MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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050-002
Product number
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GlemeCleaner
Glass Glass Cleaner
Product name
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29-Jun-2010
Effective date
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Sprayway, Inc.
Claire Manufacturing Co.
Company information
500 Vista Ave.
484
Addison, IL 60101 United States
United States
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General Assistance 630-543-7600
Company phone
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800-424-9300
Emergency telephone US
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703-527-3887
Emergency telephone outside US
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18
Version #
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12-Feb-2010
Supersedes date
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2. Hazards Identification
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Aerosol. CONTENTS UNDER PRESSURE.
Emergency overview
Prolonged exposure may cause chronic effects. May be ignited by heat, sparks or
flames.
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Potential health effects
Skin contact. Ingestion.
Routes of exposure
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Health injuries are not known or expected under normal use.
Eyes
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May be harmful if absorbed through skin. Frequent or prolonged contact may defat and
Skin
dry the skin, leading to discomfort and dermatitis.
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Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
Inhalation
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Exposure by ingestion of an aerosol is unlikely. Components of the product may be
Ingestion
absorbed into the body by ingestion.
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Kidneys.
Target organs
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is
repeated and prolonged and may cause blood damage. These effects have not been
observed in humans.
Blood. Liver.
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Unconsciousness. Cyanosis (blue tissue condition, nails, lips, and/or skin). May be
Chronic effects
harmful if absorbed through skin. Liver injury may occur. Kidney injury may occur.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and
dermatitis.
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Cyanosis (blue tissue condition, nails, lips, and/or skin). Liver enlargement. Jaundice.
Signs and symptoms
Defatting of the skin. Skin irritation.
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3. Composition / Information on Ingredients
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Components CAS # Percent
Ethyl Alcohol 64-17-5 1-3
2-Butoxyethanol 111-76-2 1-3
Propane 74-98-6 1-3
n-Butane 106-97-8 1-3
Non-hazardous and other components below reportable levels > 90
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4. First Aid Measures
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First aid procedures
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
Eye contact
lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation
develops or persists.
Product name: Gleme Glass Cleaner MSDS US
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Product #: 050-002 Cleaner
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Immediately take off all contaminated clothing. Wash off with warm water and soap. Get
Skin contact
medical attention if irritation develops and persists.
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If symptoms develop move victim to fresh air. Get medical attention if symptoms occur.
Inhalation
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If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. If
Ingestion
ingestion of a large amount does occur, call a poison control center immediately.
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5. Fire Fighting Measures
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Heat may cause the containers to explode. Vapor or gas may spread to distant ignition
Flammable properties
sources and flash back. Runoff to sewer may cause fire or explosion hazard.
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Extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Suitable extinguishing media
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Protection of firefighters
In case of fire and/or explosion do not breathe fumes. Containers should be cooled with
Protective equipment and
water to prevent vapor pressure build up. Move containers from fire area if you can do so
precautions for firefighters
without risk. For massive fire in cargo area, use unmanned hose holder or monitor
nozzles, if possible. If not, withdraw and let fire burn out.
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6. Accidental Release Measures
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ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Methods for containment
Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer,
basements or confined areas.
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Should not be released into the environment.
Methods for cleaning up
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface
thoroughly to remove residual contamination.
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7. Handling and Storage
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Pressurized container: Do not pierce or burn, even after use. DO NOT handle, store or
Handling
open near an open flame, sources of heat or sources of ignition. Protect material from
direct sunlight. Do not smoke while using or until sprayed surface is thoroughly dry. Use
only in area provided with appropriate exhaust ventilation. Do not use if spray button is
missing or defective. Do not re-use empty containers. Avoid breathing
dust/fume/gas/mist/vapors/spray. Avoid contact with skin. Avoid contact with eyes. Wear
personal protective equipment. Avoid prolonged exposure.
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Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed
Storage
containers can increase under the influence of heat. Keep away from heat and flame. Do
not expose to heat or store at temperatures above 120癋/49癈 as can may burst. Avoid
exposure to long periods of sunlight. Store in a well-ventilated place. Keep away from
food, drink and animal feedingstuffs. Level 1 Aerosol (NFPA 30B)
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8. Exposure Controls / Personal Protection
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Exposure limits
ACGIH
Components CAS # TWA STEL Ceiling
Ethyl Alcohol 64-17-5 1000 ppm 1000 ppm Not established
2-Butoxyethanol 111-76-2 20 ppm Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
n-Butane 106-97-8 1000 ppm Not established Not established
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OSHA
Components CAS # TWA STEL Ceiling
Ethyl Alcohol 64-17-5 1000 ppm Not established Not established
2-Butoxyethanol 111-76-2 50 ppm Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
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Personal protective equipment
Chemical goggles are recommended.
Eye / face protection
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Wear appropriate chemical resistant clothing. Chemical resistant gloves.
Skin protection
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Product #: 050-002 Cleaner
Glass Revision date: 29-JUN-2010 Print date: 29-JUN-2010
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When workers are facing concentrations above the exposure limit they must use
Respiratory protection
appropriate certified respirators. If permissible levels are exceeded use NIOSH
mechanical filter / organic vapor cartridge or an air-supplied respirator.
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9. Physical & Chemical Properties
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Compressed liquefied gas.
Appearance
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204.8 癋 (96.1 癈) estimated
Boiling point
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Colorless.
Color
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3.2733 kJ/g estimated
Flammability (HOC)
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No
Flash back
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-156 癋 (-104.4 癈) Propellant
Flash point
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Aerosol.
Form
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Butyl
Odor
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9.5 - 10.5
pH
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Liquid.
Physical state
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70 - 90 psig @ 70F
Pressure
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Completely
Solubility
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0.9605 estimated
Specific gravity
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10. Chemical Stability & Reactivity Information
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Heat, flames and sparks.
Conditions to avoid
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None known.
Incompatible materials
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Hazardous decomposition products Irritants. Toxic gas.
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11. Toxicological Information
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Acute LD50: 7571 mg/kg estimated, Rat, Dermal
Acute effects
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Component analysis - LD50
Toxicology Data - Selected LD50s and LC50s
2-Butoxyethanol 111-76-2 Inhalation LC50 Rat 2.21 mg/L 4 h; Inhalation LC50 Rat 450 ppm 4 h; Oral LD50 Rat
470 mg/kg; Dermal LD50 Rat 2270 mg/kg; Dermal LD50 Rabbit 220 mg/kg
Ethyl Alcohol 64-17-5 Oral LD50 Rat 7060 mg/kg
n-Butane 106-97-8 Inhalation LC50 Rat 658 mg/L 4 h
Propane 74-98-6 Inhalation LC50 Rat 658 mg/L 4 h
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Not expected to be hazardous by OSHA criteria.
Sensitization
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Hazardous by OSHA criteria. Cancer hazard. Risk of cancer cannot be excluded with
Carcinogenicity
prolonged exposure.
IARC - Group 1 (Carcinogenic to Humans)
Ethyl Alcohol 64-17-5 Monograph 96 [in preparation] (in alcoholic beverages)
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Hazardous by OSHA criteria. Possible reproductive hazard.
Reproductive effects
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Not expected to be hazardous by OSHA criteria.
Teratogenicity
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12. Ecological Information
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Components of this product have been identified as having potential environmental
Ecotoxicity
concerns.
LC50 36327 mg/L estimated, Fish, 96.00 Hours,
EC50 26428 mg/L estimated, Daphnia, 48.00 Hours,
IC50 11902 mg/L estimated, Algae, 72.00 Hours,
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13. Disposal Considerations
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Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material
Disposal instructions
to drain into sewers/water supplies. This product, in its present state, when discarded or
disposed of, is not a hazardous waste according to Federal regulations (40 CFR 261.4
(b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at
the time of disposal, whether the product meets RCRA criteria for hazardous waste.
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Product #: 050-002 Cleaner
Glass Revision date: 29-JUN-2010 Print date: 29-JUN-2010
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14. Transport Information
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Department of Transportation (DOT) Requirements
Basic shipping requirements:
Consumer commodity
Proper shipping name
ORM-D
Hazard class
None
Subsidiary hazard class
Additional information:
156, 306
Packaging exceptions
156, 306
Packaging non bulk
None
Packaging bulk
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IMDG
Basic shipping requirements:
AEROSOLS
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
5F
Item
None
Labels required
2
Transport Category
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IATA
Basic shipping requirements:
Aerosols, flammable
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
2.1
Labels required
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15. Regulatory Information
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
US federal regulations
Standard, 29 CFR 1910.1200.
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
2-Butoxyethanol 111-76-2 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3,
R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or
less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or
sulfonate, Chemical Category N230)
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
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CERCLA (Superfund) reportable quantity
None
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Immediate Hazard - Yes
Hazard categories (311/312)
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
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Product #: 050-002 Cleaner
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of New and Existing Chemicals (EINECS) No
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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State regulations
U.S. - Pennsylvania - RTK (Right to Know) List
2-Butoxyethanol 111-76-2 Present
Ethyl Alcohol 64-17-5 Present
n-Butane 106-97-8 Present
Propane 74-98-6 Present
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16. Other Information
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HMIS?is a registered trade and service mark of the NPCA.
Further information
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Health: 1
HMIS?ratings
Flammability: 2
Physical hazard: 0
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The information provided in this Safety Data Sheet is correct to the best of our
Disclaimer
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text. The information in the sheet was written based on the best knowledge and
experience currently available.
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Toxicological Information: Reproductivity
MSDS sections updated
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Regulatory Compliance
Prepared by
Product name: Gleme Glass Cleaner MSDS US
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Product #: 050-002 Cleaner
Glass Revision date: 29-JUN-2010 Print date: 29-JUN-2010
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