidic Cleaner
Formula: Proprietary Mixture
SECTION 2 HAZARDS IDENTIFICATION
PHYSICAL STATE: Liquid
COLOR: Crystal clear, water white
ODOR: Light Lavender
WARNING OVERVIEW: Irritating to eyes. Keep container closed when not in use.
POTENTIAL HEALTH EFFECTS
Routes of Exposure: Eyes. Skin. Inhalation. Ingestion.
Target Organs: No data.
Eye Contact: Irritation and blurred vision. Effects may vary depending on length of exposure,
solution concentration, and first aid measures. Prolonged contact may cause permanent damage.
Skin Contact: Not a primary skin irritant. Prolonged contact may cause dermatitis, and itching.
Inhalation: Irritation, breathing difficulties, headaches, dizziness.
Ingestion: Oral burns, vomiting, and gastrointestinal disturbance.
Medical conditions aggravated by exposure to product: Eye, skin, and respiratory disorders.
Cancer Information: This product does not contain >0.10% of the known potential carcinogens listed in
NTP, IRAC, or OSHA.
DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCT AS TOXIC FUMES MAY RESULT. KEEP OUT
OF REACH OF CHILDREN.
SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS
Component CAS# OSHA HAZARD % by Weight
1. Water 7732-18-5 NO 81-89
2. Lactic Acid 79-33-4 YES 8-12
3. Lauryldimethyl Hydroxysultaine 13197-76-7 N0 2-5
4. Propylene Glycol Normal Butyl Ether 5131-66-8 YES 1-2
SECTION 4 FIRST AID MEASURES
EYE CONTACT:
In case of eye contact, immediately rinse eye thoroughly with plenty of water. Remove contact lenses, and
continue rinsing for at least 15 minutes. Get immediate medical attention.
SKIN CONTACT: Can be irritating to skin, prolonged contact can be more severe, no adverse effects
during normal usage. In case of skin contact, rinse area for at least 15 minutes. Remove contaminated
clothing and shoes, wash thoroughly before reuse. Get immediate medical attention if irritation persists.
INHALATION: Not a significant route of exposure. Remove to fresh air. If breathing is difficult, GET
MEDICAL ATTENTION IMMEDIATELY.
Page 1 of 5
MSDS ID: 2003098 03/09
JELMAR
MATERIAL SAFETY DATA SHEET
CLR BATH & KITCHEN CLEANER
ENHANCED FORMULA
INGESTION: DO NOT induce vomiting. If fully conscious, drink 16 ounces of water. CALL A PHYSCIAN
OR POISON CONTROL CENTER IMMEDIATELY. NEVER give an unconscious person anything to ingest.
SECTION 5 FIRE FIGHTING MEASURES
FLAMMABILTY: Not flammable
FLASH POINT: None (100?C): Method: TOC
EXPLOSIVE LIMITS IN AIR: Not available
EXTINGUISHING MEDIA: Not flammable. Use appropriate media for area. Water spray, dry chemical,
alcohol foam or carbon dioxide.
FIRE FIGHTING METHODS: Evacuate area of personnel. Wear protective NIOSH-approved self-
contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition
products. Use water spray to cool fire-exposed containers. Run-off of large quantities of product from fire
control may cause pollution. Contact appropriate agencies.
HAZARDOUS COMBUSTION PRODUCTS: Carbon Monoxide. Thermal decomposition can lead to
irritating gases and vapors.
FIRE AND EXPLOSION HAZARDS: None known.
SECTION 6 ACCIDENTAL RELEASES MEASURES
Steps to be taken in Case Material is Released or Spilled: Avoid contact with skin and eyes
Small Spill: No special clean-up procedure is necessary for small (less than 1 gallon) spills. Flush spill
area with water. Wear rubber gloves.
Large Spill: Use personal protection recommended in Section 8. Isolate area, and deny entry to
unnecessary and unprotected personnel. Dam spill, and absorb with earth, sand or similar material. Place
in non-leaking containers. Dispose of collected material according to local, state, and federal regulations.
Flush residue with large amount of water. Avoid direct discharge to sewers and surface waters.
SECTION 7- HANDLING AND STORAGE
STORAGE: Store in cool, well-ventilated area, away from heat. Keep containers tightly closed. Avoid
contact with combustible materials, wood, and organic materials. Store in original container in a secure
area away from children and pets.
HANDLING: Avoid contact with eyes, skin or clothing. May be harmful or fatal if swallowed. Use with
adequate ventilation. Avoid breathing vapors or mist. Do not eat, drink, or smoke in work area. Wash hands
thoroughly after use. Consumer containers should be rinsed and recycled.
DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY
EXPLODE AND CAUSE INJURY.
DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. KEEP
OUT OF REACH OF CHILDREN.
Page 2 of 5
MSDS ID: 2003098 03/09
JELMAR
MATERIAL SAFETY DATA SHEET
CLR BATH & KITCHEN CLEANER
ENHANCED FORMULA
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
VENTILATION REQUIREMENT: Avoid prolonged breathing mists or dusts of this product. Use with
adequate ventilation. Do not use in closed or confined spaces.
RESPIRATORY PROTECTION: Not required during normal household usage. Emergency responders
should wear self-contained breathing apparatus (SCBA) to avoid inhalation of product.
EYE PROTECTION: Not required during normal household usage. Emergency responders should wear full
eye and face protection.
SKIN PROTECTION: Rubber gloves with protective cuff. Emergency responders should wear
impermeable gloves.
OTHER PROTECTION: Emergency responders should wear chemical type (impermeable) protective
clothing and footwear where direct contact with chemicals in this product is possible.
WORK/HYGIENIC PRACTICES: Wash thoroughly with soap and water after use or handling.
EXPOSURE GUIDELINES: OSHA ACGIH
COMPONENT PEL STEL/C TWA STEL/C
Water: N.E. N.E. N.E. N.E.
Lactic Acid: N.E N.E. N.E. N.E.
Lauryldimethyl Hydroxysultaine: N.E. N.E. N.E. N.E.
Propylene Glycol Normal Butyl Ether: N.E. N.E. N.E. N.E.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling point: 100?C Specific Gravity: 1.025 1.035
Vapor Pressure: N.D. Percent Volatiles: ~87.7% (Calculated)
Freezing Point: N.D. Evaporation Rate: N.D. (nBuAc=1)
Melting Point: N.D. VOC (Wt%): <1.5 (Calculated)
Vapor Density (mm Hg): N.D. VOC (LBS/GAL): <0.13 (Calculated)
pH: @20篊 ~2 Solubility in Water: 100%
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID: Avoid elevated temperatures.
INCOMPATIBLE MATERIALS: Strong oxidizing agents, metals, acids, and bases.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can lead to release of irritating
gases and vapors and carbon oxides.
POSSIBILITY OF HAZARDOUS REACTIONS: No data.
SECTION 11 TOXICOLOGICAL INFORMATION
ACUTE ORAL EFFECTS: A dose of 5 ml/kg was given to 5 male and 5 female rats and no mortality
occurred in 14 days. The acute oral LD50 was found to be > 5 ml/kg. The product is not toxic by oral
ingestion in accordance with FHSA / CPSC Guidelines.
SKIN: Not a primary dermal irritant in accordance with FHSA / CPSC Guidelines.
INHALHATION: Not Toxic in accordance with FHSA / CPSC Guidelines.
EYE: Irritant in accordance with FHSA / CPSC Guidelines.
.
Page 3 of 5
MSDS ID: 2003098 03/09
JELMAR
MATERIAL SAFETY DATA SHEET
CLR BATH & KITCHEN CLEANER
ENHANCED FORMULA
SECTION 12- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: No data available.
CHEMICAL FATE INFORMATION: 28-day biodegradation <60%. The matter is biodegradable.
SECTION 13 DISPOSAL CONSIDERATIONS
HAZARDOUS WASTE NUMBER: D002
DISPOSAL METHOD: Dispose of in a permitted hazardous waste management facility following all local,
state, and federal regulations. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND
OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER
SOURCES OF IGNITION. Follow label warnings, since containers may retain some reside of the product.
Processing, use or contamination of this product may change the waste management options. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material
generated to determine the proper waste identification and disposal methods in compliance with applicable
regulations. State and local disposal regulations may differ from federal disposal regulations.
SECTION 14 - TRANSPORTATION INFORMATION
DOT (Department of Transportation Proper Shipping Name): Not regulated by DOT.
Identification Number: N.A.
Packaging Group: N.A.
UN Number: N.A.
TDG Classification: Not Regulated
IMDG Classification: Not Regulated
IATA Classification: Passenger Not Regulated
WHIMS (Canada): This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all the information required by CPR.
SECTION 15 REGULATORY INFORMATION
FEDERAL REGULATIONS:
TSCA INVENTORY STATUS: All components of this product are listed on the TSCA Inventory or are
exempt from TSCA Inventory requirements.
SARA TITTLE III SECTION 311/312 CATEGORY:
IMMEDIATE (ACUTE) HEALTH HAZARARD: YES
DELAYED (CHRONIC) HEALTH HAZARD: YES
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE HAZARD: NO
SARA SECTIONS 302/304/313/HAP:
COMPENT RQ (LBS) RQ (LBS) TPQ (LBS) SEC 313 HAP
(1*) (2*) (3*) (4*) (5*)
Water: N.A. N.A. N.A. NO NO
Lactic Acid: N.A. N.A. N.A. NO NO
Lauryldimethyl Hydroxysultaine: N.A. N.A. N.A. NO NO
Propylene Glycol Normal Butyl Ether: N.A. N.A. N.A. NO NO
Page 4 of 5
MSDS ID: 2003098 03/09
JELMAR
MATERIAL SAFETY DATA SHEET
CLR BATH & KITCHEN CLEANER
ENHANCED FORMULA
____________________________REGULATORY AGENCIES________________________________
*1: CERCLA Reportable Quantity *4: SARA 313 Toxic Chemical / Category
*2: SARA Reportable Quantity *5: U. S. EPA Hazardous Air Pollutant
*3: SARA EHS Threshold Planning Quantity
INTERNATIONAL CHEMICAL INVENTORY STATUS:
EUROPEAN UNION (EINECS) YES
JAPAN (METI) YES
AUSTRALIA (ACIS) NO*
KOREA (KECL) YES
CANADA (DSL) YES
CANADA (NDSL ) NO
PHILIPPINES YES
STATES RIGHT TO KNOW: California, New Jersey, Pennsylvania, Minnesota, Massachusetts, and
Wisconsin. None.
The following statement is made in order to comply with the California State Drinking Water Act. California
Proposition 65: This product does not contain any chemicals known to the State of California to cause
cancer and/or to cause birth defects and other reproductive harm.
SECTION 16 OTHER INFORMATION
NFPA Rating System: Health-1 / Flammability-0 / Reactivity-0 / Special Hazard - None
Precautions to be taken in Handling and Storing: Avoid exposure to excess heat, and prevent from
freezing.
Other Precautions: None required.
MSDS ABBREVIATIONS: N. A.: Not Applicable
N. D.: Not Determined
N.E.: Not Established
C: Ceiling Limit
HAP: Hazardous Air Pollutant
VOC: Volatile Organic Compound
Revision: Section 11 March 2009 R. A. Gaudreault
Although the information and recommendations set forth herein are presented in good faith and believed to be correct
as of the date hereof, JELMAR LLC offers no representations as to the completeness or accuracy thereof.
Information is provided upon the condition that the persons receiving same will make their own determination as to its
suitability for their purposes prior to use. In no event will JELMAR LLCbe responsible for damages of any nature
whatsoever resulting from use of or reliance upon said information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH
RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION HEREIN REFERS.
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